EP0621822A1 - Method, barrel subunits and units, service installations and assembly structures for the fabrication of mouldable products, particularly based on concrete. - Google Patents
Method, barrel subunits and units, service installations and assembly structures for the fabrication of mouldable products, particularly based on concrete.Info
- Publication number
- EP0621822A1 EP0621822A1 EP93914495A EP93914495A EP0621822A1 EP 0621822 A1 EP0621822 A1 EP 0621822A1 EP 93914495 A EP93914495 A EP 93914495A EP 93914495 A EP93914495 A EP 93914495A EP 0621822 A1 EP0621822 A1 EP 0621822A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- barrel
- type
- molds
- concrete
- installation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004567 concrete Substances 0.000 title claims abstract description 67
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 33
- 238000009434 installation Methods 0.000 title claims description 144
- 238000000034 method Methods 0.000 title claims description 51
- 238000000465 moulding Methods 0.000 claims abstract description 73
- 239000000463 material Substances 0.000 claims abstract description 8
- 230000010354 integration Effects 0.000 claims abstract 2
- 230000002787 reinforcement Effects 0.000 claims description 48
- 238000010438 heat treatment Methods 0.000 claims description 45
- 210000003128 head Anatomy 0.000 claims description 37
- 238000012546 transfer Methods 0.000 claims description 32
- 230000008569 process Effects 0.000 claims description 26
- 230000002093 peripheral effect Effects 0.000 claims description 15
- 238000009826 distribution Methods 0.000 claims description 14
- 238000000605 extraction Methods 0.000 claims description 13
- 239000012528 membrane Substances 0.000 claims description 13
- 210000003454 tympanic membrane Anatomy 0.000 claims description 13
- 238000007789 sealing Methods 0.000 claims description 10
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- 238000001816 cooling Methods 0.000 claims description 8
- 238000006073 displacement reaction Methods 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 238000004140 cleaning Methods 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- 239000011513 prestressed concrete Substances 0.000 claims description 7
- 238000005056 compaction Methods 0.000 claims description 6
- 230000036571 hydration Effects 0.000 claims description 6
- 238000006703 hydration reaction Methods 0.000 claims description 6
- 238000012423 maintenance Methods 0.000 claims description 6
- 239000011150 reinforced concrete Substances 0.000 claims description 6
- 238000003860 storage Methods 0.000 claims description 6
- 238000000429 assembly Methods 0.000 claims description 5
- 230000000712 assembly Effects 0.000 claims description 5
- 235000013399 edible fruits Nutrition 0.000 claims description 5
- 239000007789 gas Substances 0.000 claims description 5
- 238000005096 rolling process Methods 0.000 claims description 5
- 230000008901 benefit Effects 0.000 claims description 4
- 238000005253 cladding Methods 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
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- 238000004873 anchoring Methods 0.000 claims description 3
- 238000005266 casting Methods 0.000 claims description 3
- 239000004568 cement Substances 0.000 claims description 3
- 230000008859 change Effects 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 230000005855 radiation Effects 0.000 claims description 3
- 230000001360 synchronised effect Effects 0.000 claims description 3
- 230000005540 biological transmission Effects 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- 238000001704 evaporation Methods 0.000 claims description 2
- 230000008020 evaporation Effects 0.000 claims description 2
- 230000008595 infiltration Effects 0.000 claims description 2
- 238000001764 infiltration Methods 0.000 claims description 2
- 239000004570 mortar (masonry) Substances 0.000 claims description 2
- 238000006386 neutralization reaction Methods 0.000 claims description 2
- 230000008520 organization Effects 0.000 claims description 2
- 239000011505 plaster Substances 0.000 claims description 2
- 239000004033 plastic Substances 0.000 claims description 2
- 230000001737 promoting effect Effects 0.000 claims description 2
- 238000011084 recovery Methods 0.000 claims description 2
- 230000003014 reinforcing effect Effects 0.000 claims description 2
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B15/00—General arrangement or layout of plant ; Industrial outlines or plant installations
- B28B15/002—Mobile plants, e.g. on vehicles or on boats
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B5/00—Producing shaped articles from the material in moulds or on moulding surfaces, carried or formed by, in or on conveyors irrespective of the manner of shaping
- B28B5/10—Producing shaped articles from the material in moulds or on moulding surfaces, carried or formed by, in or on conveyors irrespective of the manner of shaping in moulds carried on the circumference of a rotating drum
- B28B5/12—Producing shaped articles from the material in moulds or on moulding surfaces, carried or formed by, in or on conveyors irrespective of the manner of shaping in moulds carried on the circumference of a rotating drum intermittently rotated
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S425/00—Plastic article or earthenware shaping or treating: apparatus
- Y10S425/116—Mold cleaning
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S425/00—Plastic article or earthenware shaping or treating: apparatus
- Y10S425/238—Boat hull mold
Definitions
- the present invention relates to a process and equipment of the rotary drum type, using deferred demou ⁇ lage for the manufacture of moldable products, in particular concrete-based products, aimed at improving the concentration, automation and flexibility of the manufacturing process as well as the hardening of the molded material.
