Classifications

• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
  • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
  • C09C1/02—Compounds of alkaline earth metals or magnesium
  • C09C1/021—Calcium carbonates
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
  • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
  • C09C1/0081—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
  • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
  • C09C1/40—Compounds of aluminium
  • C09C1/42—Clays

Definitions

• the present invention relates to a method for manufacturing of a filler material from a sludge containing organic mate ⁇ rial material and calcium carbonate and/or kaolin.
• filler is meant a finely divided solid to be added to a liquid, semisolid, or solid composition, e.g. paint, paper, plastics or elastomers, to modify the properties of the composition, its colour and reduce its costs.
• PCC Precipitated Calcium Carbonate
• PCC is often used together with another filler, viz. kaolin ((A1 2 0 3 ) (Si0 2 ) 2 (H 2 0) 2 ).
• the kaolin lends gloss to the paper, whereas the PCC gives the paper its bright white colour, and makes it soft and susceptible to ink and printing ink.
• the use of PCC in paper ranges between 5 and 40 per cent by weight, depending on the quality which is desired.
• paper sludge is produced as a by-product, its main ingredients being cellulose fibres, printing ink and colour, water and a mineral residue of paper fillers, which mainly consist of PCC and/or kaolin.
• an environmentally acceptable method is thus indicated for treatment and reuse of paper sludge where the paper fibres are used as fuel and where it is possible to avoid the problems as e.g. malodors and emis ⁇ sion of gaseous compounds which can arise in connection with the known methods of reuse and disposing.
• the paper sludge is transformed into a product which can replace the materials which are normally utilized as fillers e.g. in paper, in plastic or rubber or is used for coating materials for paper or as pigment for paper, plastics or rubber.
• a recirculation loop is closed: instead of consuming expensive raw materials such as e.g. GCC (Ground Calcium Carbonate), PCC and kaolin, paper sludge is the primary raw material for the fillers.
• this is achieved by a method of the kind mentioned in the introduction, where the paper sludge is introduced into a stream of hot exit gas from a burning chamber and passed together with the exit gas to a drying and comminuting apparatus wherefrom the dry and finely divided paper material is directed, suspended in the exit gas, to a separator in which the paper material is separated from the exit gas.
• the paper material is subsequently fired into the burning chamber and the organic content of the material is incinerated subject to development of heat, and in the burning chamber the mineral residue is calcined for a suitable period of time at a controlled temperature, and finally the heat-treated material is cooled with air.
• the obtained product can now in accordance with known techniques be subjected to slaking, filtration and subsequent carbonization, thereby generating a product which can contain precipitated CaC0 3 , a larger or smaller amount of kaolin and smaller amounts of titanium dioxide, silicium dioxide and/or other mineral compounds in dependence of the ratio between the mineral compounds in the paper sludge contained in the source material.
• Fig.l shows a first embodiment of a plant for carrying out the method according to the invention
• Fig. 2 shows a second embodiment of such a plant
• Fig. 3 shows a third embodiment.
• the plant shown in Fig. 1 comprises a drying and comminut ⁇ ing apparatus in the form of a drier crusher 1 which, through a duct 11, is supplied partly with hot exit gas from the calciner 7 and partly with paper sludge, preferab ⁇ ly mechanically dehydrated paper sludge, from a store 2.
• the dried and finely divided paper material is conveyed, suspended in the drying gas, via a duct 3 and by means of the fan 13 to a separation cyclone 4 in which the paper material is separated from the exit gas and directed to an intermediate vessel 5.
• the paper material is extracted from • the intermediate vessel 5, for example by means of a screw conveyor, and it is fired into the plant's burning chamber, the calciner 7 via a burner 6, possibly in conjunction with oil or gas or some other back-up fuel.
• Hot combustion air is supplied to the calciner from the cyclone cooler 9, causing the organic content of the paper material to be incinerated subject to development of heat.
• the mineral residue normally consist ⁇ ing mainly of CaC0 3 and kaolin will, depending on the chosen temperature, become more or less calcined, i.e. with expulsion of C0 2 from the lime and H 2 0 from the kaolin.
• the temperature in the calciner will depend of the mineral composition of the paper sludge, expulsion of H 2 0 from the kaolin begins at 400°C and expulsion of C0 2 from the CaC0 3 may typically vary between 800 and 1000°C, which is suffi- cient for eliminating any toxic and/or malodorous compounds in the paper sludge.
• the heat-treated material is carried, suspended in the combustion gases, to the separation cyclone 8, in which it is separated from the gas and directed to the cyclone cooler 9. In this cooler it is cooled in counterflow with fresh air from the fresh-air intake 10, while the air is simultaneously heated, and the finished product is extracted at the bottom of the cyclone cooler 9 at the outlet 16.
