EP0738205B1 - Agents de demoulage pour liants hydrauliques - Google Patents

Agents de demoulage pour liants hydrauliques Download PDF

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Publication number
EP0738205B1
EP0738205B1 EP95905599A EP95905599A EP0738205B1 EP 0738205 B1 EP0738205 B1 EP 0738205B1 EP 95905599 A EP95905599 A EP 95905599A EP 95905599 A EP95905599 A EP 95905599A EP 0738205 B1 EP0738205 B1 EP 0738205B1
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EP
European Patent Office
Prior art keywords
release agent
carbon atoms
weight
water
emulsifiers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP95905599A
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German (de)
English (en)
Other versions
EP0738205A1 (fr
Inventor
Leonhard Wittich
Stephan Heck
Lothar Friesenhagen
Günther DEMMERING
Horst-Dieter Komp
Michael KÖHLER
Ingo Wegener
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
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Publication date
Priority claimed from DE4400272A external-priority patent/DE4400272A1/de
Priority claimed from DE4418807A external-priority patent/DE4418807A1/de
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP0738205A1 publication Critical patent/EP0738205A1/fr
Application granted granted Critical
Publication of EP0738205B1 publication Critical patent/EP0738205B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B7/00—Moulds; Cores; Mandrels
    • B28B7/38—Treating surfaces of moulds, cores, or mandrels to prevent sticking
    • B28B7/384—Treating agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
    • C10M105/10—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M105/12—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms monohydroxy
    • C—CHEMISTRY; METALLURGY
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    • C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
    • C10M125/24—Compounds containing phosphorus, arsenic or antimony
    • C—CHEMISTRY; METALLURGY
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    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/04—Hydroxy compounds
    • C10M129/06—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
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    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/04—Hydroxy compounds
    • C10M129/06—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M129/08—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least 2 hydroxy groups
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    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/16—Ethers
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    • C10M129/52—Carboxylic acids; Salts thereof having carboxyl groups bound to a carbon atom of a six-membered aromatic ring polycarboxylic
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    • C10M129/68—Esters
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    • C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
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    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
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    • C10N2040/42—Flashing oils or marking oils
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    • C10N2070/00—Specific manufacturing methods for lubricant compositions
    • C10N2070/02—Concentrating of additives

Definitions

  • Additives e.g. Anti-rust agents, antioxidants, Antipore agents, preservatives, wetting agents and Adhesives as release agents for hydraulic binders be used.
  • the rust inhibitor can be used in the water-free release agent for hydraulic binders, provided they are soluble in it. It is also possible to use the anti-rust agent in that for emulsifying the release agents for hydraulic binders required water or after Add emulsification to the finished emulsion.
  • Emulsion concentrate :
  • Anti-rust agent E.g Anti-rust agent a Tri-sodium phosphate, Na 3 PO 4 b N- (2-aminoethyl) ethanolamine c Texamin R KE 3160 d Texamin R KE 3161
  • Texamin R KE 3161 is a rust inhibitor from Henkel, which is a mixture of fatty acid monoethanolamide, alkanolamines and short-chain fatty acids.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Ceramic Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Moulds, Cores, Or Mandrels (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Lubricants (AREA)
  • Polishing Bodies And Polishing Tools (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Claims (14)

