EP0790873B1 - Tundish impact pad - Google Patents

Tundish impact pad Download PDF

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Publication number
EP0790873B1
EP0790873B1 EP95934731A EP95934731A EP0790873B1 EP 0790873 B1 EP0790873 B1 EP 0790873B1 EP 95934731 A EP95934731 A EP 95934731A EP 95934731 A EP95934731 A EP 95934731A EP 0790873 B1 EP0790873 B1 EP 0790873B1
Authority
EP
European Patent Office
Prior art keywords
impact
tundish
sidewall
pad
opening
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP95934731A
Other languages
German (de)
French (fr)
Other versions
EP0790873A1 (en
Inventor
Donald Richard Zacharias
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foseco International Ltd
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Foseco International Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority claimed from US08/338,123 external-priority patent/US5518153A/en
Priority claimed from GBGB9508070.1A external-priority patent/GB9508070D0/en
Application filed by Foseco International Ltd filed Critical Foseco International Ltd
Publication of EP0790873A1 publication Critical patent/EP0790873A1/en
Application granted granted Critical
Publication of EP0790873B1 publication Critical patent/EP0790873B1/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D41/00Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
    • B22D41/003Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like with impact pads

Definitions

  • This invention relates to a tundish impact pad, i.e. a pad of erosion resistant material positioned on the floor of a tundish to receive the incoming stream of molten metal poured into the tundish from a ladle.
  • U.S. patent 5169591 discloses an impact pad for a tundish for continuous casting of steel that comprises a base, a peripheral top surface and a discontinuous sidewall extending between the base and the peripheral top surface, the sidewall having an undercut inner surface, which may be curvilinear.
  • U.S. patent 4776570 discloses a ladle stream breaker in the form of a closed box into which the ladle stream is directed via a pouring tube.
  • the box has apertured walls through which the stream flows out of the box as a series of sub-streams each flowing perpendicularly to and impinging against a wall of a tundish.
  • the invention provides a tundish impact pad comprising a body of refractory material capable of withstanding contact with molten steel in a tundish; the body comprising a base having an impact surface, an outer sidewall extending upwardly from the impact surface, a top surface connected to the sidewall, an opening being defined in the top surface, which opening provides open access for molten steel to and from the impact surface; the top surface having an inner annular portion substantially parallel to the impact surface, and the sidewall having a continuous interior face which is substantially perpendicular to the impact surface and wherein a substantially right angle corner is provided between the sidewall and the impact surface and a substantially right angle corner is provided between the sidewall and the top surface inner annular portion.
  • Molten steel entering through the opening and contacting the impact surface flows outwardly then is turned inwardly by the sidewall interior face and then flows out of the opening.
  • the sidewall is endless, i.e. it extends continuously around the impact surface.
  • the opening is non-uniform in that it has a long dimension and a short dimension perpendicular to the long dimension.
  • the opening may be, for example, rectangular or oval.
  • the top outer surface of the pad may conveniently also be parallel to the impact surface.
  • the impact pads of the present invention uniformly disperse the flow of incoming steel rather than merely redirecting it.
  • the invention is particularly useful in providing improved residence time distribution parameters in the poured molten steel. It can also be of reduced cost due to its simplified internal chamber shapes and may be of reduced overall size relative to known impact pads.
  • the impact pads according to the present invention are formed of a refractory composition which is capable of withstanding continuous contact with molten metal, in particular, molten steel such as used in continuous casting operations.
  • molten metal in particular, molten steel
  • a standard medium-to-high alumina monolithic refractory with an alumina content in the range of about 55 to 85% by weight is desirable.
  • a basic refractory is preferred because of steel chemistry, it is preferred that a magnesia based monolithic refractory be utilised, with MgO in the range of about 58 to 93% by weight.
  • the invention provides a tundish for holding a volume of molten steel and having a floor and side walls enclosing a region of impact and a drain, an impact pad of the present invention being provided on the floor of the tundish in the region of impact.
  • the sidewall 28, with impact surface 24 and underside portion 42 of top surface 32 provides two sharp corners 28A and 28B respectively, which corners also extend continuously around the inside of the impact pad.
  • the impact pad 20 be rectangular in shape, as illustrated in Figures 1 through 4, other non-uniform configurations can also be provided.
  • an oval impact pad may be utilised, or another type of multi-sided polygon configuration, as long as there is an opening with a long dimension which is aligned with the long dimension of the tundish 10 and a short dimension aligned with the short dimension of the tundish 10.