- the object of the invention is essentially to remedy, as far as possible, the aforementioned drawbacks.
- the invention proposes a process which is essentially characterized: - in that an enlarged and improved range of molding means and closing lids thereof is integrated into structures rotary and thus forms modular rotary barrels, having at least two sides, capable of promoting the concentration, automation and flexibility of the manufacturing process, on the one hand, by allocating the material to hardening molded (concrete, mortar, plaster, clay, plastic, etc.) with a rotary path greater than 270 * and preferably equal to 360 * and, on the other hand, by grouping the main work stations according to at least five preferred technology flow solutions general:
- the equipment according to the invention overcomes the aforementioned drawbacks by the implementation of an evolving association of rotary barrels and of installation facilities specific to the process, using a few optimized assembly structures, said association giving birth of "barrel workshops” for the lowest association levels and “barrel factories” for the highest association levels.
- workshops and barrel factories can be produced both in the form of small mobile units by water, rail or road as in the form of larger fixed or removable units.
- process and the equipment according to the invention relate to the manufacture of all moldable products, but to simplify their presentation, the descriptions which follow refer to the production with deferred release of concrete products, especially in prestressed concrete and reinforced concrete.
- the first family uses "multifunction barrels" associated with servitude installations, ordinary and / or process-specific, in such a way that the main work stations can be grouped together (fitting of the frames, tensioning of the frames, concreting, deferred release, removal of hardened products and cleaning-oiling of the molds) can be carried out according to the first three aforementioned flow solutions general technological process;
- the second family uses "single-function barrels" associated with ordinary and / or specific facilities for easements so that the abovementioned workstations are grouped together, according to the fourth or fifth solution of general technological flow of the process.
- the multifunction barrels of the first family of factories comprise firstly a rotary structure, self-supporting or not with respect to the stressing efforts of the reinforcements (with or without tensioning devices), then secondly means of molding (molds or sets of molds) usually provided with their own compacting means, and thirdly with means for closing said molding means, so that these barrels mainly perform the following functions:
- the single-function barrels of the second family of factories comprise, on the one hand, a lighter rotary structure (because it is no longer required to take charge of the tensioning forces of the reinforcements) and, on the other hand, a series of peripheral niches equipping or forming part of said structure, niches which allow the extraction and reintroduction of the molding means (molds or mold batteries) at the top, bottom or laterally relative to the barrels, so that the latter have only a single main function to perform, the moving whenever said concrete filled molding means and closed in a rotary curing circuit of 360 ° with all the aforesaid advantages.
- a first type of multifunctional barrel is produced using a mixed rotary structure (steel-concrete), self-supporting in relation to the tensioning efforts of the reinforcements and using a few batteries of preferably heated molds with own means of vibration, batteries which are fixed using removable devices on each side of the structure, in the form of interchangeable assemblies.
- a mixed rotary structure steel-concrete
- self-supporting in relation to the tensioning efforts of the reinforcements and using a few batteries of preferably heated molds with own means of vibration, batteries which are fixed using removable devices on each side of the structure, in the form of interchangeable assemblies.
- a second type of multifunctional barrel is produced using a rotary metal structure, self-supporting or not with respect to the tensioning forces, provided with two head shields, which are also self-supporting or not, and using batteries. preferably non-heating molds with their own vibration means, batteries which in their rotary curing path are subjected to intensive heating, preferably by radiation.
