EP0656050B2 - Gerüststoff für waschmittel - Google Patents
Gerüststoff für waschmittel Download PDFInfo
- Publication number
- EP0656050B2 EP0656050B2 EP93919063A EP93919063A EP0656050B2 EP 0656050 B2 EP0656050 B2 EP 0656050B2 EP 93919063 A EP93919063 A EP 93919063A EP 93919063 A EP93919063 A EP 93919063A EP 0656050 B2 EP0656050 B2 EP 0656050B2
- Authority
- EP
- European Patent Office
- Prior art keywords
- acids
- salts
- acid
- polyhydroxymonocarboxylic
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003599 detergent Substances 0.000 title claims description 32
- 239000002253 acid Substances 0.000 claims abstract description 98
- 150000003839 salts Chemical class 0.000 claims abstract description 67
- 150000007513 acids Chemical class 0.000 claims abstract description 53
- 239000000203 mixture Substances 0.000 claims abstract description 52
- 239000010457 zeolite Substances 0.000 claims abstract description 34
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 32
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 32
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 26
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 17
- 239000011734 sodium Substances 0.000 claims abstract description 16
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 15
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 14
- 229920001577 copolymer Polymers 0.000 claims abstract description 12
- 150000004760 silicates Chemical class 0.000 claims abstract description 12
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims abstract description 11
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims abstract description 10
- 229910052739 hydrogen Chemical group 0.000 claims abstract description 9
- 239000001257 hydrogen Chemical group 0.000 claims abstract description 9
- 125000000468 ketone group Chemical group 0.000 claims abstract description 7
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims abstract description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 4
- 229910000027 potassium carbonate Inorganic materials 0.000 claims abstract description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract 5
- 239000008139 complexing agent Substances 0.000 claims description 21
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 16
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims description 15
- 239000000344 soap Substances 0.000 claims description 14
- 239000007844 bleaching agent Substances 0.000 claims description 13
- 239000003945 anionic surfactant Substances 0.000 claims description 10
- 239000002736 nonionic surfactant Substances 0.000 claims description 9
- 229960005070 ascorbic acid Drugs 0.000 claims description 8
- 150000000996 L-ascorbic acids Chemical class 0.000 claims description 7
- 235000010323 ascorbic acid Nutrition 0.000 claims description 7
- 239000011668 ascorbic acid Substances 0.000 claims description 7
- 235000012208 gluconic acid Nutrition 0.000 claims description 6
- 239000008187 granular material Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 4
- 239000000174 gluconic acid Substances 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 238000001694 spray drying Methods 0.000 claims description 4
- 239000000470 constituent Substances 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 125000000864 peroxy group Chemical group O(O*)* 0.000 claims description 3
- 125000000129 anionic group Chemical group 0.000 claims description 2
- 238000001125 extrusion Methods 0.000 claims description 2
- 235000002639 sodium chloride Nutrition 0.000 claims 24
- 239000003795 chemical substances by application Substances 0.000 abstract description 40
- -1 monocarboxylic acid salts Chemical class 0.000 abstract description 30
- 238000005406 washing Methods 0.000 abstract description 25
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract description 18
- 239000012459 cleaning agent Substances 0.000 abstract description 13
- 239000004753 textile Substances 0.000 abstract description 6
- 229920005646 polycarboxylate Polymers 0.000 abstract description 4
- 150000002763 monocarboxylic acids Chemical class 0.000 abstract 2
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 abstract 1
- 150000003628 tricarboxylic acids Chemical class 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 22
- 239000000194 fatty acid Substances 0.000 description 22
- 229930195729 fatty acid Natural products 0.000 description 22
- 150000002191 fatty alcohols Chemical class 0.000 description 12
- 150000004665 fatty acids Chemical class 0.000 description 11
- 108090000790 Enzymes Proteins 0.000 description 10
- 102000004190 Enzymes Human genes 0.000 description 10
- 229940088598 enzyme Drugs 0.000 description 10
- 150000001298 alcohols Chemical class 0.000 description 8
- 239000002956 ash Substances 0.000 description 8
- 239000004744 fabric Substances 0.000 description 8
- 239000004094 surface-active agent Substances 0.000 description 8
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 229920002472 Starch Polymers 0.000 description 6
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 6
- 239000012190 activator Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 235000019698 starch Nutrition 0.000 description 6
- 239000003760 tallow Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000006260 foam Substances 0.000 description 5
- 239000003112 inhibitor Substances 0.000 description 5
- 229920000058 polyacrylate Polymers 0.000 description 5
- 150000004671 saturated fatty acids Chemical class 0.000 description 5
- 239000008107 starch Substances 0.000 description 5
- 238000006277 sulfonation reaction Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 108091005804 Peptidases Proteins 0.000 description 4
- 102000035195 Peptidases Human genes 0.000 description 4
- 239000004365 Protease Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000004115 Sodium Silicate Substances 0.000 description 4
- 125000005907 alkyl ester group Chemical group 0.000 description 4
- 150000008051 alkyl sulfates Chemical class 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 229950006191 gluconic acid Drugs 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- 238000006386 neutralization reaction Methods 0.000 description 4
- 235000003441 saturated fatty acids Nutrition 0.000 description 4
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 4
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 4
- 238000005303 weighing Methods 0.000 description 4
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 159000000007 calcium salts Chemical class 0.000 description 3
- 239000003240 coconut oil Substances 0.000 description 3
- 235000019864 coconut oil Nutrition 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 150000002431 hydrogen Chemical group 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 229940055577 oleyl alcohol Drugs 0.000 description 3
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 3
- 239000003346 palm kernel oil Substances 0.000 description 3
- 235000019865 palm kernel oil Nutrition 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 229910052615 phyllosilicate Inorganic materials 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 229910052911 sodium silicate Inorganic materials 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000019635 sulfation Effects 0.000 description 3
- 238000005670 sulfation reaction Methods 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 239000004435 Oxo alcohol Substances 0.000 description 2
- 235000019482 Palm oil Nutrition 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000013065 commercial product Substances 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 150000005690 diesters Chemical class 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 150000002596 lactones Chemical class 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 150000004702 methyl esters Chemical class 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000002540 palm oil Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- 159000000001 potassium salts Chemical class 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 150000003138 primary alcohols Chemical class 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