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  • Mechanical Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Casting Support Devices, Ladles, And Melt Control Thereby (AREA)
  • Laminated Bodies (AREA)
  • Vehicle Step Arrangements And Article Storage (AREA)
  • Cold Cathode And The Manufacture (AREA)
  • Excavating Of Shafts Or Tunnels (AREA)
  • Silicon Polymers (AREA)
  • Fluid-Damping Devices (AREA)
  • Investigating Strength Of Materials By Application Of Mechanical Stress (AREA)
  • Refuge Islands, Traffic Blockers, Or Guard Fence (AREA)
  • Molds, Cores, And Manufacturing Methods Thereof (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)
  • Ultra Sonic Daignosis Equipment (AREA)
  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
  • Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
  • Details Of Garments (AREA)
  • Ceramic Products (AREA)

Abstract

A tundish impact pad (20) to reduce turbulence in the tundish comprises a body of refractory material capable of withstanding contact with molten steel in a tundish (10), the body comprising a base (22) having an impact surface (24), an outer sidewall (26, 40) extending upwardly from the impact surface (24), a top surface (32) connected to the sidewall (26, 40) and defining an opening (30) therein, in which the top surface (32) has an inner annular portion (42) substantially parallel to the impact surface (24), and the sidewall (26, 40) has an interior face (28) which is substantially perpendicular to the impact surface (24) and wherein a substantially right angle corner (28A) is provided between the sidewall (28) and the impact surface (24) and a substantially right angle corner is provided between the sidewall (28) and the top surface inner annular portion (42).