- a third type of multifunctional barrel is produced using a rotary structure, self-supporting or not, in the form of a hollow cylinder including the molds, structure mounted around a support beam provided in certain cases with two bogies head, so that this barrel (including the mold closing covers) can be moved in one piece by rail either on its own bogies or on a platform wagon.
- a fourth type of multifunctional barrel is produced using a rotary structure, self-supporting or not, of monolithic type integrating the molds so that it can be transported in one piece by normal road convoy either on its own axles , or on a low trailer.
- a fifth type of multifunctional barrel is produced using a rotary structure, self-supporting or not, reinforced with a few peripheral beams, serving at the same time as mold supports and working platforms, structure having of preferably four sides so that it can be fitted with molding means either on all sides, or only on two opposite sides when it is desired that the width of the barrel does not exceed the normal size of road transport.
- a sixth type of multifunctional barrel is produced using a "light rotating structure" (not responsible for taking up the tensioning efforts of the reinforcements) and using a few sets of molds comprising a fixed support shell and a removable core, also multifunctional, a core which may or may not be self-supporting with respect to the stressing efforts of the reinforcements.
- a seventh type of multifunctional barrel is produced using a light rotary structure and using mold batteries comprising tilting side walls and a removable multifunctional core, preferably self-supporting with respect to tensioning forces.
- a first type of single-function barrel is produced using a lightened rotary structure, equipped with a few beams-rails and a rotary device for distributing the steam, structure equipped with a series of niches which may or may not be removable, so that the molding means provided with rollers are extracted, loaded with hardened products, and reintroduced, filled with fresh concrete, in said niches preferably at the top of the barrel.
- a second type of single-function barrel is produced using a light rotary structure including a series of niches, preferably higher than wide, niches provided with rollers so that the molding means can be extracted, loaded hardened products, and reintroduced, filled with fresh concrete, especially at the bottom of the barrel.
- a third type of single-function barrel is produced using a light rotary structure having rolling rings disposed inwardly between which are housed several niches, preferably wider than tall, niches allowing the extraction and reintroduction of the molding means, in particular laterally compared to the barrel.
- Service facilities ordinary or specific to the process, use the means associated with the barrels to ensure the actual manufacturing process (from the arrival of fresh concrete and until the exit of hardened products from the workshop) according to any of the five general technology flow solutions for the process.
- the first type is a "prehensible installation of covers” mainly comprising a lifting device advantageously constituted by two synchronized electropalans, positioned above the serviced barrel, so as to ensure the handling of the closing covers. molds (removal, maintenance and replacement) in anti-spoiling conditions with regard to their lightening.
- the second type is a "gripping installation of hardened products and armatures", mobile above the barrel preferably served in its longitudinal axial plane, installation comprising means which firstly release the mold and transfer the hardened products to the depot and secondly (in the return stroke) the transfer of the reinforcements into the molds being cleaned and oiled at the top of the barrel.
- the third type is a "gripping installation of covers, hardened products and armatures", movable above the barrel served, preferably in its longitudinal axial plane, installation comprising means which ensure:
- the fourth type is a "prehensible installation of removable cores, hardened products and armatures", movable above the serviced barrel, preferably in its longitudinal axial plane, installation provided with means which ensure the handling of the removable cores, cores provided first of hardened products and secondly of reinforcements.
- the fifth type is a "prehensible installation of covers, cores, hardened products and armatures" movable above the barrel preferably served transversely with respect thereto, installation provided with means which ensure: - removal of the cover closing the battery of molds stopped at the top of the barrel and its installation on the floor, side opposite to the work stations;
- the sixth type is a “two-phase deferred demolding installation”, the first phase of which, called “initial deferred demolding”, is carried out, at the top of the barrel served, by the opening of the side walls of the battery of molds on site, then by the removal, using a gripping installation of the fifth type, of the removable core having hardened products bonded to these sides and the second phase of which, called “final deferred demolding", takes place outside the barrel served , in a work station provided with means which take off the hardened products from the core, so that said products and the core are subsequently handled independently using the same aforementioned prehensible installation.
- the seventh type is a "radiation heat treatment installation” comprising a circular thermal screen mounted in a fixed position all around the barrel served, a screen equipped with a series of radiant heaters (electric or gas) over approximately a quarter of its circumference, in the initial part thereof relative to the direction of rotation of the barrel.
