EP0679854B1 - System for cleaning tubes by means of elastic balls - Google Patents

System for cleaning tubes by means of elastic balls Download PDF

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Publication number
EP0679854B1
EP0679854B1 EP95400920A EP95400920A EP0679854B1 EP 0679854 B1 EP0679854 B1 EP 0679854B1 EP 95400920 A EP95400920 A EP 95400920A EP 95400920 A EP95400920 A EP 95400920A EP 0679854 B1 EP0679854 B1 EP 0679854B1
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EP
European Patent Office
Prior art keywords
balls
receptacle
cleaning
sections
installation according
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EP95400920A
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German (de)
French (fr)
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EP0679854A1 (en
Inventor
Roger Ricard
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Technos et Cie
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Technos et Cie
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28GCLEANING OF INTERNAL OR EXTERNAL SURFACES OF HEAT-EXCHANGE OR HEAT-TRANSFER CONDUITS, e.g. WATER TUBES OR BOILERS
    • F28G1/00Non-rotary, e.g. reciprocated, appliances
    • F28G1/12Fluid-propelled scrapers, bullets, or like solid bodies
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B9/00Cleaning hollow articles by methods or apparatus specially adapted thereto 
    • B08B9/02Cleaning pipes or tubes or systems of pipes or tubes
    • B08B9/027Cleaning the internal surfaces; Removal of blockages
    • B08B9/04Cleaning the internal surfaces; Removal of blockages using cleaning devices introduced into and moved along the pipes
    • B08B9/053Cleaning the internal surfaces; Removal of blockages using cleaning devices introduced into and moved along the pipes moved along the pipes by a fluid, e.g. by fluid pressure or by suction
    • B08B9/055Cleaning the internal surfaces; Removal of blockages using cleaning devices introduced into and moved along the pipes moved along the pipes by a fluid, e.g. by fluid pressure or by suction the cleaning devices conforming to, or being conformable to, substantially the same cross-section of the pipes, e.g. pigs or moles
    • B08B9/0552Spherically shaped pigs

Definitions

  • the invention relates to an installation of the type described in the preamble of claim 1.
  • Such an installation is known, for example, from document DE-A-25 41 902.
  • the balls in question wear out and must be replace when their diameter has become too small to keep them effective.
  • This replacement requires, on the one hand, evacuation worn balls and, on the other hand, their replacement by new balls.
  • Worn balls can be removed all simultaneously as soon as it is estimated that the percentage of those that are worn out among all of those that are high enough to be suitable for change the whole load.
  • sorter for example of the type of that which was the subject of document EP-A-0 353 154 which sorter can be associated with a ball counter counting the number of balls remaining in circulation and thus indicating the number of new balls that it is appropriate inject into the circuit to complete the charge, last number being equal to that of the worn balls removed from the circuit.
  • This impregnation can be done by kneading the balls by hand underwater or, preferably, at using an impregnator, for example of the type having been the subject of application EP-A-0 631 103.
  • the cleaning systems of the different sections are then mounted in parallel with each other others or in series following each other.
  • the balls collected downstream of each section are directed to a common recycling pump different systems, which drives them upstream sections.
  • the unique charge renewal system of balls is then placed on the section of the circuit recycling of balls common to the different systems.
  • the balls collected downstream of a given section are sent by the pump to recycle the cleaning system from this section to upstream of the neighboring section so that the balls successively run through the different sections.
  • the unique ball charge renewal system is then placed on any of the sections of recycling.
  • the invention aims, above all, to remedy these various disadvantages in proposing, for the cleaning of all the tubes of a compound exchanger or condenser of several sections in parallel, an installation at the both very efficient and very economical, comprising only some devices in common for all sections.
  • the installations according to the invention intended for cleaning the tubes of an assembly composed of n sections in parallel, n being an integer greater than 1, also include, for each of these sections, a section of branched piping. comprising an upstream ball recovery device mounted on the outlet of the section in question, a drive pump, a ball collector and a ball reinjection device mounted at the entrance of said section, and they are essentially characterized in that that they comprise a single device for injecting new balls mounted so as to serve each of the n sections alternately.
  • the invention includes, apart from these arrangements main, certain other provisions which preferably used at the same time and which will be more explicitly question below.
  • FIG. 1 shows schematically a ball cleaning installation in accordance with the invention.
  • FIGS 2 and 3 schematically show in more detail two embodiments of one of the devices included in this installation.
  • Figures 4 and 5 show similarly to the Figure 1 two variants according to the invention of a part of the cleaning installation.
  • FIGS 6 and 7 schematically show advantageous embodiments and in accordance with the invention of two of the devices included in the installation of cleaning.
  • Each section is served by a pipeline 2 cooling water inlet itself connected to a common upstream pipe 3 and by a pipe 4 of heated water outlet connected to a common downstream pipe 5.
  • a set of these different devices 6 to 10, which works in regime with a given ball load, is assigned individually to each of the different sections of the condenser.
  • Said unique means pooled include essentially a receptacle 11 suitable for being supplied in new balls and connected to the four sections 6 by four pipes, each equipped with a valve.
  • the receptacle 11 of Figure 1 is connected by four pipes 15 equipped with as many valves 16 to the four ball collectors 9 and, by a duct 17 fitted with a valve 18, to the upstream pipe 3, and it is itself connected to a drain pipe 19 fitted with a valve 20.
  • the collector 9 can be designed in the way that has been shown diagrammatically in the figure 2, that is to say comprises a housing 21 containing a basket strainer 22 fitted with a ball trapping valve 23, and the pipe 15 associated with this manifold 9 opens in the housing 21 upstream of the basket 22.
  • valve 23 As long as valve 23 is open and valve 16 associated with line 15 is closed, the balls circulating in section 6 cross without hindrance the collector 9.
  • receptacle 11 To inject a load of new balls, we fills receptacle 11 with water, all valves 13 and 16 being closed, this receptacle 11 is introduced into through its upper opening, then cleared, the load new balls to inject and we impregnate this charge of water, kneading it by hand underwater.
  • the pressure in the latter leads, connected to the upstream line 3, always being greater than the pressure in the suction pipe of pump 8, the water flows from the conduit 17, through the receptacle 11 and line 12, up to the section 6 concerned, bringing with it the new balls to be injected.
  • Such an operation of injecting new balls can be performed successively for each of sections of the condenser.
  • the impregnation of the balls water can be carried out using a device mechanical.
  • Such a device is advantageously one of those which have been described in the cited FRANCE patent application above and which implement at least one cycle of pumping a piston pump or the like.
  • each new ball collector can be associated with or replaced by a ball sorter 24 ( Figure 3) itself mounted on section 6 and combined with a housing 25 containing a perforated partition 26 capable to be crossed by water but not by balls, the inner portion of this housing, located upstream of the partition 26 being connected to the corresponding pipe 15 and its downstream portion being connected to section 6 through a diaphragm 27 of adjustable section and a valve 28 (as for example described in the patent FRANCE cited above).
  • the implementation of the assembly constituted by these elements 24 to 28 differs from that of collector 9 in that that only those evacuated by line 15 are those, balls in circulation in section 6, which are the more worn, i.e. with a diameter below a predetermined threshold value: these balls are collected in the case 25 and the value of the diameter minimum considered as defining the wear threshold can be adjusted by adjusting the aperture of the diaphragm 27.
  • FIGS. 4 and 5 Two variants of the overall diagram of the figure 1 which can be envisaged in accordance with the invention are illustrated respectively in FIGS. 4 and 5.
  • conduit 17 is equipped with a pump circulation 30 likely to increase the strength of circulation of water from line 3 in the conduit 17, in the direction of receptacle 11.
  • this pump is capable of delivering water at a pressure higher than that prevailing in the collectors 9.
  • the used balls are evacuated as before, the valve 18 then being closed and the pump 30, out of service.
  • This variant is particularly interesting since it allows to remove all the pipes 12 and their valves 13.
  • lines 12 and 15 are relatively long (their length being schematized by the space between the two lines interrupted parallels T which cut said pipes) and have the smallest possible diameter.
  • Such a vortex movement can be obtained through a tangential orientation of the admission of the water in the case as shown on the figure 6.
  • This advantage is particularly appreciable when the device for injecting new balls is associated with a more or less automatic water impregnator.
  • the pooling of the injection device new balls also has the great advantage of require only one reserve of new balls for the whole of installation, which simplifies problems while improving security.
  • the invention makes it possible to put in common the single station, of the whole installation cleaning, which in all circumstances requires a chronic external intervention, namely the reserve of new balls: it is not necessary here to take care to supply of new balls only from one tank and not more than a number of tanks equal to that of "sections".
  • the installation does not have any of the above drawbacks for parallel or serial mounting of different sections: the relative cleaning circuits to the different sections remaining individualized and autonomous during their operation, there is no risk of uneven distribution of the balls between the different sections; similarly, the occurrence of a incident on any of the said sections does not no interruption of cleaning on others sections.
  • the receptacle 11 can easily be installed far from the tube bundle to be cleaned, in a place with more access easy for operating personnel that said beam tubular, since this receptacle can be connected to 6 sections of bypass via pipelines (12, 15) long (their length can easily reach or even exceed one hundred meters), and of which the inside diameter is relatively small and very little greater than the diameter of the balls: whereas, in the current achievements, the diameter of the pipes connecting the new ball injection devices to the installations considered is around 80 mm, the diameter in question is advantageously here of the order only 1.1 to 1.5 times the diameter of the balls, which is generally between 18 and 40 mm; in particular, for a diameter of the balls of the order of 19 mm, the outside diameter of the pipes considered can be equal to 25.4 mm (one inch) only for a thickness of wall of the order of 2 mm.

