EP0635334A2 - Eine von Schleifteilchen enthaltendem Harz imprägnierte Scheibe, Verfahren zum Herstellen der Scheibe und Läppenverfahren - Google Patents
Eine von Schleifteilchen enthaltendem Harz imprägnierte Scheibe, Verfahren zum Herstellen der Scheibe und Läppenverfahren Download PDFInfo
- Publication number
- EP0635334A2 EP0635334A2 EP94830368A EP94830368A EP0635334A2 EP 0635334 A2 EP0635334 A2 EP 0635334A2 EP 94830368 A EP94830368 A EP 94830368A EP 94830368 A EP94830368 A EP 94830368A EP 0635334 A2 EP0635334 A2 EP 0635334A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- disc
- discs
- abrasive
- resin
- wheel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011347 resin Substances 0.000 title claims abstract description 31
- 229920005989 resin Polymers 0.000 title claims abstract description 31
- 239000004753 textile Substances 0.000 title claims abstract description 11
- 238000000034 method Methods 0.000 title claims description 22
- 239000002245 particle Substances 0.000 title claims description 16
- 230000008569 process Effects 0.000 title claims description 9
- 238000002360 preparation method Methods 0.000 title description 2
- 239000000843 powder Substances 0.000 claims abstract description 21
- 239000003082 abrasive agent Substances 0.000 claims abstract description 8
- 239000004744 fabric Substances 0.000 claims description 29
- 238000011282 treatment Methods 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 12
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 9
- 229920000742 Cotton Polymers 0.000 claims description 8
- 244000198134 Agave sisalana Species 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 7
- 239000006185 dispersion Substances 0.000 claims description 7
- 238000013021 overheating Methods 0.000 claims description 6
- 239000000725 suspension Substances 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- 244000025254 Cannabis sativa Species 0.000 claims description 5
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 claims description 5
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 claims description 5
- 240000000491 Corchorus aestuans Species 0.000 claims description 5
- 235000011777 Corchorus aestuans Nutrition 0.000 claims description 5
- 235000010862 Corchorus capsularis Nutrition 0.000 claims description 5
- 235000004431 Linum usitatissimum Nutrition 0.000 claims description 5
- 235000009120 camo Nutrition 0.000 claims description 5
- 235000005607 chanvre indien Nutrition 0.000 claims description 5
- 239000011487 hemp Substances 0.000 claims description 5
- 229910044991 metal oxide Inorganic materials 0.000 claims description 5
- 150000004706 metal oxides Chemical class 0.000 claims description 5
- 210000002268 wool Anatomy 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 4
- 239000004925 Acrylic resin Substances 0.000 claims description 3
- 229920000178 Acrylic resin Polymers 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- 230000001804 emulsifying effect Effects 0.000 claims description 2
- 239000003822 epoxy resin Substances 0.000 claims description 2
- 239000012530 fluid Substances 0.000 claims description 2
- 230000006872 improvement Effects 0.000 claims description 2
- 238000011065 in-situ storage Methods 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 241000208202 Linaceae Species 0.000 claims 3
- 238000009434 installation Methods 0.000 claims 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims 1
- 238000005470 impregnation Methods 0.000 abstract description 5
- 238000005119 centrifugation Methods 0.000 abstract description 3
- 230000000379 polymerizing effect Effects 0.000 abstract description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 150000004665 fatty acids Chemical class 0.000 description 6
- 239000003995 emulsifying agent Substances 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- 239000003760 tallow Substances 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 4
- 238000004381 surface treatment Methods 0.000 description 4
- 239000001055 blue pigment Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 240000006240 Linum usitatissimum Species 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- 229910001369 Brass Inorganic materials 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002991 molded plastic Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 230000007425 progressive decline Effects 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D18/00—Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
- B24D18/0027—Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for by impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D13/00—Wheels having flexibly-acting working parts, e.g. buffing wheels; Mountings therefor
- B24D13/02—Wheels having flexibly-acting working parts, e.g. buffing wheels; Mountings therefor acting by their periphery
- B24D13/12—Wheels having flexibly-acting working parts, e.g. buffing wheels; Mountings therefor acting by their periphery comprising assemblies of felted or spongy material, e.g. felt, steel wool, foamed latex
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/02—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
- B24D3/20—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially organic
- B24D3/28—Resins or natural or synthetic macromolecular compounds
Definitions
- This invention concerns the mechanical surface treatment by which the untreated surface is lapped and eventually buffed in the final treatment stages.
