EP0686209B1 - Procede et installation de traitement continu d'une bande d'acier galvanisee - Google Patents
Procede et installation de traitement continu d'une bande d'acier galvanisee Download PDFInfo
- Publication number
- EP0686209B1 EP0686209B1 EP95902008A EP95902008A EP0686209B1 EP 0686209 B1 EP0686209 B1 EP 0686209B1 EP 95902008 A EP95902008 A EP 95902008A EP 95902008 A EP95902008 A EP 95902008A EP 0686209 B1 EP0686209 B1 EP 0686209B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- strip
- temperature
- rapidly
- heating
- cooling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 21
- 229910001335 Galvanized steel Inorganic materials 0.000 title claims abstract description 10
- 239000008397 galvanized steel Substances 0.000 title claims abstract description 10
- 238000001816 cooling Methods 0.000 claims abstract description 30
- 238000010438 heat treatment Methods 0.000 claims abstract description 30
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000011701 zinc Substances 0.000 claims abstract description 18
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 18
- 230000006698 induction Effects 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000003595 mist Substances 0.000 claims abstract description 5
- 230000001174 ascending effect Effects 0.000 claims description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- 238000003303 reheating Methods 0.000 abstract description 3
- 230000004907 flux Effects 0.000 abstract 2
- 238000001035 drying Methods 0.000 abstract 1
- 238000010981 drying operation Methods 0.000 abstract 1
- 230000002045 lasting effect Effects 0.000 abstract 1
- 239000007921 spray Substances 0.000 abstract 1
- 238000005244 galvannealing Methods 0.000 description 19
- 238000009434 installation Methods 0.000 description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 10
- 229910000831 Steel Inorganic materials 0.000 description 10
- 239000010959 steel Substances 0.000 description 10
- 238000012423 maintenance Methods 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 229910052742 iron Inorganic materials 0.000 description 5
- 238000010586 diagram Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 238000009987 spinning Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000010410 dusting Methods 0.000 description 2
- 238000005246 galvanizing Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- KFZAUHNPPZCSCR-UHFFFAOYSA-N iron zinc Chemical compound [Fe].[Zn] KFZAUHNPPZCSCR-UHFFFAOYSA-N 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
- C23C2/28—Thermal after-treatment, e.g. treatment in oil bath
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
- C23C2/28—Thermal after-treatment, e.g. treatment in oil bath
- C23C2/29—Cooling or quenching
Definitions
- the present invention relates to a method for the continuous treatment of a galvanized steel strip, in particular by galvannealing. She wears also on an installation.
- the galvannealing operation is performed in an instalation where the strip describes at least two vertical passes, namely a ascending pass and descending pass.
- this installation can also be used to manufacture a galvanized strip conventional.
- a heating and maintaining temperature above the galvanizing bath immediately after the wringing device consisting of air knives.
- This oven is generally retractable, because it is not not used in the production of conventional galvanized strips.
- a first cooling device usually a group of supply air fans, so that do not damage the coating on the deflection rollers. All of the oven and the cooling device determine the height of the ascending pass, which generally does not exceed 50 meters due to the vibrations produced in the air knives.
- a second device cooling system for example a second group of fans, is usually placed at the start of the following downward pass.
- the coated strip leaves the zinc bath at a temperature of about 450 ° C to 480 ° C then, after spinning with the knives of air, it undergoes the galvannealing operation by heating and keeping in the above-mentioned oven at a temperature between 460 ° C. and 600 ° C depending on the steel grade considered. It is then cooled first by a first group of fans at the end of the pass rising, then at the start of the falling pass, to a temperature suitable for further processing of the coated strip.
- said means for heating the strip include a direct fire oven or an induction oven.
- These means of heaters are capable of increasing from 50 ° C to 100 ° C the temperature of the strip, with a speed which is however moderate and for example, for a strip 0.7 mm thick, 6 ° C / s in a oven equipped with burners and 30 ° C / s in a frequency induction oven 10 kHz.
- heating by gas burners has a yield low energy, around 30%, while with conventional induction with multispire coils, with longitudinal flow or transverse, we may have to correct the transverse distribution irregular temperatures.
- the means for maintaining the temperature are generally consisting of an insulated tunnel, possibly equipped with means of heating, for example with electricity or gas; they occupy approximately a quarter of the height of the ascending vertical strand. All ovens heating and holding should be long enough to ensure residence time greater than 10 seconds, and preferably greater at 15 seconds, at a temperature above 450 ° C.
- the present invention aims to remedy this situation by offering a thermal cycle which ensures excellent conditions of execution of the galvannealing treatment: instead of the cycles that one currently practiced, the method of the invention performs a "square" cycle with a long holding time at a temperature which can be relatively low given the long duration of treatment.
