EP0626460B1 - Acier inoxydable austénitique à haute résistance à la corrosion par les milieux chlorurés et sulfuriques et utilisations - Google Patents
Acier inoxydable austénitique à haute résistance à la corrosion par les milieux chlorurés et sulfuriques et utilisations Download PDFInfo
- Publication number
- EP0626460B1 EP0626460B1 EP94401110A EP94401110A EP0626460B1 EP 0626460 B1 EP0626460 B1 EP 0626460B1 EP 94401110 A EP94401110 A EP 94401110A EP 94401110 A EP94401110 A EP 94401110A EP 0626460 B1 EP0626460 B1 EP 0626460B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- stainless steel
- austenitic stainless
- steel according
- steel
- equipment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C30/00—Alloys containing less than 50% by weight of each constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
Definitions
- the present invention relates to stainless steel austenitic with high mechanical strength and high corrosion resistance.
- stainless steels with high mechanical resistance and high corrosion resistance in chlorinated media and sulfuric media or even in media at a time chlorinated and sulfuric are superaustenitic steels, austenoferritic steels or superaustenitic steels with a high nitrogen content.
- superaustenitic steels with a high nitrogen content are, for these applications, the steels which offer the better performance in terms of combination of characteristics mechanical and corrosion resistance. They are described by two European patents: EP-A-0.438.992 and EP-A-0.342.574.
- the subject of the present invention is an austenitic stainless steel with high mechanical strength and high corrosion resistance, characterized in that it contains by weight: 23% ⁇ Cr ⁇ 28% 25% ⁇ Ni ⁇ 28% 4.5% ⁇ Mo ⁇ 7% 0.35% ⁇ N ⁇ 0.8% 0.5% ⁇ Mn ⁇ 5.4% C ⁇ 0.06% S ⁇ 0.010% If ⁇ 1% 0.5% ⁇ Cu ⁇ 3%, and at least one of the elements B, Nb, V, Al in the following contents: B 0.0001 to 0.003%, Nb 0.001 to 0.3%, V 0.001 to 0.3% and Al 0.001 to 0.1 %, the rest, with the exception of iron, being made up of impurities resulting from processing.
- the carbon content is less than 0.04%.
- this steel can contain from 1% to 2% copper.
- the composition of the steel according to the invention is as follows: 25% ⁇ Cr ⁇ 26% 25% ⁇ Ni ⁇ 26% 6% ⁇ Mo ⁇ 7% 0.4% ⁇ N ⁇ 0.5% 2.5% ⁇ Mn ⁇ 3.5% C ⁇ 0.03% If ⁇ 0.3% 1% ⁇ Cu ⁇ 2%, the rest, with the exception of iron, being constituted by impurities resulting from the production.
- the invention also relates to the use steel according to the invention for the manufacture of equipment pollution control from thermal power plants and household waste incineration plants, especially gas or smoke washing towers, gas lines or smoke and chimneys; for manufacturing equipment delignification, in particular by the process bisulfite, filtration and bleaching of the pulp paper; for manufacturing equipment for industry chemical in chlorinated or acidic medium and in particular for the manufacture of tanks, reservoirs, reactors, tubes pump casing and pump shafts; for the manufacture off-shore platform equipment subject to corrosion by sea water and / or hydrocarbons and in particular supports for flares, heat exchangers, separators, tubular plates, piping transport of sea water, pipes used for the transport of hydrocarbons, elements of protection of pylon areas in the vicinity of the free surface from the sea, mace rods, pump shafts, flanges connection, wellheads, manifolds and risers; for the manufacture road or rail transport tanks of chlorides or highly corrosive acids.
- Such steel must contain less than 0.06% of carbon to avoid precipitation of carbides to grain boundaries which deteriorate corrosion resistance and it is preferable to limit this content to 0.04% and even better at 0.03%.
- the steel always contains a little sulfur must be up to 0.010% which is favorable to machinability but which promotes corrosion by bites, too, it's better to have a sulfur content less than 0.01%.
- copper between 0.5% and 3% and preferably between 1% and 2%; copper also has the advantage of improving machinability.
- Additions of copper, vanadium, niobium, boron, aluminum are optional and can be made alone or in combination.
- the main alloying elements have, for certain properties, effects all the more favorable as their content is high and for other properties, effects all the less unfavorable as the content is lower; therefore, it is preferable to choose the chemical composition in a composition range which is not too wide.
- the domains of chromium, nickel and molybdenum must be limited to: 23% ⁇ Cr ⁇ 28% 25% ⁇ Ni ⁇ 28% 4.5% ⁇ Mo ⁇ 7%.
