FORMING A LAYER The present invention relates to arrangements in which a layer of material is formed on a surface, so that the material is introduced into holes or trenches in the surface. It is particularly, but not exclusively, concerned with arrangements in which that surface is a surface of a semiconductor wafer (or substrate used for integrated circuits)-
There are a number of situations during the formation of a semiconductor device in a semiconductor wafer where it is necessary to deposit a layer onto the wafer. One such situation arises when conductive or semiconductive tracks are to be formed over the wafer, so that those tracks may make contact with active regions of the device or circuit. Normally, such tracks must then extend through an insulating layer on the surface of the wafer so as to make contact with active regions below that insulating layer, or with further conductive tracks below that insulating layer (when the holes are usually called "vias"). Where the track extends through a hole in this way, it is important that the amount of material e.g. metal filling that hole is sufficient to ensure good electrical contact. Another situation is when an electrically insulating layer is to be formed over the wafer, in order to isolate active regions and/or conductive tracks from each other, or to form a protective covering known as a passivation layer. Such a layer
is often required to cover conductive tracks or other structures on the wafer, and these structures may be close to each other so that the gaps between them form narrow trenches. It is important that the insulating material covers all the surface with sufficient thickness to provide good electrical insulation, and that the top surface of the insulating layer shall be sufficiently smooth for the next stage of wafer processing. The normal way of forming layers on the surface of a semiconductor wafer, is by the use of a deposition technique, such as sputtering for conductive layers, or chemical vapour deposition for insulating layers. In such a technique, the surface on which the layer to be formed is bombarded with particles of the material to be deposited until a layer of a suitable thickness has been achieved.
Where that surface is the surface of a layer with a hole or trench therein extending to the surface of the wafer, the particles of the material are deposited on the sides and base of the hole or trench, but it has been found that there is a tendency for the particles to be deposited primarily at the mouth of the hole or trench, so that the width of the mouth is reduced as the deposition continues. The effect of this is that the interior of the hole or trench may suffer from shadowing, and a suitably thick layer of the material may not be deposited inside the hole
before deposition at the mouth of the hole or trench effectively closes the hole or trench and prevents further deposition therein, or before the required thickness has already been deposited elsewhere on the surface. This problem becomes increasingly significant as the width of the structure decreases, and developments in semiconductor technology have resulted in moves towards smaller and narrower structures. An alternative method of producing a suitable conductive layer is firstly to fill the hole with one metal, and then form the metal layer over the insulation and the filled hole. Thus, the hole may be filled with tungsten using a technique such as chemical vapour deposition, and then a more common metal, such as aluminium or aluminium alloy may be deposited over the surface by the sputtering technique discussed above. However, the gaseous sources for the materials used to fill the holes by chemical vapour deposition are expensive, and a two-stage process involving different materials is necessary, increasing the cost of the whole device.
Holes can be filled by sputtering at high temperature (>500°C) and/or using bias sputtering, but the quality of the metal is degraded, and the process is inconsistent and hard to control. Aluminium CVD is possible and does fill holes, but the process is slow, hard to control, and requires previous deposition of
a suitable seed layer. Again, a two-stage process involving different materials is then necessary.
There are alternative methods of producing a suitable insulating layer. One method is to deposit part of the required thickness by chemical vapour deposition (CVD) , and then to remove the parts of the layer that overhang the trench by sputter etching or reactive ion etching. This cycle may be repeated until sufficient thickness has been deposited, the etching steps being used to prevent the closing of the mouth of the trench. However the process is slow, requires several steps, and must be adjusted for different geometries.
Another method is to deposit an insulating material that can be reflowed by melting, such as silicon oxide doped with boron or phosphorous. The material may be deposited by CVD, and then heated until it flows into the trench. However the temperature required for reflow of such material is greater than 800°C, which will cause melting of any aluminium tracks present, and can cause undesirable diffusion in active regions of devices in the water.
A third method is to apply a liquid solution onto the surface of the wafer, where such liquid when subsequently heated forms a solid insulating layer, such as that known as "spin-on-glass" . The material flows into the trenches when first applied. However, the material tends to retain some moisture after the
heating process, and this moisture can cause device unreliability due to corrosion. It may require a capping layer to seal against moisture, which increases the number of process steps and hence the device costs.
In our European patent application number 92304633.8, we proposed that a layer was formed on the surface of an article, in which surface there was a recess such as a hole or trench, the sides and base of which were to be provided with a covering so as, e.g. in a wafer to provide electrical contact or insulation. Then, it was proposed that the article, including the layer, was subjected to elevated pressure and elevated temperature sufficient to cause the layer to deform.