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- 239000001509 sodium citrate Substances 0.000 description 2
- UPMFZISCCZSDND-JJKGCWMISA-M sodium gluconate Chemical compound [Na+].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O UPMFZISCCZSDND-JJKGCWMISA-M 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical compound [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 150000003470 sulfuric acid monoesters Chemical class 0.000 description 2
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- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- LYPVKWMHGFMDPD-UHFFFAOYSA-N 1,5-diacetyl-1,3,5-triazinane-2,4-dione Chemical compound CC(=O)N1CN(C(C)=O)C(=O)NC1=O LYPVKWMHGFMDPD-UHFFFAOYSA-N 0.000 description 1
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N 1-Tetradecanol Natural products CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- NSMMFSKPGXCMOE-UHFFFAOYSA-N 2-[2-(2-sulfophenyl)ethenyl]benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1C=CC1=CC=CC=C1S(O)(=O)=O NSMMFSKPGXCMOE-UHFFFAOYSA-N 0.000 description 1
- IKOKHHBZFDFMJW-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-3-(2-morpholin-4-ylethoxy)pyrazol-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C=1C(=NN(C=1)CC(=O)N1CC2=C(CC1)NN=N2)OCCN1CCOCC1 IKOKHHBZFDFMJW-UHFFFAOYSA-N 0.000 description 1
- XDVOLDOITVSJGL-UHFFFAOYSA-N 3,7-dihydroxy-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound O1B(O)OB2OB(O)OB1O2 XDVOLDOITVSJGL-UHFFFAOYSA-N 0.000 description 1
- REJHVSOVQBJEBF-OWOJBTEDSA-N 5-azaniumyl-2-[(e)-2-(4-azaniumyl-2-sulfonatophenyl)ethenyl]benzenesulfonate Chemical class OS(=O)(=O)C1=CC(N)=CC=C1\C=C\C1=CC=C(N)C=C1S(O)(=O)=O REJHVSOVQBJEBF-OWOJBTEDSA-N 0.000 description 1
- XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 241000193422 Bacillus lentus Species 0.000 description 1
- 241000194108 Bacillus licheniformis Species 0.000 description 1
- 244000063299 Bacillus subtilis Species 0.000 description 1
- 235000014469 Bacillus subtilis Nutrition 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 102000005701 Calcium-Binding Proteins Human genes 0.000 description 1
- 108010045403 Calcium-Binding Proteins Proteins 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 102000005575 Cellulases Human genes 0.000 description 1
- 108010084185 Cellulases Proteins 0.000 description 1
- RGHNJXZEOKUKBD-SQOUGZDYSA-M D-gluconate Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O RGHNJXZEOKUKBD-SQOUGZDYSA-M 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical group [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 description 1
- 239000002211 L-ascorbic acid Substances 0.000 description 1
- 235000000069 L-ascorbic acid Nutrition 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- RXTCWPTWYYNTOA-UHFFFAOYSA-N O=P1OCCCCCO1 Chemical compound O=P1OCCCCCO1 RXTCWPTWYYNTOA-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 235000019483 Peanut oil Nutrition 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 239000004280 Sodium formate Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 241000187392 Streptomyces griseus Species 0.000 description 1
- 108090000787 Subtilisin Proteins 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 235000019486 Sunflower oil Nutrition 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 244000274883 Urtica dioica Species 0.000 description 1
- 235000009108 Urtica dioica Nutrition 0.000 description 1
- 238000001792 White test Methods 0.000 description 1
- 239000001083 [(2R,3R,4S,5R)-1,2,4,5-tetraacetyloxy-6-oxohexan-3-yl] acetate Substances 0.000 description 1
- UAOKXEHOENRFMP-ZJIFWQFVSA-N [(2r,3r,4s,5r)-2,3,4,5-tetraacetyloxy-6-oxohexyl] acetate Chemical compound CC(=O)OC[C@@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)C=O UAOKXEHOENRFMP-ZJIFWQFVSA-N 0.000 description 1
- 238000005903 acid hydrolysis reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
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- 150000001299 aldehydes Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000005904 alkaline hydrolysis reaction Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 229940025131 amylases Drugs 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 238000004380 ashing Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000001045 blue dye Substances 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 235000010338 boric acid Nutrition 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229960002645 boric acid Drugs 0.000 description 1
- 150000001639 boron compounds Chemical class 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 239000010636 coriander oil Substances 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000007257 deesterification reaction Methods 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 150000004683 dihydrates Chemical class 0.000 description 1
- FSBVERYRVPGNGG-UHFFFAOYSA-N dimagnesium dioxido-bis[[oxido(oxo)silyl]oxy]silane hydrate Chemical compound O.[Mg+2].[Mg+2].[O-][Si](=O)O[Si]([O-])([O-])O[Si]([O-])=O FSBVERYRVPGNGG-UHFFFAOYSA-N 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 229940050410 gluconate Drugs 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 159000000011 group IA salts Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000010699 lard oil Substances 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 150000005673 monoalkenes Chemical class 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- 125000004573 morpholin-4-yl group Chemical group N1(CCOCC1)* 0.000 description 1
- 229940043348 myristyl alcohol Drugs 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N n-hexadecyl alcohol Natural products CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- SXLLDUPXUVRMEE-UHFFFAOYSA-N nonanediperoxoic acid Chemical compound OOC(=O)CCCCCCCC(=O)OO SXLLDUPXUVRMEE-UHFFFAOYSA-N 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 150000004967 organic peroxy acids Chemical class 0.000 description 1
- VGTPKLINSHNZRD-UHFFFAOYSA-N oxoborinic acid Chemical compound OB=O VGTPKLINSHNZRD-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- BXNRKCXZILSQHE-UHFFFAOYSA-N propane-1,2,3-triol;sulfuric acid Chemical class OS(O)(=O)=O.OCC(O)CO BXNRKCXZILSQHE-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000010499 rapseed oil Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 1
- 235000019254 sodium formate Nutrition 0.000 description 1
- 239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- 235000019351 sodium silicates Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 1
- IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/02—Preparation in the form of powder by spray drying
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/1273—Crystalline layered silicates of type NaMeSixO2x+1YH2O
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
Definitions
- the invention relates to a detergent and cleaning agent, the phosphate-free Contains builders and complexing agents, as well as a phosphate-free combination of builders and a process for their manufacture.
- phosphate substitutes in detergents and cleaning agents especially zeolite, especially zeolite NaA, and mixtures of zeolite with alkali silicates and carbonates as well as polymeric polycarboxylates used.
- complexing agents such as the salts of nitrilotriacetic acid (NTA), ethylenediaminetetraacetic acid (EDTA) and phosphonic acids.
- NTA nitrilotriacetic acid
- EDTA ethylenediaminetetraacetic acid
- the mostly selective complexing agents have the task Heavy metal ions, which already have a very negative impact on traces may have to eliminate the washing process (Ullmann, 1987, vol. 8, pages 351 to 354).
- the phosphonates are known to also precipitate poorly soluble calcium salts and thus that of poorly soluble Calcium salts caused incrustation and graying of the tissue counteract ("use of phosphonates in liquid detergents", M. Paladini, G. Schnorbus, Soap-Oil-Fat-Waxes, 115th year (1989), Pages 508 to 511). Finally, the combined use of phosphonates works and copolymers based on acrylic acid and maleic acid in comparison with formulations that contain only one of these two components, a higher degree of whiteness of the textiles ("use of phosphonates in Household detergents with a low phosphorus content (1%) ", M. Paladini, G. Schnorbus, Seifen- ⁇ le-Fette-Wwachs, 114th year (1988), pages 756 to 760).
