EP0649888A2 - Tintenzusammensetzung für Tintenstrahl-Aufzeichnung - Google Patents
Tintenzusammensetzung für Tintenstrahl-Aufzeichnung Download PDFInfo
- Publication number
- EP0649888A2 EP0649888A2 EP94307867A EP94307867A EP0649888A2 EP 0649888 A2 EP0649888 A2 EP 0649888A2 EP 94307867 A EP94307867 A EP 94307867A EP 94307867 A EP94307867 A EP 94307867A EP 0649888 A2 EP0649888 A2 EP 0649888A2
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- EP
- European Patent Office
- Prior art keywords
- ink composition
- pgmbe
- composition according
- ether
- ink
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
Definitions
- the present invention relates to an ink composition for ink jet recording.
- ink compositions for ink jet recording should provide a print on various recording media without bleeding.
- various ink compositions have hitherto been proposed in the art (for example, Japanese Patent Publication Nos. 2907/1990, 15542/1989 and 3837/1990).
- U.S. Patent No. 5,156,675 discloses an ink composition containing diethylene glycol monobutyl ether.
- U.S. Patent No. 5,183,502 discloses an ink composition containing a surfactant.
- U.S. Patent No. 5,196,056 discloses an ink composition containing diethylene glycol monobutyl ether and a surfactant.
- Diethylene glycol monobutyl ether is called "butylcarbitol" and disclosed in, for example, U.S. Patent No. 3,291,580.
- U.S. Patent No. 2,083,372 discloses an ink composition containing diethylene glycol ether.
- recycled paper has become used from the viewpoint of environmental protection.
- the recycled paper comprises components of various types of paper.
- penetration of an ink composition into the recycled paper varies from component to component, which results in bleeding in the print.
- a method has been proposed wherein recording paper is heated at the time of printing. In this method, however, a certain period of time is required for the paper to be heated to a predetermined temperature. Furthermore, power consumption becomes high, which is not cost-effective. Moreover, there is a fear of the recording paper and print being deteriorated by heating.
- the ink composition for ink jet recording should satisfy further property requirements including that it should provide a good print density and a long intermittent printing time and be stable and less likely to clogging of nozzles.
- an object of the present invention is to provide an ink composition for ink jet recording which has various excellent properties, especially an ink composition for ink jet recording which can realize printing with less bleeding.
- the ink composition for ink jet recording comprises a dye, propylene glycol mono-n-butyl ether (PGmBE) and/or dipropylene glycol mono-n-butyl ether (DPGmBE) and a water-soluble glycol ether other than PGmBE and DPGmBE, the amount of PGmBE and DPGmBE being 3 to 30% by weight based on the ink composition.
- PGmBE propylene glycol mono-n-butyl ether
- DPGmBE dipropylene glycol mono-n-butyl ether
- the ink composition of the present invention comprises PGmBE and/or DPGmBE in a total amount of 3 to 30% by weight, preferably 5 to 10% by weight, based on the ink composition.
- the content of PGmBE and DPGmBE within the range can effectively prevent bleeding of the ink on recording paper.
- the ink composition of the present invention may comprise a water-soluble glycol ether in addition to PGmBE and/or DPGmBE.
- PGmBE and/or DPGmBE with a water-soluble glycol ether enables the above amount of PGmBE and DPGmBE to be realized.
- PGmBE and DPGmBE has only a limited solubility in water. According to studies of the present inventors, for example, when PGmBE and DPGmBE are used alone, the solubility thereof in water is 5 to 6%, whereas the presence of other components of the ink composition, such as dyes, lowers the solubility to less than about 2%.
- the addition of a water-soluble glycol ether to the system enables the above amount of PGmBE and DPGmBE to be realized.
- various properties of the ink composition can be improved. More specifically, for example, prints free from bleeding can be provided.
- water-soluble glycol examples include ethylene glycol monoalkyl ethers, diethylene glycol monoalkyl ethers, triethylene glycol monoalkyl ethers, propylene glycol monoalkyl ethers, dipropylene glycol monoalkyl ethers and alkoxy-substituted aliphatic alcohols.
