EP0650157A1 - Magnetisches aufzeichnungsmedium, dessen aufzeichnungs-/wiedergabeverfahren und informationsprozessor, der dieses medium und das verfahren gebraucht - Google Patents

Magnetisches aufzeichnungsmedium, dessen aufzeichnungs-/wiedergabeverfahren und informationsprozessor, der dieses medium und das verfahren gebraucht Download PDF

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Publication number
EP0650157A1
EP0650157A1 EP93924171A EP93924171A EP0650157A1 EP 0650157 A1 EP0650157 A1 EP 0650157A1 EP 93924171 A EP93924171 A EP 93924171A EP 93924171 A EP93924171 A EP 93924171A EP 0650157 A1 EP0650157 A1 EP 0650157A1
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EP
European Patent Office
Prior art keywords
magnetic
dye
signals
recording medium
magnetic recording
Prior art date
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Granted
Application number
EP93924171A
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English (en)
French (fr)
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EP0650157B1 (de
EP0650157A4 (de
Inventor
Yuzo Seo
Shuichi Maeda
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Mitsubishi Chemical Corp
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Mitsubishi Chemical Corp
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Publication date
Priority claimed from JP29707692A external-priority patent/JPH06150442A/ja
Priority claimed from JP33627992A external-priority patent/JPH06187630A/ja
Priority claimed from JP33753692A external-priority patent/JPH06187631A/ja
Priority claimed from JP24713693A external-priority patent/JPH07105643A/ja
Application filed by Mitsubishi Chemical Corp filed Critical Mitsubishi Chemical Corp
Publication of EP0650157A4 publication Critical patent/EP0650157A4/de
Publication of EP0650157A1 publication Critical patent/EP0650157A1/de
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Publication of EP0650157B1 publication Critical patent/EP0650157B1/de
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    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B5/00—Recording by magnetisation or demagnetisation of a record carrier; Reproducing by magnetic means; Record carriers therefor
    • G11B5/48—Disposition or mounting of heads or head supports relative to record carriers ; arrangements of heads, e.g. for scanning the record carrier to increase the relative speed
    • G11B5/58—Disposition or mounting of heads or head supports relative to record carriers ; arrangements of heads, e.g. for scanning the record carrier to increase the relative speed with provision for moving the head for the purpose of maintaining alignment of the head relative to the record carrier during transducing operation, e.g. to compensate for surface irregularities of the latter or for track following
    • G11B5/596—Disposition or mounting of heads or head supports relative to record carriers ; arrangements of heads, e.g. for scanning the record carrier to increase the relative speed with provision for moving the head for the purpose of maintaining alignment of the head relative to the record carrier during transducing operation, e.g. to compensate for surface irregularities of the latter or for track following for track following on disks
    • G11B5/59677—Disposition or mounting of heads or head supports relative to record carriers ; arrangements of heads, e.g. for scanning the record carrier to increase the relative speed with provision for moving the head for the purpose of maintaining alignment of the head relative to the record carrier during transducing operation, e.g. to compensate for surface irregularities of the latter or for track following for track following on disks with optical servo tracking
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B5/00—Recording by magnetisation or demagnetisation of a record carrier; Reproducing by magnetic means; Record carriers therefor
    • G11B5/62—Record carriers characterised by the selection of the material
    • G11B5/73—Base layers, i.e. all non-magnetic layers lying under a lowermost magnetic recording layer, e.g. including any non-magnetic layer in between a first magnetic recording layer and either an underlying substrate or a soft magnetic underlayer
    • G11B5/733—Base layers, i.e. all non-magnetic layers lying under a lowermost magnetic recording layer, e.g. including any non-magnetic layer in between a first magnetic recording layer and either an underlying substrate or a soft magnetic underlayer characterised by the addition of non-magnetic particles
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B5/00—Recording by magnetisation or demagnetisation of a record carrier; Reproducing by magnetic means; Record carriers therefor
    • G11B5/74—Record carriers characterised by the form, e.g. sheet shaped to wrap around a drum
    • G11B5/82—Disk carriers
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B5/00—Recording by magnetisation or demagnetisation of a record carrier; Reproducing by magnetic means; Record carriers therefor
    • G11B5/74—Record carriers characterised by the form, e.g. sheet shaped to wrap around a drum
    • G11B5/82—Disk carriers
    • G11B5/825—Disk carriers flexible discs

Definitions

  • the present invention relates to a magnetic recording medium suitable for tracking by an optical means and a recording/reproducing method therefor as well as an information processing apparatus by means thereof.
  • Floppy disk devices are used in a large quantity for information recording of e.g. computers or wordprocessors.
  • Usual floppy disk devices had a problem that since positioning of the head is conducted by an open loop control using a step motor (control without feedback), positioning precision is poor, and it is impossible to increase the track density.
  • Figures 11 and 12 One example of a floppy disk utilizing this principle is shown in Figures 11 and 12.
  • Reference numeral 19 indicates a floppy disk
  • Figure 12 is an enlarged view of a part of the magnetic recording medium 4 of Figure 11.
  • Figure 14 is a cross-sectional view vertical to the medium plane, illustrating a servo-signal reading system of an optical track servo-mechanism.
  • On the surface of the magnetic recording medium 4 numerous pits 5 are formed in accordance with a track pitch.
  • a light from a light-emitting element 8 is projected on the surface of the magnetic recording medium 4. Tracking is carried out by reading a reflected light thereof by a light receptor 10 via an optical system 9.
  • the light receptor 10 is composed of four unit elements arranged in a square lattice pattern and upon receiving the above-mentioned reflected light, outputs four signals A to D.
  • signal B is deducted from signal A by a differential amplifier 11 to obtain a signal proportional to cos(2 ⁇ R/P) .
  • signal D is deducted from signal C by a differential amplifier 12 to obtain a signal proportional to sin(2 ⁇ R/P) .
  • binary codes for target value T are input to address terminals of ROM 13 and 14 in which a sin table and a cos table are written, to prepare binary codes representing sin(2 ⁇ T/P) and cos(2 ⁇ T/P) .