- European patent application 291 869 describes phosphate-free building material combinations from zeolite, aminoalkane polyphosphonate, 1-hydroxyethane-1,1-diphosphonate (HEDP) and polymeric polycarboxylate, with certain Weight ratios of the last three components related to synergism the prevention of the formation of fiber incrustations.
- European patent application 448 298 describes detergents which are known as Builders zeolite and 3 to 18 wt .-% of the complexing agent sodium citrate contain, the ratio of zeolite (calculated as anhydrous active substance) to sodium citrate (calculated as dihydrate) is 2.5: 1 to 6: 1.
- the agents have a washing performance that matches the washing performance of agents that are comparable as builders zeolite and polyacrylates contain.
- phosphate-free agents which certain complexing Polyhydroxycarboxylic acids or their salts or mixtures thereof but no (co) polymeric polycarboxylic acids or Polycarboxylic acid salts included, have a primary wash capacity that matches the primary wash capacity citrate-containing agent is comparable, the secondary washing ability These agents have great advantages over agents containing citrate having.
- the invention relates in a first embodiment to a phosphate-free washing and cleaning agent, in particular a textile washing agent, which contains zeolite and / or crystalline phyllosilicates of the general formula (I) NaMSi x O 2x + 1 .yH 2 O, where M is sodium or Hydrogen means x is a number from 1.9 to 4 and y is a number from 0 to 20, and as complexing agent polyhydroxymonocarboxylic acids or polyhydroxymonocarboxylic acid salts with 4 to 6 carbon atoms and at least 3 hydroxyl groups per molecule or mixtures of these acids and / or Salts but does not contain (co) polymeric polycarboxylic acids or polycarboxylic acid salts.
- a textile washing agent which contains zeolite and / or crystalline phyllosilicates of the general formula (I) NaMSi x O 2x + 1 .yH 2 O, where M is sodium or Hydrogen means x is a number from 1.9 to
- the content of the builders in the builders zeolite and / or crystalline phyllosilicates of the general formula (I) is 15 to 60% by weight, the weight ratio builders to polyhydroxymonocarboxylic acid or polyhydroxymonocarboxylic acid salt or mixtures of these acids and / or salts 30: 1 is up to 1: 1.
- the invention relates to a builder combination which comprises zeolite and / or crystalline phyllosilicates of the general formula (I) NaMSi x O 2x + 1 .yH 2 O, where M is sodium or hydrogen, x is a number of 1, 9 to 4 and y is a number from 0 to 20, and as complexing agents polyhydroxymonocarboxylic acids or polyhydroxymonocarboxylic acid salts with 4 to 6 carbons and at least 3 hydroxyl groups per molecule or mixtures of these acids and / or salts but no (co) polymeric polycarboxylic acids or Contain polycarboxylic acid salts, the weight ratio of builders to polyhydroxymonocarboxylic acid or polyhydroxymonocarboxylic acid salt or mixtures of these acids and / or salts being 30: 1 to 1: 1.
- polyhydroxymonocarboxylic acids or polyhydroxymonocarboxylic acid salts have one keto group per molecule
- these Polyhydroxymonocarboxylic acids preferably form lactones.
- Preferred polyhydroxymonocarboxylic acids or polyhydroxymonocarboxylic acid salts are those which contain 4 to 6 carbon atoms and on each carbon atom that bears no carboxyl group or keto group, have a hydroxyl group.
- polyhydroxymonocarboxylic acids and / or polyhydroxymonocarboxylic acid salts with 4 carbon atoms and 3 hydroxyl groups, with 5 Carbon atoms and 4 hydroxyl groups and with 6 carbon atoms and 4 or 5 hydroxy groups are preferred.
- Particularly advantageous properties have polyhydroxymonocarboxylic acids or polyhydroxymonocarboxylic acids with 6 carbon atoms and 5 hydroxyl groups, such as D-gluconic acid (also Called maltonic acid or dextronic acid) or their salts, and polyhydroxymonocarboxylic acids or polyhydroxymonocarboxylic acid salts with 6 carbon atoms, a keto group and 4 hydroxyl groups, such as L-ascorbic acid, which is present as a lactone, and L ascorbic acid salts.
- Mixtures of acids can also be used and / or the salts are used, the latter preferably in the form of their sodium or potassium salts
- the zeolites are used in the usual hydrated, finely crystalline form. Their water content is preferably between 19 and 22% by weight. They have practically no particles larger than 30 ⁇ m and exist preferably at least 80% of particles smaller than 10 microns in size. Your calcium binding capacity, according to the information given in German patent application 24 12 837 is in the range from 100 to 200 mg CaO / g
- the zeolite NaA is particularly suitable, as is the zeolite NaX and mixtures of NaA and NaX and weight ratios relating to the zeolite builder are within the scope of this invention - unless otherwise stated - based on anhydrous active substance.
- Suitable substitutes or partial substitutes for phosphates and zeolites are crystalline, layered sodium silicates of the general formula (I) NaMSi x O 2x + 1 .yH 2 O, where M is sodium or hydrogen, x is a number from 1.9 to 4 and y is a number of Is 0 to 20 and preferred values for x are 2, 3 or 4.
- Such crystalline layered silicates are described, for example, in European patent application 164 514.
- Preferred crystalline layered silicates of the formula (I) are those in which M represents sodium and x assumes the values 2 or 3. In particular, both ⁇ - and ⁇ -sodium disilicates Na 2 Si 2 O 5 .yH 2 O are preferred.
- the agents or builders combinations according to the invention can also be mixtures of zeolite and the crystalline ones Layered silicates of the general formula (I) contain, the mixing ratio is arbitrary.
- zeolite is used either alone or in a zeolite to crystalline layered silicate (I) weight ratio of 10: 1 to 1: 3 and in particular from 3: 1 to 1: 1.
- the agents or builders combinations according to the invention contain the builders zeolite and / or crystalline layered silicates (I) and the complexing agents polyhydroxymonocarboxylic acid or polyhydroxymonocarboxylic acid salt or mixtures of these acids and / or salts advantageously in a weight ratio of 20 1 to 1: 1, preferably from 10: 1 to 1.5: 1 and in particular from 5: 1 to 1.5: 1.
- the detergents and cleaning agents according to the invention are preferably located in granular form.
- Advantageous agents contain 15 to 50% by weight of zeolite and / or crystalline layered silicates (I) and 1 to 20 wt .-% polyhydroxymonocarboxylic acids or polyhydroxymonocarboxylic acid salts with 4 to 6 carbon atoms and at least 3 hydroxyl groups per molecule, such polyhydroxymonocarboxylic acids or polyhydroxymonocarboxylic acid salts are preferred in which any carbon atom that has no carboxyl group or keto group carries, has a hydroxy group.
- such agents have advantages, which 2 to 15 wt .-% and preferably 4 to 12 wt .-% gluconic acid or gluconic acid salt, ascorbic acid or Contain ascorbic acid salt or mixtures of these acids and / or salts.
