EP0696808B1 - Winding-type noise-suppressing high-tension resistive cord - Google Patents
Winding-type noise-suppressing high-tension resistive cord Download PDFInfo
- Publication number
- EP0696808B1 EP0696808B1 EP19950111676 EP95111676A EP0696808B1 EP 0696808 B1 EP0696808 B1 EP 0696808B1 EP 19950111676 EP19950111676 EP 19950111676 EP 95111676 A EP95111676 A EP 95111676A EP 0696808 B1 EP0696808 B1 EP 0696808B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- polymer
- winding
- core
- tension resistive
- type noise
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000642 polymer Polymers 0.000 claims description 30
- 230000003014 reinforcing effect Effects 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 15
- 229920000181 Ethylene propylene rubber Polymers 0.000 claims description 10
- 229920005601 base polymer Polymers 0.000 claims description 10
- 229910000859 α-Fe Inorganic materials 0.000 claims description 10
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 9
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 8
- 239000004698 Polyethylene Substances 0.000 claims description 7
- 229920000573 polyethylene Polymers 0.000 claims description 7
- -1 polyethylene Polymers 0.000 claims description 6
- 239000004743 Polypropylene Substances 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 229920001155 polypropylene Polymers 0.000 claims description 4
- 238000004073 vulcanization Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims 1
- 229920002943 EPDM rubber Polymers 0.000 description 7
- 239000002184 metal Substances 0.000 description 5
- 238000007765 extrusion coating Methods 0.000 description 4
- 229920001973 fluoroelastomer Polymers 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 229920002379 silicone rubber Polymers 0.000 description 3
- 239000004945 silicone rubber Substances 0.000 description 3
- 239000004760 aramid Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910018487 Ni—Cr Inorganic materials 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 239000000696 magnetic material Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/0063—Ignition cables
Definitions
- the present invention relates to a winding-type noise-suppressing high-tension resistive cord to be used as an ignition cable for an internal combustion engine of an automotive vehicle and the like.
- High-tension resistive cords for transmitting a high voltage generated at an ignition coil to a spark plug directly or through a distributer have been required to have a low electric transmission loss, a good noise suppressing effect, and high resistance to heat and voltage.
- currently used high-tension resistive cords are of two types: a string-type high-tension resistive cord which includes fibers impregnated with carbon; and a winding-type high-tension resistive cord which includes a metal small-gage wire having a high specific resistance and wound about a core made of a magnetic material or the like.
- the winding-type high-tension resistive cord which comprises a reinforcing string 51 of aramid fibers, glass fibers or the like; a core 52 formed by extrusion-coating the reinforcing string 51 with a base polymer including ferrite powder mixed therein; a resistance wire 53 coiled around the core 52; an insulating layer 54 for extrusion-coating the core 52 and the resistance wire 53; a braid 55 for coating the insulating layer 54; and an outermost sheath 56 for coating the braid 55 (Japanese Utility Model Publication No. 1-32253 (1989)).
- the material of the core 52 generally used is fluororubber and silicone rubber which are a base polymer of high heat-resistance and high strength (Japanese Utility Model Publication No. 60-28002 (1985) and Japanese Utility Model Publication No. 5-20467 (1993)).
- fluororubber and silicone rubber which are a base polymer of high heat-resistance and high strength
- EPR ethylene propylene rubber
- the EPR used as the base polymer of the core does not provide a suitable hardness when it is unvulcanized, failing to cause the resistance wire to suitably resiliently dent the surface of the core when the resistance wire is wound around the core of the unvulcanized base polymer. Further, vulcanized EPR has a low strength and low elongation, resulting in the core torn off during the removal of the insulating layer and cracks in the core when bent for connection to the terminal.
- Document EP-A-0 329 188 which is considered to represent the most relevant state of the art discloses a winding-type noise-suppressing high-voltage resistive cord comprising a core, a resistance wire coiled around the core and an insulating layer for coating said core around which the resistance wire is coiled.
- the core is formed as ferrite rubber layer comprising a base polymer, for example ethylene-propylene, which contains ferrite powder and electrically conductive particles.
- Object of the present invention is to improve a winding-type noise-suppressing high-voltage cord according to the preamble of claim 1 in such a way that tensile strength and hardness of a core of the cord and adhesion of a resistance wire on the core are increased.
- the reinforcing polymer is ethylene-vinyl acetate copolymer.
- the reinforcing polymer is polyethylene.
- the reinforcing polymer is polypropylene.
- the presence of the reinforcing polymer having the good compatibility with EPR allows the unvulcanized core to have a strength suitable to coil the resistance wire therearound.
- the vulcanization causes cross-linkage in the EPR, in the reinforcing polymer, and between the EPR and reinforcing polymer to increase the strength of the vulcanized core. Therefore, the winding-type noise-suppressing high-tension resistive cord having physical properties identical with those of the conventional cord including the core of fluororubber and silicone rubber is fabricated at low costs.
- a winding-type noise-suppressing high-tension resistive cord 10 comprises a reinforcing string 11 including three twisted 1000-denier aramid yarns, and a core 12 of a 1.3 mm outer diameter formed by extrusion-coating the reinforcing string 11 with a polymer including ferrite powder mixed therein.
- the ferrite powder preferably includes Mn-Zn based ferrite such as Mn-Zn-Fe (manganese-zinc-ferric oxide).
- the polymer is a blend of ethylene-propylene-diene terpolymer (EPDM) which is one of the EPR as a base polymer and ethylene-vinyl acetate copolymer (EVA) which is EPDM-compatible and to be covulcanized during vulcanization as a reinforcing polymer.
- EPDM ethylene-propylene-diene terpolymer
- EVA ethylene-vinyl acetate copolymer
- the core 12 contains 100 parts by weight of the blend polymer and 500 parts by weight of the ferrite powder.