Description

This invention relates to a tundish impact pad, i.e. a pad of erosion resistant material positioned on the floor of a tundish to receive the incoming stream of molten metal poured into the tundish from a ladle.
U.S. patent 5169591 discloses an impact pad for a tundish for continuous casting of steel that comprises a base, a peripheral top surface and a discontinuous sidewall extending between the base and the peripheral top surface, the sidewall having an undercut inner surface, which may be curvilinear.
U.S. patent 5358551 discloses an impact pad which comprises a base, a sidewall extending around the base, the sidewall having an inner surface having a portion which extends inwardly and upwardly. That inner surface may be concave.
U.S. patent 4776570 discloses a ladle stream breaker in the form of a closed box into which the ladle stream is directed via a pouring tube. The box has apertured walls through which the stream flows out of the box as a series of sub-streams each flowing perpendicularly to and impinging against a wall of a tundish.
Whereas the aforesaid devices are designed to reduce turbulence in the tundish, we have surprisingly found that improved turbulence reduction can be achieved by providing an impact pad with internal corners defined between its base, its peripheral wall and its upper surface. Thus, we have now found that it can be advantageous to provide such internal corners and that improvements in the reduction of surface turbulence, minimisation of slag entrainment, prevention of break-up of tundish flux cover, reoxidation of the molten steel and ensuring a proper flow path of the steel within the tundish, may be achieved.
Accordingly, in one aspect, the invention provides a tundish impact pad comprising a body of refractory material capable of withstanding contact with molten steel in a tundish; the body comprising a base having an impact surface, an outer sidewall extending upwardly from the impact surface, a top surface connected to the sidewall, an opening being defined in the top surface, which opening provides open access for molten steel to and from the impact surface; the top surface having an inner annular portion substantially parallel to the impact surface, and the sidewall having a continuous interior face which is substantially perpendicular to the impact surface and wherein a substantially right angle corner is provided between the sidewall and the impact surface and a substantially right angle corner is provided between the sidewall and the top surface inner annular portion.
Molten steel entering through the opening and contacting the impact surface flows outwardly then is turned inwardly by the sidewall interior face and then flows out of the opening.
Preferably, the sidewall is endless, i.e. it extends continuously around the impact surface.
Preferably, the opening is non-uniform in that it has a long dimension and a short dimension perpendicular to the long dimension. Thus, it may be, for example, rectangular or oval.
The top outer surface of the pad may conveniently also be parallel to the impact surface.
The impact pads of the present invention uniformly disperse the flow of incoming steel rather than merely redirecting it.
Since the steel flow can be dispersed over a larger area than if a circular or other uniform configuration were used, the result is more uniformly surface directed flow while maintaining the benefits of reduced splash and turbulence. Also due to the non-uniform configuration of the impact pad it presents a larger "target" to the incoming steel than a similar width uniform shaped pad (e.g. circular or square), with the desired results obtained even if the steel stream is imperfectly aligned with the centre of the impact pad.
The invention is particularly useful in providing improved residence time distribution parameters in the poured molten steel. It can also be of reduced cost due to its simplified internal chamber shapes and may be of reduced overall size relative to known impact pads.
The impact pads according to the present invention are formed of a refractory composition which is capable of withstanding continuous contact with molten metal, in particular, molten steel such as used in continuous casting operations. Usually a standard medium-to-high alumina monolithic refractory, with an alumina content in the range of about 55 to 85% by weight is desirable. Where a basic refractory is preferred because of steel chemistry, it is preferred that a magnesia based monolithic refractory be utilised, with MgO in the range of about 58 to 93% by weight.
In another aspect the invention provides a tundish for holding a volume of molten steel and having a floor and side walls enclosing a region of impact and a drain, an impact pad of the present invention being provided on the floor of the tundish in the region of impact.
Embodiments of the invention will now be described by way of example only with reference to the accompanying drawings in which:
  • Figure 1 is a side cross-sectional view of a tundish including an impact pad of the invention disposed on the floor of the tundish;
  • Figure 2 is a top plan view of the impact pad of Figure 1, which illustrates where the cross-section of Figure 1 is taken (along line I to I);
  • Figure 3 is a cross-section along line III to III of Figure 2; and
  • Figure 4 is an enlarged sectional view of a portion of the impact pad of Figure 3.
  • In Figure 1, a conventional tundish 10 is shown and includes an inner lining 12 and a pair of well blocks or outlets 14 to allow molten metal (typically steel) from a bath 16 contained in the tundish 10 to continuously exit the tundish 10 and enter moulds (not shown) which form metal castings. As is also conventional, a ladle shroud 18 or like tundish filling device, is positioned above the tundish 10 and continuously directs a stream of molten metal into the tundish 10. A tundish impact pad 20 constructed according to the present invention is placed generally centrally on the floor 15 of the tundish 10.
    As seen in Figures 1 to 4, the tundish impact pad 20 is preferably rectangular in shape and is positioned with its longer sides parallel to the longitudinal axis of the tundish. The pad includes a base 22 having a planar, horizontal, impact surface 24. The pad 20 further includes an endless, annular outer sidewall 26, 40 having an inner wall face surface 28. The impact pad 20 also has a top surface 32 parallel to the impact surface 24 and connected to the sidewall 26, 40 and defining a non-uniform opening 30 therein. By "non-uniform" it is meant that the opening 30 is not circular or square; rather it has a long dimension 30' (see Figure 2) and a short dimension 30'' substantially perpendicular to the long dimension 30'.
    As seen in all of Figures 1 through 4, the interior face 28 of the sidewall extends upwardly substantially at right angles to the impact surface 24 around the entire periphery thereof. The continuous nature of the inner surface 28 is perhaps seen most clearly in Figure 2, being shown in dotted line therein.
    As shown in Figures 3 and 4, the sidewall 28, with impact surface 24 and underside portion 42 of top surface 32, provides two sharp corners 28A and 28B respectively, which corners also extend continuously around the inside of the impact pad.
    As seen in Figure 1, the outer sidewall 26 may be tapered inwardly from the top surface 32 toward the base 22, defining ears 27 at opposite ends. The ears 27 facilitate connection of the impact pad 20 to the base or floor 15 of the tundish when certain types of tundishes are utilised. Alternatively, the impact pad 20 may merely be mounted in a conventional manner on the bottom of the tundish.
    It is also noted that the bottom portion of the top surface 32 has annular portions 39, 42 (see Figure 3) thereof, which lie parallel to the impact surface 24. This annular, overhang surface 42 facilitates proper directing of the molten steel during filling of the tundish 10. Note that the long dimension 30' of the opening 30 is positioned aligned with the long dimension of the tundish (the dimension between the outlets 14, as seen in Figure 1), whereas the short dimension 30'' of the opening 30 is aligned with the short dimension of the tundish 10.
    The outer sidewall portions 40, rather than being tapered inwardly like the sidewall portions 26, preferably taper very slightly (e.g. 2 to 5°) outwardly, as seen in Figure 3. Alternatively, straight sides may be provided for both walls 26, 40 and straight sidewalls 26 may or may not contain ears 27.
    The refractory material of which the impact pad 20 is made must be capable of withstanding continuous contact with molten steel during the entire use cycle of the tundish 10. It must have adequate refractoriness normally available from a standard medium-to-high alumina monolithic refractory. For example, an alumina content in the range of about 55 to 85% may be utilised. Where a basic refractory is preferred because of the steel chemistry, typically an MgO-based monolithic refractory, with MgO in the range of about 58 to 93% is preferred.
    While it is preferred that the impact pad 20 be rectangular in shape, as illustrated in Figures 1 through 4, other non-uniform configurations can also be provided. For example, an oval impact pad may be utilised, or another type of multi-sided polygon configuration, as long as there is an opening with a long dimension which is aligned with the long dimension of the tundish 10 and a short dimension aligned with the short dimension of the tundish 10.
    In use of the tundish pad 20 illustrated in Figure 1, molten steel flowing in the path 34 from a location disposed above the pad 20 strikes the impact surface 24 and then moves radially outwardly as illustrated by arrows 35. When the steel impacts the inner face 28 of the sidewall, it is directed inwardly then upwardly, flowing as illustrated at 36 in Figure 1 and ultimately being dispersed generally radially outwardly as indicated by arrows 37, 38 in Figure 1. This minimises turbulence on the surface of the bath 16 and helps direct slag and other impurities away from the stream 34.
    It is not essential that the corners shown in dotted line in plan in Figure 2 be radiused as shown and the corners may, if desired, be right-angled.
    If desired, small corner fillets may be present in the right-angle corners between the sidewall and the impact surface and/or the top surface inner annular portion.