- the detergents and cleaning agents according to the invention can also contain other customary builders and complexing agents, for example phosphonates, the polycarboxylic acids used preferably in the form of their sodium salts, such as citric acid, adipic acid, succinic acid, glutaric acid, aminocarboxylic acids, nitrilotriacetic acid (NTA), if such use is not objectionable for ecological reasons, but no (co-) polymeric polycarboxylic acids or polycarboxylates contain.
- these additional builders and complexing agents do not carry on to significantly improve the secondary washing ability.
- Phosphonates preferably the neutral sodium salts of, for example, 1-hydroxyethane-1,1-diphosphonate and diethylene triamine pentamethylene phosphonate are often used as enzyme or bleach stabilizers used in amounts of 0.1 to 1.5 wt .-%.
- the secondary washing power of the agents according to the invention is due to the use of the polyhydroxymonocarboxylic acids or their salts increased so that the use of phosphonates without sacrificing performance can be dispensed with. Therefore, agents that do not contain phosphonates are preferred.
- the agents according to the invention act as complexing agents Polyhydroxymonocarboxylic acids, polyhydroxymonocarboxylic acid salts or mixtures of these, compared to one Agent that instead of the complexing agent according to the invention polyhydroxytricarboxylic acids or polyhydroxytricarboxylic acid salts such as citric acid or Citrate contains a significant amount with the same primary washing performance have a higher secondary washing effect.
- polyhydroxytricarboxylic acids or polyhydroxytricarboxylic acid salts such as citric acid or Citrate contains a significant amount with the same primary washing performance have a higher secondary washing effect.
- Citric acid or citrate are not significant Improvements in secondary washing ability achieved, so that particularly preferred Agents are free from citric acid or citrate.
- the builders combinations according to the invention can also contain further constituents contain, for example inorganic, alkaline in water or neutral reacting salts.
- the builders combinations with liquid to wax-like components for example silicone oils and paraffin oils, but preferably with non-ionic surfactants are sprayed.
- the agents according to the invention known additives commonly used in washing and cleaning agents, for example surfactants, bleaches and bleach activators, in Water alkaline salts, solubility improvers like conventional ones Hydrotropes or polyalkylene glycols, for example polyethylene glycols, Foam inhibitors, optical brighteners, enzymes, enzyme stabilizers, small amounts of neutral filling salts as well as colors and fragrances, opacifiers or pearlescent agents.
- surfactants for example surfactants, bleaches and bleach activators
- solubility improvers like conventional ones Hydrotropes or polyalkylene glycols, for example polyethylene glycols, Foam inhibitors, optical brighteners, enzymes, enzyme stabilizers, small amounts of neutral filling salts as well as colors and fragrances, opacifiers or pearlescent agents.
- the content of the agent in anionic and nonionic surfactants including Soap is preferably 10 to 35% by weight, advantageously 12 to 28% by weight and in particular 15 to 25% by weight.
- surfactants of the sulfonate type are C 9 -C 13 alkylbenzenesulfonates, olefin sulfonates, ie mixtures of alkene and hydroxyalkanesulfonates and disulfonates such as are obtained, for example, from C 12 -C 18 monoolefins with a terminal or internal double bond by sulfonating with gaseous Sulfur trioxide and subsequent alkaline or acidic hydrolysis of the sulfonation products is considered.
- alkanesulfonates obtained from C 12 -C 18 alkanes, for example by sulfochlorination or sulfoxidation with subsequent hydrolysis or neutralization.
- esters of ⁇ -sulfofatty acids are also suitable.
- esters of ⁇ -sulfo fatty acids which are produced by ⁇ -sulfonation of the alkyl esters of fatty acids of plant and / or animal origin with 8 to 20 C atoms in the fatty acid molecule and subsequent neutralization to form water-soluble mono-salts are suitable.
- These are preferably the ⁇ -sulfonated esters of hydrogenated coconut, palm kernel or tallow fatty acids, and sulfonation products of unsaturated fatty acids, for example oleic acid, are also present in small amounts, preferably in amounts not above about 2 to 3% by weight could be.
- ⁇ -sulfofatty acid alkyl esters are preferred which have an alkyl chain with no more than 4 carbon atoms in the ester group, for example methyl esters, ethyl esters, propyl esters and butyl esters.
- the methyl esters of ⁇ -sulfofatty acids (MES) are used with particular advantage.
- Further suitable anionic surfactants are the ⁇ -sulfofatty acids obtainable by ester cleavage of the ⁇ -sulfofatty acid alkyl esters or their di-salts.
- the mono-salts of the ⁇ -sulfofatty acid alkyl esters are obtained in their industrial production as an aqueous mixture with limited amounts of di-salts. Mixtures of mono-salts and di-salts with other surfactants, for example with alkylbenzenesulfonate, are also preferred.
- Suitable anionic surfactants are sulfonated fatty acid glycerol esters.
- Fatty acid glycerol esters are the mono-, di- and triesters as well as their To understand mixtures as they are made by esterification through a monoglycerin with 1 to 3 moles of fatty acid or in the transesterification of Triglycerides with 0.3 to 2 moles of glycerin can be obtained.
- Preferred sulfated Fatty acid glycerol esters are the sulfonation products of saturated Fatty acids with 6 to 22 carbon atoms, for example caproic acid, Caprylic acid, capric acid, myristic acid, lauric acid, palmitic acid, Stearic acid or behenic acid.
- Feedstocks are palm oil, palm kernel oil, palm stearin, olive oil, Rape oil, coriander oil, sunflower oil, cottonseed oil, peanut oil, linseed oil, Lard oil or lard. Because of their high natural content saturated fatty acids, however, has proven to be particularly advantageous from coconut oil, palm kernel oil or beef tallow.
- the sulfation saturated fatty acids with 6 to 22 carbon atoms or mixtures from fatty acid glycerol esters with iodine numbers less than 5, the fatty acids containing 6 to 22 carbon atoms is preferably carried out by reaction with gaseous sulfur trioxide and subsequent neutralization with aqueous bases, as described in the international patent application WO 91/9009 is specified.
- the sulfonation products are a complex mixture that essentially Mono-, di- and triglyceride sulfonates with ⁇ and / or internal Contains sulfonic acid grouping.
- Sulfonated form as by-products Fatty acid salts, glyceride sulfates, glycerine sulfates, glycerin and soaps. Goes with the sulfation of saturated fatty acids or hydrogenated ones Fatty acid glycerol ester mixtures, so the proportion of ⁇ -sulfonated Depending on the procedure, fatty acid disalts can be up to about 60 % By weight.
- alkanesulfonates obtained from C 12 -C 18 alkanes, for example by sulfochlorination or sulfoxidation with subsequent hydrolysis or neutralization.
- the sulfonate group is statistically distributed over the entire carbon chain, with the secondary alkanesulfonates predominating.