- Still preferred examples thereof include ethylene glycol mono-C1 ⁇ 6alkyl ethers, diethylene glycol mono-C1 ⁇ 6alkyl ethers, triethylene glycol mono-C1 ⁇ 6alkyl ethers, propylene glycol mono-C1 ⁇ 6alkyl ethers, dipropylene glycol mono-C1 ⁇ 6alkyl ethers and C1 ⁇ 6alkoxy-substituted C1 ⁇ 6aliphatic alcohols.
- water-soluble glycols include ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, ethylene glycol monomethyl ether acetate, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol mono-n-propyl ether, ethylene glycol mono-iso-propyl ether, diethylene glycol monoiso-propyl ether, ethylene glycol mono-n-butyl ether, diethylene glycol mono-n-butyl ether, ethylene glycol mono-t-butyl ether, diethylene glycol mono-t-butyl ether, triethylene glycol monobutyl ether, 1-methyl-1-methoxy butanol, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol mono-t-butyl ether, propylene glycol mono-n-propyl ether, propylene glycol monomethyl
- the water-soluble glycol ether may be added in any amount so far as the ink penetration rate is sufficient and PGmBE and DPGmBE are not subjected to phase separation.
- the amount of the water-soluble glycol ether added is preferably in the range of from 5 to 60% by weight, still preferably in the range of from 5 to 15% by weight, based on the ink composition.
- the water-soluble glycol ether is preferably added in an amount of not less than 0.5% by weight, still preferably 0.8 to 3% by weight, based on the total amount of PGmBE and DPGmBE.
- the amount of the water-soluble glycol ether within the range improves the dissolution stability of PGmBE and DPGmBE.
- the odor of glycol ether can be reduced.
- the ink composition of the present invention may contain urea and/or a urea derivative.
- the addition of the urea and/or urea derivative can surprisingly improve print density and prevent clogging of ink delivery ports.
- the urea derivative include ethyleneurea, thiourea, biurea, biuret or tetramethylurea.
- the amount of the urea and/or urea derivative added can be freely determined so far as the print density of the ink composition can be improved and, at the same time, clogging of nozzles can be effectively prevented. It, however, is preferably in the range of from 2 to 20% by weight, still preferably in the range of from 5 to 10% by weight, based on the ink composition.
- the ink composition of the present invention may further comprise thioglycol.
- thioglycol surprisingly enables the intermittent printing time to be prolonged.
- the term "intermittent printing time" used herein is intended to mean the period of time for which the ink can remain undelivered without causing any unfavorable phenomena, such as clogging, in the subsequent resumption of printing.
- the ink is delivered at given time intervals for the purpose of preventing nozzles from being clogged due to drying of the vicinity of the nozzles. This operation is generally called “flushing.”
- the ink composition having a long intermittent printing time can prolong the time interval for flushing. This can advantageously avoid wasting the ink composition and, at the same time, increase the printing speed.
- the addition of thioglycol is advantageous also from the viewpoint of improving the stability of the ink composition.
- the ink composition of the present invention may further comprise a surfactant.
- the addition of the surfactant may improve properties of the ink composition, such as the intermittent printing time.
- Preferred examples of the surfactant include anionic surfactants, amphoteric surfactants, cationic surfactants and nonionic surfactants.
- anionic surfactant examples include alkylsulfocarbonates, ⁇ -olefinsulfonates, polyoxyethylene alkyl ether acetates, N-acylamino acid and its salts, N-acylmethyltaurine salts, alkylsulfate polyoxyalkyl ether sulfates, alkylsulfate polyoxyethylene ether phosphates, rosin soap, castor oil sulfates, lauryl alcohol sulfates, alkylphenol phosphates, alkyl phosphates, alkylallylsulfonates, diethylsulfosuccinates, diethylhexylsulfosuccinates and dioctylsulfosuccinates.
- Examples of the cationic surfactant include 2-vinylpyridine derivatives and poly(4-vinylpyridine) derivatives.
- Examples of the amphoteric surfactant include lauryldimethylaminoacetic acid betaine, 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, coconut oil fatty acid amide propyldimethylaminoacetic acid betaine, polyoctylpolyaminoethylglycine and other imidazoline derivatives.
