EP0780460A1 - Benzinzusatzkonzentrat - Google Patents
Benzinzusatzkonzentrat Download PDFInfo
- Publication number
- EP0780460A1 EP0780460A1 EP96309357A EP96309357A EP0780460A1 EP 0780460 A1 EP0780460 A1 EP 0780460A1 EP 96309357 A EP96309357 A EP 96309357A EP 96309357 A EP96309357 A EP 96309357A EP 0780460 A1 EP0780460 A1 EP 0780460A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alcohol
- amine
- concentrate
- fatty acids
- lubricity additive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012141 concentrate Substances 0.000 title claims abstract description 22
- 239000003254 gasoline additive Substances 0.000 title abstract description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000000203 mixture Substances 0.000 claims abstract description 23
- 150000001412 amines Chemical class 0.000 claims abstract description 22
- 150000002148 esters Chemical class 0.000 claims abstract description 14
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 10
- 239000000194 fatty acid Substances 0.000 claims abstract description 10
- 229930195729 fatty acid Natural products 0.000 claims abstract description 10
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 10
- 239000007788 liquid Substances 0.000 claims abstract description 8
- 239000000654 additive Substances 0.000 claims description 28
- 230000000996 additive effect Effects 0.000 claims description 23
- 239000003849 aromatic solvent Substances 0.000 claims description 11
- 239000002904 solvent Substances 0.000 claims description 10
- 229920006395 saturated elastomer Polymers 0.000 claims description 8
- 150000004671 saturated fatty acids Chemical class 0.000 claims description 8
- 235000003441 saturated fatty acids Nutrition 0.000 claims description 8
- 235000021122 unsaturated fatty acids Nutrition 0.000 claims description 8
- 150000004670 unsaturated fatty acids Chemical class 0.000 claims description 8
- -1 C75 amine Chemical class 0.000 claims description 4
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 230000001050 lubricating effect Effects 0.000 claims 1
- 125000004433 nitrogen atom Chemical group N* 0.000 claims 1
- 239000002253 acid Substances 0.000 description 9
- 125000003118 aryl group Chemical group 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 5
- 239000012530 fluid Substances 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 239000003112 inhibitor Substances 0.000 description 4
- 239000003599 detergent Substances 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical compound CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 235000006708 antioxidants Nutrition 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 239000002816 fuel additive Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- 239000003784 tall oil Substances 0.000 description 2
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 235000009470 Theobroma cacao Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000005233 alkylalcohol group Chemical group 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 244000240602 cacao Species 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- XXUJMEYKYHETBZ-UHFFFAOYSA-N ethyl 4-nitrophenyl ethylphosphonate Chemical compound CCOP(=O)(CC)OC1=CC=C([N+]([O-])=O)C=C1 XXUJMEYKYHETBZ-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- 239000012855 volatile organic compound Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/08—Use of additives to fuels or fires for particular purposes for improving lubricity; for reducing wear
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/143—Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/16—Hydrocarbons
- C10L1/1608—Well defined compounds, e.g. hexane, benzene
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/16—Hydrocarbons
- C10L1/1616—Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
- C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/188—Carboxylic acids; metal salts thereof
- C10L1/1881—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/188—Carboxylic acids; metal salts thereof
- C10L1/1881—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
- C10L1/1883—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom polycarboxylic acid
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/188—Carboxylic acids; metal salts thereof
- C10L1/1888—Carboxylic acids; metal salts thereof tall oil
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
- C10L1/1905—Esters ester radical containing compounds; ester ethers; carbonic acid esters of di- or polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
- C10L1/2225—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates hydroxy containing
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/234—Macromolecular compounds
- C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/234—Macromolecular compounds
- C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C10L1/2383—Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)
Definitions
- the present invention relates to a gasoline additive concentrate containing solubilizers to maintain the concentrate in the liquid state at low temperatures.
