EP0702115B1 - Plaque de plâtre avec feuille en fibre de verre revêtu - Google Patents

Plaque de plâtre avec feuille en fibre de verre revêtu Download PDF

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Publication number
EP0702115B1
EP0702115B1 EP95114350A EP95114350A EP0702115B1 EP 0702115 B1 EP0702115 B1 EP 0702115B1 EP 95114350 A EP95114350 A EP 95114350A EP 95114350 A EP95114350 A EP 95114350A EP 0702115 B1 EP0702115 B1 EP 0702115B1
Authority
EP
European Patent Office
Prior art keywords
coating
calcium sulphate
plasterboard
coating mass
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP95114350A
Other languages
German (de)
English (en)
Other versions
EP0702115A1 (fr
Inventor
Jürgen MARTIN
Lothar Dr. Dipl. Chem. Scheller
Gerhard Dr. Dipl. Chem. Neuhauser
Hans-Ulrich Dr. Dipl.Chem. Hummel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Knauf Gips KG
Original Assignee
Gebr Knauf Westdeutsche Gipswerke
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19527857A external-priority patent/DE19527857C2/de
Application filed by Gebr Knauf Westdeutsche Gipswerke filed Critical Gebr Knauf Westdeutsche Gipswerke
Publication of EP0702115A1 publication Critical patent/EP0702115A1/fr
Application granted granted Critical
Publication of EP0702115B1 publication Critical patent/EP0702115B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/02Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
    • E04C2/04Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of concrete or other stone-like material; of asbestos cement; of cement and other mineral fibres
    • E04C2/043Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of concrete or other stone-like material; of asbestos cement; of cement and other mineral fibres of plaster