- nonionic surfactant examples include ether nonionic surfactants such as polyoxyethylene nonylphenyl ether, polyoxyethylene octylphenol ether, polyoxyethylene dodecylphenyl ether, polyoxyethylene alkylallyl ether, polyoxyethylene oleyl ether, polyoxyethylene lauryl ether, polyoxyethylene alkyl ethers and polyoxyalkylene alkyl ether; ester nonionic surfactants such as polyoxyethyleneoleic acid, polyoxyethyleneoleic acid esters, polyoxyethylenedistearic acid esters, sorbitan laurate, sorbitan monostearate, sorbitan monooleate, sorbitan sesquioleate, polyoxyethylene monooleate and polyoxyethylene stearate; acetyl glycol nonionic surfactants such as 2,4,7,9-tetramethyl-5-decyn-4,7-diol, 3,6-dimethyl-4-octyn
- Fluorosurfactants particularly amphoteric or nonionic surfactants are especially preferably used. While the amount of the surfactant added may be freely determined, for the fluorosurfactant, the amount is preferably about 1 to 10,000 ppm.
- the ink composition of the present invention may further comprise a water-soluble organic solvent.
- the water-soluble organic solvent include alkyl alcohols having 1 to 4 carbon atoms such as ethanol, methanol, butanol, propanol and isopropanol; polyhydric alcohols or glycols such as ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol having a molecular weight of not more than 600, propylene glycol, dipropylene glycol, tripropylene glycol, polypropylene glycol having a molecular weight of not more than 400, 1,3-butylene glycol, 1,3-propanediol, 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, thiodiglycol, glycerin, meso-erythritol and pentaerythritol; formamide, acetamide; dimethyl
- the ink composition of the present invention may contain various additives for the purpose of improving various properties of the ink composition.
- the additive include antiseptic agents, mildewproofing agents, pH adjustors and viscosity modifiers.
- Specific examples of the antiseptic and mildewproofing agents include sodium benzoate, sodium pentachlorophenol, sodium 2-pyridinethiol-1-oxide, sodium sorbicate, sodium dehydroacetate and 1,2-dibenzothiazolin-3-one (Proxel CRL, Proxel BDN, Proxel GXL, Proxel XL-2 and Proxel TN manufactured by ICI).
- Examples of the pH adjustor include amines such a diethanolamine, triethanolamine, propanolamine and morpholine; inorganic salts such as potassium hydroxide, sodium hydroxide and lithium hydroxide; ammonium hydroxide; quaternary ammonium hydroxide such as tetramethylammonium; carbonates and phosphates such as potassium carbonate, sodium carbonate and lithium carbonate; N-methyl-2-pyrrolidone; ureas such as urea, tiourea and tetramethylurea; allophanates such as allophanate and methyl allophanate; and biurets such as biuret, dimethylbiuret and tetramethylbiuret.
- amines such a diethanolamine, triethanolamine, propanolamine and morpholine
- inorganic salts such as potassium hydroxide, sodium hydroxide and lithium hydroxide
- ammonium hydroxide such as tetramethylammonium
- viscosity adjustor examples include polyvinyl alcohol, hydroxypropyl cellulose, hydroxyethyl cellulose, methyl cellulose, polyacrylates, polyvinylpyrrolidone and gum arabic starchi.
- the colorants usable in the ink composition of the present invention include, but not limited to, direct dyes, acid dyes, basic dyes, reactive dyes and food dyes.
- the direct dye include C.I. Direct Black 2, 4, 9, 11, 14, 17, 19, 22, 27, 32, 36, 41, 48, 51, 56, 62, 71, 74, 75, 77, 78, 80, 105, 106, 107, 108, 112, 113, 117, 132, 146, 154, 168, 171 and 194, C.I. Direct Yellow 1, 2, 4, 8, 11, 12, 24, 26, 27, 28, 33, 34, 39, 41, 42, 44, 48, 50, 51, 58, 72, 85, 86, 87, 88, 98, 100, 110, 127, 135, 141, 142 and 144, C.I. Direct Orange 6, 8, 10, 26, 29, 39, 41, 49, 51, 62 and 102, C.I.