- U.S. Patent 4,617,026 is directed to a method for reducing the fuel consumption in an automotive internal combustion engine by employing a gasoline fuel containing an effective fuel consumption reducing amount of an additive which is a hydroxyl-containing ester of a monocarboxylic acid and a glycol or trihydric alcohol, said ester additive having at least one free hydroxyl group.
- an additive which is a hydroxyl-containing ester of a monocarboxylic acid and a glycol or trihydric alcohol, said ester additive having at least one free hydroxyl group.
- U.S. Patent 5,279,626 is directed to a fuel additive concentrate having an enhanced shelf life, the concentrate comprising a major amount of detergent/dispersant, a minor amount of demulsifier and an amount of solvent stabilizer sufficient to enhance the shelf life of the fuel additive package.
- the solvent stabilizer is formed from at least one aromatic hydrocarbon solvent and at least one alkyl or cycle alkyl alcohol wherein the solvent stabilizer composition contains more than 50 wt% aromatic hydrocarbon solvent and 10 to less than 50 wt% alcohol.
- the demulsifiers include organic sulfonates, polyoxyalkylene glycols, oxyalkylated phenolic resins and the like.
- Corrosion inhibitors include dimers and trimer acids such as those produced from tall oil fatty acids, oleic acid, linoleic acid, and the like.
- gasolines are additized by injecting a homogeneous, low viscosity and liquid additive concentrate into the gasoline while it is being loaded into trucks at the terminal rack.
- additives are diluted in ' an aromatic solvent (e.g., xylene, aromatic 100, heavy aromatic naphtha) to produce a homogeneous, low viscosity fluid which is suitable for rack injection.
- aromatic solvent e.g., xylene, aromatic 100, heavy aromatic naphtha
- additive solution must be fluid, homogenous and low viscosity under all atmospheric conditions encountered at such outdoor truck loading facilities.
- additives such as Tolad 9103 (a mixture of polymerized fatty acids, non-polymerized fatty acids and heavy aromatic naphtha, commercially available from Petrolite Corp.) is not suitable for additization under low temperature. It turns solid by 0°F within one day.
- fatty acids, oligomers of such acids and the esters of such acids useful as anti friction and wear reducing additives in gasoline and diesel fuels are formulated into an additive concentrate which remains liquid at low temperatures of about 0°F and lower by the additional presence in the concentrate of an alcohol, an amine or a mixture of alcohol and amine.
- the fatty acids and their esters are typically derived from naturally occurring fats and oils and includes those known as tall oil acids and their esters.
- the concentrate comprises fatty acids, oligomers of fatty acids, their esters and mixtures thereof in an aromatic solvent diluent and further a C 2 to C 10 alcohol, preferably a C 2 to C 8 alcohol, most preferably ethanol, which remains liquid at temperatures of at least as low as 0°C (32°F), a C 12 to C 75 amine having at least one nitrogen, preferably a C 12 to C 18 amine and which has a glass transition temperature or is liquid at temperatures of at least as low as 0°C (32°F), and mixtures of such alcohols and amines.
- a C 2 to C 10 alcohol preferably a C 2 to C 8 alcohol, most preferably ethanol
- the concentrate comprises a lubricity additive selected from the group consisting of saturated or unsaturated fatty acids, oligomerized saturated or unsaturated fatty acids, primarily dimerized and trimerized acids, their esters and mixtures thereof, preferably the acid(s), in an aromatic solvent, preferably an aromatic solvent of 8 to 14 carbons, the acid(s), ester(s) or mixture thereof being present in the solvent in an amount of about 85 wt% or less, preferably about 50 wt% or less, more preferably 30 wt% or less, and a compatibilizer selected from the group consisting of an alcohol, an amine or a mixture thereof wherein, the alcohol or amine, preferably alcohol, used individually is present in an amount of at least about 30 wt% preferably about 35 wt%, more preferably about 40 wt% most preferably about 50 wt% based on the acid(s), ester(s) or mixture thereof, preferably when the lubricity additive component concentration in the diluent is about 50
- the concentration of amine plus alcohol compatibilizer should be about 3 parts or more compatibilizer to 25 parts lubricity additive.