- This type of surface treatment can be carried out on metals, painted or varnished surfaces, cast or injection-molded plastics and the like.
- cloths or plaits used are usually made of natural fibres such as cotton, agave sisal, flax, hemp, wool and jute, on account of these natural fibres' higher resistance to overheating during treatment.
- a wide range of cloths and abrasive pastes selections may create operating conditions ranging from highly abrasive lapping to almost purely buffing treatments. As experienced operators know, there may be several intermediate stages of leveling/buffing through which abrasive properties are progressively reduced and viceversa buffing/polishing properties increased.
- the work area is the wheel outer periphery. Therefore, the air radially flowing from the wheel center towards the periphery - accelerated by appropriately-shaped holes or air intakes in the wheel truing plates - "cools down" the peripheral work area of the wheel, thus allowing non-stop machining.
- the abrasive paste is intermittently distributed on the work area, by injecting it through appropriately oriented nozzles.
- the intermittent feeding of abrasive paste in the work area entails periodic, even drastic changes in the operating conditions.
- the work run shows performance "peaks” alternating with performance "drops", "synchronized” through repeated feeds of fresh abrasive paste during treatment.
- a lot of the abrasive paste is inevitably lost due to the centrifugal force. Losses increase when the disc or wheel work area gets overheated, since the paste tends to become more fluid as the temperature rises.
- the lost abrasive paste cannot be recovered, nor can it be recycled. Therefore, the lost paste not only represents an important cost item in the working process, but its disposal also causes environmental problems.
- Buffing discs and wheels are essentially expendable materials, since they undergo progressive wearing. Ventilated wheels are to be replaced when their outer diameter has decreased below a certain limit, which in many cases can be as low as 60 ⁇ 70% of the original wheel diameter.
- a widely-used technique to increase the cloth or plait wear resistance is to provide "rigidity" to the cloth of which the wheel or disc are made by impregnating it with special emulsions of an acrylic, vinyl, epoxy or oily resin. If necessary, the resin impregnating the cloth is then submitted to a polymerization heat-treatment.
- the cloth is vacuum-impregnated by placing it in a special evacuable "autoclave" into which the impregnating emulsion is poured. After draining the emulsion from the vacuum chamber, the buffing discs or wheels are removed and then heated in the oven, to eliminate possible traces of solvent, till the temperature reached and the time elapsed are sufficient to allow resin polymerization.
- this new techinque consists in impregnating a buffing disc or wheel with an emulsion-suspension containing both a polymerizable resin and an abrasive powder and successively polymerizing the resin.
- This treatment of the textile discs or wheels brings about an unexpected series of highly positive effects.
- the abrasive powder (of a given particle size) incorporated in the resin with which the lapping/buffing disc/wheel cloth is impregnated produces an extra source of lapping agent (e.g., a metal oxide) "in situ".
- lapping agent e.g., a metal oxide
- the abrasive powder incorporated in the impregnating resin of the disc/wheel cloth is gradually released onto the surface or work area.
- This extra abrasive powder rather than merely adding to the intermittently fed abrasive paste, tends to supplement it during the intervals between intermittent distributions of abrasive paste on the work area, so as to make up for and decrease the occurrence of abrasive powder shortages occurring between two successive distribution cycles of fresh abrasive paste.