    Claims (9)

    1. A tundish impact pad (20) comprising a body of refractory material capable of withstanding contact with molten steel in a tundish (10), the body comprising a base (22) having an impact surface (24), an outer sidewall (26, 40) extending upwardly from the impact surface (24), a top surface (32) connected to the sidewall (26, 40), an opening (30) being defined in the top surface, which opening provides open access for molten steel to and from the impact surface (24), the top surface (32) having an inner annular portion (42) substantially parallel to the impact surface (24), and the sidewall (26, 40) having a continuous interior face (28) which is substantially perpendicular to the impact surface (24) and wherein a substantially right angle corner (28A) is provided between the sidewall (28) and the impact surface (24) and a substantially right angle corner (28B) is provided between the sidewall (28) and the top surface inner annular portion (42).
    2. A tundish impact pad according to Claim 1, wherein the opening (30) has a long dimension (30') and a short dimension (30'') perpendicular to the long dimension.
    3. A tundish impact pad according to Claim 2, wherein the opening (30) is rectangular or oval.
    4. A tundish impact pad according to Claim 1, 2, or 3, wherein the top outer surface (32) of the pad is parallel to the impact surface (24).
    5. A tundish impact pad according to any preceding claim, whereinthe sidewall (26.40) is endless.
    6. A tundish impact pad according to any preceding claim, wherein the pad (20) is a monolithic refractory having an alumina content of from 55% to 85% by weight.
    7. A tundish impact pad according to any one of Claims 1 to 5, wherein the pad (20) is a monolithic refractory comprising magnesia and containing from 58% to 93% by weight of magnesia.
    8. A tundish (10) for holding a volume of molten steel (16) and having a floor (15) and sidewalls (12) enclosing a region of impact and a drain (14), wherein the tundish (10) contains an impact pad (20) as claimed in any preceding claim on the floor (15) in the region of impact.
    9. A tundish according to Claim 8, wherein the impact pad (20) has an opening (30) to receive a stream of molten metal, the opening (30) having a long dimension (30') and a short dimension (30'') perpendicular to the long dimension (30') and the long dimension (30') of the opening (30) is aligned with the long dimension of the tundish.
    EP95934731A 1994-11-09 1995-10-24 Tundish impact pad Expired - Lifetime EP0790873B1 (en)