  • a magnetic recording medium to be used for such a method is required to have grooves (pits) preliminarily formed on its surface.
  • a method for forming such grooves a method of pressing to the medium a die having convexes formed to correspond to the grooves, to transfer the shapes of the die to the medium (stamping processing) and a method of irradiating a laser beam to decompose and remove part of the magnetic layer (laser processing) are known.
  • the magnetic recording medium of the present invention is a magnetic recording medium of a disk shape having a magnetic layer containing a magnetic material formed on a non-magnetic support and having, between the non-magnetic layer and the magnetic layer, a layer containing a dye, of which the optical property changes by irradiation of energy rays, characterized in that, in the above-mentioned layer containing a dye, continuous servo-signals based on the change of the optical property of said dye by irradiation of energy rays are recorded on concentric tracks.
  • the recording/reproducing method for a magnetic recording medium of the present invention is a recording/reproducing method for a magnetic recording medium, which comprises recording/reproducing magnetic data by means of a magnetic recording medium of a disk shape having a magnetic layer containing a magnetic material formed on a non-magnetic support, characterized in that using, as said magnetic recording medium, a magnetic recording medium of a disk shape having a magnetic layer containing a magnetic material formed on a non-magnetic support and having, between the non-magnetic layer and the magnetic layer, a layer containing a dye, of which the optical property changes by irradiation of energy rays, wherein in the above-mentioned layer containing a dye, continuous servo-signals based on the change of the optical property of said dye by irradiation of energy rays are recorded on concentric tracks, recording/reproducing of the magnetic data is conducted while tracking of a magnetic head is conducted by means of servo-signals detected by an optical means from the layer containing a
  • the information treating apparatus of the present invention is an information processing apparatus for recording/reproducing magnetic data while tracking a magnetic head by means of servo-signals detected by an optical means from a magnetic recording medium, characterized in that a means is provided to read the above-mentioned servo-signals from a magnetic recording medium of a disk shape having a magnetic layer containing a magnetic material formed on a non-magnetic support and having, between the non-magnetic support and the magnetic layer, a layer containing a dye, of which the optical property changes by irradiation of energy rays, wherein in the above-mentioned layer containing a dye, continuous servo-signals based on the change of the optical property of said dye by irradiation of energy rays, are recorded on concentric tracks.
  • Figure 1 is a schematic view illustrating a first embodiment in which a servo-signal pattern of a magnetic recording medium of the present invention is read by a detector.
  • Figure 2 is a schematic view illustrating a second embodiment in which a servo-signal pattern of a magnetic recording medium of the present invention is read by a detector.
  • Figure 3 is a schematic view illustrating a third embodiment in which a servo-signal pattern of a magnetic recording medium of the present invention is read by a detector.
  • Figure 4 is a conceptual view illustrating a state in which signals having two different frequency components are recorded on tracks.
  • Figure 5 is a schematic view illustrating a fourth embodiment wherein a servo-signal pattern of a magnetic recording medium of the present invention is read by a detector.
  • Figure 6 is a schematic view illustrating a first embodiment of a device for writing a servo-signal pattern of a magnetic recording medium of the present invention.
  • Figure 7 is a schematic view illustrating a second embodiment of a device for writing a servo-signal pattern of a magnetic recording medium of the present invention.
  • Figure 8 is a view showing the absorbance curve of a magnetic recording medium prepared in Example 1.
  • Figure 9 is a detailed schematic view illustrating an embodiment of a pattern for writing an optical signal into a magnetic recording medium by irradiation of energy rays.
  • Figure 10 is a schematic view illustrating an embodiment of a pattern for writing an optical signal into a magnetic recording medium by irradiation of energy rays.
  • Figure 11 is a perspective view of a floppy disk.
  • Figure 12 is a schematic view of an enlarged disk surface of the portion 4 of Figure 11.
  • Figure 13 is a schematic view illustrating a manner in which a servo-signal pattern of a conventional magnetic recording medium is read by a detector.
  • Figure 14 is a cross-sectional view illustrating a servo-signal reading system of a conventional optical track servo mechanism.
  • Figure 15 is a block diagram of a detecting circuit of a conventional optical track servo mechanism.
  • the magnetic recording medium of the present invention is a magnetic recording medium of a disk shape having a magnetic layer containing a magnetic material formed on a non-magnetic support and having, between the non-magnetic support and the magnetic layer, a layer containing a dye, of which the optical property changes by irradiation of energy rays (a dye-containing layer), characterized in that, in the above-mentioned dye-containing layer, continuous servo-signals based on the change of the optical property of the dye by irradiation of energy rays, are recorded on concentric tracks.
  • the optical property of the dye-containing layer changes by irradiation with energy rays such as laser beam, electron beam or ultraviolet rays. Accordingly, optically detectable servo-signals can easily be recorded on a medium by conducting irradiation of energy rays in correspondence with servo-signals to be recorded, whereby writing of optical signals can be done.
  • a method for irradiating energy rays to write optical signals into the dye-containing layer it is possible to employ a method of irradiating a laser beam focused to have a certain spot diameter, for example, by an optical system, or irradiating a light beam (such as a strobo light or ultraviolet rays) or an electron beam through a mask having light-shielding areas and light transmitting areas corresponding to the signals to be recorded.
  • a light beam such as a strobo light or ultraviolet rays
  • the above-mentioned change of the optical property may, for example, be an increase of the light transmittance, a decrease of the light transmittance, an increase of the light reflectance or a decrease of the light reflectance.
  • an optical signal can be obtained from a portion where the light transmittance is high in the medium surface having a low light transmittance.
  • an optical signal can be obtained from a portion where the light transmittance is low in the medium having a high light transmittance.
  • the dye to be used for the dye-containing layer is not particularly limited so long as its optical property changes by irradiation with energy rays and it is capable of effectively absorbing the irradiated energy rays, and it may optionally be selected for use.
  • the dye to be used for the dye-containing layer is preferably the one having a light absorption within this range, and it is preferred to irradiate a laser having a wavelength within this range for writing an optical signal.
  • the one having the dye incorporated in a binder resin is preferably used as the dye-containing layer.