It was thought that the primary factor causing the deformation was plastic flow by dislocation slips, activated by the elevated pressure and temperature. Surface diffusion, grain boundary diffusion and lattice diffusion were also thought to have an effect, activated by the elevated temperature.
It has been realised that if the elevated pressure is sufficiently high, it is not necessary also to elevate the temperature. Therefore, in a first aspect, the present invention proposes that a layer be formed on the surface of an article in which surface there is a recess such as a hole or trench, with the layer covering the mouth of the hole or
trench. Then, without elevating the temperature, the article and layer are subject to elevated pressures sufficient to cause the layer to deform into the hole or trench. The precise pressure conditions necessary to acheive the deformation of the layer will depend on the materials used, but for aluminium or aluminium alloys, the pressure will have to be higher than 200 x 106Pa (30,000 p.s.i) and pressures in excess of 700 x 106Pa (100,000 p.s.i) have been found to be suitable.
Alloys commonly used for forming conductive tracks are of composition Al/0-2% Si/0-4% Cu/O-2% Ti, and these have been found to deform suitably under such conditions. The present invention is not limited to one particular method of forming the layer, and sputtering or chemical vapour deposition techniques may be used as discussed above, although other alternatives such as vacuum evaporation or application of a liquid may also be used. Indeed, it is possible for the layer to be pre-formed, as a film, which film is then positioned on the article.
Thus, to form a layer on a semiconductor wafer, which layer is to extend through holes or trenches in an underlying layer on the surface of the wafer, material for forming the layer (e.g. aluminium or other suitable material) is first deposited on the surface of the underlying layer by e.g. sputtering.
The material may then be deposited on the sides and base of the hole or trench, although the thickness at the mouth of the structure will be greater. When a suitable amount of material has been deposited deposition stops and the result is subject to elevated pressure for a period sufficiently long to cause movement of the material to fill the structure, or to move into the structure sufficiently to allow a reliable electrical contact if the material is a metal, or to provide a reliable electrical insulation if the material is an insulator.
It is important that the mouth of the structure is completely closed by the deposition, leaving a void below the closed mouth within the structure. Such closing of the mouth of the structure enables the material to be pushed down into the structure, collapsing the void by the elevated pressure outside it. The void will therefore be filled when the material moves under the elevated pressure conditions. Thus, unlike the prior art arrangements, the closing of the mouth of the structure does not represent a limit to the amount of the material that may, at the end of the procedure, fill the structure to achieve a satisfactory contact or insulator. Aluminium, or some aluminium alloys, are particularly suitable for use with the present invention because their yield strengths are lower than other metals commonly used. Thus, they will deform to
move into or fill the hole at relatively lower pressures. For other materials, pressures will need to be higher.
Whilst the elevated pressures required by the present invention may be achievable using a gas, it is preferable that a liquid is used. Furthermore, it has been realised a liquid may also be used within the technique of European patent application 89304633.8. Therefore, although the use of a liquid for achieving elevated pressures is a preferred feature of the first aspect of the present invention, it also forms the basis of a second, independent, aspect.
In the second aspect, a layer is formed on the surface of an article, in which surface there is a recess such as a hole or trench, with the layer covering the mouth of the hole or trench. Then, at least the exposed surface of the layer is brought into contact with a pressurised liquid. The elevated pressure to which the layer is exposed then causes the layer to deform into the hole or trench, possibly due to the pressure alone or alternatively due to both elevated pressures and temperatures.
It is preferred to use a liquid for achieving very high pressures because such pressures may be achieved more quickly and safely. Since liquids are almost imcompressible, much less work needs to be done in the compression system in order to achieve very high pressure. For example, compression of ethanol by
10% produces a pressure of approx. 130 MPa, whereas compression of argon by 10% produces a pressure rise of only 0.01 MPa. A liquid under very high pressure has less stored energy that a gas under the same pressure because less work has been done on it, so less energy can be released in an uncontrolled decompression reducing the safety risks.
It is desirable to use a liquid which does not leave behind residues on the article after processing. Preferably, the liquid is one with no dissolved solids. It is preferred that the liquid be one which can be allowed to evaporate from the workpiece at the end of the processing. Ethanol is a suitable example, as is liquid carbon dioxide. The liquid used must be compatible with the temperature employed during the processing. If the temperature of a liquid exceeds that of its triple point then the liquid turns to gas. Ethanol and carbon dioxide have triple points at critical temperatures 514K and 304K respectively. These liquids may be used provided the temperature in each case does not exceed the respective critical temperature.