Description

L'invention est relative à une installation du type décrit dans le préambule de la revendication 1. Une telle installation est connue, par exemple, du document DE-A-25 41 902.The invention relates to an installation of the type described in the preamble of claim 1. Such an installation is known, for example, from document DE-A-25 41 902.

Les boules en question s'usent et il faut les remplacer lorsque leur diamètre est devenu trop faible pour qu'elles restent efficaces.The balls in question wear out and must be replace when their diameter has become too small to keep them effective.

Ce remplacement nécessite, d'une part, l'évacuation des boules usées et, d'autre part, leur remplacement par des boules neuves.This replacement requires, on the one hand, evacuation worn balls and, on the other hand, their replacement by new balls.

Les boules usées peuvent être évacuées toutes simultanément dès que l'on estime que le pourcentage de celles qui sont usées parmi l'ensemble de celles qui circulent est suffisamment élevé pour qu'il convienne de changer toute la charge.Worn balls can be removed all simultaneously as soon as it is estimated that the percentage of those that are worn out among all of those that are high enough to be suitable for change the whole load.

Ou bien, ce qui est préférable, on les retire du circuit au fur et à mesure qu'elles atteignent leur diamètre minimum au moyen d'un trieur, par exemple du type de celui ayant fait l'objet du document EP-A-0 353 154 lequel trieur peut être associé à un compteur de boules comptant le nombre de boules restant en circulation et indiquant ainsi le nombre de boules neuves qu'il convient d'injecter dans le circuit pour compléter la charge, ce dernier nombre étant égal à celui des boules usées retirées du circuit.Or, which is preferable, we remove them from the circuit as they reach their minimum diameter by means of a sorter, for example of the type of that which was the subject of document EP-A-0 353 154 which sorter can be associated with a ball counter counting the number of balls remaining in circulation and thus indicating the number of new balls that it is appropriate inject into the circuit to complete the charge, last number being equal to that of the worn balls removed from the circuit.

L'injection des boules neuves est en général accompagnée d'une imprégnation de ces boules en eau de façon que leur densité apparente soit voisine de celle de l'eau.The injection of new balls is generally accompanied by an impregnation of these balls with so that their apparent density is close to that of the water.

Cette imprégnation peut se faire en pétrissant les boules à la main sous l'eau ou, ce qui est préférable, au moyen d'un imprégnateur, par exemple du type de celui ayant fait l'objet de la demande EP-A-0 631 103.This impregnation can be done by kneading the balls by hand underwater or, preferably, at using an impregnator, for example of the type having been the subject of application EP-A-0 631 103.

L'ensemble des opérations ci-dessus engendre des frais importants d'appareillage et de main-d'oeuvre.All of the above operations generate significant equipment and labor costs.