  1. Agent de démoulage pour liants hydrauliques,
    contenant
    a) un composant alcool monofonctionnel non miscible à l'eau, liquide à des températures de 5 à 15°C, du groupe des alcools gras insaturés ayant de 12 à 22 atomes de carbone ainsi que des indices d'iode compris entre 40 et 170
       et/ou des alcools de Guerbet ayant de 16 à 28 atomes de carbone
       et/ou des oxo-alcools ayant de 8 à 15 atomes de carbone
       et/ou des alcools saturés ayant de 6 à 10 atomes de carbone,
    b) si on le désire d'autres composés organiques non miscibles à l'eau, a) et b) formant le composant huileux,
    c) si on le désire, d'autres additifs habituels dans les agents de démoulage pour liants hydrauliques,
    d) de l'eau, caractérisée en ce qu'elle contient
    e) de 0,5 à 5 % en poids d'un émulsifiant - par rapport au composant huileux.
  2. Concentré pour la fabrication d'un agent de démoulage selon la revendication 1,
    constitué de
    a) au moins 68 % en poids d'un composant alcool monofonctionnel non miscible à l'eau, liquide à des températures de 5 à 15°C, du groupe des alcools gras insaturés ayant de 12 à 22 atomes de carbone, ainsi qu'ayant des indices d'iode compris entre 40 et 170 et/ou des alcools de Guerbet ayant de 16 à 28 atomes de carbone et/ou des oxo-alcools ayant de 8 à 15 atomes de carbone et/ou des alcools saturés ayant de 6 à 10 atomes de carbone,
    b) jusqu'à 15 % en poids d'autres composés organiques non miscibles à l'eau, a) et b) formant le composant huileux,
    c) de 0,5 à 5 % en poids d'un émulsifiant,
    d) jusqu'à 15 % en poids d'autres additifs habituels dans les agents de démoulage hydrauliques, la somme de a) + b) + c) + d) étant égale à 100 % en poids.
  3. Agent de démoulage selon la revendication 1,
    caractérisé en ce que
    le liant hydraulique est du béton.
  4. Agent de démoulage selon les revendications 1 et 3,
    caractérisé en ce qu'
    il se compose de
    15-55 % en poids d'une phase organique faite d'un composant huileux, d'additifs et d'émulsifiants, et
    85-45 % en poids d'eau.
  5. Agent de démoulage selon les revendications 1 à 4,
    caractérisé en ce que
    le composant alcool monofonctionnel, non miscible à l'eau, liquide à des températures de 5 à 15°C, est constitué d'alcools gras insaturés ayant principalement de 16 à 18 atomes de carbone ainsi que des indices d'iode compris entre 70 et 100.
  6. Agent de démoulage selon les revendications 1 à 5,
    caractérisé en ce que
    les émulsifiants sont contenus à des quantités de 0,5 à 3 % en poids - par rapport au composant huileux constitué de composants alcools et d'autres composés organiques non miscibles à l'eau.
  7. Agent de démoulage selon les revendications 1 à 6,
    caractérisé en ce que
    les émulsifiants sont des savons d'acides gras saturés ou insaturés ayant de 12 à 22 atomes de carbone.
  8. Agent de démoulage selon les revendications 1 à 7,
    caractérisé en ce que
    les émulsifiants sont des émulsifiants non ioniques.
  9. Agent de démoulage selon les revendications 1 à 8,
    caractérisé en ce que
    les mélanges d'émulsifiants sont des mélanges d'émulsifiants.
  10. Agent de démoulage selon les revendications 1 à 9,
    caractérisé en ce que
    les additifs sont des agents antirouille, des antioxydants, des agents anti-porosité, des agents de conservation, des colloïdes protecteurs, des stabilisateurs, des agents mouillants, des anti-mousses et des colles.
  11. Agent de démoulage selon les revendications 1 à 10,
    caractérisé en ce que
    les agents antirouille sont des composés du groupe des amines, alcanolamines, sels d'acide gras, sels d'esters d'acide phosphorique acides, sels d'acide phosphorique et amides d'acides gras.
  12. Agent de démoulage selon les revendications 1 à 11,
    caractérisé en ce que
    les agents antirouille sont présents à des quantités allant de 0,01 à 2 % en poids, de préférence de 0,1 à 1 % en poids - par rapport à l'ensemble de l'agent sans eau.
  13. Agent de démoulage selon les revendications 1 à 12,
    caractérisé en ce que
    les autres composés organiques non miscibles à l'eau sont des esters d'acide gras, des esters gras, des triglycérides et/ou une huile minérale.
  14. Utilisation des agents de démoulage selon les revendications 1 à 13 pour le traitement des matériaux de coffrage dans la construction en béton.
EP95905599A 1994-01-10 1994-12-27 Agents de demoulage pour liants hydrauliques Expired - Lifetime EP0738205B1 (fr)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
DE4400272 1994-01-10
DE4400272A DE4400272A1 (de) 1994-01-10 1994-01-10 Betontrennmittel
DE4418807A DE4418807A1 (de) 1994-05-30 1994-05-30 Betontrennmittel mit verbessertem Korrosionsschutz
DE4418807 1994-05-30
PCT/EP1994/004324 WO1995018704A1 (fr) 1994-01-10 1994-12-27 Agents de demoulage pour liants hydrauliques

Publications (2)

Publication Number Publication Date
EP0738205A1 EP0738205A1 (fr) 1996-10-23
EP0738205B1 true EP0738205B1 (fr) 1998-03-11

Family

ID=25932887

Family Applications (1)

Application Number Title Priority Date Filing Date
EP95905599A Expired - Lifetime EP0738205B1 (fr) 1994-01-10 1994-12-27 Agents de demoulage pour liants hydrauliques

Country Status (10)