- This steel may also contain Nb, V, B or Al as previously stated.
- the steel according to the invention has an additional advantage which comes from the fact that the product A x R of the elongation at break by the break limit is very high (two times more than for the steels of the prior art used for transport) so that resistance to impact of the walls made with this steel is very high and in particular much higher than for steels of prior art.
- This feature has the advantage of allowing to make tanks, containers or pipes for transporting much safer corrosives in the event of an impact, that the equivalent equipment produced with steels according to the prior art.
- This steel makes it particularly suitable for the manufacture of reactors (scrubbers, washing tower, filter tanks, attack tanks), tubes (welded and seamless), chimneys, parts junction such as flanges, manifolds, flow lines, separators and road or rail transport tanks, for industries in which this equipment is subject to very severe corrosion by chlorinated media and / or pure or polluted sulfuric and in particular for off-shore oil exploitation platforms, for combustion smoke abatement facilities thermal power plants or incineration of household waste, for the preparation of paper pulp in particular by the process called "bisulfite", and in particular for filtration, bleaching and delignification equipment, for the chemical industry and more particularly for hydrometallurgy equipment and the industry fertilizer using mineral attack by media concentrated sulfurics.
- This steel also makes it possible to carry out any part subject to abrasion / corrosion in environments chlorides and / or acids.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Paper (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Physical Vapour Deposition (AREA)
- Structures Of Non-Positive Displacement Pumps (AREA)
- Heat Treatment Of Steel (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9306468A FR2705689B1 (fr) | 1993-05-28 | 1993-05-28 | Acier inoxydable austénitique à haute résistance à la corrosion par les milieux chlorurés et sulfuriques et utilisations. |
| FR9306468 | 1993-05-28 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0626460A1 EP0626460A1 (fr) | 1994-11-30 |
| EP0626460B1 true EP0626460B1 (fr) | 2000-02-02 |
Family
ID=9447577
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP94401110A Expired - Lifetime EP0626460B1 (fr) | 1993-05-28 | 1994-05-18 | Acier inoxydable austénitique à haute résistance à la corrosion par les milieux chlorurés et sulfuriques et utilisations |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5480609A (da) |
| EP (1) | EP0626460B1 (da) |
| AT (1) | ATE189483T1 (da) |
| DE (1) | DE69422850T2 (da) |
| DK (1) | DK0626460T3 (da) |
| ES (1) | ES2141806T3 (da) |
| FI (1) | FI110010B (da) |
| FR (1) | FR2705689B1 (da) |
| GR (1) | GR3033108T3 (da) |
| NO (1) | NO302623B1 (da) |
| PT (1) | PT626460E (da) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2711674B1 (fr) * | 1993-10-21 | 1996-01-12 | Creusot Loire | Acier inoxydable austénitique à hautes caractéristiques ayant une grande stabilité structurale et utilisations. |
| US5841046A (en) * | 1996-05-30 | 1998-11-24 | Crucible Materials Corporation | High strength, corrosion resistant austenitic stainless steel and consolidated article |
| WO1999061673A1 (en) * | 1998-05-27 | 1999-12-02 | U.S. Department Of Commerce And National Institute Of Standards And Technology | High nitrogen stainless steel |
| JP4312408B2 (ja) * | 2000-03-15 | 2009-08-12 | ハンチントン、アロイス、コーポレーション | 耐蝕性オーステナイト合金 |
| SE520027C2 (sv) * | 2000-05-22 | 2003-05-13 | Sandvik Ab | Austenitisk legering |
| US20040156737A1 (en) * | 2003-02-06 | 2004-08-12 | Rakowski James M. | Austenitic stainless steels including molybdenum |
| SE527177C2 (sv) * | 2001-09-25 | 2006-01-17 | Sandvik Intellectual Property | Användning av ett austenitiskt rostfritt stål |