Ces frais sont multipliés lorsque le faisceau de tubes à nettoyer est divisé en plusieurs sections fonctionnant en parallèle qui comportent chacune leur système de nettoyage : c'est ainsi que les condenseurs de vapeur des turbines des centrales électriques sont en général divisés en plusieurs sections ou "poumons" lorsque la puissance de la turbine est supérieure à 200 MW. Le nombre de ces sections est en général d'autant plus élevé que la puissance de la turbine est grande : il est souvent égal à 6 pour les turbines de puissance supérieure à 1000 MW.These costs are multiplied when the bundle of tubes to be cleaned is divided into several working sections in parallel which each have their own system cleaning: this is how steam condensers turbines of power plants are generally divided into several sections or "lungs" when the turbine power is more than 200 MW. The number of these sections is generally higher as the turbine power is large: it is often equal to 6 for turbines with a power greater than 1000 MW.

Dans un tel cas, il est courant d'affecter à chaque section ou "poumon" un système complet de nettoyage, comprenant en particulier des moyens pour récupérer les boules à la sortie de la section considérée, des moyens pour entraíner ces boules en dérivation en vue de leur recyclage à l'entrée de ladite section et des moyens pour renouveler les charges desdites boules.In such a case, it is common to assign to each section or "lung" a complete cleaning system, comprising in particular means for recovering the balls at the exit of the section in question, means for driving these balls in diversion with a view to recycling them at the entrance to the said section and resources to renew the charges of said balls.

Pour réduire les frais d'appareillage et de main d'oeuvre dus à cette multiplication des équipements, il a déjà été proposé de mettre en commun un système permettant le renouvellement des charges de boules qui est unique et complet pour plusieurs sections ou même pour la totalité de celles-ci.To reduce equipment and labor costs of work due to this multiplication of equipment, there has already been proposed to pool a system allowing the renewal of the charges of balls which is single and complete for several sections or even for the all of these.

Les systèmes de nettoyage des différentes sections sont alors montés en parallèle les uns par rapport aux autres ou en série à la suite les uns des autres.The cleaning systems of the different sections are then mounted in parallel with each other others or in series following each other.

Lorsque les systèmes de nettoyage sont montés en parallèle, les boules collectées à l'aval de chaque section sont dirigées vers une pompe de recyclage commune aux différents systèmes, qui les refoule vers l'amont des sections. Le système unique de renouvellement des charges de boules est alors disposé sur le tronçon du circuit de recyclage de boules commun aux différents systèmes.When the cleaning systems are fitted in parallel, the balls collected downstream of each section are directed to a common recycling pump different systems, which drives them upstream sections. The unique charge renewal system of balls is then placed on the section of the circuit recycling of balls common to the different systems.

Lorsque les systèmes de nettoyage sont montés en série à la suite les uns des autres, les boules collectées à l'aval d'une section donnée sont envoyées par la pompe de recyclage du système de nettoyage de cette section vers l'amont de la section voisine de telle sorte que les boules parcourent successivement les différentes sections. Le système unique de renouvellement des charges de boules est alors disposé sur l'un quelconque des tronçons de recyclage.When the cleaning systems are fitted in series following each other, the balls collected downstream of a given section are sent by the pump to recycle the cleaning system from this section to upstream of the neighboring section so that the balls successively run through the different sections. The unique ball charge renewal system is then placed on any of the sections of recycling.

Chacune de ces solutions présente des inconvénients importants :

  • si les systèmes de nettoyage sont montés en parallèle les uns par rapport aux autres, il est difficile de répartir convenablement les débits de boules entre les sections, vu les différences inévitables qui existent entre les pertes de charge dans ces sections, lesquelles pertes sont liées aux degrés d'encrassement locaux des tubes de faisceaux : on observe alors un risque de concentration des boules dans les sections où les tubes sont les plus propres et au contraire de pénurie dans les sections les plus sales qui sont pourtant celles qui ont le plus besoin de nettoyage,
  • si les systèmes de nettoyage sont montés en série à la suite les uns des autres, une avarie localisée en un point quelconque de l'ensemble du circuit en série réalisé, par exemple au niveau d'une pompe de recyclage, ou l'arrêt temporaire de la circulation d'eau dans l'une des sections due à une fuite d'un tube de son faisceau, se traduit par une interruption du nettoyage de la totalité des tubes du condenseur.
Each of these solutions has significant drawbacks:
  • if the cleaning systems are mounted in parallel with each other, it is difficult to properly distribute the ball flow rates between the sections, given the inevitable differences which exist between the pressure losses in these sections, which losses are linked to degrees of local fouling of the bundle tubes: there is then a risk of concentrating the balls in the sections where the tubes are the cleanest and on the contrary of shortage in the dirtiest sections which are, however, those which need most cleaning,
  • if the cleaning systems are connected in series following each other, localized damage at any point in the entire circuit in series produced, for example at a recycling pump, or temporary shutdown of the circulation of water in one of the sections due to a leak in a tube from its bundle, results in an interruption in the cleaning of all the condenser tubes.

L'invention a pour but, surtout, de remédier à ces divers inconvénients en proposant, pour le nettoyage de l'ensemble des tubes d'un échangeur ou condenseur composé de plusieurs sections en parallèle, une installation à la fois très efficace et très économique, comportant seulement certains dispositifs en commun pour toutes les sections.The invention aims, above all, to remedy these various disadvantages in proposing, for the cleaning of all the tubes of a compound exchanger or condenser of several sections in parallel, an installation at the both very efficient and very economical, comprising only some devices in common for all sections.

A cet effet, les installations selon l'invention, destinées au nettoyage des tubes d'un ensemble composé de n sections en parallèle, n étant un entier supérieur à 1, comprennent encore, pour chacune de ces sections, un tronçon de tuyauterie en dérivation comportant un dispositif amont de récupération de boules monté sur la sortie de la section considérée, une pompe d'entraínement, un collecteur de boules et un dispositif de réinjection de boules monté à l'entrée de ladite section, et elles sont essentiellement caractérisées en ce qu'elles comprennent un dispositif unique d'injection de boules neuves monté de façon à desservir alternativement chacun des n tronçons.To this end, the installations according to the invention, intended for cleaning the tubes of an assembly composed of n sections in parallel, n being an integer greater than 1, also include, for each of these sections, a section of branched piping. comprising an upstream ball recovery device mounted on the outlet of the section in question, a drive pump, a ball collector and a ball reinjection device mounted at the entrance of said section, and they are essentially characterized in that that they comprise a single device for injecting new balls mounted so as to serve each of the n sections alternately.