- this not only helps maintaining suitable lapping properties, but it also reduces overall treatment time and allows a drastic reduction in the amount of abrasive paste to be progressively distributed during the entire working cycle.
- this technique reduces cloth disc overheating and wearing, during the abrasive paste shortage phases between two subsequent abrasive paste feeds, thus prolonging the life of the ventilated disc or wheel.
- Fig. 1 shows a buffing disc 1 consisting of a "pack” or pile of cloth discs (2), piled up one on top of the other and joined by concentric seams (3). Hub (4) allows the disc to be installed on a rotating spindle.
- the disc may also include two side strengthening discs (5) made of cardboard or other suitable material.
- Fig. 2 shows a ventilated buffing disc (or wheel) obtained by placing together a certain number of strips (2') of slanting cloth folded into a "V". Cloth strips are anchored to a metal hub (4') which may include two side discs (5'), provided with openings or air intakes (6) to let cooling air flow from the hub core towards the peripheral work area of the wheel, through air passages.
- the cloth may be made up of cotton, agave sisal, wool, flax, hemp, jute, or similar fibres with adequate resistance against overheating.
- the fabric may be made up of a single type of fibre or may be obtained by combining different fibres in different amounts.
- Cotton and sisal are among the most widely used fibres. The latter is particularly suitable for roughing discs. This fiber can in fact generate a higher abrasive power and is therefore recommended for preliminary surface lapping.
- abrasive power is gradually reduced and buffing conditions are enhanced by using increasingly "softer" (e.g., cotton) buffing discs and increasingly thinner abrasive pastes.
- the type of cloth or plaited cord used for these discs may change depending on the characteristics required. Therefore, besides combining different fibres, more or less "napped" cloths are used to adjust the abrasive and/or buffing power of the disc.
- An abrasive powder suspension of the required particle size and characteristics is prepared in a special tank - fitted with a stirrer - containing a liquid mixture consisting of an aqueous dispersion of a soluble resin, which may be an acrylic, vinyl, or epoxy resin, together with emulsifying agents, such as fatty acids obtained from tallow or other oily compounds.
- a liquid mixture consisting of an aqueous dispersion of a soluble resin, which may be an acrylic, vinyl, or epoxy resin, together with emulsifying agents, such as fatty acids obtained from tallow or other oily compounds.
- the mixture is kept homogeneous through continuous stirring.
- the discs are removed from the autoclave and centrifuged in a special centrifugal chamber (centrifuge) until they reach a substantial dynamic balance.
- This centrifugation process besides eliminating the impregnating mixture in excess, ensures a substantially uniform distribution of the impregnating substance.
- the impregnated and centrifuged discs are finally oven-treated by progressively raising the temperature of the oven up to about 140°-170°C.
- the impregnating mixture is dried by evaporation of the aqueous solvent and the resin is polymerized and fixed onto the cloth fibres incorporating the particles of the abrasive material contained in the impregnating suspension.
- the mixing ratio between the resin and the abrasive powder usually ranges in weight between 0.5:1 and 1.5:1. Tests show that if aluminum oxide (Al2O3), with a 50% to 98% ⁇ -alumina content, in terms of overall weight, is used as abrasive material together with an acrylic resin, the ratio between the abrasive material absorbed and the incorporating resin should be about 1:1.
- the particle size of the abrasive powder incorporated in the cloth-impregnating resin may range between 20 and 100 ⁇ m.
- the particle size is selected according to the type of disc required. A coarse particle size is recommended for the preparation of "roughing" discs, whereas a finer size is more suitable for discs to be used at the lapping/buffing stage, to get extremely leveled and buffed surfaces.
- fatty acids or similar emulsifying compounds in percentages ranging from about 10% to 20% of the overall mixture weight facilitates the dispersion and suspension of the abrasive particles in the mixture.