Definitions

  • the invention relates to a plasterboard with coated Glass fleece layer, with at least one side of a plate core is covered with the glass fleece layer, the plate core Apply a calcium sulfate coating on the opposite side is, in the core mass forms the plate core and on the one hand penetrated into the glass fleece layer and coating compound forms the calcium sulfate coating and on the other hand has penetrated into the glass fleece layer where the coating mass is formed on the basis of a calcium sulfate and contains organic binder and in which the core mass is formed from calcium sulfate dihydrate, the calcium sulfate coating including glass fleece layer on the plate core at any point across the plate level with a right angle lifting strength measured at the plate level is and the plasterboard in the shortly after the state of manufacture is present.
  • the plasterboard is in an unprocessed condition and the A certain setting behavior can be assigned to coating compound.
  • a plasterboard of this type is essentially known (DE-OS 39 37 433). As is usual with plasterboard, this is Core mass formed on the basis of calcium sulfate dihydrate.
  • the coating composition consists of an at least partially inorganic binder set with water, under other from plaster. About setting degree or setting speed nothing is said about the mixture. Additions to the setting the setting speed of the plaster are not intended.
  • the plasterboard at issue here has the Advantage that a subsequent filling of the surface is eliminated and this surface is coated directly with emulsion paint, Wallpaper, tiles or mats can be covered.
  • the plasterboard is made by first laying a glass fleece sheet unilaterally with a set mixture from a inorganic binders, e.g.
  • Calcium sulfate hemihydrate and Water coated after partial setting and drying the coating rolled up and then with the uncoated Side with a pasty mixture that can be set a mixture based on calcium sulfate hemihydrate and water is brought into contact so that it Mixture only partially penetrates into the glass fleece while doing so after the plaster has set one with a coated Glass fleece-laminated plasterboard is created.
  • the coating composition sets quickly. No information is given on the extent of the at least partially existing binding. It is also not specified that the core composition and the coating composition have contact with one another in the glass fleece layer. If a gypsum building board of the type mentioned at the outset is to be useful in practice, then the quality of the bond from the calcium sulfate coating to the board core is important. The quality of this composite can be described by the lifting strength, which indicates the force / area with which a measuring disc adhered to the coating is pulled until the composite is destroyed. According to experiments with the known plasterboard of the type mentioned, a lifting strength of 0.1 N / mm 2 is not sufficient for the practical use of the plasterboard.
  • Delaminations or internal splitting can occur in the glass fleece layer, which is a considerable disadvantage particularly when applying heavy coatings such as heavy paper or textile wallpapers or ceramic tiles.
  • To remedy this disadvantage there is no other option than to fill the surface with a suitable filler in a thin consistency so that it penetrates deeply into the fleece, thus strengthening the surface and improving the bond to the gypsum core. This means an additional cost-intensive operation on the construction site.
  • the coating causes glass fiber abrasion on the outer surface the plasterboard prevented. If the plasterboard is cut or drilled, but then occurs on the Processing points fiberglass abrasion in a considerable Scope on.
  • a non-woven area in which the non-woven fibers are not enveloped by mass is not enveloped by mass.
  • the coating compound relatively brittle and brittle, which can sometimes already on the wound rolls of the coated Fleece shows that when processing, i.e. when drilling and Saws, glass fibers from the fleece, initially from coating material are enveloped, released. At the processing points Glass fiber abrasion therefore occurs disadvantageously.
  • the gypsum building board according to the invention solves this problem, characterized in that the calcium sulfate of the coating composition is not or almost not set and that the core composition is brought into contact with the coating composition almost continuously so that the lifting strength is at least 0.15 N / mm 2 is.
  • the coating mass is tough and strong and does not release glass fibers. Because the core mass almost in contact with the coating compound brought, there are no more non-woven fibers that are not are enveloped by mass.
  • the practically fiberglass-free The new plasterboard also makes the surface for the Suitable for ventilation ducts and cable ducts. The extent of penetration of the glass fleece layer with Core mass or the application of core mass to coating mass can by the improved lifting resistance specify at every point of the calcium sulfate coating.
  • the plasterboard according to the invention has excellent Coating properties, so that even heavy Coating materials such as Wallpaper, tiles or Mats, a firm and permanent bond with the plate come in without first filling or any other elaborate treatment of the surface would be required.
  • the bond quality is particularly increased in that the Calcium sulfate of the coating composition as a nucleating agent for the Gypsum formation of the core mass is used. This creates the Connection point between core mass and coating directional growth of a plaster layer, which extremely improves adhesion works (epitaxy).
  • the slow setting speed is within the scope of the invention usually given when the coating material is on the start of stiffening according to DIN 1168 is at least 1.5 hours and a maximum of 6 hours. Especially It is expedient and advantageous if the stiffening begins the coating mass at least 2.5 hours and / or is a maximum of 5 hours. Proven in this setting time range the invention is particularly good in practice.
  • the calcium sulfate of the gypsum board not yet processed is not or almost not set; the Degree of rehydration of the coating mass is ⁇ 5%, i.e. that a maximum of 5% of what was initially planned when switching on Calcium sulfate converted to calcium sulfate dihydrate to have. As a rule, however, the calcium sulfate is the coating material up to a maximum degree of rehydration 2% not tied.
  • each other the core mass and the coating mass in the glass fleece layer almost continuous.
  • the interface between the core mass area and the coating mass area is partially formed from nonwoven fibers, so that in this Area of contact between the core mass and coating mass cannot take place.
  • the Gypsum body of the core through the usual addition of air entraining agents and by evaporating the excess Mixing water is porous during drying. To that extent it doesn't help the degree of touch between Core mass and coating mass by proportions of one Separation area between core mass area and coating mass area specify. The extent of the touch is therefore described by its resistance to lifting.