Dans des modes de réalisation avantageux, on a recours en outre à l'une et/ou à l'autre des dispositions suivantes :

  • le dispositif d'injection de boules neuves comprend un réceptacle unique de boules neuves connecté aux n tronçons par l'intermédiaire de n tuyaux équipés respectivement de n vannes,
  • le réceptacle est connecté, par l'intermédiaire d'un conduit équipé d'une vanne, à une source d'eau sous pression,
  • le réceptacle est connecté, par l'intermédiaire d'un conduit équipé d'une vanne et d'une pompe, à la conduite d'eau amont de l'ensemble tubulaire à nettoyer,
  • le réceptacle selon l'un quelconque des deux alinéas précédents, présente une forme générale de révolution autour d'un axe et le conduit débouche tangentiellement dans ledit réceptacle,
  • le réceptacle est associé à un dispositif propre à imprégner d'eau les boules neuves qu'il reçoit,
  • l'installation de nettoyage comprend en outre un dispositif unique d'extraction de boules usées monté de façon à être relié alternativement à chacun des n tronçons,
  • les n tuyaux associés aux n vannes sont communs aux deux dispositifs d'extraction des boules usées et d'injection des boules neuves et sont à cet effet utilisables alternativement dans les deux sens pour respectivement ces deux fonctions,
  • les n tuyaux reliant au moins le dispositif d'injection de boules neuves aux n tronçons de dérivation présentent des diamètres intérieurs très peu supérieurs aux diamètres des boules.
In advantageous embodiments, use is also made of one and / or the other of the following arrangements:
  • the device for injecting new balls comprises a single receptacle for new balls connected to the n sections by means of n pipes fitted respectively with n valves,
  • the receptacle is connected, via a conduit fitted with a valve, to a source of pressurized water,
  • the receptacle is connected, via a conduit fitted with a valve and a pump, to the upstream water pipe of the tubular assembly to be cleaned,
  • the receptacle according to any one of the two preceding paragraphs, has a general shape of revolution about an axis and the duct opens tangentially in said receptacle,
  • the receptacle is associated with a device capable of impregnating the new balls which it receives with water,
  • the cleaning installation also comprises a single device for extracting used balls mounted so as to be connected alternately to each of the n sections,
  • the n pipes associated with the n valves are common to the two devices for extracting used balls and for injecting new balls and can therefore be used alternately in both directions for these two functions respectively,
  • the n pipes connecting at least the injection device for new balls to the n branch sections have internal diameters very little greater than the diameters of the balls.

L'invention comprend, mises à part ces dispositions principales, certaines autres dispositions qui s'utilisent de préférence en même temps et dont il sera plus explicitement question ci-après.The invention includes, apart from these arrangements main, certain other provisions which preferably used at the same time and which will be more explicitly question below.

Dans ce qui suit, l'on va décrire quelques modes de réalisation préférés de l'invention en se référant aux dessins ci-annexés d'une manière bien entendu non limitative.In the following, we will describe some modes preferred embodiments of the invention with reference to attached drawings of course in a nonlimiting manner.

La figure 1, de ces dessins, montre schématiquement une installation de nettoyage de boules conforme à l'invention.Figure 1, of these drawings, shows schematically a ball cleaning installation in accordance with the invention.

Les figures 2 et 3 montrent schématiquement de manière plus détaillée deux modes de réalisation de l'un des dispositifs compris par cette installation.Figures 2 and 3 schematically show in more detail two embodiments of one of the devices included in this installation.

Les figures 4 et 5 montrent semblablement à la figure 1 deux variantes conformes à l'invention d'une partie de l'installation de nettoyage.Figures 4 and 5 show similarly to the Figure 1 two variants according to the invention of a part of the cleaning installation.

Les figures 6 et 7 montrent schématiquement des modes de réalisation avantageux et conformes à l'invention de deux des dispositifs compris par l'installation de nettoyage.Figures 6 and 7 schematically show advantageous embodiments and in accordance with the invention of two of the devices included in the installation of cleaning.

Les dessins considérés concernent d'une façon générale une installation de nettoyage des tubes d'un condenseur tubulaire 1 comprenant quatre sections identiques montées en parallèle.The drawings considered concern in a way general an installation for cleaning the tubes of a tubular condenser 1 comprising four identical sections mounted in parallel.

Chaque section est desservie par une canalisation 2 d'arrivée d'eau de refroidissement elle-même reliée à une conduite amont commune 3 et par une canalisation 4 de sortie d'eau réchauffée reliée à une conduite aval commune 5.Each section is served by a pipeline 2 cooling water inlet itself connected to a common upstream pipe 3 and by a pipe 4 of heated water outlet connected to a common downstream pipe 5.

Chaque section est en outre équipée d'un système de nettoyage continu à boules comprenant, d'une façon connue en soi, un tronçon de tuyauterie de dérivation 6 comportant lui-même successivement :

  • un dispositif amont 7 à grilles propre à récupérer les boules circulant dans la canalisation de sortie 4,
  • une pompe 8 propre à entraíner dans le tronçon 6 un courant d'eau chargé de boules,
  • un collecteur de boules 9,
  • et une canne aval 10 de réinjection des boules dans la canalisation d'arrivée 2.
Each section is further equipped with a continuous ball cleaning system comprising, in a manner known per se, a section of bypass piping 6 itself comprising successively:
  • an upstream device 7 with grids suitable for recovering the balls circulating in the outlet pipe 4,
  • a pump 8 suitable for entraining in the section 6 a stream of water loaded with balls,
  • a ball collector 9,
  • and a downstream rod 10 for reinjecting the balls into the inlet pipe 2.

Un ensemble de ces différents dispositifs 6 à 10, qui fonctionne en régime avec une charge de boules donnée, est affecté individuellement à chacune des différentes sections du condenseur.A set of these different devices 6 to 10, which works in regime with a given ball load, is assigned individually to each of the different sections of the condenser.

Il en est différemment pour les moyens affectés au renouvellement de la charge de boules de nettoyage, ou tout au moins à l'injection des boules neuves, lesquels moyens sont ici uniques et mis en commun pour l'ensemble des quatre sections, étant agencés et montés à cet effet de façon à pouvoir desservir alternativement et successivement ces quatre sections.It is different for the resources allocated to renewal of the load of cleaning balls, or at least when injecting new balls, which means here are unique and pooled for the whole of the four sections, being arranged and mounted for this purpose so as to be able to serve alternately and successively these four sections.