- the process of continuous treatment of a steel strip galvanized with hardened, object of the present invention is characterized in that, after the strip wringing operation at the outlet of the zinc bath, we quickly warms up the strip to a temperature between 460 ° C and 600 ° C with a heating power density greater than 180 kW / m2 per side of product, keeping the strip at substantially constant temperature for a period between 10 seconds and 30 seconds, in that we then quickly cool the tape up to a temperature below 420 ° C with a density of cooling power greater than 100 kW / m2 per product side.
- the temperature at which the strip is worn depends on the shade of treated steel, like what happens in the galvannealing operation traditional; in practice, however, it can be a little lower and be for example between 460 and 560 ° C.
- the heating power density - respectively cooling - which is expressed in kW / m2 is a concept well known to practitioners, and in particular practitioners of heat treatment of steel sheets. We can easily convert power density to rate of change temperature, depending on the thickness of the product.
- a heating power density of 180 kW / m2 per side of product means a heating rate of 100 ° C / s for a sheet of 0.7 mm thick, and 60 ° C / s for a sheet 1.25 mm thick.
- a cooling power density of 100 kW / m2 per product side means a cooling rate of 54 ° C / s for a thickness of 0.7 mm and 30 ° C / s for a sheet of 1.25 mm.
- the rapid heating of the strip by means of a very high induction furnace frequency, for example between 100 kHz and 500 kHz; this modality achieves very high power densities and therefore to achieve very high heating rates, for example already 150 ° C / s for a 0.7 mm thick strip in an oven at 100 kHz.
- the temperature holding zone is constituted by an enclosure possibly provided with means of reheating such as gas burners to provide calories intended to compensate for local heat losses.
- the strip on leaving the temperature-maintaining zone, the strip is cooled to a temperature below 350 ° C.
- the operating parameters of the cooling system are adjusted to ensure a cooling density greater than 125 kW / m 2 per product face.
- the cooling is provided rapid strip by means of water / air mist nozzles.
- the rise in temperature by heating to induction allows, as we already know, better control of the operation of galvannealing treatment, provided that the distribution of temperatures in the strip be as homogeneous as possible at the outlet of the oven, which depends on the conditions after leaving the zinc bath.
- a homogenization section of temperatures for example equipped with burners arranged across the band and provided with individual means for adjusting the feed.
- FIG. 1 shows an installation of treatment of a galvanized steel strip, typical of the technique current.
- the strip 1 is deflected by a first deflection roller 4, and it leaves the zinc bath 2 in vertical direction, guided by rollers 5.
- the steel strip 1 successively describes a trajectory upward vertical to a second deflection roller 7, a trajectory horizontal to a third deflection roller 8, then a trajectory downward vertical towards a later operation.
- an oven is placed comprising a heating section composed of zones 9 and 10 followed a temperature maintenance section 11.
- This oven makes it possible to operate the heating the strip and keeping it at the temperature chosen for cause the migration of iron into zinc which characterizes the treatment of galvannealing. All or part of this oven is retractable in order to ability to produce conventionally galvanized steel strips, without galvannealing treatment; in particular, this oven can make room for other equipment, such as for example a minimum flowering, often used in conventional galvanization.
- the strip temperature is around 450 ° C after spinning; by the galvannealing operation in the oven, it is raised up to 460 ° C at 600 ° C depending on the grade of steel treated.
- the conventional installation includes a device 12 for cooling the galvanized steel strip, which usually consists of a group of supply air fans. These devices ensure the cooling of the galvanized strip, possibly after galvannealing, to a sufficiently low temperature to prevent it from sticking to the idler rollers 7.
- This modality does not differ from the prior art as far as the actual galvanization of the strip, as well as the spin of the zinc layer.
- the essential difference relates to the galvannealing oven which, according to the invention has a short heating section 10 rapid galvanized steel strip, followed by a short zone 13 temperature equalization and a long holding zone 11 at substantially constant temperature; at the outlet of the oven is arranged a rapid cooling section 14 fitted with mist nozzles water / air.
- the length of the vertical path upward (4.7) cannot currently exceed fifty meters, in particular due to transverse vibrations of the strip and difficulty adjusting the thickness of the coating.
- the facilities conventional as shown in Figure 1 given the presence of a long cooling device 12 before the first idler roller 7 and the length of the heating oven 10 space available for temperature maintenance zone 11 is limited.
- the invention makes it possible to greatly lengthen the duration of temperature maintenance, which on the one hand facilitates adjustment temperatures and the conduct of treatment and secondly allows to apply a long hold at a lower temperature than in the conventional operation, which is favorable for the properties of the coating.
- section AB represents the slight cooling which affects the strip at the outlet of the zinc bath at A and the section EF illustrates the temperature decrease following forced cooling before contact with deflection roller 7.