Country Link
US (1) US5709739A (fr)
EP (1) EP0738205B1 (fr)
JP (1) JPH09507181A (fr)
AT (1) ATE163879T1 (fr)
CA (1) CA2180866A1 (fr)
DE (1) DE59405440D1 (fr)
DK (1) DK0738205T3 (fr)
ES (1) ES2113183T3 (fr)
GR (1) GR3026394T3 (fr)
WO (1) WO1995018704A1 (fr)

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DE19637841A1 (de) 1996-09-17 1998-03-26 Henkel Kgaa Wäßrige Betontrennmittel
JP4216371B2 (ja) * 1998-06-23 2009-01-28 Ｂａｓｆポゾリス株式会社 セメント組成物用防錆剤
US6435760B1 (en) * 1999-10-12 2002-08-20 Universal Valve Co., Inc. Quick re-install bumper guard system and method
CA2371096C (fr) * 2001-02-07 2006-10-31 The Hill And Griffith Company Composes antiadherents pour coffrage a beton
US6960367B2 (en) * 2001-02-07 2005-11-01 The Hill And Griffith Company Sandcasting pattern coating compositions
US6620230B1 (en) 2001-02-12 2003-09-16 Franklynn Industries, Inc. Mold release composition
DE102006049523A1 (de) * 2006-10-20 2008-04-24 Cognis Ip Management Gmbh Additivzubereitungen für Betontrennmittel
FR2909918B1 (fr) * 2006-12-18 2013-10-11 Lafarge Sa Composition de demoulage pour materiaux a prise hydraulique
DE102007039274A1 (de) 2007-08-20 2009-02-26 Breitenbach, Ralf H. von, Dipl.-Ing. Verfahren zur oberflächenschonenden Sanierung von Mauerwerk
CA2645238C (fr) * 2007-12-18 2013-08-06 Gordon Davies Formules et methodes applicables aux agents anticollants
US20100308506A1 (en) * 2009-06-04 2010-12-09 Dayton Superior Corporation Form Release Composition and Method
FR2969599B1 (fr) * 2010-12-23 2013-05-10 Francais Ciments Additif anti-mousse hydrosoluble pour composition cimentaire, solution aqueuse le contenant et leur utilisation dans des mortiers ou betons
RU2466181C2 (ru) * 2011-01-21 2012-11-10 Открытое акционерное общество "Ангарский завод катализаторов и органического синтеза" (ОАО "АЗКиОС") Эмульсол для смазки металлических форм при изготовлении бетонных и железобетонных изделий
ES2623159T3 (es) 2011-12-01 2017-07-10 Gcp Applied Technologies Inc. Composición y procedimiento para la obtención de agregados expuestos en superficies de hormigón moldeado y otros materiales cementosos
EP3130653B1 (fr) * 2015-08-13 2018-11-21 Fuchs Petrolub SE Composition destinee a la lubrification a quantites minimales et son utilisation
US20180237712A1 (en) * 2015-08-13 2018-08-23 Fuchs Petrolub Se Composition for Minimum Quantity Lubrication, and Use of Same
CN105296122B (zh) * 2015-11-20 2018-11-02 科之杰新材料集团有限公司 一种混凝土脱模剂及其制备方法
US10495235B1 (en) 2017-10-10 2019-12-03 Waskey Bridges, Inc. Cryogenic trench/trough apparatus and method
US10487510B1 (en) * 2017-10-10 2019-11-26 Waskey Bridges, Inc. Cryogenic trench/trough apparatus and method
WO2020059885A1 (fr) * 2018-09-20 2020-03-26 バイオ燃料技研工業株式会社 Procédé et système de purification de glycérine, procédé de production d'agent de décapage et procédé de décapage
US11542700B1 (en) 2019-06-19 2023-01-03 Waskey Bridges, Inc. Cryogenic trench/trough apparatus and method
CN115161101A (zh) * 2022-02-22 2022-10-11 马鞍山中集瑞江润滑油有限公司 一种光亮水泥制品脱模剂

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ATE158222T1 (de) * 1992-03-20 1997-10-15 Unichema Chemie Bv Formtrennzusammensetzung

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ATE163879T1 (de) 1998-03-15
ES2113183T3 (es) 1998-04-16
JPH09507181A (ja) 1997-07-22
EP0738205A1 (fr) 1996-10-23
WO1995018704A1 (fr) 1995-07-13
DK0738205T3 (da) 1999-01-04
CA2180866A1 (fr) 1995-07-13
DE59405440D1 (de) 1998-04-16
GR3026394T3 (en) 1998-06-30
US5709739A (en) 1998-01-20

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