  • the color-developing properties (the absorption wavelength and the absorbance) at that time may vary from those in an organic solvent in many cases. Therefore, it is preferred that a dye-containing layer having a dye incorporated into a binder resin, is formed into a film for evaluation of the absorbance characteristics.
  • the maximum absorption wavelength ( ⁇ max) of the dye is preferably at least 600 nm, preferably at least 750 nm, more preferably from 750 to 900 nm, in the above-mentioned coated film.
  • various known dyes of e.g. polymethine type, cyanin type, phthalocyanin type, naphthalocyanin type, azo type, anthraquinone type, naphthoquinone type, pyrylium type, azulenium type, squarylium type, indophenol type, indoaniline type and triallylmethane type, may be employed.
  • a polymethine type dye may be mentioned.
  • a polymethine type dye a polymethine dye of the following general formula (I) is particularly preferred: (in the general formula (I), each of R1 to R4, which may be the same or different, is a hydrogen atom, a halogen atom, a hydroxyl group, a carboxyl group, or a substituted or unsubstituted alkyl, amino, alkylamino, acyl, aryl, alkoxy, aralkyl, alkenyl or acyloxy group, X is an anion, m is 0, 1 or 2, and l is 1 or 2, provided that when l is 2, the plurality of R1, R2, R3 and R4 may be the same or different from each other).
  • each of R1 to R4 which may be the same or different, is a hydrogen atom, a halogen atom, a hydrdxyl group, a carboxyl group, or a substituted or unsubstituted alkyl, amino, alkylamino, acyl, allyl, alkoxy, aralkyl, alkenyl or acyloxy group.
  • the alkyl group may, for example, be a methyl group, an ethyl group, a propyl group, a butyl group or an amyl group or may further be a substituted alkyl group such as a 2-hydroxyethyl group, a 2-sulfoethyl group, a 2-carboxyethyl group, or an alkyl group substituted by e.g. a halogen atom.
  • a mono-substituted or di-substituted amino group which is substituted by e.g. a methyl group, an ethyl group or a benzyl group, especialy a di-substituted alkyl group, is particularly preferred.
  • R1 to R4 a hydrogen atom, a halogen atom (such as chlorine), an alkoxy group (such as a methoxy group or an ethoxy group), an amino group or an alkylamino group is preferred, and a dialkylamino group is particularly preferred.
  • a halogen atom such as chlorine
  • an alkoxy group such as a methoxy group or an ethoxy group
  • an amino group or an alkylamino group is preferred, and a dialkylamino group is particularly preferred.
  • X is an anion, and for example, ClO4, BF4, CH3C6H4SO3, Cl or I may be mentioned.
  • the content of the dye in the dye-containing layer varies depending upon the type of the dye to be used, the thickness of the dye-containing layer, the performance of the light signal detector, etc., but may be such an amount that the light transmittance, the light reflectance or the like changes to a measurable extent by irradiation of energy rays. It is usually from 0.001 to 30 wt% in the dye-containing layer.
  • the dye-containing layer may contain additives such as an antistatic agent, a deterioration-preventing agent and a crosslinking agent within a range not to impair the effects of the present invention.
  • the dye-containing layer is formed between the non-magnetic support and the magnetic layer.
  • the dye-containing layer is formed between the non-magnetic support and the magnetic layer, and in that dye-containing layer, continuous servo-signals based on the change on the optical property of the dye by irradiation of energy rays, will be recorded on concentric tracks.
  • a method for forming the dye-containing layer between the non-magnetic support and the magnetic layer a method may, for example, be mentioned wherein a dye solution having a dye dissolved or dispersed in a solvent, is a mixed with a binder resin, a dispersant, etc., as the case requires, to prepare a coating solution, which is coated directly or with another layer interposed, on the non-magnetic support before formation of the magnetic layer.
  • the coating method commonly used various coating methods such as air doctor coating, blade coating, reverse roll coating and gravure coating, may be employed. Further, coating may be conducted by a method such as vapor deposition or transfer.
  • the resin, the solvent or the like to be used for the preparation of the coating solution conventional materials may be used alone or in combination as a mixture, as will be described hereinafter.
  • a polyester such as polyethylene terephthalate or polyethylene naphthalate is usually employed in view of the excellent mechanical properties, heat resistance, electrical properties and chemical resistance.
  • a polyester film is poor in the adhesive property with the magnetic layer, since it has a high degree of crystal orientation. Therefore, in order to improve the adhesive property between the non-magnetic support and the magnetic layer, treatment with a surface modifier such as an alkali, an aqueous amine solution, trichloroacetic acid or a phenol may sometimes be applied to the surface of the non-magnetic support.
  • a dye may be mixed to the surface modifier, and a such a mixture may be coated on the non-magnetic support.
  • an easily adhesive layer may sometimes be formed by means of various easily adhesive resins in order to improve the adhesion between the non-magnetic support and the magnetic layer.
  • a dye may be incorporated in such an easily adhesive layer.
  • a material having a dye blended to a conventional adhesive resin such as an acrylic resin, a polyurethane resin or a polyester resin may, usually, be adjusted as a coating solution, which is then coated on the magnetic layer side surface of the non-magnetic support.
  • the thickness of the easily adhesive layer is usually from 0.005 to 5 ⁇ m as a dry film thickness.
  • an interlayer containing an electrically conductive material and a binder resin may be formed between the magnetic layer and the non-magnetic support in order to improve the electrification property of the magnetic layer.
  • a method of incorporating a dye in such an interlayer may be mentioned.
  • an electrically conductive metal powder or a metal compound may, for example, be mentioned.
  • a powder of a metal such as silver or platinum, or a powder of a metal compound such as tin oxide, zinc oxide or potassium titanate may be used, although the electrically conductive material is not particularly limited.
  • the average particle size of such a powder is preferably from 0.005 to 0.6 ⁇ m.