    Applications Claiming Priority (5)

    Application Number Priority Date Filing Date Title
    US338123 1994-11-09
    US08/338,123 US5518153A (en) 1994-11-09 1994-11-09 Tundish impact pad
    GB9508070 1995-04-20
    GBGB9508070.1A GB9508070D0 (en) 1995-04-20 1995-04-20 Tundish impact pad
    PCT/GB1995/002505 WO1996014951A1 (en) 1994-11-09 1995-10-24 Tundish impact pad

    Publications (2)

    Publication Number Publication Date
    EP0790873A1 EP0790873A1 (en) 1997-08-27
    EP0790873B1 true EP0790873B1 (en) 1998-06-03

    Family

    ID=26306906

    Family Applications (1)

    Application Number Title Priority Date Filing Date
    EP95934731A Expired - Lifetime EP0790873B1 (en) 1994-11-09 1995-10-24 Tundish impact pad

    Country Status (14)

    Country Link
    EP (1) EP0790873B1 (en)
    JP (1) JP4007429B2 (en)
    CN (1) CN1069243C (en)
    AT (1) ATE166814T1 (en)
    AU (1) AU692622B2 (en)
    BR (1) BR9509706A (en)
    CA (1) CA2162551C (en)
    DE (1) DE69502838T2 (en)
    DK (1) DK0790873T3 (en)
    ES (1) ES2104525T3 (en)
    FI (1) FI110312B (en)
    TR (1) TR199501393A2 (en)
    TW (1) TW321615B (en)
    WO (1) WO1996014951A1 (en)

    Cited By (5)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    DE10143396C1 (en) * 2001-09-04 2002-11-28 Rhi Ag Wien Baffle pot used for casting molten metal comprises a base and a peripheral wall which delimits a chamber and a feed opening for a molten metal lying opposite the base
    WO2004014585A1 (en) * 2002-08-05 2004-02-19 Refractory Intellectual Property Gmbh & Co. Kg Fire resistant ceramic part
    DE10257395A1 (en) * 2002-12-06 2004-06-24 Weerulin Feuerfeste Produkte Gmbh & Co. Kg Tundish fabricated of incombustible material has perforated steel cover protecting surrounding holding vessel from the impact of incoming molten metal
    DE102007035452A1 (en) 2007-07-26 2009-01-29 Pa-Ha-Ge Feuerfeste Erzeugnisse Gmbh & Co. Kg impact absorber
    EP2193861A1 (en) 2008-12-02 2010-06-09 Foseco International Limited Tundish Impact pad.

    Families Citing this family (11)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    FR2756761B1 (en) * 1996-12-11 1999-01-08 Ugine Savoie Sa SUPPLY TANK INTENDED TO RETAIN MELTED METAL AND IN PARTICULAR STEEL
    GB9816458D0 (en) * 1998-07-29 1998-09-23 Foseco Int Tundish impact pad
    GB9903937D0 (en) * 1999-02-22 1999-04-14 Foseco Int Tundish impact pad
    GB9913241D0 (en) * 1999-06-08 1999-08-04 Foseco Int Impact pad for tundish
    ES1048253Y (en) * 2001-02-14 2002-05-01 Refractaria S A IMPACT BLOCK FOR CONTINUOUS COLADA.
    ZA200206261B (en) * 2002-03-28 2003-04-07 Foseco Int Metallurgical impact pad.
    EP2537609A1 (en) * 2011-06-23 2012-12-26 Calderys Ukraine Ltd. Metal-flow impact pad and diffuser for tundish
    JP5751078B2 (en) * 2011-08-04 2015-07-22 Jfeスチール株式会社 Manufacturing method of high cleanliness steel slab by continuous casting
    CN103273027B (en) * 2013-05-20 2015-08-12 江苏永钢集团有限公司 A kind of Tundish rotational flow type turbulence controller
    EP2865464B1 (en) * 2013-10-22 2016-03-16 Refractory Intellectual Property GmbH & Co. KG Fireproof ceramic impact pad
    CN110814330A (en) * 2019-12-25 2020-02-21 武汉科技大学 Top rotating type turbulence controller for continuous casting tundish