- the additive concentrate may, of course, contain other typical components such as detergents, carrier fluids, octane boosters, antioxidants, metal corrosion inhibitor (especially copper corrosion inhibitors), and the like.
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Lubricants (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US577658 | 1984-02-07 | ||
US57765895A | 1995-12-22 | 1995-12-22 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0780460A1 true EP0780460A1 (de) | 1997-06-25 |
EP0780460B1 EP0780460B1 (de) | 2001-06-27 |
Family
ID=24309630
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96309357A Revoked EP0780460B1 (de) | 1995-12-22 | 1996-12-20 | Benzinzusatzkonzentrat |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0780460B1 (de) |
AT (1) | ATE202595T1 (de) |
DE (1) | DE69613549T2 (de) |
NO (1) | NO315126B1 (de) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0869163A1 (de) * | 1997-04-03 | 1998-10-07 | Mobil Oil Corporation | Verfahren zur Motorreibungsherabsetzung |
WO1999036489A1 (en) * | 1998-01-13 | 1999-07-22 | Baker Hughes Incorporated | Composition and method to improve lubricity in fuels |
US6203584B1 (en) | 1998-03-31 | 2001-03-20 | Chevron Chemical Company Llc | Fuel composition containing an amine compound and an ester |
WO2001038461A1 (en) * | 1999-11-23 | 2001-05-31 | The Associated Octel Company Limited | Composition |
WO2001051592A1 (en) * | 2000-01-14 | 2001-07-19 | Exxonmobil Research And Engineering Company | Gasoline composition |
EP1209215A2 (de) * | 2000-11-24 | 2002-05-29 | Clariant GmbH | Brennstofföle mit verbesserter Schmierwirkung, enthaltend Mischungen aus Festtsäuren mit Paraffindispergatoren, sowie ein schmierverbesserndes Additiv |
WO2002055636A1 (en) * | 2001-01-12 | 2002-07-18 | Exxonmobil Research And Engineering Company | Gasoline composition |
WO2010136436A1 (en) * | 2009-05-25 | 2010-12-02 | Shell Internationale Research Maatschappij B.V. | Gasoline compositions |
US8518129B2 (en) | 2009-05-25 | 2013-08-27 | Shell Oil Company | Gasoline compositions |
US9163196B2 (en) | 2009-11-30 | 2015-10-20 | The Lubrizol Corporation | Stabilized blends containing friction modifiers |
WO2017144378A1 (de) | 2016-02-23 | 2017-08-31 | Basf Se | HYDROPHOBE POLYCARBONSÄUREN ALS REIBVERSCHLEIß-VERMINDERNDER ZUSATZ ZU KRAFTSTOFFEN |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102004038113A1 (de) | 2004-08-05 | 2006-03-16 | Basf Ag | Stickstoffhaltige heterocyclische Verbindungen als Reibverschleißvermindernder Zusatz zu Kraftstoffen |
Citations (10)
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FR1399466A (fr) * | 1963-06-26 | 1965-05-14 | Exxon Research Engineering Co | Procédé pour améliorer l'onctuosité de liquides oléophiles et additifs utilisés dans ce procédé |
US4451265A (en) * | 1981-04-21 | 1984-05-29 | The United States Of America As Represented By The Secretary Of Agriculture | Diesel fuel-aqueous alcohol microemulsions |
US4565547A (en) * | 1983-07-12 | 1986-01-21 | Toyoto Jidosha Kabushiki Kaisha | Detergent composition for fuel-system parts |
US4617026A (en) | 1983-03-28 | 1986-10-14 | Exxon Research And Engineering Company | Method for improving the fuel economy of an internal combustion engine using fuel having hydroxyl-containing ester additive |