  • various ferromagnetic powders including a powder of a ferromagnetic metal such as Fe, Ni or Co, or a magnetic alloy containing such a ferromagnetic metal as the main component, such as Fe, Ni, Co, a Fe-Co alloy, a Fe-Ni alloy, a Fe-Co-Ni alloy, a Fe-Ni-Zn alloy, a Fe-Co-Ni-Cr alloy or a Co-Ni alloy, an iron oxide magnetic powder such as ⁇ -Fe2O3, Fe3O4, Co-containing ⁇ -Fe2O3 or Co-containing Fe3O4, and a metal oxide type magnetic powder such as CrO2, barium ferrite or strontium ferrite, may be mentioned. From the viewpoint of the light transmittance, etc., barium ferrite is particularly preferred.
  • the amount of the magnetic material to be used is preferably such that the content in the magnetic layer will be from 50 to 90 wt%, particularly from 55 to 85 wt%, as the amount of the ferromagnetic powder.
  • the binder resin to be used for the magnetic layer the one which is excellent in the adhesion with the support and in the abrasion resistance, is suitably used.
  • a polyurethane resin a polyester resin, a cellulose derivative such as a cellulose acetate butyrate, cellulose diacetate or nitrocellulose, a vinyl chloride type resin such as a vinyl chloride-vinyl acetate copolymer, a vinyl chloride-vinylidene chloride copolymer or a vinyl chloride-acrylic copolymer, various synthetic rubbers such as a styrene-butadiene copolymer, an epoxy resin or a phenoxy resin may be mentioned. These resins may be used alone or in combination as a mixture of two or more of them.
  • the binder resin is preferably used so that the content in the magnetic layer would be from 2 to 50 wt%, particularly from 5 to 35 wt%.
  • a low molecular weight polyisocyanate compound having a plurality of isocyanate groups may be incorporated, so that a three dimensional network structure will be formed in the magnetic layer to improve the mechanical strength.
  • a trimethylol propane adduct of tolylenediisocyanate may, for example, be mentioned.
  • Such a low molecular weight polyisocyanate compound is preferably used in an amount of from 5 to 100 wt% relative to the binder resin.
  • various additives such as a lubricant, an abrasive agent, an antistatic agent, a dispersant, etc., may be incorporated, as the case requires.
  • lubricant various lubricants of e.g. an aliphatic type, a fluorine type, a silicone type or a hydrocarbon type, may be used.
  • aliphatic lubricant a fatty acid, a metal salt of a fatty acid, a fatty acid ester, a fatty acid amide or an aliphatic alcohol may, for example, be mentioned.
  • fatty acid oleic acid, lauric acid, myristic acid, palmitic acid, stearic acid or behenic acid may, for example, be mentioned.
  • a magnesium salt, an aluminum salt, a sodium salt or a calcium salt of such a fatty acid may, for example, be mentioned.
  • a fatty acid ester a butyl ester, an octyl ester or a glyceride of the above-mentioned fatty acid may, for example, be mentioned.
  • fatty acid amide an amide of the above-mentioned acid as well as linolic acid amide or caproic acid amide may, for example, be mentioned.
  • the aliphatic alcohol lauryl alcohol, myristyl alcohol, palmityl alcohol, stearyl alcohol or oleyl alcohol may, for example, be mentioned.
  • a perfluoroalkyl polyether or a perfluoroalkyl carboxylic acid may, for example, be mentioned.
  • silicone type lubricant silicone oil or modified silicone oil may, for example, be mentioned.
  • a solid lubricant such as molybdenum disulfide or tungsten disulfide, or a phosphoric acid ester may, for example, be used.
  • hydrocarbon type lubricant paraffin, squalane or wax may, for example, be mentioned.
  • the amount of the lubricant to be used is usually such that the content in the magnetic layer is within a range of from 0.1 to 20 wt%, preferably from 1 to 10 wt%. In a case where the magnetic layer is formed in two laminated layers, the content of the lubricant may be varied between the upper layer and the lower layer.
  • abrasive agent alumina, molten alumina, corandom, silicone carbide, chromium oxide or silicone nitride may, for example, be mentioned.
  • relatively hard material is preferably used.
  • the number average particle size is preferably at most 2 ⁇ m.
  • the amount of the abrasive agent to be used is preferably such that the content in the magnetic layer is within a range of from 1 to 20 wt%.
  • a natural surfactant such as carbon black, graphite or saponin, a non-ionic surfactant such as an alkylene oxide type or a glycerine type surfactant, a cationic surfactant such as a higher alkylamine type, a quaternary ammonium salt type, pyridine or other heterocyclic type surfactant containing an acid group such as a carboxylic acid group, a sulfonic acid group, a phosphoric acid group, a sulfuric acid ester group or a phosphoric acid ester group, an amphoteric surfactant such as an amino acid type, an amino sulfonic acid type, a sulfuric acid or phosphoric acid ester of an amino alcohol type surfactant may, for example, be used.
  • a non-ionic surfactant such as an alkylene oxide type or a glycerine type surfactant
  • a cationic surfactant such as a higher alkylamine type, a quatern
  • the amount of the antistatic agent to be used is usually such that the content in the magnetic layer is within a range of from 1 to 15 wt%.
  • These materials are those useful as antistatic agents, but in some cases, they may be used for the purpose of improving the dispersibility or the lubricating property.
  • a C12 ⁇ 18 fatty acid such as capric acid, lauric acid, myristic acid, oleic acid or linolic acid, a metal soap composed of an alkali metal or alkaline earth metal salt of such a fatty acid, or lecithin, may, for example, be used.
  • the amount of the dispersant is usually such that the content in the magnetic layer is within a range of from 0 to 20 wt%.
  • a ketone such as methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone
  • an alcohol such as methanol, ethanol, propanol or isopropyl alcohol
  • an ester such as methyl acetate, ethyl acetate or butyl acetate
  • an ether such as diethyl ether or tetrahydrofuran
  • an aromatic hydrocarbon such as benzene, toluene or xylene, or an aliphatic hydrocarbon such as hexane
  • an aromatic hydrocarbon such as benzene, toluene or xylene
  • an aliphatic hydrocarbon such as hexane
  • various plastics such as, a polyester such as polyethylene terephthalate or polyethylene naphthalate, a polyolefin such as polypropylene or polyethylene, a cellulose derivative such as cellulose acetate, polycarbonate, polyamide and polyimide, may, for example, be used.