Lesdits moyens uniques mis en commun comprennent essentiellement un réceptacle 11 propre à être alimenté en boules neuves et connecté aux quatre tronçons 6 par quatre canalisations équipées chacune d'une vanne.Said unique means pooled include essentially a receptacle 11 suitable for being supplied in new balls and connected to the four sections 6 by four pipes, each equipped with a valve.

Dans le premier mode de réalisation schématisé sur la figure 1, les canalisations et vannes en question sont désignées respectivement par les références 12 et 13 et lesdites canalisations sont respectivement branchées sur les tronçons 6 en des points 14, de ces tronçons, situés juste en amont des pompes 8.In the first embodiment shown schematically on Figure 1, the pipes and valves in question are designated respectively by the references 12 and 13 and said pipes are respectively connected to the sections 6 at points 14, of these sections, located just upstream of the pumps 8.

En outre, le réceptacle 11 de la figure 1 est relié par quatre canalisations 15 équipées d'autant de vannes 16 aux quatre collecteurs de boules 9 et, par un conduit 17 équipé d'une vanne 18, à la conduite amont 3, et il est raccordé lui-même à une tubulure 19 de vidange équipée d'une vanne 20.In addition, the receptacle 11 of Figure 1 is connected by four pipes 15 equipped with as many valves 16 to the four ball collectors 9 and, by a duct 17 fitted with a valve 18, to the upstream pipe 3, and it is itself connected to a drain pipe 19 fitted with a valve 20.

Dans un cas simple, le collecteur 9 peut être conçu de la manière qui a été schématisée sur la figure 2, c'est-à-dire comprend un boítier 21 contenant un panier crépiné 22 équipé d'une vanne de piégeage des boules 23, et la canalisation 15 associée à ce collecteur 9 débouche dans le boítier 21 en amont du panier 22.In a simple case, the collector 9 can be designed in the way that has been shown diagrammatically in the figure 2, that is to say comprises a housing 21 containing a basket strainer 22 fitted with a ball trapping valve 23, and the pipe 15 associated with this manifold 9 opens in the housing 21 upstream of the basket 22.

Tant que la vanne 23 est ouverte et que la vanne 16 associée à la canalisation 15 est fermée, les boules circulant dans le tronçon 6 traversent sans encombre le collecteur 9.As long as valve 23 is open and valve 16 associated with line 15 is closed, the balls circulating in section 6 cross without hindrance the collector 9.

L'installation type ainsi schématisée sur les figures 1 et 2 fonctionne de la façon suivante, pour ce qui est du renouvellement des boules usées.The typical installation thus schematized on the Figures 1 and 2 work as follows, for this which is the renewal of used balls.

Lorsque les boules de nettoyage de l'une des sections du condenseur sont usées et que l'on désire les évacuer, on collecte les boules de cette section dans son collecteur 9 en fermant la vanne 23 concernée, puis on ouvre la vanne 16 associée ainsi que la vanne 20, toutes les autres vannes 16 et 13 demeurant fermées.When the cleaning balls of one of the sections of the condenser are worn and we want them evacuate, we collect the balls from this section in its manifold 9 by closing the valve 23 concerned, then opens the associated valve 16 as well as valve 20, all the other valves 16 and 13 remaining closed.

La pression au refoulement de la pompe 8 étant toujours supérieure à la pression atmosphérique, l'eau s'écoule depuis le collecteur 9 par la canalisation 15 jusqu'au réceptacle 11 et sa vidange à travers la tubulure 19 entraíne avec elle les boules usées rassemblées dans le collecteur 9.The discharge pressure of pump 8 being always higher than atmospheric pressure, water flows from the collector 9 through the line 15 to receptacle 11 and its emptying through the tubing 19 brings with it the used balls gathered in the collector 9.

Pour injecter une charge de boules neuves, on remplit d'eau le réceptacle 11, toutes les vannes 13 et 16 étant fermées, on introduit dans ce réceptacle 11, à travers son ouverture supérieure, alors dégagée, la charge de boules neuves à injecter et l'on imprègne cette charge d'eau, en la pétrissant à la main sous l'eau.To inject a load of new balls, we fills receptacle 11 with water, all valves 13 and 16 being closed, this receptacle 11 is introduced into through its upper opening, then cleared, the load new balls to inject and we impregnate this charge of water, kneading it by hand underwater.

Puis on referme le réceptacle 11 et l'on ouvre la vanne 13 de la canalisation 12 relative à la section de condenseur concernée ainsi que la vanne 18 du conduit 17.Then we close the receptacle 11 and we open the valve 13 of the pipe 12 relating to the section of condenser concerned as well as the valve 18 of the conduit 17.

La pression dans ce dernier conduit, relié à la conduite amont 3, étant toujours supérieure à la pression dans la tuyauterie d'aspiration de la pompe 8, l'eau s'écoule depuis le conduit 17, à travers le réceptacle 11 et la canalisation 12, jusqu'au tronçon 6 concerné, entraínant avec elle les boules neuves à injecter.The pressure in the latter leads, connected to the upstream line 3, always being greater than the pressure in the suction pipe of pump 8, the water flows from the conduit 17, through the receptacle 11 and line 12, up to the section 6 concerned, bringing with it the new balls to be injected.

Une telle opération d'injection de boules neuves peut être effectuée successivement pour chacune des sections du condenseur.Such an operation of injecting new balls can be performed successively for each of sections of the condenser.

Un certain nombre de perfectionnements peuvent être apportés à l'ensemble simplifié qui vient d'être décrit.A number of improvements can be brought to the simplified set that has just been described.

En particulier, au lieu d'être effectuée manuellement comme indiqué ci-dessus, l'imprégnation des boules neuves en eau peut être effectuée à l'aide d'un dispositif mécanique.In particular, instead of being done manually as indicated above, the impregnation of the balls water can be carried out using a device mechanical.

Un tel dispositif est avantageusement l'un de ceux qui ont été décrits dans la demande de brevet FRANCE citée ci-dessus et qui mettent en oeuvre au moins un cycle de pompage d'une pompe à piston ou analogue.Such a device is advantageously one of those which have been described in the cited FRANCE patent application above and which implement at least one cycle of pumping a piston pump or the like.