Water may also be a suitable liquid for use in the processing. The use of water allows operation at higher temperatures, since its triple point occurs at a critical temperature of 647K.
Other liquids may be used. Techniques already
described for forming the layer may be used whether the layer is conductive, insulating or semiconductive. It has previously been mentioned that it is important for the mouth of the structure to be completely closed by the deposition, leaving a void below the closed mouth. If the deposition is vertical, or substantially vertical, it has been found that such closing of the mouth requires a long deposition of a thickness at least as great as the width of the hole. It may be desirable to reduce this thickness, so that after subsequent pattern etching of the layer, the step heights are reduced, to ease (for example) subsequent layer step coverage, or photolithography (by reducing the depth of focus field required). Therefore, in a further development of the present invention, it is proposed that the deposition be carried out by magnetron sputtering, such that the flux of material is from a large range of angles to the surface of the wafer, and that the wafer be heated to increase the mobility of the deposited material. Under the correct surface and heat conditions, the material deposited in the hole or trench can flow out of that hole or trench and contribute to the bridging. For magnetron sputter deposition of aluminium alloys, a platen temperature of 350-450°C has been found to be suitable, but other temperatures may also enhance the bridging effect.
An embodiment of the present invention will now
be described in detail, by way of example, with reference to the accompanying drawing, in which:
Fig. 1 shows a cross-section of a semiconductor wafer prior to the formation of a layer according to the present invention;
Fig. 2 shows a cross-section of the wafer of Fig.
1, at an intermediate stage in the formation of a layer according to the present invention; and
Fig. 3 shows a cross-sectional view of the wafer, after the layer has been completed.
Fig. 4 shows a cross-sectional view of the wafer, after exposure to elevated pressure.
Fig. 5 is a sectional view corresponding to Fig.
2, but for when higher temperatures are used during the formation of the film;
Fig. 6 is a schematic plan view of an apparatus for carrying out the present invention; and
Fig. 7 is a schematic sectional view of the part of the apparatus of Fig. 6, which part subjects the article to elevated pressures. This part is also able to subject the article to elevated temperature for when a method according to the second aspect of the present invention is used.
Fig. 1 shows a semiconductor wafer 1 with a pre- existing layer 2 thereon. The wafer 1 itself may contain a plurality of layers and/or regions of different properties, to form a semiconductor device, and will be the result of a fabrication process
involving a plurality of stages for forming those layers and/or regions. The internal structure of the wafer 1 is not of significance in the present invention, and therefore these layers and/or regions will not be discussed further.
The layer 2 has a hole or trench structure 3 therein, and the present invention is concerned with the problem of forming a layer over the pre-existing layer 2, e.g. so that either an electrical contact can be made by a metal layer to the surface 4 of the wafer
1 within the hole or trench structure 3, or an electrical insulator can be formed on the surface 4 of the wafer 1 within the hole or trench structure 3, or a layer can be formed that can be made semiconductive in known manner. That surface 4 may thus be in contact with e.g. active regions within the wafer, or further conductive tracks within the structure on the wafer.
To form a metal layer, a material such as aluminium is sputtered onto the surface of the layer
2 e.g. in a downward or sideways direction in Fig. 1. Sputtering can also be done upwards if desired. To form an insulating layer, a material such as silicon dioxide is deposited onto the surface of the layer 2 by e.g. chemical vapour deposition. This process continues until the new layer over the pre-existing layer 2 has a suitable thickness. This is shown in Fig. 2, with the new layer shown at 10. With such
deposition techniques, deposition of the material to form the layer 10 tends to occur more rapidly at the mouth of the structure 3, as compared with its side walls and its base, formed by surface 4. As a result, as shown in Fig. 2, the side walls 11 of the hole or trench structure 3, and the surface 4, have a relatively thin layer of material thereon, as compared with the layer 10 covering the surface of the pre¬ existing layer 2. It can thus be seen that satisfactorily reliable electrical connection or insulation to the wafer 1 at the surface 4 may not be achieved. Furthermore, it is not normally possible to increase the amount of deposition on the side walls 11 and the surface 4 by continuing the deposition process, because that deposition process will eventually close the gap 12 in the layer 10 above the hole or trench structure 3, preventing further deposition within that structure 3 and leaving a void.
The technique described above represents the currently standard method, and the poor coverage to the surface 4 may thus become a defect or weak point in the device.