- Suitable surfactants of the sulfate type are the sulfuric acid monoesters from primary alcohols of natural and synthetic origin, in particular from fatty alcohols, for example from tallow fatty alcohol, oleyl alcohol, lauryl, myristyl, cetyl or stearyl alcohol, or the C 10 -C 20 oxo alcohols, and those secondary alcohols of this chain length.
- Preferred fatty alkyl sulfates are derived from fatty alcohol mixtures obtained from coconut oil, palm oil and palm kernel oil, which may additionally contain fractions of unsaturated alcohols, for example oleyl alcohol. Mixtures in which the proportion of the alkyl radicals is 50 to 70% by weight on C 12 , 18 to 30% by weight on C 14 , 5 to 15% by weight on C 16 , are preferred 3% by weight on C 10 and less than 10% by weight on C 18 are distributed.
- anionic surfactants are the salts of alkylsulfosuccinic acid, which are also referred to as sulfosuccinates or as sulfosuccinic acid esters and which are monoesters and / or diesters of sulfosuccinic acid with alcohols, preferably fatty alcohols and in particular ethoxylated fatty alcohols.
- Preferred sulfosuccinates contain C 8 to C 18 fatty alcohol residues or mixtures thereof.
- Particularly preferred sulfosuccinates contain a fatty alcohol residue which is derived from ethoxylated fatty alcohols, which in themselves are nonionic surfactants (description see below).
- sulfosuccinates whose fatty alcohol residues are derived from ethoxylated fatty alcohols with a narrow homolog distribution are particularly preferred.
- Preferred granular detergents and cleaning agents contain as anionic Surfactants alkyl benzene sulfonates and / or alkyl sulfate, preferably fatty alkyl sulfate, and / or sulfonated fatty acid glycerol esters, the weight ratio sulfonated fatty acid glycerol esters to alkylbenzenesulfonate and / or Alkyl sulfate is 1: 9 to 4: 1 and in particular 2: 5 to 2: 1.
- Suitable anionic surfactants are, in particular, soaps, preferably in amounts from 0.2 to 8 and in particular from 0.5 to 5% by weight.
- Saturated fatty acid soaps are suitable, such as the salts of lauric acid, myristic acid, palmitic acid or stearic acid, and in particular soap mixtures derived from natural fatty acids, for example coconut, palm kernel or tallow fatty acids.
- soap mixtures are preferred which are composed of 50 to 100% by weight of saturated C 12 -C 24 fatty acid soaps and 0 to 50% by weight of oleic acid soap.
- the anionic surfactants can be in the form of their sodium, potassium or ammonium salts as well as soluble salts of organic bases, such as mono-, di- or Triethanolamine.
- the anionic surfactants are preferably in Form of their sodium or potassium salts.
- the granular ones contain Detergents and cleaning agents in addition to the anionic surfactants nonionic surfactants, preferably in amounts of 1 to 15% by weight, in particular in amounts of 2 to 12% by weight.
- the nonionic surfactants used are preferably liquid ethoxylated and / or propoxylated alcohols which are derived from primary alcohols preferably having 8 to 18 carbon atoms and an average of 1 to 12 mol of alkylene oxide, in which the alcohol radical can be linear or methyl-branched in the 2-position, or linear and May contain methyl-branched radicals in the mixture, as they are usually present in oxo alcohol radicals.
- linear residues of alcohols of native origin with 12 to 18 carbon atoms such as, for example, coconut oil, tallow oil or oleyl alcohol, are particularly preferred.
- the degrees of ethoxylation given represent statistical averages, that are an integer or a fraction for a specific product can.
- Preferred alcohol ethoxylates have a narrow homolog distribution on (narrow range ethoxylates, NRE).
- NRE narrow range ethoxylates
- alcohol ethoxylates preferred which have an average of 2 to 8 ethylene oxide groups.
- alkyl glycosides of the general formula RO (G) x can also be used as further nonionic surfactants, in which R denotes a primary straight-chain or aliphatic radical with 8 to 22, preferably 12 to 18, carbon atoms branched in the 2-position and G denotes the symbol which stands for a glycose unit with 5 or 6 carbon atoms, preferably for glucose.
- the degree of oligomerization x which indicates the distribution of monoglycosides and oligoglycosides, is any number between 1 and 10.
- Suitable ingredients of the granular agents are water-soluble inorganic salts such as bicarbonates, carbonates, amorphous or crystalline silicates or mixtures of these;
- alkali carbonate and alkali silicate especially sodium silicate with a molar ratio Na 2 0: Si0 2 from 1: 1 to 1: 4.5, preferably from 1: 2 to 1: 3.5, are used.
- the sodium silicate content of the agents is generally up to 10% by weight, preferably between 2 and 8% by weight and in particular 2 to 5% by weight.
- bleaching agents which can be used are, for example, sodium percarbonate, peroxypyrophosphates, citrate perhydrates and H 2 O 2 -producing peracid salts or peracids, such as perbenzoates, peroxaphthalates, diperazelaic acid or diperdodecanedioic acid.
- the bleaching agent content of the agents is preferably 5 to 25% by weight and in particular 10 to 20% by weight, with perborate monohydrate being advantageously used. Since, as is known, peroxy compounds react with ascorbic acid and there is a loss of active oxygen, agents which contain ascorbic acid or ascorbic acid salts are preferably free from peroxy bleaching agents.
- bleach activators can be incorporated into the preparations.
- these are N-acyl or O-acyl compounds which form organic peracids with H 2 O 2 , preferably N, N'-tetraacylated diamines, furthermore carboxylic acid anhydrides and esters of polyols such as glucose pentaacetate.
- the bleach activators contain bleach activators in the usual range, preferably between 1 and 10% by weight and in particular between 3 and 8% by weight.
- Particularly preferred bleach activators are N, N, N ', N'-tetraacetylethylenediamine and 1,5-diacetyl-2,4-dioxo-hexahydro-1,3,5-triazine.
- Graying inhibitors have the task of detaching from the fiber Keep dirt suspended in the fleet and prevent graying.
- Water-soluble colloids of mostly organic nature are suitable for this, for example Glue, gelatin, salts of ether carboxylic acids or ether sulfonic acids Starch or the cellulose or salts of acidic sulfuric acid esters Cellulose or starch. Also water-soluble containing acidic groups Polyamides are suitable for this purpose.
- soluble ones Use starch preparations and other starch products than those mentioned above, e.g. degraded starch, aldehyde starches, etc. Polyvinylpyrrolidone is also useful.
- carboxymethyl cellulose Na salt
- Methyl cellulose methyl hydroxyethyl cellulose and their mixtures and polyvinyl pyrrolidone, for example in amounts of 0.1 to 5% by weight on the means.
- the foaming power of the surfactants can be increased or decreased by combining suitable types of surfactants; a reduction can also be achieved by adding non-surfactant-like substances.
- a reduced foaming power, which is desirable when working in machines, is often achieved by combining different types of surfactants, for example sulfates and / or sulfonates with nonionic surfactants and / or with soaps.