De même, chaque collecteur de boules neuves peut être associé à ou remplacé par un trieur de boules 24 (figure 3) lui-même monté sur le tronçon 6 et combiné avec un boítier 25 contenant une cloison perforée 26 susceptible d'être traversée par l'eau mais non par les boules, la portion intérieure, de ce boítier, située en amont de la cloison 26 étant connectée à la canalisation 15 correspondante et sa portion aval étant raccordée au tronçon 6 à travers un diaphragme 27 de section réglable et une vanne 28 (ainsi que par exemple décrit dans le brevet FRANCE cité ci-dessus). Likewise, each new ball collector can be associated with or replaced by a ball sorter 24 (Figure 3) itself mounted on section 6 and combined with a housing 25 containing a perforated partition 26 capable to be crossed by water but not by balls, the inner portion of this housing, located upstream of the partition 26 being connected to the corresponding pipe 15 and its downstream portion being connected to section 6 through a diaphragm 27 of adjustable section and a valve 28 (as for example described in the patent FRANCE cited above).

La mise en oeuvre de l'ensemble constitué par ces éléments 24 à 28 diffère de celle du collecteur 9 en ce que seules sont évacuées par la canalisation 15 celles, des boules en circulation dans le tronçon 6, qui sont le plus usées, c'est-à-dire dont le diamètre passe au-dessous d'une valeur de seuil prédéterminée : ces boules sont recueillies dans le boítier 25 et la valeur du diamètre minimum considéré comme définissant le seuil d'usure peut être ajustée par réglage de l'ouverture du diaphragme 27.The implementation of the assembly constituted by these elements 24 to 28 differs from that of collector 9 in that that only those evacuated by line 15 are those, balls in circulation in section 6, which are the more worn, i.e. with a diameter below a predetermined threshold value: these balls are collected in the case 25 and the value of the diameter minimum considered as defining the wear threshold can be adjusted by adjusting the aperture of the diaphragm 27.

Deux variantes du schéma d'ensemble de la figure 1 qui peuvent être envisagées conformément à l'invention sont illustrées respectivement sur les figures 4 et 5.Two variants of the overall diagram of the figure 1 which can be envisaged in accordance with the invention are illustrated respectively in FIGS. 4 and 5.

Sur la figure 4, on n'a fait figurer que la portion, de l'installation, qui se trouve au-dessous d'un trait interrompu T.In Figure 4, only the portion of the installation, which is located below a broken line T.

On retrouve ici l'ensemble des éléments qui étaient précédemment désignés par les références 2, 3, 11, 12, 13, 15, 16, 17, 18, 19 et 20.Here we find all the elements that were previously designated by references 2, 3, 11, 12, 13, 15, 16, 17, 18, 19 and 20.

Mais ici, au lieu que les extrémités aval des canalisations 15 débouchent dans le réceptacle 11, ces extrémités débouchent directement dans un panier crépiné 29 dans lequel les boules usées peuvent être rassemblées.But here, instead of the downstream ends of pipes 15 open into receptacle 11, these ends open directly into a strainer basket 29 in which the worn balls can be collected.

Dans le mode de réalisation de la figure 5, on s'est encore contenté de représenter les portions, de l'installation, qui se trouvent au-dessous du trait interrompu T.In the embodiment of FIG. 5, we was still content to represent the portions, the installation, which can be found below the line interrupted T.

On y retrouve à nouveau l'ensemble des éléments désignés par les références 2, 3, 11, 15, 16, 17, 18, 19 et 20 sur la figure 1.We find again all the elements designated by the references 2, 3, 11, 15, 16, 17, 18, 19 and 20 in Figure 1.

Cette nouvelle variante diffère de la réalisation de la figure 1 en ce que les canalisations 12 avec leurs vannes 13 sont totalement supprimées (ce qui suppose bien entendu également une suppression des portions des traits verticaux de la figure 1 qui correspondent aux canalisations 12 et se trouvent au-dessus du trait T).This new variant differs from the realization of Figure 1 in that the pipes 12 with their valves 13 are completely removed (which presupposes also heard a deletion of portions of the lines verticals of figure 1 which correspond to the pipes 12 and are above the line T).

En outre, le conduit 17 est équipé d'une pompe de circulation 30 susceptible d'augmenter la force de circulation de l'eau provenant de la conduite 3 dans le conduit 17, en direction du réceptacle 11.In addition, the conduit 17 is equipped with a pump circulation 30 likely to increase the strength of circulation of water from line 3 in the conduit 17, in the direction of receptacle 11.

En particulier, cette pompe est propre à refouler l'eau à une pression supérieure à celle régnant dans les collecteurs 9.In particular, this pump is capable of delivering water at a pressure higher than that prevailing in the collectors 9.

Dans ce cas, l'évacuation des boules usées se fait comme précédemment, la vanne 18 étant alors fermée et la pompe 30, hors service.In this case, the used balls are evacuated as before, the valve 18 then being closed and the pump 30, out of service.

Pour ce qui est de l'injection des boules neuves qui ont été imprégnées d'eau, elle se fait au moyen du courant d'eau engendré par la pompe 30, après ouverture de la vanne 18 et de la vanne 16 correspondant à la section considérée, ladite injection se faisant alors à travers la même canalisation 15 que l'évacuation antérieure de boules usées.Regarding the injection of new balls which have been impregnated with water, it is done by means of the water current generated by pump 30, after opening valve 18 and valve 16 corresponding to the section considered, said injection then being made at through the same pipe 15 as the previous evacuation of worn balls.

Cette variante est particulièrement intéressante puisqu'elle permet de supprimer la totalité des canalisations 12 et de leurs vannes 13.This variant is particularly interesting since it allows to remove all the pipes 12 and their valves 13.

Bien entendu, le conduit 17, au lieu d'être relié à la conduite amont 3 par l'intermédiaire de la pompe 30, pourrait être relié directement à toute autre source d'eau dont la pression est supérieure à celle qui règne dans les collecteurs de boules 9 : ce serait en particulier le cas pour un réseau d'eau sous pression disponible à proximité du condenseur à nettoyer, réseau qui pourrait être par exemple un réseau d'eau d'incendie équipant une centrale associée audit condenseur.Of course, the conduit 17, instead of being connected to the upstream pipe 3 via the pump 30, could be connected directly to any other source of water whose pressure is higher than that prevailing in the 9 ball collectors: this would be particularly the case for a pressurized water network available nearby of the condenser to be cleaned, a network which could be example a fire water network fitted to a power plant associated with said condenser.