  • the core mass is brought into contact with the coating mass in such a way that the internal strength of the system, expressed by the lifting strength, is at least 0.15 N / mm 2 at every point. It is particularly expedient and advantageous if there is an average lifting strength of at least 0.20 N / mm 2 .
  • the plate according to the invention proves particularly well in practice at this limit value of the lifting resistance.
  • the coating composition Calcium sulfate is hemihydrate and additives contains a slow setting speed of the calcium sulfate hemihydrate cause.
  • calcium sulfate hemihydrate is achieved by the additions that the coating mass of the gypsum building board not or almost is not set.
  • the calcium sulfate hemihydrate is more effective Stucco.
  • additives in the form of retarders include e.g. Citric acid and protein hydrolyzates.
  • the coating composition when switching on, regardless of what is added Water has the following composition: 60-95 % By weight stucco, 0.01-1% by weight cellulose ether, 0.03-0.5 % By weight retarder, 0.05-1.0% by weight of condenser.
  • the coating composition up to 25% by weight limestone powder and up to 5% by weight PVAC dispersion contains. With such a coating compound the fleece fibers in the plate are particularly well held and the glass fiber abrasion resistance is particularly good.
  • the Limestone flour is a filler.
  • the condenser is e.g. Lignin sulfonate, a naphthalene sulfonic acid condensation product or a melamine resin.
  • the Coating composition contains a plasticizer.
  • the plasticizer is only in small quantities, e.g. maximum 5% by weight available and e.g. a polyacrylate or a styrene / butadiene.
  • the plasticizer makes the coating compound plastic and flexible, which is their ability to make the fibers permanent and firm to envelop, improved.
  • the calcium sulfate is a calcium sulfate anhydrite which is fine-grained with a grain size of ⁇ 200 ⁇ m , preferably ⁇ 63 ⁇ m and is partially capable of setting.
  • this special anhydrite can be provided as a plaster coating on the glass fleece layer.
  • This anhydrite has an advantageous ability to penetrate the fleece surface and forms an optimal bond with the binder and fleece.
  • the anhydrite preferably has a grain size average d 50 between 8 and 12 ⁇ m .
  • the coating mass when starting, regardless of added water has the following composition: At least 94% by weight calcium sulfate anhydrite, 0.01-0.8 % By weight cellulose ether, 0.01-1.0% by weight plasticizer and maximum 0.2% wetting agent.
  • the organic binder which in the present case in the Coating mass is provided, e.g. Polyacrylate or Styrene acrylate.
  • Organic binders deteriorate in the Rule the fire behavior and increase the toxicity of the resulting Smoke gases in the event of a fire.
  • Plasterboard can contain the binder proportion relatively be kept low. Particularly useful and advantageous so it is when the organic binder is less than 6% by weight of the dry coating composition.
  • the calcium sulfate that has not set or has not set, but is still reactive the coating composition thus enables a reduction the proportion of organic binder.
  • the coating composition up to 40% by weight aluminum hydroxide or boric acid admitted. This ensures that the Plasterboard meets the criteria for building material class A1 according to DIN 4102 fulfilled.
  • the abrasion resistance is determined on the basis of this to DIN 53109, "Testing of paper and cardboard: determination of abrasion using the friction wheel method "and ISO 4586-2 "Abration resistance of decorative laminated sheets.”
  • abrasion device is used by the Teldyne Taber Standard Abrasion Tester.
  • the standardized emery paper S-33 is placed on the friction wheels upset.
  • Each friction wheel comes with an additional weight loaded by 500 g.
  • the friction wheels are left during the test with the emery paper S-33 for 10 turns on the Act on the surface of the plate. After that the abrasion is through Determination of the weight difference determined.
  • plasterboard according to the invention Another advantage of the plasterboard according to the invention is that the resistance to lifting off after further surface treatment (primer, paint, wallpaper or plaster) is increased.
  • Plates of a manufacture according to the invention have an average lifting strength of 0.34 N / mm 2 after production, the minimum value from six measurements across the plate width being 0.23 N / mm 2 .
  • Part of the boards is painted with an aqueous dispersion primer, the other part is coated with a thin plaster based on gypsum.
  • the average lifting strength reaches 0.42 N / mm 2 after priming and 0.43 N / mm 2 after thin-plaster application: the minimum values increase to 0.24 and 0.28 N / mm 2 .
  • the coating composition based on calcium sulfate comprises when dressing as an inorganic binder either only hemihydrate or only anhydrite.
  • the core mass is composed as is discussed for plasterboard here standing type is common and as with conventional plasterboard is used.
  • the plasterboard according to the invention is used on conventional production lines for plasterboard manufactured.
  • the plasterboard is behind their manufacture in the unprocessed state when stored and / or transported and / or mechanically fastened becomes. A processed state exists when the plasterboard is built into a building. If the coating mass with the built-in plasterboard with wallpaper, Tiles or foils is covered, it absorbs water and the calcium sulfate can partially rehydrate.
  • the plasterboard according to Figures 1 and 2 has a board core 1, on the one side of which there is a glass fleece layer 2 connects to the outside with a calcium sulfate coating 3 is provided.
  • the glass fleece layer 2 is in two layer-like regions 4, 5, one region 4 is filled with a coating compound, which is also the coating 3 forms, and the other area 5 with a core mass is filled, which also forms the plate core 1.
  • the core mass and the coating mass touch each other the glass fleece layer 2 along a separating surface 6.
  • the intimate contact between the core mass and the coating mass can be determined using scanning electron microscopy Show recordings.
  • Fig. 3 shows the perfect one Contact of both layers that penetrated the glass fleece layer are.
  • 4 is the underlying plate Stucco was added to iron oxide before mixing.
  • Electron beam microsensor is used to determine how far the Core mass has penetrated the glass fleece. How to get out the spectra can see is the nuclear mass up to that point marked with "2" penetrated. The digit "1" shows no iron peak. Because such analyzes in practice too are elaborate, the degree of contact is affected by the Lift resistance described.
  • the calcium sulfate coating 3 is as thin as a film and a maximum of 200 ⁇ m thick.
  • the structure of the fleece can be seen through the coating 3, since this is like a thin spread on the fleece.