- the strip cools slightly, passing from 460 ° C to 445 ° C at its entry into an induction furnace whose heating density is 190 kW / m 2 and which raises the temperature to 490 ° C; the strip is maintained at this temperature for 15.5 seconds, after which it is subjected to intense cooling in an enclosure 3 m in length, the first part of which is equipped with a battery of water / air jets, the cooling power of which is 180 kW / m 2 per product face; the temperature of the strip leaving the enclosure is 330 ° C.
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Thermal Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Coating With Molten Metal (AREA)
- Coating Apparatus (AREA)
Description
- Fig. 1
- montre une installation typique de l'état actuel de la technique de galvannealing; la
- Fig. 2
- représente une modalité de réalisation de l'invention, et la
- Fig. 3
- représente les diagrammes température/temps du cycle thermique objet de l'invention et d'un cycle thermique conventionnel.
Claims (8)
- Procédé de traitement continu d'une bande d'acier galvanisée au trempé, caractérisé en ce que, après l'opération d'essorage de la bande à la sortie du bain de zinc, on réchauffe rapidement la bande jusqu'à une température comprise entre 460°C et 600°C avec une densité de puissance de chauffage supérieure à 180 kW/m2 par face de produit, en ce qu'on maintient la bande à température sensiblement constante pendant une période comprise entre 10 secondes et 30 secondes, en ce que l'on refroidit ensuite rapidement la bande jusqu'à une température inférieure à 420°C avec une densité de puissance de refroidissement supérieure à 100 kW/m2 par face de produit.
- Procédé de traitement suivant la revendication 1, caractérisé en ce que l'on assure le chauffage rapide de la bande au moyen d'un four à induction à fréquence comprise entre 100 kHz et 500 kHz.
- Procédé de traitement suivant la revendication 2, caractérisé en ce que l'on assure le chauffage en combinant l'emploi du four à induction avec celui d'un inducteur à spire unique par exemple constitué d'une feuille de cuivre entourant la bande.
- Procédé de traitement suivant l'une ou l'autre des revendications 1 à 3, caractérisé en ce que l'on assure le maintien à température dans une enceinte éventuellement pourvue de moyens de réchauffage tels que des brûleurs à gaz.
- Procédé de traitement suivant l'une ou l'autre des revendications 1 à 4, caractérisé en ce que l'on refroidit rapidement la bande jusqu'à une température inférieure à 350°C.
- Procédé de traitement suivant l'une ou l'autre des revendications 1 à 5, caractérisé en ce que l'on refroidit rapidement la bande avec une densité de puissance de refroidissement supérieure à 125 kW/m2 par face de produit.
- Procédé de traitement suivant l'une ou l'autre des revendications 1 à 6, caractérisé en ce que l'on assure le refroidissement rapide de la bande au moyen de gicleurs à brouillard eau/air.
- Installation de traitement continu d'une bande d'acier galvanisée, qui comporte une cuve contenant un bain de zinc, des rouleaux de renvoi définissant une trajectoire verticale ascendante de la bande, ainsi que des moyens essoreurs placés après la sortie de ladite cuve sur ladite trajectoire verticale ascendante de la bande, caractérisée en ce qu'elle comporte successivement des moyens de chauffage rapide de la bande constitués par un four à induction à fréquence comprise entre 100 kHz et 500 kHz, des moyens de maintien de la bande à une température sensiblement constante, et des moyens de refroidissement rapide constitués par des gicleurs à brouillard eau/air, tous moyens situés le long de la trajectoire verticale ascendante de la bande.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE9301453A BE1007793A6 (fr) | 1993-12-24 | 1993-12-24 | Procede et installation de traitement continu d'une bande d'acier galvanisee. |
BE9301453 | 1993-12-24 | ||
PCT/BE1994/000094 WO1995018245A1 (fr) | 1993-12-24 | 1994-12-13 | Procede et installation de traitement continu d'une bande d'acier galvanisee |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0686209A1 EP0686209A1 (fr) | 1995-12-13 |
