EP0685551B1 - Intern beheizter Drehofen zur Pyrolyse von Abfällen - Google Patents

Intern beheizter Drehofen zur Pyrolyse von Abfällen Download PDF

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Publication number
EP0685551B1
EP0685551B1 EP95401177A EP95401177A EP0685551B1 EP 0685551 B1 EP0685551 B1 EP 0685551B1 EP 95401177 A EP95401177 A EP 95401177A EP 95401177 A EP95401177 A EP 95401177A EP 0685551 B1 EP0685551 B1 EP 0685551B1
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EP
European Patent Office
Prior art keywords
furnace
heating
solid materials
heating means
waste
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP95401177A
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English (en)
French (fr)
Other versions
EP0685551A1 (de
Inventor
Gérard Martin
Eric Marty
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B1/00Retorts
    • C10B1/10Rotary retorts
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B11/00Machines or apparatus for drying solid materials or objects with movement which is non-progressive
    • F26B11/02Machines or apparatus for drying solid materials or objects with movement which is non-progressive in moving drums or other mainly-closed receptacles
    • F26B11/026Arrangements for charging or discharging the materials to be dried, e.g. discharging by reversing drum rotation, using spiral-type inserts
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B11/00Machines or apparatus for drying solid materials or objects with movement which is non-progressive
    • F26B11/02Machines or apparatus for drying solid materials or objects with movement which is non-progressive in moving drums or other mainly-closed receptacles
    • F26B11/04Machines or apparatus for drying solid materials or objects with movement which is non-progressive in moving drums or other mainly-closed receptacles rotating about a horizontal or slightly-inclined axis
    • F26B11/0404Machines or apparatus for drying solid materials or objects with movement which is non-progressive in moving drums or other mainly-closed receptacles rotating about a horizontal or slightly-inclined axis with internal subdivision of the drum, e.g. for subdividing or recycling the material to be dried
    • F26B11/0413Machines or apparatus for drying solid materials or objects with movement which is non-progressive in moving drums or other mainly-closed receptacles rotating about a horizontal or slightly-inclined axis with internal subdivision of the drum, e.g. for subdividing or recycling the material to be dried the subdivision consisting of concentric walls, e.g. multi-pass or recirculation systems; the subdivision consisting of spiral-shaped walls
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B11/00Machines or apparatus for drying solid materials or objects with movement which is non-progressive
    • F26B11/02Machines or apparatus for drying solid materials or objects with movement which is non-progressive in moving drums or other mainly-closed receptacles
    • F26B11/04Machines or apparatus for drying solid materials or objects with movement which is non-progressive in moving drums or other mainly-closed receptacles rotating about a horizontal or slightly-inclined axis
    • F26B11/0445Machines or apparatus for drying solid materials or objects with movement which is non-progressive in moving drums or other mainly-closed receptacles rotating about a horizontal or slightly-inclined axis having conductive heating arrangements, e.g. heated drum wall
    • F26B11/045Machines or apparatus for drying solid materials or objects with movement which is non-progressive in moving drums or other mainly-closed receptacles rotating about a horizontal or slightly-inclined axis having conductive heating arrangements, e.g. heated drum wall using heated internal elements, e.g. which move through or convey the materials to be dried
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F5/00Elements specially adapted for movement