Landscapes

  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Laminated Bodies (AREA)
  • Force Measurement Appropriate To Specific Purposes (AREA)
  • Investigating Strength Of Materials By Application Of Mechanical Stress (AREA)
  • Lining And Supports For Tunnels (AREA)
  • Finishing Walls (AREA)
  • Building Environments (AREA)

Claims (18)

  1. Panneau de plâtre à couche de feutre de fibres de verre revêtue, où au moins un côté d'un noyau de panneau est recouvert de la couche de feutre de fibres de verre, dont le côté opposé au noyau de panneau est muni d'un revêtement de sulfate de calcium, où la masse de noyau forme le noyau de panneau et d'une part pénètre dans la couche de feutre de fibres de verre et la masse de revêtement forme le revêtement de sulfate de calcium et d'autre part pénètre dans la couche de feutre de fibres de verre, où la masse de revêtement est formée à base d'un sulfate de calcium et contient un liant organique et où la masse de noyau est constituée par du sulfate de calcium dihydraté, où le revêtement de sulfate de calcium ainsi que la couche de feutre de fibres de verre adhèrent au noyau de panneau en tout point au-dessus du plan du panneau avec une résistance à l'arrachement mesurée perpendiculairement au plan du panneau, et où le panneau de plâtre se trouve à l'état existant peu de temps après la fabrication, caractérisé en ce que le sulfate de calcium de la masse de revêtement n'est pas ou presque pas pris et en ce que la masse de noyau est mise en contact avec la masse de revêtement de manière sensiblement continue sur la surface de telle sorte que la résistance à l'arrachement est d'au moins 0,15 N/mm2.
  2. Panneau de plâtre selon la revendication 1, caractérisé en ce que le début de la consolidation de la masse de revêtement est d'au moins 1,5 h.
  3. Panneau de plâtre selon la revendication 1 ou 2, caractérisé en ce que le début de la consolidation de la masse de revêtement est d'au moins 2,5 h.
  4. Panneau de plâtre selon la revendication 1, 2 ou 3, caractérisé en ce que le début de la consolidation de la masse de revêtement est d'au maximum 6 h.
  5. Panneau de plâtre selon l'une des revendications précédentes, caractérisé en ce que le début de la consolidation de la masse de revêtement est d'au maximum 5 h.
  6. Panneau de plâtre selon l'une des revendications précédentes, caractérisé en ce qu'une résistance à l'arrachement moyenne d'au moins 0,20 N/mm2 est assurée.
  7. Panneau de plâtre selon l'une des revendications précédentes, caractérisé en ce que le sulfate de calcium de la masse de revêtement est du sulfate de calcium hémi hydraté qui contient des additifs qui conduisent à une faible vitesse de prise du sulfate de calcium hémi hydraté.
  8. Panneau de plâtre selon la revendication 7, caractérisé en ce que, lors du gâchage, la masse de revêtement, indépendamment de l'eau ajoutée, présente la composition suivante: 60-95 % en masse de plâtre de moulage, 0,01-1 % en masse d'éther cellulosique, 0,03-0,5 % en masse de retardateur, 0,05-1,0 % en masse de fluidifiant.
  9. Panneau de plâtre selon la revendication 7 ou 8, caractérisé en ce que la masse de revêtement contient jusqu'à 25 % en masse de poudre de calcaire et jusqu'à 5 % en masse de dispersion de PVAC.
  10. Panneau de plâtre selon l'une des revendications 1 à 6, caractérisé en ce que le sulfate de calcium est un sulfate de calcium anhydrite qui est à grains fins avec une taille de grain < 200 µm et qui est en partie capable de prendre.
  11. Panneau de plâtre selon la revendication 10, caractérisé en ce que la taille de grain du sulfate de calcium anhydrite est < 63 µm.
  12. Panneau de plâtre selon la revendication 10 ou 11, caractérisé en ce que la masse de revêtement en sulfate de calcium anhydrite présente une valeur moyenne des tailles de grain d50 entre 8 et 12 µm.
  13. Panneau de plâtre selon l'une des revendications 10 à 12, caractérisé en ce que la masse de revêtement présente, lors du gâchage, indépendamment de l'eau ajoutée, la composition suivante : au moins 94 % en masse de sulfate de calcium anhydrite, 0,01-0,8 % en masse d'éther cellulosique, 0,01-1,0 % en masse de fluidifiant et au maximum 0,2 % en masse d'agent mouillant.
  14. Panneau de plâtre selon la revendication 1, caractérisé en ce que le sulfate de calcium de la masse de revêtement n'est pas pris jusqu'à un degré de réhydratation d'au maximum 2 %.
  15. Panneau de plâtre selon l'une des revendications précédentes, caractérisé en ce que la masse de revêtement contient un plastifiant.
  16. Panneau de plâtre selon l'une des revendications précédentes, caractérisé en ce que l'abrasion de la masse de revêtement, mesurée avec le Teledyne Taber Standard Abrasion Tester conformément à ISO 4586-2 et DIN 53109, est d'au maximum 0,2 g.
  17. Panneau de plâtre selon l'une des revendications précédentes, caractérisé en ce que le liant organique constitue moins de 6 % en masse de la masse de revêtement sèche.
  18. Panneau de plâtre selon l'une des revendications précédentes, caractérisé en ce que la masse de revêtement contient jusqu'à 40 % en masse d'hydroxyde d'aluminium ou d'acide borique.
EP95114350A 1994-09-15 1995-09-13 Plaque de plâtre avec feuille en fibre de verre revêtu Expired - Lifetime EP0702115B1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE4432792 1994-09-15
DE4432792 1994-09-15
DE19527857A DE19527857C2 (de) 1994-09-15 1995-07-29 Gipsbauplatte mit beschichteter Glasvlieslage
DE19527857 1995-07-29