It is important that deposition should close the mouth of the structure. In some case, this may require more thickness than required elsewhere to be deposited, in which case excess material can be removed by etching, after the structure has been filled. Fig. 3 thus shows a processing stage similar
to Fig. 2, but in which the mouth of the structure is closed, to have a void below the layer 10. This idea of wholly sealing the void may also be achieved by providing a capping layer over the layer which thus may seal any open voids. Such a capping layer may also improve the configuration of the final surface. Such a capping layer may be any suitable material, and may have a higher Youngs modulus than the layer being capped at the temperature/pressure at which it is to deform. After the wafer has been subject to the elevated pressure conditions, the capping layer may be removed or may be left in place depending on the material of that capping layer.
Therefore, according to the first aspect of the present invention, once the stage of Fig. 3 has been reached, further deposition of the material ceases, and the structure shown in Fig. 3 is then sub ected to elevated pressure, e.g. pressures above 700 x 106 Pa (100,000 p.s.i.), assuming that the material of the layer 10 is aluminium. Such elevated pressure causes the material of layer 10 to flow proximate the structure 3, and this process may continue until the structure 3 is filled, as shown in Fig. 4. Material 13 then entirely fills the structure 3 and thus a satisfactory electrical contact to, the surface 4 may then be achieved. There may be a small depression 14 in the layer 10 above the structure 3, due to the flow of material 13 into the structure 3 to fill it, but
this depression does not affect the electrical properties of the device.
In this way, a satisfactory contact can be achieved, and it is found that this method is not affected by the width of the structure 3.
According to the second aspect of the present invention, once the stage of Fig. 3 has been reached, further deposition of the material (conductive, insulating or semiconducting) ceases, and the structure shown in Fig. 3 is then subjected to elevated pressure by contact with pressurised liquid. Optionally, the temperature is elevated as well. The result is as described above for when a method according to the first aspect of the present invention is employed. Satisfactory contact or insulation can be achieved using e.g. temperature above 350°c to 400°c and pressures above 20 x 106 Pa (3000 p.s.i.).
As has previously been mentioned, it is important for the layer 10 wholly to cover the hole or trench structure 3, so that the void is sealed. This closing of the mouth of the structure 3 enables the material to be pushed down into the structure 3, because of the pressure differential across the layer 10 at the site of the structure 3. Therefore, there is little advantage to be gained by depositing material within the structure 3, as shown in Figs. 2 and 3. Although the arrangement described with respect to Figs. 2 and 3 assumes that a relatively thin layer of material is
deposited on the side walls 11 of the structure 3, and the surface 4, such deposition, retards closing of the mouth of the structure 3, thereby increasing the thickness of the layer 10 which needs to be deposited in order to close that mouth. However, it has been found if deposition occurs at elevated temperatures, e.g. 400°C to 450°C, the shape of the layer 10 adjacent the structure 3, before the mouth of the structure 3 is closed, may be different, as shown in Fig. 5. Deposition occurs preferentially at the mouth of the structure 3, thereby speeding up the closing of the mouth of that structure 3. Thus, it is preferable that the layer 10 is deposited at elevated temperatures. For deposition at lower temperatures, the thickness of the layer 10 is normally at least 2 times the width of the structure 3, but this limit may be avoided by use of elevated temperatures as described above.
It should further be noted that it is important that the structure 3 must be wholly filled by the material 13, as shown in Fig. 4. If the pressures are not sufficiently high, or are not maintained for sufficiently long, the flow of material 13 into the structure 3 may not wholly fill it, and consideration must be given to this during the carrying out of the present invention. It may also be desirable to form a barrier layer (not shown) between the layer 2 and the layer 10. Furthermore, care needs to be taken if
there are a multiplicity of adjacent structures 3, to ensure that there is sufficient material in the layer 10 to fill them all.
An apparatus for carrying out the present invention, when the article is a semiconductor wafer, is shown in Fig. 6. The majority of components of that apparatus are conventional, with the exception of the parts for subjecting the article (wafer) to elevated pressure, and, if employed in a method according to the second aspect of the present invention, elevated temperatures.
Thus, semiconductor wafers are loaded into the apparatus via an interface 20, from which interface 20 the wafers are transferred individually to a lock chamber 21. That lock chamber 21 acts as a seal between the interior of the apparatus, in which the wafer is processed, and the exterior. A transport arm
22, receives a wafer from the lock chamber 21 and transports the wafer successfully to one of a series of modules, in which processing of the wafer occurs. Normally, the wafer is pre-heated in a pre-heat module
23. The pre-heating of the wafer, in vacuum, ensures that the wafer is fully out-gased, and temperature of approximately 400°C are maintained for 60s. For some hydroscopic wafers, a prolonged heating may be necessary.