Definitions

  • the present invention relates to the field of heat treatment of solid materials, and more particularly pyrolysis (or thermolysis) ovens intended for treat solids such as waste of any kind.
  • the ovens targeted are generally cylindrical and rotate around their axis of symmetry.
  • the calorific intake necessary for pyrolysis can consist of solids or gases in contact or not with the solids to be treated.
  • patent application FR-A- 2,668,774 shows an oven pyrolysis in which heating can be carried out outside the oven by burners supplied with pyrolysis gases; according to another embodiment, heat transfer solids are supplied in contact with the waste to be pyrolyzed in the oven itself. A additional reactor is then necessary to heat the solids heat transfer fluids.
  • This type of installation is a complex implementation, and is reveals to the heavy consumer use of energy.
  • the document DE-A- 29 03 280 discloses a compact rotary oven in which the waste to be treated successively passes through a first cylinder turning then a rotating ring coaxial with the cylinder. Waste are heated by heat transfer gases circulating around the cylinders. An external rotating envelope delimits the area of heater.
  • this type of installation remains particularly complex in terms of the shape of the cylinders; Moreover the means of heating and smoke evacuation not being problems may arise at the level of connections.
  • This type of installation like most ovens known turning points (see US-A-1 508 578), must be considered as ovens rotary external indirect heating.
  • the present invention represents an improvement of ovens known pyrolysis turning points
  • this invention avoids the problems of obstructions by solids large, inert or not yet thermally degraded; the risks of snagging are almost non-existent, very clearly reduced compared to known systems.
  • the thermal efficiency is further improved by the fact that the highest temperatures are clearly located at center of the system.
  • a solid material heat treatment oven comprising a rotating element in which said longitudinally circulates solid materials, and a heating means therefor materials, which extends longitudinally in the oven, the solid materials progressing in about two lengths to inside the rotating element.
  • the heating means is fixed, intended for channel solid materials and ensure their preheating and / or their heating.
  • the heating means is fixed, arranged coaxially and inside the rotating element so that that in the axial zone delimited by the heating means, the solid materials exhibit the highest temperatures.
  • the heating means comprises at least a tubular element whose branch (s) are parallel to the axis longitudinal of the oven, the branch or branches are connected by membranes, the assembly having a generally cylindrical shape.
  • a heat transfer fluid circulates in the co-current and / or counter current of solid materials.
  • the oven according to the invention can comprise tubular elements which are independently supplied each other.
  • the oven according to the invention allows easier reuse of hot fluids than in the case of a rotary heating system; this is still a way to increase the energy performance of the installation, since it is possible to efficiently recover the sensible heat from fumes produced.
  • the heating means may constitute an element of generally cylindrical shape around or inside which resistive elements are arranged.
  • the type of oven illustrated in Figure 1 has a cylinder turning 1 with a horizontal or slightly inclined axis depending on the inventory and disposal requirements for solids.
  • This cylinder turning is mounted for example on rollers 2, themselves fixed on a base 3 which supports most of the furnace equipment.
  • Said rotating cylinder is equipped with a set 4 which ensures its rotation at a speed preferably between 0.1 and 20 rpm.
  • the cylinder is connected to a fixed part 5, via a connection 6 which ensures a complete seal between the atmosphere in the oven and outside.
  • This bond 6 can be what man of art commonly calls for a rotary joint.
  • Said fixed part 5 has an outlet 7 for the gases produced in the cylinder turning and an outlet 8 for the solids resulting from the treatment.
  • This same fixed part supports a fixed element 9, of form substantially cylindrical having one end or "outlet" 9a.
  • Element 9 preferably extends over almost the entire length of cylinder 1.
  • the device 9 is used for heating from inside the oven and channeling the waste to the end of the rotating cylinder 1 opposite to that into which said said are introduced waste to be treated.
  • the waste comes from a hopper or any storage device 10. They are introduced into the oven at a controlled flow rate thanks to a push device 11 such as shown in Figure 1, or by any other known device those skilled in the art (worm gear for example).
  • waste is more or less compacted if it present in abundant form in the raw state. Waste progress in the device 9 following a piston flow more or less compact, while being preheated. At the end 9a of the heating element 9, the waste falls by gravity into the rotating cylinder, and gradually flow longitudinally towards exit 8. The waste therefore goes back and forth in the oven.
  • the heater 9 can consist of a set of tubular elements 20 connected between them by membranes 21, ensuring continuity on the whole of the device which has a generally cylindrical shape.
  • the tubular elements are preferably grouped together by 2, 4, 6, etc. in the form of pins in which a hot fluid or in which an operation of combustion. These pins are connected to a collector 13 fixed on the fixed part 5 or placed near this fixed part 5.
  • the collector 13 includes a zone 13a for the supply in hot fluid or for air and fuel supply, and a zone 13b for the evacuation of the cooled fluid or the fumes. In no case, there is contact between the fluid or the fumes used for the heating of the tubes 20 on the one hand, and the gases contained in the cylinder 1 and the fixed part 5 on the other hand.
  • the device 9 is made up simple pins having two types of tubes 20: type tubes 22 in which the fluid circulates co-current from the waste to the interior of the device 9 and of the type 23 tubes interposed between the tubes 22 in which the fluid circulates against the current of the waste.
  • the tubes can be heated for example by combustion of a gaseous fuel.
  • the gaseous fuel can be natural gas or even gases from the pyrolytic treatment of waste, said gases having been beforehand and preferably treated to remove tar and particles that could lead to phenomena unwanted fouling.
  • the heater 9 could just as well consist of a substantially cylindrical tube, equipped with electric heating means like resistors, coiled around or inside said tube, helically, with connections carried outside to the level of a box feed.
  • the oven according to the invention is preferably intended for waste treatment at temperatures between 50 and 900 ° C, with final temperatures of the pyrolysis products in oven outlet preferably between 400 and 600 ° C.
  • the temperatures at heater 9 are included between 100 and 2000 ° C and preferably between 600 and 1000 ° C.
  • the tubes 20, 21, 22 provide a first heating (or preheating) waste by the internal face of the device 9, during progression of these inside the device 9.
  • the calorific intake the waste continues when these have left the device 9, via the external face of said device 9.
  • the heating of the waste is then carried out by the external face of the device 9 which emits energy by radiation, ie directly on the waste, i.e. on the internal wall of cylinder 1 which then returns it to the waste.
  • Part of the internal face or the external face can be hidden by an insulating mask 14, as shown in Figure 1, to control and limit the supply of heat at any point in the system.
  • the oven according to the present invention presupposes, a priori, use for heating, hot fluids or fuels clean such as natural gas or pyrolysis gases free of their tars and other particles.
  • the hot fluid can be preheated air for example at a temperature between 500 and 1000 ° C, in a boiler which burns gases of gross pyrolysis.
  • the present invention has a number of advantages, in particular with regard to a conventional installation including a heated rotating cylinder externally by burners or a heat transfer fluid which surrounds the rotating cylinder.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Thermal Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Sustainable Development (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Muffle Furnaces And Rotary Kilns (AREA)
  • Processing Of Solid Wastes (AREA)
  • Gasification And Melting Of Waste (AREA)
  • Incineration Of Waste (AREA)