US4797134A (en) * | 1987-08-27 | 1989-01-10 | Wynn Oil Company | Additive composition, for gasoline |
EP0482253A1 (de) * | 1990-10-23 | 1992-04-29 | Ethyl Petroleum Additives Limited | Umweltfreundliche Kraftstoffzusammensetzungen und Zusätze dafür |
US5279626A (en) | 1992-06-02 | 1994-01-18 | Ethyl Petroleum Additives Inc. | Enhanced fuel additive concentrate |
DE4225951A1 (de) * | 1992-08-06 | 1994-02-10 | Leuna Werke Ag | Additive zur Verbesserung der Tieftemperatureigenschaften von Mitteldestillaten |
WO1995002654A1 (en) * | 1993-07-16 | 1995-01-26 | Victorian Chemical International Pty Ltd | Fuel blends |
WO1995003377A1 (en) * | 1993-07-22 | 1995-02-02 | Exxon Chemical Patents Inc. | Additives and fuel compositions |
-
1996
- 1996-12-20 DE DE69613549T patent/DE69613549T2/de not_active Expired - Fee Related
- 1996-12-20 AT AT96309357T patent/ATE202595T1/de not_active IP Right Cessation
- 1996-12-20 EP EP96309357A patent/EP0780460B1/de not_active Revoked
-
1997
- 1997-03-03 NO NO19970968A patent/NO315126B1/no not_active IP Right Cessation
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
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FR1399466A (fr) * | 1963-06-26 | 1965-05-14 | Exxon Research Engineering Co | Procédé pour améliorer l'onctuosité de liquides oléophiles et additifs utilisés dans ce procédé |
US4451265A (en) * | 1981-04-21 | 1984-05-29 | The United States Of America As Represented By The Secretary Of Agriculture | Diesel fuel-aqueous alcohol microemulsions |
US4617026A (en) | 1983-03-28 | 1986-10-14 | Exxon Research And Engineering Company | Method for improving the fuel economy of an internal combustion engine using fuel having hydroxyl-containing ester additive |
US4565547A (en) * | 1983-07-12 | 1986-01-21 | Toyoto Jidosha Kabushiki Kaisha | Detergent composition for fuel-system parts |
US4797134A (en) * | 1987-08-27 | 1989-01-10 | Wynn Oil Company | Additive composition, for gasoline |
EP0482253A1 (de) * | 1990-10-23 | 1992-04-29 | Ethyl Petroleum Additives Limited | Umweltfreundliche Kraftstoffzusammensetzungen und Zusätze dafür |
US5279626A (en) | 1992-06-02 | 1994-01-18 | Ethyl Petroleum Additives Inc. | Enhanced fuel additive concentrate |
DE4225951A1 (de) * | 1992-08-06 | 1994-02-10 | Leuna Werke Ag | Additive zur Verbesserung der Tieftemperatureigenschaften von Mitteldestillaten |
WO1995002654A1 (en) * | 1993-07-16 | 1995-01-26 | Victorian Chemical International Pty Ltd | Fuel blends |
WO1995003377A1 (en) * | 1993-07-22 | 1995-02-02 | Exxon Chemical Patents Inc. | Additives and fuel compositions |
Cited By (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0869163A1 (de) * | 1997-04-03 | 1998-10-07 | Mobil Oil Corporation | Verfahren zur Motorreibungsherabsetzung |
WO1999036489A1 (en) * | 1998-01-13 | 1999-07-22 | Baker Hughes Incorporated | Composition and method to improve lubricity in fuels |
US6129772A (en) * | 1998-01-13 | 2000-10-10 | Baker Hughes Incorporated | Composition and method to improve lubricity in fuels |
US6203584B1 (en) | 1998-03-31 | 2001-03-20 | Chevron Chemical Company Llc | Fuel composition containing an amine compound and an ester |