- Examples of the acid dye include C.I. Acid Black 1, 2, 7, 16, 17, 24, 26, 28, 31, 41, 48, 52, 58, 60, 63, 94, 107, 109, 112, 118, 119, 121, 122, 131, 155 and 156, C.I. Acid Yellow 1, 3, 4, 7, 11, 12, 13, 14, 17, 18, 19, 23, 25, 29, 34, 36, 38, 40, 41, 42, 44, 49, 53, 55, 59, 61, 71, 72, 76, 78, 79, 99, 111, 114, 116, 122, 135, 142, 161 and 172, C.I. Acid Orange 7, 8, 10, 19, 20, 24, 28, 33, 41, 45, 51, 56 and 64, C.I.
- Acid Blue 1 7, 9, 15, 22, 23, 25, 27, 29, 40, 41, 43, 45, 51, 53, 55, 56, 59, 62, 78, 80, 81, 83, 90, 92, 93, 102, 104, 111, 113, 117, 120, 124, 126, 138, 145, 167, 171, 175, 183, 229, 234, 236 and 249, C.I. Acid Green 3, 9, 12, 16, 19, 20, 25, 27, 41 and 44, and C.I. Acid Brown 4 and 14.
- Examples of the basic dye include C.I. Basic Black 2 and 8, C.I. Basic Yellow 1, 2, 11, 14, 21, 32 and 36, C.I. Basic Orange 2, 15, 21 and 22, C.I. Basic Red 1, 2, 9, 12, 13 and 37, C.I. Basic Violet 1, 3, 7, 10 and 14, C.I. Basic Blue 1, 3, 5, 7, 9, 24, 25, 26, 28 and 29, C.I. Basic Green 1 and 4, and C.I. Basic Brown 1 and 12.
- Examples of the reactive dye include C.I. Reactive Black 1, 3, 5, 6, 8, 12 and 14, C.I. Reactive Yellow 1, 2, 3, 12, 13, 14, 15 and 17, C.I. Reactive Orange 2, 5, 7, 16, 20 and 24, C.I. Reactive Red 6, 7, 11, 12, 15, 17, 21, 23, 24, 35, 36, 42, 63, 66, 84 and 184, C.I. Reactive Violet 2, 4, 5, 8 and 9, C.I. Reactive Blue 2, 5, 7, 12, 13, 14, 15, 17, 18, 19, 20, 21, 25, 27, 28, 37, 38, 40 and 41, C.I. Reactive Green 5 and 7, and C.I. Reactive Brown 1, 7 and 16.
- Examples of the food dye include C.I. Food Black 1 and 2, C.I. Food Yellow 3, 4 and 5, C.I. Food Red 2, 3, 7, 9, 14, 52, 87, 92, 94, 102, 104, 105 and 106, C.I. Food Violet 2, C.I. Food Blue 1 and 2, and C.I. Food Green 2 and 3.
- Kayaset Black 009A, Direct Deep Black XA and Direct Special Black AXN manufactured by Nippon Kayaku Co., Ltd. Special Black SP Liquid, Bayscript Black SP Liquid, Levacell Turquoise Blue KS-6GLL and Pyranine manufactured by Bayer Japan Ltd., JI. BK-2 and JI. BK-3 manufactured by Sumitomo Chemical Co., Ltd., JPK-81L, JPX-127L, JPK-139 and C.I. Fluorescent Brightening Agent 14, 22, 24, 32, 84, 85, 86, 87, 90, 134, 166, 167, 169, 175, 176 and 177 manufactured by Orient Chemical Industries, Ltd.
- the foamability of the ink composition as measured at 15°C by the Ross-Miles test is not more than 200 mm as the initial value and not more than 100 mm 5 min after the initiation of the test.
- the Ross-Miles test is a foamability test wherein 200 ml of a test solution is fallen down from a height of 90 cm through a small tube of 29 mm inner diameter into a graduated tube of 50mm inner diameter containing 50 ml of the test solution to determine the height of the resultant foam.
- the initial value and the value 5 min after the initiation of the test within the above range can prevent the occurrence of foam in an ink passage and an recording head.
- the ink composition can be easily filled into nozzles, which enables dropout and other unfavorable phenomena to be effectively prevented.