Claims (9)

  1. Ofen zur thermischen Behandlung fester Materialien, ein Drehelement (1), in welchem in Längsrichtung diese festen Materialien zirkulieren und ein Heizmittel (9) für diese Feststoffmaterialien umfassend, das sich in Längsrichtung im Ofen erstreckt, wobei die Feststoffmaterialien gemäß etwa zwei Längen im Inneren des Drehelements (1) wandern, dadurch gekennzeichnet, daß das Heizmittel (9) fest ist, dazu bestimmt, die Feststoffmaterialien zu kanalisieren und deren Vorwärmung und/oder Erwärmung sicherzustellen.
  2. Ofen nach Anspruch 1, dadurch gekennzeichnet, daß das Heizmittel (9) koaxial und im Inneren des Drehelements (1) derart angeordnet ist, daß in der durch das Heizmittel begrenzten Axialzone die Feststoffmaterialien die höchsten Temperaturen aufweisen.
  3. Behandlungsofen nach einem der Ansprüche 1 oder 2, dadurch gekennzeichnet, daß dieses Heizmittel wenigstens ein röhrenförmiges Element (22, 23) umfaßt, dessen Abzweigung bzw. Abzweigungen parallel zur Längsachse des Ofens verlaufen und daß die Abzweigung(en) durch Membranen (21) verbunden sind, wobei die Gesamtanordnung eine im allgemeinen zylindrische Gestalt hat.
  4. Ofen nach Anspruch 3, dadurch gekennzeichnet, daß ein Wärmeträgerfluid im Heizmittel (22, 23) im Gleichstrom und/oder im Gegenstrom zu den Feststoffmaterialien zirkuliert.
  5. Ofen nach einem der Ansprüche 3 oder 4, dadurch gekennzeichnet, daß die röhrenförmigen Elemente (22, 23) unabhängig voneinander geschweißt sind.
  6. Ofen nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß er im übrigen über ein erstes Mittel (7), das fest ist, und das dazu bestimmt ist, die im drehenden Element (1) erzeugten Gase abzuziehen und über ein zweites Mittel (8), das fest ist, verfügt, um die aus der thermischen Behandlung resultierenden Feststoffe abzuziehen.
  7. Ofen nach einem der Ansprüche 1 oder 2, dadurch gekennzeichnet, daß das Heizmittel (9) ein Element im allgemeinen zylindrischer Gestalt bildet, um das herum oder in dessen Innerem Widerstandselemente angeordnet sind.
  8. Ofen nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß er im übrigen ein isolierendes dieses Heizmittel (9) umschließendes Element (14) umfaßt.
  9. Anwendung des Ofens nach einem der vorhergehenden Ansprüche auf die Pyrolyse von Abfällen.
EP95401177A 1994-05-30 1995-05-19 Intern beheizter Drehofen zur Pyrolyse von Abfällen Expired - Lifetime EP0685551B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9406660A FR2720487B1 (fr) 1994-05-30 1994-05-30 Four tournant de pyrolyse de déchets avec chauffage interne.
FR9406660 1994-05-30

Publications (2)

Publication Number Publication Date
EP0685551A1 EP0685551A1 (de) 1995-12-06
EP0685551B1 true EP0685551B1 (de) 1999-08-25