From the pre-heat module 23, the wafer may be transported by suitable movement and rotation of the
transport arm 22, to a sputter etch module 24. This cleans out native oxide from the wafer, and may also further degas the wafer. Such sputter etching is optional. The processing thus carried out causes, the wafer to be in the state shown in Fig. 1. If, as previously described, a barrier layer is to be formed on the layer 2 before the formation of the layer 10, the wafer is transported to a barrier deposition module 25 either directly from the pre-heat module 23 or from the sputter etch module 24. The barrier layer may be formed in a conventional manner, and may be e.g. of Ti-TiN. The TiN may be deposited by reactive sputtering of pure Ti, and R.F. bias, in-situ oxygen incorporation, or vacuum breaks can be used to increase the integrity of the barrier layer. The typical thickness of the barrier layer, if formed, is of the order of lOOnm. It should be noted that formation of a barrier layer on the structure shown in Fig. 1 is known.
Then, the wafer is transported by the transporter arm 22 to a deposition module 26, in which the layer 10 is deposited. Such deposition may be by known methods, and sputter deposition is preferred. As has previously been mentioned, it is preferable for such deposition to occur at elevated temperatures. The deposition of the layer 10 continues until all hole or trench structures on the article are sealed by the
layer 10 .
The modules 23 to 26 of the apparatus described above may be conventional. In the conventional arrangement, where a layer 10 is formed, it will not seal the hole or trench structures, but the sealing of such structures may be carried out using a conventional module 26.
Then, according to the first aspect of the present invention, the wafer is transported from the deposition module 26 to a module 27 in which the wafer is subjected to elevated pressures so as to cause the layer 10 to deform so that material 13 fills the hole or trench structures, as shown in Fig. 4. The module 27 is shown in more detail in Fig. 7. Fig. 6 also shows a display 28 by which the operator can monitor the movement of the wafer.
When a method according to the second aspect of the present invention is employed the wafer is subjected to elevated pressure by contact with pressurised liquid in module 27. Optionally, the temperature is elevated as well.
As can be seen from Fig. 7, the module 27 comprises a pressure vessel 30 which is connected via a passageway 31 containing a gate valve 32 to the region of the apparatus containing the transport arm 22. Thus, wafers may be introduced into, and removed from, the pressure vessel 30 via the passageway 31 by opening and closing of gate valve 32, this movement
being shown by arrow 33. The interior of the pressure vessel 30 communicates with a vacuum chamber 34 connected to a pump 35. This enables the interior of the pressure vessel 30 to be evacuated. Support pins 39 are provided for supporting a wafer 36 which has been introduced into the pressure vessel 30.
In order to subject the wafer to elevated pressures, the pressure vessel 30 has an inlet 37 connected to a high pressure gas e.g. Argon or liquid source. By filling the interior of the pressure vessel 30 with gas or liquid, the wafer and layers thereon may be subjected to suitably controlled pressures. Furthermore, the pressure vessel 30 contains heating plates 38 which permit the temperature within the pressure vessel 30, and hence the temperature of the wafer to be elevated, if desired when pressurised liquid is being used.
Hence, a wafer 36 introduced into the pressure vessel 30 may be subjected to elevated pressures, optionally by means of contact with pressurised liquid, and, if liquid is used, optionally subjected also to elevated temperatures so as to cause a layer 10 formed thereon to form into vias in the wafer.
Once the process is complete, the vessel 30 is de-pressurised. Pressurised gas may simply be allowed to escape through an outlet, which may actually be the inlet 37. The gas may be pumped out. Where pressurised liquid is used, it may be allowed to drain
from the vessel under the influence of gravity through an approximately positioned outlet, or it may be pumped out. Depending on the liquid used, it may be allowed to evaporate, with the vapour so formed being let out of, or pumped out of the vessel.
Thus, although the trend in semiconductor devices is to smaller and smaller dimensions, including smaller dimensions for contact holes, the present invention permits satisfactory electrical contact to be achieved through small contact holes. In the existing techniques using sputtering, as can be seen from consideration of Fig. 2, deposition at the mouth of the hole would rapidly close a small hole, so that the existing techniques offered only poor electrical contact. With the present invention, on the other hand, the closing of the mouth of the hole during the initial deposition of the metal layer, before the elevated temperature and pressure conditions are applied, may improve the success of contact after those elevated pressure and temperature conditions have been applied.