  • the magnetic coating material directly or with another layer interposed, on the non-magnetic support
  • various methods commonly used such as air doctor coating, blade coating, reverse coating and gravure coating, may be employed.
  • the coating solution of the lower layer and the coating solution for the upper layer may simultaneously be coated in wet states, or the respective layers may sequentially be coated.
  • the thickness of the magnetic layer is usually from 0.1 to 10 ⁇ m, preferably from 0.3 to 2 ⁇ m, as the thickness after drying.
  • a top coating layer for imparting a lubricating property or a back coating layer for antistatic purpose may be formed.
  • orientation treatment random treatment or smoothing treatment may be carried out.
  • the magnetic recording medium of the present invention is characterized in that in the dye-containing layer formed between the non-magnetic support and the magnetic layer, continuous servo-signals based on the change of the optical property of the dye by irradiation of energy rays, are recorded on concentric tracks.
  • Servo-signals may be recorded by forming areas where the optical property of the dye has changed by irradiation of energy rays, on the concentric tracks of the dye-containing layer.
  • the areas where the optical property of the dye has changed may be continuously formed on the tracks, or an area where the optical property of the dye has changed and an area where no such change has occurred may be formed alternately. Further, the areas where the optical property of the dye has changed may be formed so that signals containing one type of a frequency component are obtained as the servo-signals, or the areas where the optical property of the dye has changed, may be formed so that signals containing two types of frequency components, may be obtained.
  • the signals containing two types of frequency components as the servo-signals may be recorded on one servo track, or two types of signals differing in the frequency may respectively be recorded at spatially different close positions. In the latter case, the two signals may be detected simultaneously by means of a single detector, whereby it is possible to obtain signals having two types of frequency components superposed on each other.
  • the servo-signals read by an optical means by the detector will be separated into the respective frequency components by a frequency separating means, and from such frequency components, an error signal for detecting a tracking error, can be obtained, whereby accurate tracking will be possible.
  • the above-mentioned respective frequency components are recorded so that they have sequentially mutually different phase servo-signals among the respective servo-tracks.
  • the present head position can be detected by measuring the phase servo-signals, and the head position can be controlled so that the measured values will be the prescribed values.
  • Figure 1 illustrates one embodiment of the magnetic recording medium of the present invention, and shows the manner of reading a signal 21 having a long wavelength and a signal 22 having a short wavelength by a detector 31.
  • signals 21 and 22 are recorded at different close positions on the surface of the medium.
  • the signals thus recorded to be close to each other will be mixed at the time of the reproduction, and a signal representing the sum of the two will be output from the detector.
  • the wavelength of the signal 22 is adjusted to be 1/2 of the wavelength ( ⁇ ) of the signal 21, and the signals are recorded so that the phase of the signal 21 is sequentially different from one track to the next.
  • the signals are recorded so that the phase difference between the signal 21 and the signal 22 will sequentially be different such that it is 0 in track 3 as shown at b, ⁇ /8 in track 2 as shown at a and ⁇ /4 in track 1 as shown at c.
  • the phase difference sequentially provided among the tracks may optionally be selected, and phase differences both among signal 21 and among signal 22 may be provided among the tracks.
  • A shows a case where the detector 31 is located just above track 2.
  • the signal d output by the detector 31 corresponds to the signal of track 2.
  • the detector moves upward and arrives at the position shown at B, a signal of track 3 will be mixed to the signal d of the detector, and the phase of the short wavelength component advances.
  • the signal of track 1 will be mixed to the signal d of the detector, and the phase of the short wavelength component delays.
  • the position of the detector can be detected as a phase difference.
  • accurate tracking can be conducted by moving the head so that the phase difference thus detected will fall within a predetermined range.
  • a method for recording signals containing two types of frequency components on one servo track there may, for example, be mentioned a method wherein trigonometric functions corresponding to the two types of signals are added, and the added size is analogically recorded in correspondence with the width of the servo track or it is converted into binary signals by PWM (pulse width modulation) and recorded, or a method wherein the servo track is divided into fine sections in a circumferential direction, and the respective frequency components will be sequentially recorded in the corresponding different recording sections.
  • PWM pulse width modulation
  • Figure 2 is a schematic view illustrating an enlarged part of one embodiment of a magnetic recording medium of the present invention in which servo-signals are recorded by changing the widths of the servo tracks.
  • servo tracks 0 and 1 are provided along the circumferential direction of the magnetic recording medium.
  • the areas shown by widely spaced oblique lines represent recorded areas in the tracks, and such areas are different from other areas in the optical properties such as the light reflectance and light transmittance.
  • Other servo tracks are likewise provided, although they are not shown.
  • the width of a servo track corresponds to the intensity of the signal 20 (biased and includes a constant portion), and said signal 20 is a combined signal of a plurality of frequency components i.e. a combined signal of the signal 21 having a long wavelength and the signal 22 having a short wavelength.
  • the signals 21 and 22 are shown simply for the convenience of explanation. In reality, only their combined signal 20 is recorded.
  • Figure 3 is a schematic view illustrating an enlarged part of one embodiment of the magnetic recording medium of the present invention in which servo-signals obtained by PWM modulation are recorded.
  • the areas shown by black areas represent recorded areas in the tracks, and their widths in the circumferential direction correspond to the pulse widths of the signals obtained by PWM modulation.
  • the recorded areas are different from other areas in the optical properties such as the light reflectance and the light transmittance.
  • Figure 4 is a conceptual view illustrating a manner in which two signals having different frequencies are recorded in servo track 0 and servo track 1 on a magnetic recording medium.
  • the signal 20 has as its frequency components a signal 21 having a long wavelength and a signal 22 having a short wavelength.
  • the signals 21 and 22 are shown simply for the purpose of explanation, and in reality, only the signal 20 as their combined signal is recorded as modulated by PWM, as shown in Figure 3.