Publications (2)

Publication Number Publication Date
EP0702115A1 EP0702115A1 (fr) 1996-03-20
EP0702115B1 true EP0702115B1 (fr) 2001-07-04

Family

ID=25940134

Family Applications (1)

Application Number Title Priority Date Filing Date
EP95114350A Expired - Lifetime EP0702115B1 (fr) 1994-09-15 1995-09-13 Plaque de plâtre avec feuille en fibre de verre revêtu

Country Status (4)

Country Link
EP (1) EP0702115B1 (fr)
AT (1) ATE202821T1 (fr)
DK (1) DK0702115T3 (fr)
ES (1) ES2158923T3 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2316693B (en) * 1996-08-29 2000-05-31 Bpb Plc Building board
GB9816427D0 (en) * 1998-07-28 1998-09-23 Bpb Plc Building board and its production
US8680193B2 (en) * 2010-02-02 2014-03-25 Stauf Klebstoffwerk Gmbh Aqueous dispersion primer, coating made thereof and method for producing a vapor barrier or an intermediate layer on a substrate

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1033123B (de) * 1954-06-23 1958-06-26 Saint Gobain Gipsplatte sowie Verfahren und Vorrichtung zu deren Herstellung
US3993822A (en) * 1970-02-25 1976-11-23 Gebr. Knauf Westdeutsche Gipswerke Multi-layer plasterboard
AU5170773A (en) * 1972-02-02 1974-08-01 Commw Sceitnific And Ind Resea Plaster sheet material
IE49483B1 (en) 1979-05-30 1985-10-16 Bpb Industries Ltd Production of building board
DE3937433A1 (de) 1989-11-10 1991-05-16 Knauf Westdeutsche Gips Gipsbauplatte mit kaschierungen aus beschichteten glasfaservliesen und verfahren zur herstellung derselben

Also Published As

Publication number Publication date
ES2158923T3 (es) 2001-09-16
EP0702115A1 (fr) 1996-03-20
ATE202821T1 (de) 2001-07-15
DK0702115T3 (da) 2001-09-17

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