| SE525252C2 (sv) * | 2001-11-22 | 2005-01-11 | Sandvik Ab | Superaustenitiskt rostfritt stål samt användning av detta stål |
| RU2254394C1 (ru) * | 2004-03-16 | 2005-06-20 | Открытое акционерное общество "Синарский трубный завод" (ОАО "СинТЗ") | Высокопрочная аустенитная нержавеющая сталь и способ окончательной упрочняющей обработки изделий из нее |
| SE528008C2 (sv) * | 2004-12-28 | 2006-08-01 | Outokumpu Stainless Ab | Austenitiskt rostfritt stål och stålprodukt |
| US7658883B2 (en) * | 2006-12-18 | 2010-02-09 | Schlumberger Technology Corporation | Interstitially strengthened high carbon and high nitrogen austenitic alloys, oilfield apparatus comprising same, and methods of making and using same |
| US7985304B2 (en) | 2007-04-19 | 2011-07-26 | Ati Properties, Inc. | Nickel-base alloys and articles made therefrom |
| US8430075B2 (en) * | 2008-12-16 | 2013-04-30 | L.E. Jones Company | Superaustenitic stainless steel and method of making and use thereof |
| ES2891140T3 (es) | 2011-05-26 | 2022-01-26 | Ngenius Tech Limited | Acero inoxidable austenítico |
| US20150337419A1 (en) * | 2014-05-20 | 2015-11-26 | Crs Holdings Inc. | Austenitic Stainless Steel Alloy |
| US10179943B2 (en) | 2014-07-18 | 2019-01-15 | General Electric Company | Corrosion resistant article and methods of making |
| SI3365473T1 (sl) | 2015-10-19 | 2021-01-29 | Ab Sandvik Materials Technology | Nova avstenitna nerjavna zlitina |
| CN118326284B (zh) * | 2024-06-13 | 2024-08-16 | 成都斯杰化工机械有限公司 | 一种耐腐蚀耐汽蚀不锈钢及其制备方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55100966A (en) * | 1979-01-23 | 1980-08-01 | Kobe Steel Ltd | High strength austenite stainless steel having excellent corrosion resistance |
| SE441455B (sv) * | 1983-10-21 | 1985-10-07 | Avesta Ab | Stal av austenitisk typ |
| CA1263041A (en) * | 1984-11-13 | 1989-11-21 | William Lawrence Mankins | Nickel-chromium-molybdenum alloy |
| US4765957A (en) * | 1986-12-29 | 1988-08-23 | Carondelet Foundry Company | Alloy resistant to seawater and other corrosive fluids |
| DE3716665A1 (de) * | 1987-05-19 | 1988-12-08 | Vdm Nickel Tech | Korrosionsbestaendige legierung |
| NO891969L (no) * | 1988-05-17 | 1989-11-20 | Thyssen Edelstahlwerke Ag | Korrosjonsbestandig austenittisk staal. |
| US4981646A (en) * | 1989-04-17 | 1991-01-01 | Carondelet Foundry Company | Corrosion resistant alloy |
| SE465373B (sv) * | 1990-01-15 | 1991-09-02 | Avesta Ab | Austenitiskt rostfritt staal |
-
1993
- 1993-05-28 FR FR9306468A patent/FR2705689B1/fr not_active Expired - Lifetime
-
1994
- 1994-05-18 ES ES94401110T patent/ES2141806T3/es not_active Expired - Lifetime
- 1994-05-18 DE DE69422850T patent/DE69422850T2/de not_active Expired - Fee Related
- 1994-05-18 PT PT94401110T patent/PT626460E/pt unknown
- 1994-05-18 EP EP94401110A patent/EP0626460B1/fr not_active Expired - Lifetime
- 1994-05-18 DK DK94401110T patent/DK0626460T3/da active
- 1994-05-18 AT AT94401110T patent/ATE189483T1/de not_active IP Right Cessation
- 1994-05-27 US US08/250,687 patent/US5480609A/en not_active Expired - Fee Related
- 1994-05-27 NO NO941991A patent/NO302623B1/no unknown
- 1994-05-27 FI FI942490A patent/FI110010B/fi active
-
2000
- 2000-03-29 GR GR20000400797T patent/GR3033108T3/el not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| DK0626460T3 (da) | 2000-05-01 |
| NO941991L (no) | 1994-11-29 |
| ES2141806T3 (es) | 2000-04-01 |
| US5480609A (en) | 1996-01-02 |
| FI942490L (fi) | 1994-11-29 |
| NO302623B1 (no) | 1998-03-30 |
| FI942490A0 (fi) | 1994-05-27 |
| FR2705689A1 (fr) | 1994-12-02 |
| DE69422850T2 (de) | 2000-08-17 |
| DE69422850D1 (de) | 2000-03-09 |
| NO941991D0 (no) | 1994-05-27 |
| GR3033108T3 (en) | 2000-08-31 |
| PT626460E (pt) | 2000-06-30 |
| FI110010B (fi) | 2002-11-15 |
| EP0626460A1 (fr) | 1994-11-30 |
| FR2705689B1 (fr) | 1995-08-25 |
| ATE189483T1 (de) | 2000-02-15 |
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