    Family Cites Families (4)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    US4776570A (en) * 1987-07-08 1988-10-11 Sidbec Dosco Inc. Ladle stream breaker
    US5169591A (en) * 1992-02-07 1992-12-08 Bethlehem Steel Corporation Impact pad for a continuous caster tundish
    CN2204668Y (en) * 1993-08-21 1995-08-09 鞍山钢铁学院 Impact-proof cushion for ingot underpan
    US5358551A (en) * 1993-11-16 1994-10-25 Ccpi, Inc. Turbulence inhibiting tundish and impact pad and method of using

    Cited By (9)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    DE10143396C1 (en) * 2001-09-04 2002-11-28 Rhi Ag Wien Baffle pot used for casting molten metal comprises a base and a peripheral wall which delimits a chamber and a feed opening for a molten metal lying opposite the base
    WO2004014585A1 (en) * 2002-08-05 2004-02-19 Refractory Intellectual Property Gmbh & Co. Kg Fire resistant ceramic part
    DE10235867B3 (en) * 2002-08-05 2004-04-08 Refractory Intellectual Property Gmbh & Co.Kg Refractory ceramic component
    US7128247B2 (en) 2002-08-05 2006-10-31 Refractory Intellectual Property Gmbh & Co. Kg Fire resistant ceramic part
    DE10257395A1 (en) * 2002-12-06 2004-06-24 Weerulin Feuerfeste Produkte Gmbh & Co. Kg Tundish fabricated of incombustible material has perforated steel cover protecting surrounding holding vessel from the impact of incoming molten metal
    DE102007035452A1 (en) 2007-07-26 2009-01-29 Pa-Ha-Ge Feuerfeste Erzeugnisse Gmbh & Co. Kg impact absorber
    DE102007035452B4 (en) * 2007-07-26 2013-02-21 Pa-Ha-Ge Feuerfeste Erzeugnisse Gmbh & Co. Kg impact absorber
    EP2193861A1 (en) 2008-12-02 2010-06-09 Foseco International Limited Tundish Impact pad.
    US8746516B2 (en) 2008-12-02 2014-06-10 Vesuvius Crucible Company Tundish impact pad

    Also Published As

    Publication number Publication date
    MX9703352A (en) 1997-09-30
    TW321615B (en) 1997-12-01
    JP4007429B2 (en) 2007-11-14
    DK0790873T3 (en) 1999-02-15
    DE69502838T2 (en) 1999-03-18
    JP2000505728A (en) 2000-05-16
    CA2162551A1 (en) 1996-05-10
    FI971968A (en) 1997-05-07
    AU692622B2 (en) 1998-06-11
    FI110312B (en) 2002-12-31
    CN1171752A (en) 1998-01-28
    AU3704395A (en) 1996-06-06
    BR9509706A (en) 1997-10-28
    CA2162551C (en) 2000-08-01
    ES2104525T3 (en) 1998-09-16
    CN1069243C (en) 2001-08-08
    WO1996014951A1 (en) 1996-05-23
    TR199501393A2 (en) 1996-07-21
    FI971968A0 (en) 1997-05-07
    DE69502838D1 (en) 1998-07-09
    ATE166814T1 (en) 1998-06-15
    ES2104525T1 (en) 1997-10-16
    EP0790873A1 (en) 1997-08-27

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