Family

ID=9463735

Family Applications (1)

Application Number Title Priority Date Filing Date
EP95401177A Expired - Lifetime EP0685551B1 (de) 1994-05-30 1995-05-19 Intern beheizter Drehofen zur Pyrolyse von Abfällen

Country Status (7)

Country Link
US (1) US5644997A (de)
EP (1) EP0685551B1 (de)
CN (1) CN1118665C (de)
AT (1) ATE183770T1 (de)
DE (1) DE69511626T2 (de)
FR (1) FR2720487B1 (de)
PL (1) PL178782B1 (de)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19617617C2 (de) * 1996-05-02 1998-11-12 Buck Chem Tech Werke Verfahren zur Entsorgung von Explosivstoff-Wirkmassen sowie Vorrichtung hierfür
US6189463B1 (en) * 1998-05-12 2001-02-20 General Technology, Inc. Methods and apparatus for incinerating combustible waste material such as farm animal biomass
DE102008030983B4 (de) 2008-06-27 2012-06-06 Corina Projahn Verfahren und Vorrichtung zur Durchführung einer Pyrolyse und deren Verwendung zum Verschwelen von Altreifen und Biomasse
WO2009094962A1 (de) 2008-01-28 2009-08-06 Corina Projahn Verfahren und vorrichtung zur durchführung einer pyrolyse
DE202008008767U1 (de) 2008-06-27 2008-09-11 Projahn, Corina Vorrichtung zur Durchführung einer Pyrolyse
DE202008007674U1 (de) 2008-06-09 2009-02-12 Fittkau, Wilfried, Dipl.-Ing. Anlage zur Erzeugung von Elektroenergie durch Depolimerisation von Polimeren, insbesondere Altreifen
DE102008039817A1 (de) 2008-08-22 2010-02-25 Corina Projahn Pyrolyseprodukt und seine Verwendung
US8833276B2 (en) * 2009-02-06 2014-09-16 William Hunkyun Bang Burner system for waste plastic fuel
FR2944344B1 (fr) 2009-04-10 2013-12-27 Inst Francais Du Petrole Four tournant pour traitement thermique de materiaux solides
FR2948448B1 (fr) 2009-07-21 2014-01-10 Inst Francais Du Petrole Four tournant pour traitement thermique radiatif de materiaux solides
CN102994103A (zh) * 2011-09-14 2013-03-27 邢献军 一种生物质干燥炭化炉
CN103292468B (zh) * 2012-02-24 2017-11-24 江苏圣奥化学科技有限公司 换热器
DE102012109874A1 (de) 2012-10-16 2014-04-17 Merenas Trust Reg. Vorrichtung und Verfahren zur stofflichen Behandlung von Rohstoffen
US8603558B1 (en) 2013-03-27 2013-12-10 Jarrah Ali Abdullah Ali Jaddan Almutairi Waste food recycling machine
CN114739129B (zh) * 2022-04-08 2023-09-26 郑州沃特节能科技股份有限公司 一种基于余热回收再利用的烘干系统

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US1508578A (en) * 1923-10-09 1924-09-16 Kohlenscheidungsgesellschaft M Apparatus for the distillation of coal and other substances
US3481720A (en) * 1966-04-29 1969-12-02 Sun Oil Co Process and apparatus for the distillation of solids
US3861336A (en) * 1973-11-07 1975-01-21 Shinzaburo Koyanagi Garbage incinerator
US4066024A (en) * 1975-12-24 1978-01-03 Oconnor Chadwell Rotating fluidized bed combustor
DE2903280C3 (de) 1979-01-29 1981-11-19 Peter 5439 Bretthausen Voelskow Entgasungsdrehtrommel
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GB2103772B (en) * 1981-08-12 1984-09-26 British Nuclear Fuels Ltd Rotary kiln arrangements
US4730564A (en) * 1987-06-08 1988-03-15 Abboud Harry I Multi-stage kiln
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US5273355A (en) * 1992-04-23 1993-12-28 Astec Industries Inc. Aggregate dryer and soil incinerator

Also Published As

Publication number Publication date
FR2720487A1 (fr) 1995-12-01
US5644997A (en) 1997-07-08
CN1113310A (zh) 1995-12-13
FR2720487B1 (fr) 1996-07-12
PL308842A1 (en) 1995-12-11
PL178782B1 (pl) 2000-06-30
CN1118665C (zh) 2003-08-20
DE69511626T2 (de) 1999-12-09
ATE183770T1 (de) 1999-09-15
EP0685551A1 (de) 1995-12-06
DE69511626D1 (de) 1999-09-30

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