- the surface tension of the ink composition is preferably in the range of from 15 to 40 mN/m. When the surface tension falls within the above range, the ink composition can be easily filled into nozzles. Moreover, at the same time, a print having a good quality can be provided.
- the contact angle of the ink composition to the nozzle plate of the recording head is preferably in the range of from 10 to 50° . When the contact angle falls within the range, the ink composition can homogeneously wet nozzle faces, so that a print having a good quality can be provided. Further, this provides an advantage that the intermittent printing time can be prolonged.
- the ink composition of the present invention can be produced by the conventional method. Specifically, the above components are sufficiently stirred and mixed together, optionally filtered to remove solid matter, thereby preparing an ink composition.
- Example A contains 0.1 to 1% of Proxel XL-2 as corrosion inhibitor and 0.001 to 0.005% of benzotriazole for preventing the corrosion of recording head members.
- Ink compositions of Examples A1 to A8 and Comparative Examples A1 to A3 were prepared by the conventional method. Specifically, the following ingredients were stirred and 5 mixed together, and the mixture was filtered to prepare an ink composition.
- the circularity of dots was evaluated according to the following criteria as a measure of penetration of the ink wherein uneven penetration of the ink gave rise to a lowering in circularity of the dots.
- the recording papers specified in the table are available from the following companies. CONQUEROR Paper: Arjo Wigging Co., Ltd. FAVORIT X Paper: Favorit Co., Ltd. MODO COPY Paper: Mode Co., Ltd. RAPID COPY Paper: Igepa Co., Ltd. EPSON EPP Paper: Seiko Epson Corporation XEROX P Paper: Fuji Xerox Co., Ltd. XEROX 4024 Paper: Xerox Corp. XEROX 10 Paper: Xerox Corp. NEENACH BOND Paper: Kimberly-Clark Co., Ltd. RICOPY 6200 Paper: Ricoh Co., Ltd. Yamayuri Paper: Honshu Paper Co., Ltd. XEROX R Paper: Xerox Corp.
- the amounts of diethylene glycol monoethyl ether and 1,4-butanediol added as organic solvents were varied in the range of from 2 to 35% (an increase or a decrease in the amount of the organic solvents was balanced by water) with the ratio of diethylene glycol monoethyl ether to 1,4-butanediol being maintained at 2 : 1.
- One (1) ⁇ l of the ink composition was dropped in a spot form on DERSCHER paper. The time taken for drying the ink spot was measured as a penetration time. The results are indicated as ⁇ in Fig. 1.
- Example Al 10% Surfynol 465 was used instead of 10% PGmBE, and the amounts of diethylene glycol monoethyl ether and 1,4-butanediol added as organic solvents were varied with the ratio of diethylene glycol monoethyl ether to 1,4-butanediol being maintained at 2 : 1.
- the penetration time of the ink composition was measured in the same manner as described above. The results are indicated as ⁇ in Fig. 1.
- Example A1 10% diethylene glycol mono-n-butyl ether and 1% Surfynol 465 were used instead of 10% PGmBE, respectively, and the amounts of diethylene glycol monoethyl ether and 1,4-butanediol added as organic solvents were varied with the ratio of diethylene glycol monoethyl ether to 1,4-butanediol being maintained at 2 : 1.
- the penetration time of the ink composition was measured in the same manner as described above. The results are indicated as ⁇ and ⁇ in Fig. 1.
- Example A1 In the ink composition prepared in Example A1, the amounts of PGmBE and diethylene glycol monoethyl ether added were varied with the ratio of PGmBE to diethylene glycol monoethyl ether being maintained at 1 : 1.
- the penetration time of the ink composition was measured in the same manner as in Evaluation test A2. The results are indicated as ⁇ in Fig. 2.
- the penetration time of the ink composition was measured in the same manner as described above, except that DPGmBE was used instead of PGmBE. The results are indicated as ⁇ in Fig. 2.
- Ink compositions of Examples B1 to B8 and Comparative Examples B1 to B3 were prepared by the conventional method.