  • the signals 21 and 22 have common wavelengths ⁇ and ⁇ /2, respectively, in the respective tracks. However, there is no particular restriction as to these wavelengths. The wavelengths may optionally be determined depending upon the required response characteristics, etc. Further, between the signals 21 and 22, a different phase difference is sequentially provided from one track to the next. Namely, in Figure 2, the signal 21 has the same phase in tracks 0 and 1, whereas the signal 22 has a phase difference of ⁇ between tracks 0 and 1. In such a manner, by setting the phase of the signal 21 to be equal in all tracks while sequentially differentiating the phase of the signal 22 by ⁇ , the phase difference between the signals 21 and 22 will sequentially be different by ⁇ from one track to the next. Of course, there is no particular restriction as to the value for ⁇ , and it may optionally be selected. Otherwise, phase differences both among the signals 21 and among the signals 22 may be provided among tracks.
  • Figure 5 is a schematic view illustrating an enlarged part of one embodiment of a magnetic recording medium of the present invention in which a plurality of frequency components are, respectively, recorded in the sections divided in the circumferential direction on the servo tracks.
  • Figure 5 shows a manner in which optical signals having two types of frequency components i.e. the signal 21 having a long wavelength and the signal 22 having a short wavelength, which are recorded in the servo tracks 0 to 3 formed in the circumferential direction, are read from a detection site 31.
  • the servo tracks are divided in fine sections in the circumferential direction so that the areas for recording the two types of frequency components i.e. the signals 21 and 22, are formed alternately.
  • 1 shown above indicates a section in which the signal 21 having a long wavelength is to be recorded
  • 2 indicates a section in which the signal 22 having a short wavelength is to be recorded.
  • 1 and 2 are divided in the circumferential direction and alternately formed.
  • track 1 with respect to the positions 1 at which the signal 21 is to be recorded, continuous 8 sections from position 0 in the circumferential direction are in a recorded state (shown by a black area in the Figure), and the following 8 sections are blanc (shown by a blanc area in the Figure).
  • the signals 21 and 22 have common wavelengths ⁇ and ⁇ /2, respectively, in the respective tracks. However, there is no particular restriction as to these wavelengths, and they may optionally be selected depending upon the desired response characteristics, etc. Further, between the signals 21 and 22, sequentially different phase difference is provided from one track to the next. Namely, in Figure 5, the signal 21 has the same phase in tracks 0 to 3, whereas the signal 22 has the phase sequentially changed by ⁇ /8 among the tracks 0 to 3, whereby the phase difference between the signals 21 and 22 will be sequentially different by ⁇ /8 from one track to the next. Of course, the difference in the phase difference sequentially provided from one track to the next is not limited to ⁇ /8 and may optionally be selected. Further, phase differences both among the signals 21 and among the signal 22 may be provided among the tracks.
  • the widths of the sections divided in the circumferential direction on the servo tracks may simply be sufficiently be smaller than the wavelength of the respective frequency components, and by setting the widths of the sections to be adequately smaller than the detection range of the detector, a signal having the respective frequency components combined will be output from the detector.
  • tracking is conducted, for example, as follows.
  • a detector, not shown, is integrally formed with a magnetic head, not shown, and detects a reflected light or a transmitted light from the detection region 31 by irradiation of light rays from a light source, not shown.
  • Which one as between the reflected light and the transmitted light is to be detected is determined depending upon which optical property as between the reflectance and the transmittance was utilized for recording on the servo tracks of the substrate.
  • the optical property is different between the recorded areas and the non-recorded areas in the servo tracks, whereby the quantity of light received by the detector by the rotation of the magnetic recording medium will periodically changes, and an alternate signal will be output from the detector.
  • the detection region 31 is adequately larger than the modulation cycle by PWM, whereby the recorded signals in this region are averaged for output, whereby an optical record by PWM with an adequately high frequency will be detected as a signal which changes in an analogue fashion. Accordingly, the alternate signal output from the detector will be substantially the same signal as the signal 20.
  • the signal of the PWM-modulation frequency will be contained in the output signal of the detector. In such a case, it can be removed by means of e.g. an electron filter.
  • the detected alternate signal has two frequency components i.e. the signals 21 and 22, which can be separated by means of a frequency separation means such as a band pass filter.
  • a frequency separation means such as a band pass filter.
  • the phase difference between the signals 21 and 22 sequentially differs by ⁇ from one track to the next, whereby the present position of the magnetic head can be detected by measuring the phase difference between the separated respective frequency components by e.g. a phase difference detector.
  • the phase difference between the signals 21 and 22 differs by ⁇ between the adjacent tracks, whereby the phase difference to be detected will be an intermediate value corresponding to the above error. Therefore, by controlling the position of the magnetic head so that this phase difference will be the prescribed value, accurate tracking will be possible.
  • a servo circuit generally known as PLL phase locked loop
  • PLL phase locked loop
  • PLL phase locked loop
  • PLL phase locked loop
  • the rise times of the above-mentioned two signals are read by a digital signal processor, and their difference is computed to readily obtain a tracking error.
  • the above-mentioned servo-signals will be recorded by forming in a magnetic recording medium areas where an optical property such as light reflectance or light transmittance is locally different.
  • a method for recording servo-signals on the above-mentioned magnetic recording medium it is possible to employ, for example, a method of irradiating a laser beam at a certain specified position on the surface of the magnetic recording medium or irradiating a light beam (such as a strobo light or ultraviolet rays) or an electron beam through a mask having light shielding areas and light-transmitting areas corresponding to the signals to be recorded.
  • the optical property such as the light reflectance or light transmittance will change due to the chemical change of the dye preliminarily incorporated in the magnetic recording medium, and such areas will be in a recorded state.
  • FIG. 6 is a schematic view illustrating an embodiment of a method suitable for recording servo-signals.
  • reference numeral 30 indicates a laser generator which generates a laser beam 45 under excitation by a powder source apparatus, not shown.
  • Reference numeral 32 is AOM (accousto-optical modulator), which has a function of diffracting or deflecting the laser beam by a compressional wave in a crystal which is formed by applying a supersonic wave to the crystal placed in the optical path.