- soaps the foam-suppressing effect increases with the degree of saturation and the C number of the fatty acid salt. Soaps of natural or synthetic origin which contain a high proportion of C 18 -C 24 fatty acids are therefore suitable as foam-inhibiting soaps.
- Suitable non-surfactant-like foam inhibitors are, for example, organopolysiloxanes and their mixtures with microfine, optionally silanized silica, and paraffins, waxes, microcrystalline waxes and their mixtures with silanized silica. Mixtures of various foam inhibitors are also advantageously used, for example those made of silicone, paraffins or waxes.
- the foam inhibitors are preferably bound to a granular, water-soluble or dispersible carrier substance.
- Enzymes come from the class of proteases, lipases, amylases, Cellulases or their mixtures in question. Are particularly well suited Strains of bacteria or fungi such as Bacillus subtilis, Bacillus licheniformis and Streptomyces griseus derived enzymatic agents. Preferably become proteases of the subtilisin type and in particular proteases that are obtained from Bacillus lentus. Their share can be about 0.2 up to about 2% by weight.
- the enzymes can be adsorbed on carriers and / or embedded in coating substances to prevent them from premature decomposition to protect.
- the agents can contain enzyme stabilizers.
- enzyme stabilizers For example, 0.5 to 1% by weight sodium formate can be used. It is also possible to use proteases which are stabilized with soluble calcium salts and a calcium content of preferably about 1.2% by weight, based on the enzyme.
- boron compounds for example boric acid, boron oxide, borax and other alkali metal borates such as the salts of orthoboric acid (H 3 BO 3 ), metaboric acid (HB0 2 ) and pyrobic acid (tetraboric acid H 2 B 4 O 7 ), is particularly advantageous.
- the agents can contain derivatives of diaminostilbenedisulfonic acid or its alkali metal salts. Suitable are, for example, salts of 4,4'-bis (2-anilino-4-morpholino-1,3,5-triazin-6-yl-amino) stilbene-2,2'-disulfonic acid or compounds of the same structure which are used instead of Morpholino group carry a diethanolamino group, a methylamino group, anilino group or a 2-methoxyethylamino group.
- Brighteners of the substituted 4,4'-distyryl-diphenyl type can also be present, for example the compound 4,4'-bis (4-chloro-3-sulfostyryl) diphenyl. Mixtures of the aforementioned brighteners can also be used. It has also been found that uniform white granules are obtained if, apart from the customary brighteners, the agents are used in customary amounts, for example between 0.1 and 0.5% by weight, preferably between 0.1 and 0.3% by weight. , also contains small amounts, for example 10 -6 to 10 -3 % by weight, preferably around 10 -5 % by weight, of a blue dye.
- a particularly preferred dye is Tinolux (R) (commercial product from Ciba-Geigy).
- the granular washing and cleaning agents according to the invention can be a Have bulk density between about 300 and 1100 g / l. Thereby granules preferred, which has a bulk density above 450 g / l, in particular have between 500 and 1100 g / l.
- Detergents and cleaning agents can be used in a conventional manner, for example by mixing, granulating, extruding and / or by Spray drying an aqueous slurry and optionally subsequent Admixture of temperature-sensitive components can be produced.
- detergents and cleaning agents they can be manufactured separately Builders combinations in the form of a spray-dried or granulated Compounds as an admixture to other granular components of the detergent and cleaning agent are used. It is the same possible, the builders and complexing agents individually in a conventional manner To incorporate into the funds in a manner and in any order.
- Granular detergents of the following composition were prepared and tested in a conventional manner by spray drying.
- the constituents perborate, bleach activator and enzyme granulate and the complexing agents including the copolymeric polyacrylate and 1-hydroxyethane-1,1-diphosphonate (HEDP) were subsequently mixed in Comparative Example C3.
- HEDP 1-hydroxyethane-1,1-diphosphonate
- the test was carried out under practical conditions in household washing machines. For this, the machines charged with 3.5 kg clean laundry and 0.5 kg test fabric, some of the test fabric with usual test soiling was impregnated (for testing the primary washing ability) and consisted partly of white fabric (to check the secondary washing ability). Quarreling from standardized was used as white test fabric Cotton fabric (Krefeld laundry research institute; WFK), nettle (BN), knitwear (cotton jersey; B) and terry toweling (FT) used.
- WFK white test fabric
- BN nettle
- knitwear cotton jersey
- FT terry toweling
- Washing conditions tap water of 23 ° d (equivalent to 230 mg CaO / l), used Amount of detergent per detergent and machine 146 g, washing temperature 25 to 90 ° C (heating up time 60 minutes, 15 minutes at 90 ° C), liquor ratio (kg of laundry: liters of wash water in the main wash) 1: 5,7, rinse 4 times with Tap water, centrifuging and drying.
- the total incrustation was therefore used as a control determined (1st weighing of the untreated tissue, 2nd weighing of the Tissue after 25 washing cycles, 3rd weighing of the tissue after extraction with EDTA, 4. Determination of the so-called "soluble ash” from the difference weighing 2nd and 3rd, 5th ashing of the extracted tissue for determination the remaining ash, 6. Determination of the total incrustation (sum of soluble Ash and residual ash)).