Il est avantageux, pour des raisons d'économie et de facilité d'installation, que les canalisations 12 et 15 soient relativement longues (leur longueur étant schématisée par l'espace compris entre les deux traits interrompus parallèles T qui coupent lesdites canalisations) et aient le diamètre le plus faible possible.It is advantageous, for reasons of economy and ease of installation, as lines 12 and 15 are relatively long (their length being schematized by the space between the two lines interrupted parallels T which cut said pipes) and have the smallest possible diameter.

A cet effet, on peut utiliser pour ces canalisations des tuyaux dont le diamètre intérieur est très légèrement supérieur au diamètre des boules neuves.For this purpose, one can use for these pipes pipes with an inner diameter very slightly larger than the diameter of new balls.

Dans un tel cas, pour faciliter l'introduction des boules dans de telles canalisations il peut être opportun de créer un mouvement tourbillonnaire pour l'eau en circulation à l'intérieur des boítiers collecteurs 21 et/ou 25 utilisés de façon que les boules soient présentes successivement à proximité immédiate de l'entrée de la canalisation 15 dans lequel elles doivent être aspirées, entrée qui débouche radialement dans le boítier concerné, avec tout au plus, pour favoriser l'introduction de chaque boule, un petit chanfrein annulaire de raccord (non représenté).In such a case, to facilitate the introduction of balls in such pipes it may be appropriate to create a vortex movement for water by circulation inside the manifolds 21 and / or 25 used so that the balls are present successively in the immediate vicinity of the entrance to the line 15 in which they must be sucked, entry which opens radially into the housing concerned, with at most, to favor the introduction of each ball, a small annular connection chamfer (not represented).

Un tel mouvement tourbillonnaire peut être obtenu grâce à une orientation tangentielle de l'admission de l'eau dans le boítier ainsi qu'il a été représenté sur la figure 6.Such a vortex movement can be obtained through a tangential orientation of the admission of the water in the case as shown on the figure 6.

De la même façon, et pour les mêmes raisons, il est avantageux, pour faciliter l'injection des boules neuves à travers les canalisations 12 ou 15 de relativement petit diamètre, que le raccordement du conduit 17 au réceptacle 11 se fasse tangentiellement à ce dernier, ainsi que représenté sur la figure 7.In the same way, and for the same reasons, it is advantageous, to facilitate the injection of the balls new through pipes 12 or 15 of relatively small diameter, that the connection of conduit 17 to receptacle 11 is made tangentially to the latter, as shown in Figure 7.

En suite de quoi, et quel que soit le mode de réalisation adopté, on obtient une installation de nettoyage des tubes d'un échangeur ou condenseur subdivisé en une pluralité de sections parallèles dont la constitution et le fonctionnement résultent suffisamment de ce qui précède.As a result of what, and whatever the mode of adopted implementation, an installation of cleaning the tubes of a sub-exchanger or condenser in a plurality of parallel sections whose constitution and the operation result sufficiently from what precedes.

Cette installation présente de nombreux avantages par rapport à celles antérieurement connues.This installation has many advantages compared to those previously known.

En particulier, elle est spécialement économique vu que l'ensemble des moyens adoptés pour l'injection des boules neuves et, le cas échéant, pour l'évacuation des boules usées, sont communs à toutes les sections au lieu d'être multipliés par un facteur égal au nombre de ces sections. In particular, it is especially economical considering that all the means adopted for the injection of new balls and, if necessary, for the evacuation of worn balls, are common to all sections instead to be multiplied by a factor equal to the number of these sections.

Cet avantage est particulièrement appréciable lorsque le dispositif d'injection de boules neuves est associé à un imprégnateur d'eau plus ou moins automatique.This advantage is particularly appreciable when the device for injecting new balls is associated with a more or less automatic water impregnator.

La mise en commun du dispositif d'injection de boules neuves présente également le grand avantage de requérir une seule réserve de boules neuves pour l'ensemble de l'installation, ce qui simplifie les problèmes d'approvisionnement tout en améliorant la sécurité.The pooling of the injection device new balls also has the great advantage of require only one reserve of new balls for the whole of installation, which simplifies problems while improving security.

En d'autres termes, l'invention permet de mettre en commun le seul poste, de l'ensemble de l'installation de nettoyage, qui exige en toutes circonstances une intervention extérieure chronique, savoir la réserve de boules neuves : il n'est ici nécessaire de veiller à l'approvisionnement en boules neuves que d'un seul réservoir et non plus d'un nombre de réservoirs égal à celui des "sections".In other words, the invention makes it possible to put in common the single station, of the whole installation cleaning, which in all circumstances requires a chronic external intervention, namely the reserve of new balls: it is not necessary here to take care to supply of new balls only from one tank and not more than a number of tanks equal to that of "sections".

En regard de ces avantages manifestes, l'installation ne présente aucun des inconvénients signalés ci-dessus pour les montages en parallèle ou en série des différentes sections : les circuits de nettoyage relatifs aux différentes sections demeurant individualisés et autonomes au cours de leur fonctionnement, il n'y a aucun risque de répartition inégale des boules entre les différentes sections ; de même, la survenance d'un incident sur l'une quelconque desdites sections n'entraíne aucunement l'interruption du nettoyage sur les autres sections.In view of these obvious advantages, the installation does not have any of the above drawbacks for parallel or serial mounting of different sections: the relative cleaning circuits to the different sections remaining individualized and autonomous during their operation, there is no risk of uneven distribution of the balls between the different sections; similarly, the occurrence of a incident on any of the said sections does not no interruption of cleaning on others sections.

Il importe de signaler également que le réceptacle 11 peut facilement être implanté loin du faisceau tubulaire à nettoyer, en un endroit dont l'accès est plus facile pour le personnel d'exploitation que ledit faisceau tubulaire, puisque ce réceptacle peut être relié aux tronçons 6 de dérivation par l'intermédiaire de canalisations (12, 15) longues (leur longueur pouvant facilement atteindre ou même dépasser la centaine de mètres), et dont le diamètre intérieur est relativement petit et très peu supérieur au diamètre des boules : alors que, dans les réalisations actuelles, le diamètre des canalisations reliant les dispositifs d'injection de boules neuves aux installations considérées est de l'ordre de 80 mm, le diamètre en question est avantageusement ici de l'ordre de 1,1 à 1,5 fois seulement le diamètre des boules, lequel est généralement compris entre 18 et 40 mm ; en particulier, pour un diamètre des boules de l'ordre de 19 mm, le diamètre extérieur des canalisations considérées peut être égal à 25,4 mm (un pouce) seulement pour une épaisseur de paroi de l'ordre de 2 mm.It is also important to note that the receptacle 11 can easily be installed far from the tube bundle to be cleaned, in a place with more access easy for operating personnel that said beam tubular, since this receptacle can be connected to 6 sections of bypass via pipelines (12, 15) long (their length can easily reach or even exceed one hundred meters), and of which the inside diameter is relatively small and very little greater than the diameter of the balls: whereas, in the current achievements, the diameter of the pipes connecting the new ball injection devices to the installations considered is around 80 mm, the diameter in question is advantageously here of the order only 1.1 to 1.5 times the diameter of the balls, which is generally between 18 and 40 mm; in particular, for a diameter of the balls of the order of 19 mm, the outside diameter of the pipes considered can be equal to 25.4 mm (one inch) only for a thickness of wall of the order of 2 mm.