  • AOM 32 By AOM 32, the diffraction angle changes due to the wavelength of the applied supersonic wave, and the amount of diffraction changes due to the intensity.
  • This apparatus is constructed so that the amount of diffraction is controlled by changing the intensity of generation by the signals applied to the generator 33.
  • the laser beam passed through AOM 32 is changed in its direction by a mirror 35 provided on a movable carriage of a linear motor 34 and then focused by an objective lens 36 provided on the above-mentioned movable carriage and irradiated to the magnetic recording medium 37.
  • the magnetic recording medium 37 is rotated by a spindle motor 38, and the rotational angle is transmitted to the control apparatus 39.
  • the control apparatus 39 is designed so that the focused area is set at a predetermined radial position by sending a signal to the linear motor 34, and then depending upon the rotational angle of the spindle motor, a signal for the intensity of the laser beam is sent to the generator 33 based on the predetermined pattern.
  • the area of the magnetic recording medium where the laser beam is focused will be heated, and the optical property such as the light reflectance or light transmittance will change due to e.g. a chemical change of the dye in the dye-containing layer, to form a servo track. This operation is repeated to obtain a necessary number of tracks, whereby optical signals will be recorded on the magnetic recording medium.
  • FIG. 7 is a schematic view illustrating another embodiment of a method suitable for recording servo-signals.
  • Reference numeral 40 indicates an ultraviolet light source
  • numeral 41 indicates a mask.
  • the mask 41 is the one in which patterns corresponding to writing signals are preliminarily formed by such a means as photoetching.
  • Numeral 42 indicates a magnetic recording medium having a dye-containing layer, of which the optical property changes by irradiation of ultraviolet rays. This can be accomplished, as mentioned above, by incorporating a dye in a specific layer of the medium.
  • the magnetic recording medium 42 will pass through an ultraviolet ray irradiation area 44 by a transporting means 43 at a predetermined speed in such a state that the mask 41 is overlaid thereon.
  • the optical property of the medium such as the light reflectance or light transmittance, will change depending upon the shapes of the light transmitting areas of the mask 41, whereby optically readable signals will be recorded.
  • a method of carrying out the above-described method by means of an electron beam is particularly effective.
  • a thin metal plate which does not permit transmittance of an electron beam such as a thin stainless steel plate having a thickness of about 10 ⁇ m
  • a pattern corresponding to servo-signals will be formed, and this is used as a mask.
  • This mask is overlaid and centerized on a magnetic recording medium prepared by forming a dye-containing layer and a magnetic layer on a support, followed by stamping into a disk shape, attaching a hub thereto followed by centering, and then an electron beam is irradiated.
  • the electron beam passes through the magnetic layer to form a desired servo pattern in the dye-containing layer.
  • the mask pattern is overlaid thereon, followed by irradiation with the laser or ultraviolet beam, and then the magnetic layer is formed.
  • the optical property changes due to e.g. discoloration, whereby servo-signals will be formed.
  • the magnetic layer is made of a light transmitting material such as barium ferrite.
  • the light transmittance is insufficient, it is preferred to read them from the opposite side through the substrate.
  • the magnetic layer may be provided on each side of the medium.
  • additional signals may be recorded in the dye-containing layer so that optical reading other than servo-signals can be conducted.
  • Such additional signals may be any signals so long as they have frequencies different from the servo-signals, and their number may be increased so long as the frequency separating means will permit.
  • the additional signals may be recorded as combined signals on the same servo tracks as for the servo-signals, or may be recorded at spatially different close positions.
  • Such additional signals may be used for recording e.g. information identifying the medium itself, information specifying the position in the rotational direction of the medium such as a sector number, or information for specifying the position in the radial direction of the medium such as a track number.
  • Such additional signals may be recorded in a dye-containing layer formed other than between the non-magnetic support and the magnetic layer.
  • a dye-containing layer may be formed on the magnetic layer or on a non-magnetic support on the side where no magnetic layer is formed in the case where the magnetic layer is formed only on one side. Otherwise, a dye may be incorporated in the magnetic layer, so that the magnetic layer serves also as a dye-containing layer, or a dye may be incorporated in a non-magnetic support so that the non-magnetic support serves also as a dye-containing layer.
  • a dye-containing layer is to be formed on the magnetic layer
  • a dye-containing solution is coated on the surface directly or with another layer interposed, followed by drying.
  • this dye-containing coating layer may be used as or in combination with another coating layer for the purpose of lubricating or protecting the magnetic layer.
  • a solution having a dye added to a suspension of a fluorinated hydrocarbon polymer such as tetrafluoroethylene teromer, ethylene-tetrafluoroethylene copolymer or hexafluoropropylene polymer may be coated on the magnetic layer.
  • a fluorinated hydrocarbon polymer such as tetrafluoroethylene teromer, ethylene-tetrafluoroethylene copolymer or hexafluoropropylene polymer
  • various conventional coating methods may be employed such as air doctor coating, blade coating, reverse roll coating and gravure coating.
  • a dye may be added at the time of the preparation of a magnetic coating material containing a magnetic material, binder resin, etc., followed by kneading and dispersing.
  • a dye is to be incorporated in the non-magnetic support
  • Ni-containing indoaniline dye of the following structural formula (II) On a polyethylene terephthalate film having a thickness of 75 ⁇ m, a solution of a Ni-containing indoaniline dye of the following structural formula (II) was coated to form a dye-containing interlayer in a thickness of about 0.2 ⁇ m as dry thickness.
  • the Ni-containing indoaniline dye of the structural formula (II) has a peak of absorbance in the vicinity of 780 nm, and when heated to a temperature of from 200 to 400°C, it decomposes, whereby the above peak decreases to a negligible level.
  • a magnetic coating material prepared by mixing 74 parts by weight of barium ferrite powder, 10 parts by weight of a polyurethane resin, 2 parts by weight of a phosphoric acid ester, 7 parts by weight of aluminum oxide, 1 part by weight of carbon black and 5 parts by weight of butyl stearate in tetrahydrofuran, was coated in a thickness of about 0.5 ⁇ m as dry thickness, to obtain a magnetic recording medium.