- a 50 ⁇ m Ni-Cr resistance wire 13 is coiled 7200 times per meter around the core 12, with the blend polymer unvulcanized. Since the unvulcanized blend polymer has a suitable hardness, the resistance wire 13 is half embedded in the core 12 as shown in Fig. 2. The resistance wire 13 is held half embedded in the core 12 by subsequent vulcanization (under conditions of 160°C.; 30 minutes).
- An insulating layer 14 is formed by EPDM extrusion coating on the core 12 around which the resistance wire 13 is wound.
- the insulating layer 14 is coated with a reinforcing braid 15 made of glass yarn, and the reinforcing braid 15 is coated with a sheath 16 made of EPDM.
- the reinforcing polymer is not limited to EVA but may be polypropylene (PP) and polyethylene (PE), for example.
- EVA and PE are suitable.
- the blend ratio of EPDM to PE is within the range of about 80 to about 70 parts by weight of the former to, correspondingly, about 20 to about 30 parts by weight of the latter (that is, the blend polymer includes about 20 to about 30 % by weight of the PE) and the blend ratio of EPDM to EVA is within the range of about 80 to about 40 parts by weight of the former to, correspondingly, about 20 to about 60 parts by weight of the latter (that is, the blend polymer includes about 20 to about 60 % by weight of the EVA), satisfactory extrusion workability is obtained if about 100 to about 600 parts by weight of the ferrite powder is mixed, and the physical properties of the unvulcanized polymer are a hardness of 75 to 85 and an elongation of 50 % or more. This prevents the core 12 from being cracked when the resistance wire 13 is wound therearound and from being torn off.
- the obtained physical properties of the vulcanized polymer are a strength of 5 MPa or more and an elongation of 50 % or more. This prevents the core 12 from being torn off and cracked when the insulating layer 14 is stripped and the core is bent for connection between the cord and the metal terminal.
Landscapes
- Insulated Conductors (AREA)
- Communication Cables (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP186073/94 | 1994-08-08 | ||
JP6186073A JP3013710B2 (ja) | 1994-08-08 | 1994-08-08 | 巻線型雑音防止高圧抵抗電線 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0696808A2 EP0696808A2 (en) | 1996-02-14 |
EP0696808A3 EP0696808A3 (enrdf_load_stackoverflow) | 1996-03-27 |
EP0696808B1 true EP0696808B1 (en) | 1999-03-17 |
Family
ID=16181919
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19950111676 Expired - Lifetime EP0696808B1 (en) | 1994-08-08 | 1995-07-25 | Winding-type noise-suppressing high-tension resistive cord |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0696808B1 (enrdf_load_stackoverflow) |
JP (1) | JP3013710B2 (enrdf_load_stackoverflow) |
CN (1) | CN1121632A (enrdf_load_stackoverflow) |
DE (1) | DE69508323T2 (enrdf_load_stackoverflow) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108129743A (zh) * | 2017-12-20 | 2018-06-08 | 苏州希普拉斯新材料有限公司 | 新能源汽车用无卤阻燃高弹性聚烯烃电缆料 |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6054028A (en) * | 1996-06-07 | 2000-04-25 | Raychem Corporation | Ignition cables |
JPH1068849A (ja) * | 1996-08-29 | 1998-03-10 | Tokin Corp | 光ファイバケーブル |
JP4508401B2 (ja) * | 2000-11-20 | 2010-07-21 | 三井化学株式会社 | アロイ押出成形品の製造方法、その製造装置および成形品 |
CN102385946A (zh) * | 2010-09-04 | 2012-03-21 | 深圳市沃尔核材股份有限公司 | 一种屏蔽电线及制造方法 |
US20130133921A1 (en) * | 2011-11-28 | 2013-05-30 | Prestolite Wire Llc | Anti-capillary resistor wire |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58103415U (ja) | 1981-12-31 | 1983-07-14 | 株式会社デンソー | 低静電容量巻線型高圧抵抗電線 |
JPS6028002U (ja) | 1983-08-03 | 1985-02-25 | 株式会社 堀技術研究所 | 真空保持弁 |
JPH01211807A (ja) * | 1988-02-19 | 1989-08-25 | Yazaki Corp | 巻線型高圧抵抗電線 |
JPH0770249B2 (ja) * | 1989-11-16 | 1995-07-31 | 矢崎総業株式会社 | 雑音防止用高圧抵抗電線 |
JPH0520467U (ja) | 1991-01-04 | 1993-03-12 | 日本電気株式会社 | フアクシミリ装置 |
-
1994
- 1994-08-08 JP JP6186073A patent/JP3013710B2/ja not_active Expired - Lifetime
-
1995
- 1995-07-25 DE DE1995608323 patent/DE69508323T2/de not_active Expired - Fee Related
- 1995-07-25 EP EP19950111676 patent/EP0696808B1/en not_active Expired - Lifetime
- 1995-08-08 CN CN 95109297 patent/CN1121632A/zh active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108129743A (zh) * | 2017-12-20 | 2018-06-08 | 苏州希普拉斯新材料有限公司 | 新能源汽车用无卤阻燃高弹性聚烯烃电缆料 |
Also Published As
Publication number | Publication date |
---|---|
EP0696808A2 (en) | 1996-02-14 |
DE69508323D1 (de) | 1999-04-22 |
JP3013710B2 (ja) | 2000-02-28 |
DE69508323T2 (de) | 1999-11-11 |
CN1121632A (zh) | 1996-05-01 |
EP0696808A3 (enrdf_load_stackoverflow) | 1996-03-27 |
JPH0850816A (ja) | 1996-02-20 |
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