- the eighth type is a "secondary barrel" arranged outside the main barrel served in particular in its longitudinal axial plane, comprising a modular rotary frame having the same step-by-step rate of rotation as that of the main barrel being served, frame provided with and associated with means which ensure, on the one hand, cooling, overturning and transfer to the deposit of the hardened products and, on the other hand, the preparation of the reinforcements in groups preferably using head screens and, in some cases, separation screens.
- the ninth type called “ergonomic walkways” comprises two removable walkways mounted above the barrel being served, so that it can descend at each stop thereof to ensure access for workers laterally relative to the molding means located at the top of the barrel and so that once said means are filled, vibrated and closed, the two gateways are erased to allow the barrel to rotate by one step, the time during which said gateways act as a safeguard.
- the tenth type is a "snow-melt roof” comprising a semi-circular thermal screen placed by means of a few rollers on the rings of a single-function barrel, so that said roof, while being very light and inexpensive, ensures, in addition to weather protection, the automatic closing of the heated rotary niches of said barrel and the instantaneous melting of snow.
- the method makes it possible to associate any type of barrel with several ordinary and / or specific easement installations in order to obtain a wide range of barrel workshops, flexible or specialized, either in the form of small units movable by rail. , road or water, either in the form of larger fixed or removable units.
- the associations "barrels-installations of easements” can be ordinary associations carried out in traditional hangars (existing or new) or privileged combinations made using a few optimized assembly structures.
- the first preferred combination incorporates, using an optimized type 1 assembly structure, a type 1 multifunctional barrel, at least two ordinary easement installations (one for supplying and distributing concrete and one for cleaning-oiling of the molds) and three specific easement installations (type 1, 2 and 9).
- the second preferred combination incorporates, using an optimized type 2 assembly structure, a type 2 multifunctional barrel, at least the two aforementioned ordinary installations and three specific installations (types 3, 7 and 8) .
- the third privileged association integrates, using an optimized assembly structure of type 3, a multifunction barrel of type 6, all or part of the ordinary facilities of the abovementioned easements and a specific installation of type 4.
- the fourth privileged association integrates, using an optimized assembly structure of type 4, a multifunction barrel of type 7, all or part of the ordinary facilities of the abovementioned easements and two specific facilities (types 5 and 6).
- FIG. 1 is the cross section of a flexible workshop produced according to the first general technological flow solution using a type 1 multifunctional barrel, associated with two installations of the above-mentioned easements (not shown) and to three specific installations of type 1, 2 and 9;
- Figure 2 is the longitudinal section (following line II of Figure 1) of the type 1 barrel;
- - Figure 3 is the detailed cross-section cut out of a pan of the type 1 barrel;
- FIG. 4 is the cross section of a flexible workshop produced according to the second general technological flow solution using a type 2 multi-function barrel, associated with two ordinary facilities of the above-mentioned easements (not shown) and three specific installations of types 3, 7 and 8;
- Figure 5 is the longitudinal section (along line II of Figure 4) of the aforementioned flexible workshop showing the type 2 multifunctional barrel, the specific installation of type 3 and only part of the specific installation of type 8;
- Figure 6 is the cross section of a specific type 8 installation (secondary drum);
- Figure 7 is the cross section of a type 3 multifunctional barrel equipped with its own bogies for international rail transport;
- Figure 8 is the cross section of a type 4 multifunctional barrel presented on a road transport to international size
- - Figure 9 is the cross section of a type 5 multi-function barrel presented on a road transport to international size
- - Figure 10 is the cross section of a specialized workshop housed in a boat hull, workshop carried out according to the second general technological flow solution using a type 6 multifunction barrel, associated with all or part of the installations above-mentioned easements and to a specific type 4 installation
- - Figure 11 is the cross section of a specialized workshop, produced according to the third general technological flow solution using a type 7 multi-function barrel, associated with all or part of the ordinary installations of the above-mentioned easements and two specific installations of types 5 and 6;
- FIG. 12 is the cross section of a type 1 single-function barrel, equipped with heating niches allowing the extraction and reintroduction of the molding means at the top of said barrel;
- - Figure 13 is the cross section of a type 2 single-function barrel, equipped with heating niches allowing the extraction and reintroduction of the molding means at the bottom of said barrel;
- - Figure 14 is the cross section of a type 3 single-function barrel, equipped with heating niches allowing the extraction and reintroduction of the molding means laterally, barrel associated with a specific type 10 easement installation;
- - Figure 15 is the partial longitudinal section (along the line I-I in Figure 14) of the type 3 single-function barrel.