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Description
Basis-Zusammensetzung | (in Gew.-Teilen) | |
Natriumdodecylbenzolsulfonat | 7,5 | |
C12-C18-Fettsäureseife | 1,5 | |
C12-C18-Fettalkohol mit 5 E0 | 4,5 | |
Talgfettalkohol mit 5 E0 | 0,8 | |
Zeolith | 25,0 | |
Natriumcarbonat | 13,2 | |
Natriumsilikat (1:2) | 3,5 | |
Magnesiumsilikat | 1,0 | |
Perborattetrahydrat | 25,0 | |
Tetraacetylethylendiamin | 3,0 | |
CMC/MC | 0,8 | |
opt. Aufheller | 0,2 | |
Enzym-Granulat | 1,5 | |
Silikonöl | 0,5 | |
Wasser | 7,5 | |
Natriumsulfat (und andere Salze aus Lösungen) | 4,0 | |
Zusatz an Komplexbildnern: | ||
V1 | Trinatriumcitrat-dihydrat | 5,0 |
M1/1 | Ascorbinsäure-natriumsalz | 5,0 |
M2/1 | D-Gluconsäure-natriumsalz | 5,0 |
V2 | Trinatriumcitrat-dihydrat | 10,0 |
M1/2 | Ascorbinsäure-natriumsalz | 10,0 |
M2/2 | D-Gluconsäure-natriumsalz | 10,0 |
V3 | Sokalan CP5 (R) (Copolymeres der Acrylsäure mit Maleinsäure, Handelsprodukt der BASF) | 4,0 |
HEDP | 0,5 |
FT | BN | B | WFK | Ø | |
Anfangswert | 0,25 | 0,46 | 0,19 | 0,99 | 0,47 |
V1 | 2,75 | 4,61 | 1,94 | 8,83 | 4,53 |
M1/1 | 1,29 | 2,26 | 1,17 | 5,38 | 2,52 |
M2/1 | 0,85 | 1,21 | 0,32 | 3,76 | 1,53 |
V2 | 2,73 | 3,69 | 1,70 | 7,81 | 3,98 |
M1/2 | 0,82 | 1,43 | 0,72 | 4,40 | 1,84 |
M2/2 | 0,74 | 0,90 | 0,29 | 3,15 | 1,27 |
V3 | 1,22 | 1,76 | 2,34 | 6,09 | 2,85 |
Gew.-% Gesamtinkrustation | |||
B | WFK | Ø | |
Anfangswert | 1,99 | 2,69 | 2,34 |
V1 | 9,10 | 15,44 | 12,52 |
M1/1 | 5,33 | 9,46 | 7,39 |
M2/1 | 2,71 | 6,70 | 4,70 |
V2 | 7,90 | 13,60 | 10,75 |
M1/2 | 3,65 | 8,01 | 5,83 |
M2/2 | 2,34 | 5,48 | 3,91 |
V3 | 3,78 | 8,81 | 6,29 |
Claims (17)
- Wasch- und Reinigungsmittel, insbesondere ein Textilwaschmittel, enthaltend als phosphatfreie Gerüststoffe Zeolith und/oder kristalline Schichtsilikate der allgemeinen Formel (I) NaMSixO2x+1·yH2O, wobei M Natrium oder Wasserstoff bedeutet, x eine Zahl von 1,9 bis 4 und y eine Zahl von 0 bis 20 ist, und Komplexbildner, dadurch gekennzeichnet, daß es die Gerüststoffe in Mengen von 15 bis 60 Gew.-% und Komplexbildner ausgewählt aus Polyhydroxymonocarbonsäuren bzw. Polyhydroxymonocarbonsäuresalzen mit 4 bis 6 Kohlenstoffatomen und mindestens 3 Hydroxy-Gruppen pro Molekül oder Mischungen aus diesen Säuren und/oder Salzen enthält, wobei das Gewichtsverhältnis Gerüststoffe zu Polyhydroxymonocarbonsäure bzw. Polyhydroxymonocarbonsäuresalz oder Mischungen aus diesen Säuren und/oder Salzen 30 : 1 bis 1 : 1 beträgt und das Mittel keine (co)polymeren Polycarbonsäuren bzw. Polycarbonsäuresalze enthält.
- Mittel nach Anspruch 1, dadurch gekennzeichnet, daß es 15 bis 50 Gew.-% Zeolith und/oder kristalline Schichtsilikate (I) und 1 bis 20 Gew.-% Polyhydroxymonocarbonsäuren bzw. Polyhydroxymonocarbonsäuresalze mit 4 bis 6 Kohlenstoffatomen enthält, wobei jedes Kohlenstoffatom, welches keine Carboxylgruppe oder Ketogruppe trägt eine Hydroxy-Gruppe aufweist.
- Mittel nach Anspruch 1 oder 2, dadurch gekennzeichnet, daß es 10 bis 35 Gew.-%, vorzugsweise 12 bis 28 Gew.-% und insbesondere 15 bis 25 Gew.-% anionische und nichtionische Tenside einschließlich Seife, 18 bis 40 Gew.-%, vorzugsweise 20 bis 35 Gew.-% Zeolith enthält, wobei das Gewichtsverhältnis Zeolith zu Polyhydroxymonocarbonsäure bzw. Polyhydroxymonocarbonsäuresalz oder Mischungen aus diesen Säuren und/oder Salzen 20 : 1 bis 1 : 1, vorzugsweise 10 : 1 bis 1,5 : 1 und insbesondere 5 : 1 bis 1,5 : 1 beträgt.
- Mittel nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß es 2 bis 15 Gew.-% und vorzugsweise 4 bis 12 Gew.-% Gluconsäure bzw. Gluconsäuresalz, Ascorbinsäure bzw. Ascorbinsäuresalz oder Mischungen aus diesen Säuren und/oder Salzen enthält.
- Mittel nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, daß es keine Phosphonate enthält.
- Mittel nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, daß es kein Citrat enthält.
- Mittel nach einem der Ansprüche 1 bis 6, dadurch gekennzeichnet, daß es Natriumcarbonat und/oder Kaliumcarbonat in Mengen von 2 bis 15, vorzugsweise 5 bis 14 Gew.-% enthält.
- Mittel nach einem der Ansprüche 1 bis 7, dadurch gekennzeichnet, daß es Gluconsäure bzw. Gluconsäuresalze oder Ascorbinsäure bzw. Ascorbinsäuresalze enthält, wobei es bei einem Gehalt an Ascorbinsäure bzw. Ascorbinsäuresalz vorzugsweise frei von Peroxy-Bleichmitteln ist.
- Mittel nach einem der Ansprüche 1 bis 8, dadurch gekennzeichnet, daß es ein Schüttgewicht zwischen 300 und 1100 g/l, vorzugsweise zwischen 500 und 1100 g/l aufweist.
- Gerüststoffkombination, enthaltend Gerüststoffe und einen Komplexbildner, dadurch gekennzeichnet, daß als Gerüststoffe Zeolith und/oder kristalline Schichtsilikate der allgemeinen Formel (I) NaMSixO2x+1yH2O, wobei M Natrium oder Wasserstoff bedeutet, x eine Zahl von 1,9 bis 4 und y eine Zahl von 0 bis 20 ist, und als Komplexbildner Polyhydroxymonocarbonsäuren bzw. Polyhydroxymonocarbonsäuresalze mit 4 bis 6 Kohlenstoffatomen und mindestens 3 Hydroxy-Gruppen pro Molekül oder Mischungen aus diesen Säuren und/oder Salzen enthalten sind und das Gewichtsverhältnis Gerüststoffe zu Polyhydroxymonocarbonsäure bzw. Polyhydroxymonocarbonsäuresalz oder Mischungen aus diesen Säuren und/oder Salzen 30 : 1 bis 1 : 1 beträgt und die Gerüststoffkombination keine (co)polymeren Polycarbonsäuren bzw. Polycarbonsäuresalze enthalt.
- Gerüststoffkombination nach Anspruch 10, dadurch gekennzeichnet, daß Polyhydroxymonocarbonsäuren bzw. Polyhydroxymonocarbonsäuresalze mit 4 bis 6 Kohlenstoffatomen enthalten sind, welche an jedem Kohlenstoffatom, das keine Carboxylgruppe oder Ketogruppe trägt, eine Hydroxy-Gruppe aufweist, wobei das Gewichtsverhältnis Gerüststoffe, insbesondere Zeolith, zu Polyhydroxymonocarbonsäure bzw. Polyhydroxymonocarbonsäuresalz oder Mischungen aus diesen Säuren und/oder Salzen 20 : 1 bis 1 : 1, vorzugsweise 10 : 1 bis 1,5 : 1 und insbesondere 5 : 1 bis 1,5 : 1 beträgt.