WO2001038461A1 (en) * | 1999-11-23 | 2001-05-31 | The Associated Octel Company Limited | Composition |
WO2001051592A1 (en) * | 2000-01-14 | 2001-07-19 | Exxonmobil Research And Engineering Company | Gasoline composition |
EP1803791A2 (de) * | 2000-11-24 | 2007-07-04 | Clariant Produkte (Deutschland) GmbH | Brennstofföle mit verbesserter Schmierwirkung, enthaltend Mischungen aus Fettsäuren mit Paraffindispergatoren, sowie ein schmierverbesserndes Additiv |
USRE40758E1 (en) | 2000-11-24 | 2009-06-23 | Clariant Produkte (Deutschland) Gmbh | Fuel oils having improved lubricity comprising mixtures of fatty acids with paraffin dispersants, and a lubrication-improving additive |
EP1209215A3 (de) * | 2000-11-24 | 2003-08-13 | Clariant GmbH | Brennstofföle mit verbesserter Schmierwirkung, enthaltend Mischungen aus Festtsäuren mit Paraffindispergatoren, sowie ein schmierverbesserndes Additiv |
EP1801188A2 (de) * | 2000-11-24 | 2007-06-27 | Clariant Produkte (Deutschland) GmbH | Brennstofföle mit verbesserter Schmierwirkung, enthaltend Mischungen aus Fettsäuren mit Paraffindispergatoren, sowie ein schmierverbesserndes Additiv |
EP1209215A2 (de) * | 2000-11-24 | 2002-05-29 | Clariant GmbH | Brennstofföle mit verbesserter Schmierwirkung, enthaltend Mischungen aus Festtsäuren mit Paraffindispergatoren, sowie ein schmierverbesserndes Additiv |
EP1803791A3 (de) * | 2000-11-24 | 2007-10-03 | Clariant Produkte (Deutschland) GmbH | Brennstofföle mit verbesserter Schmierwirkung, enthaltend Mischungen aus Fettsäuren mit Paraffindispergatoren, sowie ein schmierverbesserndes Additiv |
EP1801188A3 (de) * | 2000-11-24 | 2007-10-03 | Clariant Produkte (Deutschland) GmbH | Brennstofföle mit verbesserter Schmierwirkung, enthaltend Mischungen aus Fettsäuren mit Paraffindispergatoren, sowie ein schmierverbesserndes Additiv |
WO2002055636A1 (en) * | 2001-01-12 | 2002-07-18 | Exxonmobil Research And Engineering Company | Gasoline composition |
WO2010136436A1 (en) * | 2009-05-25 | 2010-12-02 | Shell Internationale Research Maatschappij B.V. | Gasoline compositions |
US8518129B2 (en) | 2009-05-25 | 2013-08-27 | Shell Oil Company | Gasoline compositions |
US8741002B2 (en) | 2009-05-25 | 2014-06-03 | Shell Oil Company | Gasoline compositions |
US9163196B2 (en) | 2009-11-30 | 2015-10-20 | The Lubrizol Corporation | Stabilized blends containing friction modifiers |
US9175241B2 (en) | 2009-11-30 | 2015-11-03 | The Lubrizol Corporation | Stabilized blends containing friction modifiers |
US9193934B2 (en) | 2009-11-30 | 2015-11-24 | The Lubrizol Corporation | Stabilized blends containing friction modifiers |
US10190071B2 (en) | 2009-11-30 | 2019-01-29 | The Lubrizol Corporation | Stabilized blends containing friction modifiers |
WO2017144378A1 (de) | 2016-02-23 | 2017-08-31 | Basf Se | HYDROPHOBE POLYCARBONSÄUREN ALS REIBVERSCHLEIß-VERMINDERNDER ZUSATZ ZU KRAFTSTOFFEN |
Also Published As
Publication number | Publication date |
---|---|
ATE202595T1 (de) | 2001-07-15 |
NO970968L (no) | 1998-09-04 |
EP0780460B1 (de) | 2001-06-27 |
NO970968D0 (no) | 1997-03-03 |
DE69613549T2 (de) | 2001-10-25 |
DE69613549D1 (de) | 2001-08-02 |
NO315126B1 (no) | 2003-07-14 |
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