- OD ratios were as follows. Examples OD ratio 1 8.8 2 9.7 3 7.7 4 9.2 5 6.5 6 2.3 7 3.2 8 1.5
- Example B1 In the ink composition of Example B1, the amount of urea added was varied. A change in the total amount of the composition caused by the increase or decrease in the amount of urea add was balanced by water. The OD values of prints obtained using the ink compositions were measured. The results were as shown in Fig. 3.
- Ink compositions of Examples C1 to C8 and ink compositions of Comparative Examples C1 to C3 were prepared by the conventional method.
- Bayscript Black SP liquid 20% DPGmBE 10% Propylene glycol monoethyl ether 10% Thiodiglycol 12% Tripropylene glycol 3% 1,3-Dimethyl-2-imidazolidinone 5% Water Balance
- Example D1 In the ink composition of Example D1, the thiodiglycol concentration was varied. A change in the total amount of the composition caused by the increase or decrease in the amount of thiodiglycol add was balanced by water. The intermittent printing time for the inks was measured. The results were as shown in Fig. 4.
- the fluorosurfactant used in the following examples and comparative examples was Ftargent 251 (manufactured by Neos Co., Ltd.).
- Bayscript Black SP liquid 20% DPGmBE 10% Propylene glycol monoethyl ether 10% Fluorosurfactant 0.2% Tripropylene glycol 3% 1,3-Dimethyl-2-imidazolidinone 5% Water Balance
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Applications Claiming Priority (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP26748193 | 1993-10-26 | ||
JP267481/93 | 1993-10-26 | ||
JP1183794 | 1994-02-03 | ||
JP11837/94 | 1994-02-03 | ||
JP1183894 | 1994-02-03 | ||
JP11838/94 | 1994-02-03 | ||
JP97678/94 | 1994-05-11 | ||
JP9767894 | 1994-05-11 | ||
JP199749/94 | 1994-08-24 | ||
JP19974994 | 1994-08-24 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0649888A2 true EP0649888A2 (de) | 1995-04-26 |
EP0649888A3 EP0649888A3 (de) | 1995-11-29 |
EP0649888B1 EP0649888B1 (de) | 1999-04-28 |
Family
ID=27519336
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP94307867A Expired - Lifetime EP0649888B1 (de) | 1993-10-26 | 1994-10-26 | Tintenzusammensetzung für Tintenstrahl-Aufzeichnung |
Country Status (3)
Country | Link |
---|---|
US (1) | US5560770A (de) |
EP (1) | EP0649888B1 (de) |
DE (1) | DE69418135T2 (de) |
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JP6169501B2 (ja) * | 2014-01-31 | 2017-07-26 | 富士フイルム株式会社 | インクジェット記録用インク |
WO2016081295A1 (en) * | 2014-11-18 | 2016-05-26 | 3M Innovative Properties Company | Compositions comprising biguanide compound and diol surfactant |
JP6582397B2 (ja) * | 2014-11-21 | 2019-10-02 | 株式会社リコー | インクジェット記録方法及びインクジェット記録装置 |
JP6866720B2 (ja) * | 2017-03-24 | 2021-04-28 | セイコーエプソン株式会社 | インクジェット記録用水系インク組成物および色材液 |
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JPH02255774A (ja) * | 1989-03-29 | 1990-10-16 | Dainippon Ink & Chem Inc | インクジェット記録用水性インク |
US5165968A (en) * | 1989-08-17 | 1992-11-24 | Hewlett-Packard Company | Ink composition having rapid dry time and high print quality for plain paper printing |
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US5156675A (en) * | 1991-05-16 | 1992-10-20 | Xerox Corporation | Ink for ink jet printing |
JP3123195B2 (ja) * | 1992-04-15 | 2001-01-09 | ミノルタ株式会社 | インクジェット用記録液 |
JP3176444B2 (ja) * | 1992-10-01 | 2001-06-18 | 株式会社リコー | 水性インク及びこれを用いた記録方法 |
US5441561A (en) * | 1993-02-23 | 1995-08-15 | Fuji Xerox Co., Ltd. | Ink-jet recording ink and ink-jet recording methods thereof |