Claims (9)

  1. An installation for cleaning tubes in an assembly (1), such as a heat exchanger or condenser, comprising n sections in parallel, where n is an integer greater than 1, by circulating balls in a flow of water inside said tubes, the installation comprising for each of said sections, a branch length of pipework (6) including an upstream device (7) for recovering balls, which device is mounted on the outlet (4) from the section under consideration, a drive pump (8), a ball collector (9), and a device (10) for reinjecting balls, which device is mounted at the inlet (2) of said section, the installation being characterized in that it comprises a single device (11) for injecting new balls that is connected in such a manner as to serve each of the n lengths (6) in turn.
  2. A cleaning installation according to claim 1, characterized in that the device for injecting new balls comprises a single new ball receptacle (11) connected to the n lengths (6) via n pipes (12; 15) fitted with n respective valves (13; 16).
  3. A cleaning installation according to claim 2, characterized in that the receptacle (11) is connected, via a duct (17) having a valve (18), to a source of water under pressure.
  4. A cleaning installation according to claim 2, characterized in that the receptacle (11) is connected, via a duct (17) fitted with a valve (18) and a pump (30), to the upstream water duct (3) for the tube assembly (1) to be cleaned.
  5. A cleaning installation according to any one of claims 3 and 4, characterized in that the receptacle (11) is generally in the form of a body of revolution about an axis, and in that the duct (17) opens out tangentially into said receptacle.
  6. A cleaning installation according to any one of claims 2 to 5, characterized in that the receptacle (11) is associated with a device suitable for impregnating the new balls it receives with water.
  7. A cleaning installation according to any one of the preceding claims,characterized in that it further includes a single device (11, 29) for extracting worn balls that is mounted in such a manner as to be connected to each of the n lengths in turn via n pipes (15) fitted with n respective valves (16).
  8. A cleaning installation according to claim 7, characterized in that the n pipes (15) associated with the n valves (16) are common both to the device for extracting worn balls and to the device for injecting new balls, and to this end are usable alternately in opposite directions for each of those two functions respectively.
  9. A cleaning installation according to any one of claims 2 to 8,characterized in that the n pipes (12, 15) connecting at least the new ball injection device to the n branch lengths (6) have inside diameters that are very slightly greater than the diameters of the balls.
EP95400920A 1994-04-28 1995-04-25 System for cleaning tubes by means of elastic balls Expired - Lifetime EP0679854B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9405169 1994-04-28
FR9405169A FR2719243B1 (en) 1994-04-28 1994-04-28 Improvements to tube cleaning installations by circulation of elastic balls.

Publications (2)

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EP0679854A1 EP0679854A1 (en) 1995-11-02
EP0679854B1 true EP0679854B1 (en) 1998-03-18

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US (1) US5518068A (en)
EP (1) EP0679854B1 (en)
JP (1) JP2922820B2 (en)
KR (1) KR100303690B1 (en)
CA (1) CA2147424C (en)
DE (1) DE69501799T2 (en)
ES (1) ES2113717T3 (en)
FR (1) FR2719243B1 (en)
TW (1) TW264407B (en)

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Publication number Priority date Publication date Assignee Title
FR2823560A1 (en) * 2001-04-13 2002-10-18 Beaudrey C S SOLID ELEMENT MANAGEMENT SYSTEM CIRCULATED IN A HEAT EXCHANGER FOR CLEANING THE SAME INCLUDING A SORTER AND SORTER FOR SUCH A MANAGEMENT INSTALLATION
AU2003217152B2 (en) * 2002-05-30 2008-03-06 Hydroball Technics Holdings Pte Ltd Cleaning System
WO2014046510A1 (en) * 2012-09-20 2014-03-27 정우산기 주식회사 Apparatus for recycling balls
EP3049195B1 (en) * 2013-10-22 2018-02-21 Bechtel Hydrocarbon Technology Solutions, Inc. Method and system for on-line cleaning pipes of a furnace
CN103769399B (en) * 2014-01-10 2016-01-20 甘肃富民生态农业科技有限公司 The cleaning device of volute wall and cleaning method thereof

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Publication number Priority date Publication date Assignee Title
JPS5135809A (en) * 1974-09-20 1976-03-26 Hitachi Ltd KAITENSHIKI HOSHU SOCHI
JPS5714193A (en) * 1980-06-30 1982-01-25 Hitachi Ltd Distributing and controlling method of cleaning balls
DE3316022C1 (en) * 1983-03-17 1984-08-30 Taprogge GmbH, 4000 Düsseldorf Method and arrangement for monitoring the operability of a device for cleaning the pipes of a power plant condenser system or the like.
FR2634672B1 (en) * 1988-07-27 1990-11-09 Technos Cie IMPROVEMENTS ON DEVICES FOR REMOVING WASTE BALLS FROM TUBULAR BEAM CLEANING PLANTS
IL94289A (en) * 1990-05-04 1992-12-01 Balls Technics Ltd Cleaning system for cleaning fluid-conducting tubing

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FR2719243A1 (en) 1995-11-03
EP0679854A1 (en) 1995-11-02
ES2113717T3 (en) 1998-05-01
KR100303690B1 (en) 2001-11-22
CA2147424C (en) 2004-06-29
DE69501799D1 (en) 1998-04-23
TW264407B (en) 1995-12-01
KR950031256A (en) 1995-12-18
FR2719243B1 (en) 1996-07-05
US5518068A (en) 1996-05-21
JP2922820B2 (en) 1999-07-26
DE69501799T2 (en) 1998-10-29
CA2147424A1 (en) 1995-10-29
JPH0849997A (en) 1996-02-20

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