- Gerüststoffkombination nach Anspruch 10 oder 11, dadurch gekennzeichnet, daß als Polyhydroxymonocarbonsäure bzw. Polyhydroxymonocarbonsäuresalz Gluconsäure bzw. Gluconsäuresalz, Ascorbinsäure bzw. Ascorbinsäuresalz oder Mischungen aus diesen Säuren und/oder Salzen enthalten sind.
- Gerüststoffkombination nach einem der Ansprüche 10 bis 12, dadurch gekennzeichnet, daß die Gerüststoffkombination mit flüssigen bis wachsartigen Komponenten, vorzugsweise mit Niotensiden, besprüht ist.
- Verfahren zu Herstellung einer Gerüststoffkombination, enthaltend als Gerüststoffe Zeolith und/oder kristalline Schichtsilikate der allgemeinen Formel (I) NaMSixO2x+1·yH2O, wobei M Natrium oder Wasserstoff bedeutet, x eine Zahl von 1,9 bis 4 und y eine Zahl von 0 bis 20 ist, jedoch keine (co)polymeren Polycarbonsäuren bzw. Polycarbonsäuresalze und als Komplexbildner Polyhydroxymonocarbonsäuren bzw. Polyhydroxymonocarbonsäuresalze mit 4 bis 6 Kohlenstoffatomen und mindestens 3 Hydroxy-Gruppen pro Molekül oder Mischungen aus diesen Säuren und/oder Salzen, dadurch gekennzeichnet, daß die Gerüststoffkombination durch Mischen, Granulieren und/oder durch Sprühtrocknung hergestellt wird.
- Verfahren zu Herstellung eines granularen Wasch- und Reinigungsmittels gemäß einem der Ansprüche 1 bis 9, dadurch gekennzeichnet, daß das Granulat durch Sprühtrocknung hergestellt wird.
- Verfahren zur Herstellung eines granularen Wasch- und Reinigungsmittels gemäß einem der Ansprüche 1 bis 9, dadurch gekennzeichnet, daß das Granulat durch ein Granulier- oder Extrudierverfahren hergestellt wird.
- Verfahren zur Herstellung eines granularen Wasch- und Reinigungsmittels gemäß einem der Ansprüche 1 bis 9, dadurch gekennzeichnet, daß die Gerüststoffkombination aus Zeolith und/oder kristallinen Schichtsilikaten der allgemeinen Formel (I) NaMSixO2x+1·yH2O, wobei M Natrium oder Wasserstoff bedeutet, x eine Zahl von 1,9 bis 4 und y eine Zahl von 0 bis 20 ist, und Polyhydroxymonocarbonsäuren bzw. Polyhydroxymonocarbonsäuresalzen mit 4 bis 6 Kohlenstoff-Atomen und mindestens 3 Hydroxy-Gruppen oder Mischungen aus diesen Säuren und/oder Salzen in Form eines sprühgetrockneten oder granulierten Compounds als Zumischkomponente zu anderen granularen Bestandteilen von Wasch- und Reinigungsmitteln eingesetzt werden.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4228043A DE4228043A1 (de) | 1992-08-24 | 1992-08-24 | Gerüststoff für Waschmittel |
DE4228043 | 1992-08-24 | ||
PCT/EP1993/002172 WO1994004649A1 (de) | 1992-08-24 | 1993-08-16 | Gerüststoff für waschmittel |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0656050A1 EP0656050A1 (de) | 1995-06-07 |
EP0656050B1 EP0656050B1 (de) | 1997-05-14 |
EP0656050B2 true EP0656050B2 (de) | 2000-03-08 |
Family
ID=6466268
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP93919063A Expired - Lifetime EP0656050B2 (de) | 1992-08-24 | 1993-08-16 | Gerüststoff für waschmittel |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0656050B2 (de) |
JP (1) | JPH08500378A (de) |
AT (1) | ATE153055T1 (de) |
DE (2) | DE4228043A1 (de) |
ES (1) | ES2102674T5 (de) |
PL (1) | PL307589A1 (de) |
WO (1) | WO1994004649A1 (de) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2796389B1 (fr) * | 1999-07-15 | 2001-10-05 | Roquette Freres | Procede de lavage contenant de l'acide arabinonique et/ou l'un, au moins, de ses sels |
EP1374849B1 (de) | 2002-06-20 | 2005-11-23 | L'oreal | Kosmetische und/oder dermatologische Verwendung einer Zusammensetzung, die mindestens einen oxidationsempfindlichen hydrophilen durch mindestens einem Polymer oder Copolymer stabilisierten Wirkstoff aus Maleinsäureanhydrid enthält |
FR2886845B1 (fr) * | 2005-06-13 | 2009-07-03 | Oreal | Produit cosmetique solide |
ITCR20060016A1 (it) * | 2006-06-07 | 2007-12-08 | Silvia Palladini | Formulazioni di detersivi a basso impatto ambientale |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT337326B (de) * | 1974-08-02 | 1977-06-27 | Henkel & Cie Gmbh | Verfahren zum waschen, reinigen bzw. bleichen der oberflachen fester werkstoffe, insbesondere von textilien, und mittel zur durchfuhrung dieses verfahrens |
AT375393B (de) * | 1974-10-04 | 1984-07-25 | Henkel Kgaa | Verfahren zum waschen bzw. bleichen von textilien sowie mittel dazu |
DE4034131C2 (de) * | 1990-10-26 | 1999-08-26 | Henkel Kgaa | Gerüststoff für Waschmittel |
-
1992
- 1992-08-24 DE DE4228043A patent/DE4228043A1/de not_active Withdrawn
-
1993
- 1993-08-16 ES ES93919063T patent/ES2102674T5/es not_active Expired - Lifetime
- 1993-08-16 JP JP6505886A patent/JPH08500378A/ja active Pending
- 1993-08-16 AT AT93919063T patent/ATE153055T1/de not_active IP Right Cessation
- 1993-08-16 WO PCT/EP1993/002172 patent/WO1994004649A1/de active IP Right Grant
- 1993-08-16 DE DE59306463T patent/DE59306463D1/de not_active Expired - Fee Related
- 1993-08-16 PL PL93307589A patent/PL307589A1/xx unknown
- 1993-08-16 EP EP93919063A patent/EP0656050B2/de not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
PL307589A1 (en) | 1995-05-29 |
DE59306463D1 (de) | 1997-06-19 |
EP0656050B1 (de) | 1997-05-14 |
JPH08500378A (ja) | 1996-01-16 |
DE4228043A1 (de) | 1994-03-03 |
ES2102674T3 (es) | 1997-08-01 |
ATE153055T1 (de) | 1997-05-15 |
ES2102674T5 (es) | 2000-05-01 |
EP0656050A1 (de) | 1995-06-07 |
WO1994004649A1 (de) | 1994-03-03 |
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