- the discs produced according to the procedure of this invention hereinafter referred to with acronym I.R.A. (Impregnazione Resistenza Abrasiva, i.e. Abrasive Resistance Impregnation) prove to be unexpectedly effective and long-lasting as compared to the discs impregnated according to the traditional technique, i.e. without incorporating abrasive particles in the dressing resin.
- a basic feature of the discs manufactured according to this invention is the improvement in the overall performance of the mechanical surface treatment, as compared to the discs produced according to the former technique.
- This important advantage has been quantified through a series of tests comparing I.R.A. discs with discs having the same features but without abrasive particles incorporated in the impregnating resin.
- This study was carried out for buffing processes on rotary tables mainly using discs of the so-called ventilated type.
- the highly automated and continuously operated type of treatment actually provides ideal conditions, on the one hand for detecting the effects produced by the treatment as a function of time, according to observable "indexes", and on the other, for comparing the actual effectiveness of the treatment.
- this treatment provided for a timed feed of abrasive paste in the work area at preset intervals.
- the lapping performance was assessed according to an empiric 0 to 100 scale. Efficacy was rated by observing the ability of the disc to level off grooves created on the surface of brass and stainless steel workpieces by sanding it with a 80 to 360 grain size sanding paper.
- the buffing discs used in a first comparative test series were ventilated discs made of agave sisal cloth and with a configuration similar to that shown in Fig. 2.
- the impregnating mixture of I.R.A. discs manufactured according to this invention was the following:
- a second set of test discs had the same configuration as the one shown in Fig. 2, but made with cotton cloth strips.
- the impregnating mixture was the following:
- Impregnation was carried out after a 25 Torr vacuum was created in the autoclave.
- the impregnated discs were centrifuged at about 1,400-2,800 r.p.m. for about ten seconds.
- the drying-polymerization process was carried out by gradually heating the discs from room temperature up to 150°C in one hour, and by keeping the 150°C temperature constant for a further 30 minutes.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Polishing Bodies And Polishing Tools (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT93VA000014A IT1265984B1 (it) | 1993-07-22 | 1993-07-22 | Disco o ruota di materiale tessile impregnato con resina contenente particelle di materiale abrasivo, procedimento di preparazione e |
ITVA930014 | 1993-07-22 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0635334A2 true EP0635334A2 (de) | 1995-01-25 |
EP0635334A3 EP0635334A3 (de) | 1995-05-24 |
EP0635334B1 EP0635334B1 (de) | 2002-06-05 |
Family
ID=11423242
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP94830368A Expired - Lifetime EP0635334B1 (de) | 1993-07-22 | 1994-07-20 | Eine von Schleifteilchen enthaltendem Harz imprägnierte Scheibe, Verfahren zum Herstellen der Scheibe und Läppenverfahren |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP0635334B1 (de) |
DE (1) | DE69430715T2 (de) |
IT (1) | IT1265984B1 (de) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997018059A1 (en) * | 1995-11-16 | 1997-05-22 | Minnesota Mining And Manufacturing Company | Surface treating articles and method of making same |