- the process in the case cited as an example of the manufacture of concrete products, achieves, by the association of barrels and service installations, the regrouping of the main workstations, installation of reinforcements (MP ), tensioning of the reinforcement (MT), concreting (B), demolding (D) and cleaning and oiling (NH) f according to any of the five solutions technological general flow with affecta ⁇ tion each time the entire rotary travel of 360 * to hardening of concrete which, on the one hand , can use any known means of acceleration (gradual heating, additives, vacuum treatment, etc.) and which, on the other hand, benefits from several conditions specific to the process favoring its acceleration:
- Molding means, molds or mold batteries b mounted on each side of the barrel in the form of modular assemblies preferably provided with own means of vibration and elastic support, so as to ensure on the one hand compaction very effective in concrete and on the other hand allow its revibration either directly or indirectly by resonance;
- TTI - intensive heat treatment
- the intensive heat treatment subdivided into three main phases, temperature rise (TT1), isotherm (TT2) and cooling (TT3), can be carried out, both in the case of multi-function barrels and in that of single-function barrels, in two technological variants, one in which the three aforementioned phases are carried out in full during the 360 * rotation of said barrels and the other in which the last phase, that of cooling, is carried out outside the barrels before or during the evacuation (E) of the cured products £.
- the type 1 multifunctional barrel shown in FIGS. 1, 2 and 3, firstly comprises a mixed rotary structure (metal-concrete) self-supporting with respect to the stressing efforts of the reinforcements a, structure equipped with a few support devices- removable molds and devices for tensioning the armatures which can also be dismantled, then, secondly, several batteries of bml heating molds provided with means for compacting the concrete and means for distributing steam, and thirdly with closing lids çJL heat insulators perfectly bondable with the aforementioned batteries.
- a mixed rotary structure metal-concrete
- the mixed structure is made up of a light metal frame and of small size, of which a first inner membrane 1, preferably cylindrical, is provided at the ends with two reinforcement rings 2, two bearing rings 3, then two eardrums of closure 4, and of which an outer membrane 5, preferably polygonal, is secured to the first membrane by head gussets 6 and by intermediate gussets 7, so that, once on site, mounted on a step-by-step rotation device 8 and filled with concrete, said framework becomes an extremely rigid rotary structure, capable of taking on very high tensioning forces very quickly.
- Each mold support device is made up of two tangent beams 9, secured to two sides of the rotary structure by chairs 10, which simultaneously ensure the seat batteries, on the one hand, and the controlled blocking by means of several removable shoes 11, on the other hand.
- Each tensioning device comprises firstly two very rigid anchor frames consist of several gussets thick plate 12 assembled with the aid of a base plate 13, a front plate 14, and an upper plate 15, frameworks mounted at the two ends of each side of the rotary structure to ensure the transfer of tensioning forces thereto, and comprises, on the other hand, at least two self-supporting head screens and removable 16, which ensure the group tensioning of the armatures using one or more clamp rods 17 mounted with vertical adjustment by means of a removable shoe 18 on the anchoring frame of the side of the active head of the barrel (this being located on the right in FIG. 2) and using a plate 19 provided with one or more fingers for hooking said screens, plate also removable, mounted by 1 ' intermediate of a vertical adjustment piece 20 on the anchoring frame on the side of the passive head of the barrel (on the left in Figure 2).
- Each battery of molds is made up of several shells 21, assembled by gussets 22 to a resistance frame 23, frame provided with elastic support pads 24, height adjustment shims 25, vibrators 26, steam distribution pipes 27 r and finally a sealing plate 28 provided with two lateral folds 29.
- Each removable cover consists of a longitudinal beam 30, a series of transverse gussets 31, then a heat-insulated envelope 32, the extreme stiffening edges of which stop the heat-insulating and, by a good contact surface, the tight junction with the lateral folds 29 of the aforementioned sealing plate 28.