EP0686209B1 true EP0686209B1 (fr) | 1998-05-27 |
Family
ID=3887676
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP95902008A Expired - Lifetime EP0686209B1 (fr) | 1993-12-24 | 1994-12-13 | Procede et installation de traitement continu d'une bande d'acier galvanisee |
Country Status (8)
Country | Link |
---|---|
US (1) | US5628842A (fr) |
EP (1) | EP0686209B1 (fr) |
JP (1) | JPH08511064A (fr) |
AT (1) | ATE166672T1 (fr) |
BE (1) | BE1007793A6 (fr) |
DE (1) | DE69410599T2 (fr) |
ES (1) | ES2118536T3 (fr) |
WO (1) | WO1995018245A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3077562B1 (fr) | 2013-12-06 | 2019-03-06 | Fives Celes | Ligne de traitement en continu d'une bande metallique amagnetique comprenant une section de galvannealing et procede de chauffage par induction de ladite bande dans ladite section de galvannealing |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2754544B1 (fr) | 1996-10-10 | 1998-11-06 | Lorraine Laminage | Tole aluminiee a faible emissivite |
US6177140B1 (en) | 1998-01-29 | 2001-01-23 | Ispat Inland, Inc. | Method for galvanizing and galvannealing employing a bath of zinc and aluminum |
DE19822156A1 (de) * | 1998-05-16 | 1999-11-18 | Schloemann Siemag Ag | Verfahren und Vorrichtung zur Durchführung der Glühung eines Galvannealing-Prozesses |
CA2666056C (fr) * | 2006-10-13 | 2012-01-03 | Nippon Steel Corporation | Appareil et procede de fabrication d'une feuille d'acier plaquee par immersion a chaud par du zinc allie |
US8025835B2 (en) * | 2007-07-31 | 2011-09-27 | ArcelorMittal Investigación y Desarrollo, S.L. | Furnace configured for use in both the galvannealing and galvanizing of a metal strip |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS608289B2 (ja) * | 1978-10-16 | 1985-03-01 | 日新製鋼株式会社 | 加工性のすぐれた溶融めつき鋼板の製造方法 |
JPS6048570B2 (ja) * | 1978-12-25 | 1985-10-28 | 日新製鋼株式会社 | 連続溶融アルミニウムメツキ鋼板の連続過時効処理法 |
JPS61223174A (ja) * | 1985-03-28 | 1986-10-03 | Sumitomo Metal Ind Ltd | 合金化溶融亜鉛めつき鋼板の製造方法 |
JPS62130268A (ja) * | 1985-12-02 | 1987-06-12 | Kawasaki Steel Corp | 加工用合金化処理溶融亜鉛めつき軟鋼板の製造方法 |
EP0406619A1 (fr) * | 1989-06-21 | 1991-01-09 | Nippon Steel Corporation | Procédé pour la fabrication de tôles d'acier laminées à froid, galvanisées non vieillissantes et ayant une bonne aptitude au formage, dans une ligne de galvanisation continue |
JPH0379748A (ja) * | 1989-08-23 | 1991-04-04 | Sumitomo Metal Ind Ltd | 合金化処理炉 |
JP2658580B2 (ja) * | 1990-12-29 | 1997-09-30 | 日本鋼管株式会社 | プレス成形性および耐パウダリング性の優れた合金化溶融亜鉛めっき鋼板の製造方法 |
JP2526320B2 (ja) * | 1991-05-07 | 1996-08-21 | 新日本製鐵株式会社 | 高張力合金化溶融亜鉛めっき鋼板の製造方法 |
JPH05247619A (ja) * | 1992-03-03 | 1993-09-24 | Nippon Steel Corp | 合金化亜鉛めっき鋼板製造用竪型合金化炉 |
-
1993
- 1993-12-24 BE BE9301453A patent/BE1007793A6/fr not_active IP Right Cessation
-
1994
- 1994-12-13 DE DE69410599T patent/DE69410599T2/de not_active Expired - Fee Related
- 1994-12-13 JP JP7517690A patent/JPH08511064A/ja not_active Ceased
- 1994-12-13 WO PCT/BE1994/000094 patent/WO1995018245A1/fr active IP Right Grant
- 1994-12-13 EP EP95902008A patent/EP0686209B1/fr not_active Expired - Lifetime
- 1994-12-13 ES ES95902008T patent/ES2118536T3/es not_active Expired - Lifetime
- 1994-12-13 AT AT95902008T patent/ATE166672T1/de not_active IP Right Cessation
-
1995
- 1995-08-21 US US08/517,262 patent/US5628842A/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3077562B1 (fr) | 2013-12-06 | 2019-03-06 | Fives Celes | Ligne de traitement en continu d'une bande metallique amagnetique comprenant une section de galvannealing et procede de chauffage par induction de ladite bande dans ladite section de galvannealing |
Also Published As
Publication number | Publication date |
---|---|
EP0686209A1 (fr) | 1995-12-13 |
DE69410599D1 (de) | 1998-07-02 |
JPH08511064A (ja) | 1996-11-19 |
ATE166672T1 (de) | 1998-06-15 |
US5628842A (en) | 1997-05-13 |
DE69410599T2 (de) | 1999-01-21 |
BE1007793A6 (fr) | 1995-10-24 |
WO1995018245A1 (fr) | 1995-07-06 |
ES2118536T3 (es) | 1998-09-16 |
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Legal Events
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PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
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