CN102794715A (zh) * | 2012-08-03 | 2012-11-28 | 河南工业大学 | 一种纤维增强砂轮基体及其制备方法 |
CN104260004A (zh) * | 2014-08-06 | 2015-01-07 | 翁博川 | 一种具有光亮剂的抛光轮及其加工方法 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH417387A (fr) * | 1961-02-06 | 1966-07-15 | Carborundum Co | Objet abrasif et son procédé de fabrication |
JPS6128573A (ja) * | 1984-07-18 | 1986-02-08 | Mitsubishi Mining & Cement Co Ltd | 研磨パツド及びその製造方法 |
DE8430781U1 (de) * | 1984-10-19 | 1987-07-23 | Brand, Jack, Toronto, Ontario, Ca | |
EP0400658A2 (de) * | 1989-05-31 | 1990-12-05 | Norton Company | Umhülltes Schleifmaterial, sein Herstellungsverfahren und seine Anwendung |
EP0446871A1 (de) * | 1990-03-12 | 1991-09-18 | Kurt Koch Gmbh | Verfahren und Vorrichtung zum Schleifen bzw. Schärfen der Schneide eines Materialbearbeitungswerkzeugs |
US5129919A (en) * | 1990-05-02 | 1992-07-14 | Norton Company | Bonded abrasive products containing sintered sol gel alumina abrasive filaments |
US5224968A (en) * | 1992-07-07 | 1993-07-06 | Ramron-Bancroft, Inc. | Method for making abrasive wheels |
-
1993
- 1993-07-22 IT IT93VA000014A patent/IT1265984B1/it active IP Right Grant
-
1994
- 1994-07-20 EP EP94830368A patent/EP0635334B1/de not_active Expired - Lifetime
- 1994-07-20 DE DE69430715T patent/DE69430715T2/de not_active Expired - Fee Related
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH417387A (fr) * | 1961-02-06 | 1966-07-15 | Carborundum Co | Objet abrasif et son procédé de fabrication |
JPS6128573A (ja) * | 1984-07-18 | 1986-02-08 | Mitsubishi Mining & Cement Co Ltd | 研磨パツド及びその製造方法 |
DE8430781U1 (de) * | 1984-10-19 | 1987-07-23 | Brand, Jack, Toronto, Ontario, Ca | |
EP0400658A2 (de) * | 1989-05-31 | 1990-12-05 | Norton Company | Umhülltes Schleifmaterial, sein Herstellungsverfahren und seine Anwendung |
EP0446871A1 (de) * | 1990-03-12 | 1991-09-18 | Kurt Koch Gmbh | Verfahren und Vorrichtung zum Schleifen bzw. Schärfen der Schneide eines Materialbearbeitungswerkzeugs |
US5129919A (en) * | 1990-05-02 | 1992-07-14 | Norton Company | Bonded abrasive products containing sintered sol gel alumina abrasive filaments |
US5224968A (en) * | 1992-07-07 | 1993-07-06 | Ramron-Bancroft, Inc. | Method for making abrasive wheels |
Non-Patent Citations (1)
Title |
---|
DATABASE WPI Week 8612, Derwent Publications Ltd., London, GB; AN 86-079162 & JP-A-61 028 573 (MITSUBISHI MINING CEMENT) 8 February 1986 * |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997018059A1 (en) * | 1995-11-16 | 1997-05-22 | Minnesota Mining And Manufacturing Company | Surface treating articles and method of making same |
US5996167A (en) * | 1995-11-16 | 1999-12-07 | 3M Innovative Properties Company | Surface treating articles and method of making same |
US6251002B1 (en) | 1995-11-16 | 2001-06-26 | 3M Innovative Properties Company | Surface treating articles and method of making same |
US6514363B2 (en) | 1995-11-16 | 2003-02-04 | 3M Innovative Properties Company | Surface treating articles and method of making same |
CN102794715A (zh) * | 2012-08-03 | 2012-11-28 | 河南工业大学 | 一种纤维增强砂轮基体及其制备方法 |
CN102794715B (zh) * | 2012-08-03 | 2015-07-15 | 河南工业大学 | 一种纤维增强砂轮基体及其制备方法 |
CN104260004A (zh) * | 2014-08-06 | 2015-01-07 | 翁博川 | 一种具有光亮剂的抛光轮及其加工方法 |
Also Published As
Publication number | Publication date |
---|---|
ITVA930014A0 (it) | 1993-07-22 |
EP0635334B1 (de) | 2002-06-05 |
DE69430715T2 (de) | 2002-09-26 |
IT1265984B1 (it) | 1996-12-16 |
ITVA930014A1 (it) | 1995-01-22 |
EP0635334A3 (de) | 1995-05-24 |
DE69430715D1 (de) | 2002-07-11 |
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