• the drying gas in this plant can contain at least measurable concentrations of malodorous gases.
• the majority of such gases which may have been developed during the drying process in the drier crusher is reabsorbed on the dried paper during the transport in the duct 3, and thus passes down through the intermediate vessel 5 down in the calciner for destruction.
• the residual, nonabsorbed fraction of gases entrained in the stream 12 exiting the separation cyclone 4 must be removed from the drying gas prior to its release into the atmosphere. This may be accomplished by means of suitable exit gas cleaning equipment 15, for example a filter which contains cartridges of activated carbon or another suitable absorbent.
• the exit gas Before the exit gas is vented to any such filter, it must, however, be cleaned of dust in a dust collector 14, and cooling of the exit gas, for example by air entrainment, may be required.
• the dust from the filter 14 may be supplied to the intermediate vessel 5, wherefrom it will be passed on to the calciner. It is a foregone conclusion that the cartridges in the filter 15, when at the end of their useful life and no longer capable of further absorption, can be disposed of by a method where they are pulverized and introduced into the calciner.
• exit gas cleaning equipment 15 it will also be possible to use a scrubber in which the exit gas is washed with a suitable fluid.
• the objective is to avoid usage of the exit gas cleaning equipment 15 for the drying gas, while still permitting the exit gas from the plant to be vented to the environment without any emissions of organic compounds.
• the plant comprises, as is the case in Figure 1, a drying and comminuting device in the form of a drier crusher 1. Through the duct 11 the drier crusher 1 is fed with hot exit gas from the calciner 7 as well as paper sludge from the store 2.
• the plant incorporates a cyclone preheater 20, to which some of the exit gas from the separation cyclone 8 is supplied, whereas the rest of the exit gas is passed to the drier crusher 1.
• a pulverulent material, which is introduced at 21, is preheated in the cyclone preheater.
• This material may constitute a part of the plant product, which is recirculated from the outlet 16 of the cyclone cooler, or it may be ground limestone or kaolin, in case it is desirable to produce more filler than can be obtained from the paper sludge.
• the preheated powder is fed to the calciner via the duct 22, whereafter it is mixed in the calciner with the dried paper material from the vessel 5 and it is subjected to the same heat treatment as the mineral-containing residue of the paper material.
• the exit gas from the separation cyclone 4 of the drier crusher which may contain organic compounds, is now passed, subsequent to dedusting in a filter 14, to the cyclone cooler 9.
• Figure 3 it is shown how the manufac ⁇ ture of filler may be combined with an existing lime kiln plant which incorporates a rotary kiln 30 with a preheater 31 to which the limestone is supplied at 32, and a dust collector 34. From the rotary kiln 30 an exit gas stream is extracted to the drier crusher 1, and the dried and finely divided paper sludge is collected via a duct 3 and a sepa ⁇ ration cyclone 4 in the intermediate vessel 5. From here it is extracted and introduced through the main burner 33 of the rotary kiln into the burning zone 35 of the lime kiln.
• the mineral residue falls down on the limestone, and is carried by the movement of the rotary kiln under the flame together with the original raw material for calcination, and after cooling in a planetary cooler 37 the blended product 36 is extracted.
• the drying gas from the drier crusher 1 is conveyed by means of a fan 13 through the duct 3, the separation cyclone 4 and one more duct 12 to the planetary cooler 37 or more simply forward to the rotary kiln burner so that it can enter the burning zone for destruction.
• the rotary kiln solution involves that the mineral residue is nodulized into balls, and, therefore, pulverization must be introduced in the subsequent treatment.
• this may consist of dry slaking, and may involve that the dry product from the slaking machine is conveyed to a separator for classification into a fine and a coarse frac ⁇ tion, and that the coarse fraction is passed to a ball mill for grinding, and that it is subsequently returned to the separator as fine material.
• the fine material thus derived that mainly consists of lime hydrate and pulverized kaolin is now stirred in water, to which C0 2 is added, and the precipitated product of PCC, kaolin and smaller amounts of other fillers is separated by filtration and constitutes the finished product which can be utilized as filler in paper, plastic or rubber manufacturing processes.

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• Chemical & Material Sciences (AREA)
• Organic Chemistry (AREA)
• Dispersion Chemistry (AREA)
• Composite Materials (AREA)
• Treatment Of Sludge (AREA)
• Paper (AREA)

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• 1995
  • 1995-01-02 WO PCT/DK1995/000001 patent/WO1995018885A1/en not_active Application Discontinuation
  • 1995-01-02 AU AU13109/95A patent/AU1310995A/en not_active Abandoned
  • 1995-01-02 EP EP95904408A patent/EP0738346A1/de not_active Withdrawn

Non-Patent Citations (1)

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