  • the absorption curve of the magnetic recording medium thus prepared is shown by a solid line in Figure 8.
  • the curve shown by a dotted line is the absorbance curve of a magnetic recording medium having no dye incorporated.
  • the dye-containing magnetic recording medium has a peak of absorbance in the vicinity of 780 nm which is the wavelength of a semiconductor laser employed for detecting records.
  • the dye is locally decomposed and discolored, whereby the absorbance of that area will be substantially equal to the absorbance of the magnetic recording medium containing no dye.
  • FIG. 9 An embodiment of a pattern for writing optical signals by irradiation of energy rays is shown in Figures 9 and 10.
  • the pitch of the recorded signals is at a level of from 5 ⁇ m to 10 ⁇ m.
  • the pitch is shown as enlarged in order to facilitate the understanding.
  • the light transmittance at the area shown by the oblique lines is measured by a light detector integrally formed with a magnetic head. As the disk rotates, an alternate signal will be output from the detector. Since optical records having two types of wavelengths are provided, the output signal contains signals for two types of frequencies. The high frequency component generated by optical records a undergoes a phase change as the detector moves across the track, whereas the phase of the low frequency component generated by optical records b will remain constant. Accordingly, by separating the respective frequency components by a band path filter and measuring the phase difference between the two frequency components, the head position will be determined, and accurate tracking can be carried out by controlling the head position so that the phase difference will be the predetermined value.
  • a semiconductor laser with a high output power is locally irradiated to record optical signals having a pattern as shown in Figures 9 and 10. Reading of the optical signals was conducted by means of a semiconductor laser with a low output power.
  • an easily adhesive layer having the Ni-containing indoaniline dye of the above-mentioned structural formula (II) blended to an acrylurethane type adhesive resin was formed in a thickness of about 0.2 ⁇ m as dry thickness.
  • a magnetic coating material prepared by mixing 74 parts by weight of barium ferrite powder, 10 parts by weight of a polyurethane resin, 2 parts by weight of a phosphoric acid ester, 7 parts by weight of aluminum oxide, 1 part by weight of carbon black and 5 parts by weight of butyl stearate in tetrahydrofuran, was coated in a thickness of about 0.5 ⁇ m as dry thickness, to obtain a magnetic recording medium.
  • a methyl ethyl ketone solution containing 4 parts by weight of a polymethine type dye ( ⁇ max about 820 nm) of the above structural formula (III), 72 parts by weight of a vinyl chloride/vinyl acetate/vinyl alcohol copolymer (VAGH, manufactured by Union Carbide) and 24 parts by weight of polyisocyanate, was prepared, and this solution was coated on one side of a polyethylene terephthalate film having a thickness of 75 ⁇ m, and the resin was cured by maintaining it at 60°C for three days to form a dye-containing layer.
  • the thickness of the dye-containing layer was about 1 ⁇ m, and the absorbance at ⁇ max was about 1.0.
  • a coating material containing 100 parts by weight of tin oxide powder (particle size: 0.03 ⁇ m), 15 parts by weight of a binder resin and 180 parts by weight of an organic solvent (methyl ethyl ketone/cyclohexanone 1/1), was prepared, and this coating material was coated on each side of the above film so that the film thickness after drying would be 0.5 ⁇ m.
  • the surface smoothing treatment was carried out by calendar treatment, and then it was punched out into a 3.5 inch disk. Thereafter, the dye was partially decomposed and discolored by a semiconductor laser with a wavelength of 830 nm to obtain a pattern as shown in Figures 9 and 10.
  • the light transmittance of 830 nm was about 11% at the areas where the dye was not decomposed. Whereas, the light transmittance at the decomposed areas was about 2%.
  • the magnetic recording medium of the present invention specific servo-signals are recorded in a dye-containing layer suitable for writing signals by energy rays, whereby writing is possible with an energy dose relatively small as compared with conventional method of writing signals, and an inexpensive writing apparatus can be employed. Further, there will be no removal of material attributable to writing, and no dust or the like will be generated, whereby no cleaning step after writing will be required. Further, writing of signals by energy rays, does not adversely affect the magnetic recording material, and the areas where signals are written by energy rays, can be used for magnetic recording. Furthermore, the change of the optical property of the dye by irradiation of energy rays is large, and the signals can be detected with a high sensitivity.
  • the head position can be measured by a single detector, whereby the apparatus can be down-sized, and the production costs can be reduced.

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  • Moving Of The Head To Find And Align With The Track (AREA)
  • Paints Or Removers (AREA)
EP93924171A 1992-11-06 1993-11-04 Magnetisches aufzeichnungsmedium, dessen aufzeichnungs-/wiedergabeverfahren und informationsverarbeitungssystem, das dieses medium und das verfahren gebraucht Expired - Lifetime EP0650157B1 (de)

Applications Claiming Priority (13)

Application Number Priority Date Filing Date Title
JP297076/92 1992-11-06
JP29707692A JPH06150442A (ja) 1992-11-06 1992-11-06 磁気記録媒体
JP29707692 1992-11-06
JP33627992A JPH06187630A (ja) 1992-12-16 1992-12-16 磁気記録媒体
JP33627992 1992-12-16
JP336279/92 1992-12-16
JP337536/92 1992-12-17
JP33753692A JPH06187631A (ja) 1992-12-17 1992-12-17 磁気記録媒体
JP33753692 1992-12-17
JP24713693 1993-10-01
JP24713693A JPH07105643A (ja) 1993-10-01 1993-10-01 磁気記録媒体およびその記録再生方法ならびにそれを用いた情報処理装置
JP247136/93 1993-10-01
PCT/JP1993/001593 WO1994011867A1 (en) 1992-11-06 1993-11-04 Magnetic recording medium, its recording/reproducing method and information processor which uses the medium and method

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EP0650157A1 true EP0650157A1 (de) 1995-04-26
EP0650157B1 EP0650157B1 (de) 1999-07-21

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EP (1) EP0650157B1 (de)
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WO1994011867A1 (en) 1994-05-26
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EP0650157A4 (de) 1995-01-12
US5619480A (en) 1997-04-08

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