-
1994
- 1994-10-25 US US08/328,892 patent/US5560770A/en not_active Expired - Fee Related
- 1994-10-26 DE DE69418135T patent/DE69418135T2/de not_active Expired - Lifetime
- 1994-10-26 EP EP94307867A patent/EP0649888B1/de not_active Expired - Lifetime
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JPH02255774A (ja) * | 1989-03-29 | 1990-10-16 | Dainippon Ink & Chem Inc | インクジェット記録用水性インク |
US5165968A (en) * | 1989-08-17 | 1992-11-24 | Hewlett-Packard Company | Ink composition having rapid dry time and high print quality for plain paper printing |
Non-Patent Citations (1)
Title |
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WORLD SURFACE COATINGS ABSTRACTS, vol.65, no.599, 1992, HILL HALL,GB page 817 'WATER-BASED INK FOR INK-JET RECORDER' & JP-A-2 255 774 (DAI-NIPPON INK & CHEMICALS) * |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
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EP1010735A1 (de) * | 1998-12-17 | 2000-06-21 | Nec Corporation | Wässrige Tinte, Tintenstrahldrucker und Tintenkartusche |
WO2001077237A1 (fr) * | 2000-04-11 | 2001-10-18 | Seiko Epson Corporation | Composition d'encre |
WO2002055619A1 (fr) * | 2001-01-15 | 2002-07-18 | Seiko Epson Corporation | Encre huileuse pour impression par jets d'encre et procede d'impression associe |
US7156909B2 (en) | 2001-01-15 | 2007-01-02 | Seiko Epson Corporation | Oily ink composition for ink-jet recording, and ink-jet recording method |
WO2003011987A1 (de) * | 2001-07-17 | 2003-02-13 | Basf Aktiengesellschaft | Farbmittelzubereitungen |
US7566361B2 (en) | 2001-07-17 | 2009-07-28 | Basf Aktiengesellschaft | Colouring preparations |
EP1308487A1 (de) * | 2001-10-30 | 2003-05-07 | Hewlett-Packard Company | Verfahren zur Ausblutkontrolle zwischen schwarzen und farbigen Tinten |
US6730152B2 (en) | 2001-10-30 | 2004-05-04 | Hewlett-Packard Development Company, L.P. | Methods of controlling bleed between black and color dye based inks in printing applications |
US7014698B2 (en) | 2003-06-12 | 2006-03-21 | Hitachi Maxell, Ltd. | Oil-based pigmented ink composition |
US7132013B2 (en) | 2003-06-12 | 2006-11-07 | Hitachi Maxell, Ltd. | Oil-based pigmented ink composition |
US7132014B2 (en) | 2003-06-12 | 2006-11-07 | Hitachi Maxell, Ltd. | Oil-based pigmented ink composition |
EP1486542A1 (de) * | 2003-06-12 | 2004-12-15 | Hitachi Maxell, Ltd. | Auf Öl basierende pigmenthaltige Tintenzusammensetzung |
US7025817B2 (en) | 2003-08-11 | 2006-04-11 | Canon Kabushiki Kaisha | Ink, recording method, recording unit, ink cartridge, and recording apparatus |
EP1657284A1 (de) * | 2003-08-11 | 2006-05-17 | Canon Kabushiki Kaisha | Tinte, aufzeichnungsverfahren, aufzeichnungseinheit, tintenpatrone und aufzeichnungsgerät |
EP1657284A4 (de) * | 2003-08-11 | 2006-08-23 | Canon Kk | Tinte, aufzeichnungsverfahren, aufzeichnungseinheit, tintenpatrone und aufzeichnungsgerät |
EP1512731A1 (de) * | 2003-08-28 | 2005-03-09 | Konica Minolta Holdings, Inc. | Tinte und Tintenstrahldruckaufzeichnungsverfahren unter Verwendung desselben |
US7169217B2 (en) | 2003-08-28 | 2007-01-30 | Konica Minolta Holdings, Inc. | Ink and ink-jet recording method using the same |
Also Published As
Publication number | Publication date |
---|---|
DE69418135T2 (de) | 1999-10-28 |
EP0649888B1 (de) | 1999-04-28 |
EP0649888A3 (de) | 1995-11-29 |
US5560770A (en) | 1996-10-01 |
DE69418135D1 (de) | 1999-06-02 |
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