- a rotary structure, self-supporting or not (with or without devices for tensioning the reinforcements) constituted by a metal membrane 33, in particular cylindrical, reinforced by a few beams radials 34 of high inertia and by a series of bracing gussets 35, structure having two head shields 36, also self-supporting or not, shields provided with axes of rotation 37, and a few sloping chairs 38, facilitating sliding out head screens 39 during demolding, and it comprises, on the other hand, batteries of non-heating molds bm2, provided with elastic support pads 24, shims 25, vibrators 26 and a few lateral fixing chairs 40 , batteries closed using removable non-insulating covers c2, so that the heating of the concrete can be carried out from the outside using, for example, a specific installation of type 7 easements.
- the multi-purpose barrel of type 3, shown in FIG. 7, comprises, on the one hand, a rotary structure, self-supporting or not (with or without devices for tensioning the reinforcements) constituted by a membrane, in particular cylindrical 33 , reinforced with box beams 41, a structure which includes the molds m and the steam pipes 27, and it comprises, on the other hand, a support beam 42, in particular tubular, provided with a rotation device step by step 43, two working platforms 44 and two rail bogies 45 or road axles, so that by mounting said structure equipped with closing covers ç_3. around the support beam 42 using bearing rings 46, a mobile and compact barrel is obtained to the point of respecting the international gauge of rail or road transport.
- a cruciform rotary structure designed for manufacturing in particular of products (solid or hollow) with longitudinal and / or transverse fruit, comprises, on the one hand, a cruciform rotary structure, self-supporting or not, the central part of which is a hollow beam 47 preferably square, reinforced longitudinally by a few sections 48 and transversely by gussets 49, and of which each of the four arms incorporates either longitudinal fruit molds m4a, or transverse fruit molds m4b, said molds being integrated as resistance elements capable, with their reinforced heating walls 50 48, 49, take up and distribute the tensioning forces and as means of easements because their insulated side walls 51 automatically become access gateways at each stop of the barrel, and it also comprises means (not shown ) closing the molds, molding cores with reservations 52 advantageously in the trunk of a pyramid and pre-balanced bearings 53 fitted out to receive seat beams on the site allowing the barrel to rest on pre-established foundations, after removal of the road 54 or rail means of transport to the international size.
- the type 5 multifunctional barrel shown in FIG. 9, firstly comprises a rotary structure with at least two sides, self-supporting or not, consisting of a central beam 55, in particular tubular, reinforced by stiffening eardrums 56 and at least four multifunctional peripheral beams, secondly comprises batteries of bm5 heating molds and thirdly comprises pre-balanced bearings 53 as mentioned above, with two seat beams not shown, so that this barrel can be legally transported on a road 54 or rail chassis, without molds or with two sets of molds (on the opposite vertical sides), and so that it can be put into operation on site quickly either with two batteries or with additional batteries mounted on site.
- Each multifunction beam is an optimized framework having a central part 57 curved along the outside radius of the tubular beam on which it is welded, also having two mold-seat arms 58 provided with blocking shoes 11 and finally having a series of gussets 59 on which are mounted a few removable plates made of striated sheet metal 60 forming lateral passageways integrated into the barrel, so that said multifunctional beams simultaneously provide:
- the type 6 multi-function barrel shown in FIG. 10, firstly comprises a lightened rotary structure (not responsible for taking up the tensioning efforts of the reinforcements) constituted by a membrane 33, in particular cylindrical, provided with a few beams- box 61 for reinforcing and fixing the molds, two eardrums 4 for closing the head and two bearing rings 3, and secondly a few batteries of molds bm6 allowing the casting of certain products on edge, batteries made up of the using, on the one hand, an open type support shell cs6 f having a support frame 62 and two fixed lateral walls 63 slightly inclined towards the outside, shell provided with elastic support pads 24, one or more vibrators 26 and some closing devices 64 for closing the upper side, and using, on the other hand, a removable na6 multifunctional core.
- This core consisting of a closed-type shell 65 provided, on the one hand, with two head closing eardrums 66 and a few transverse reinforcement gussets 67 and, on the other hand, with fastening parts 68 and d '' a steam distribution pipe 27, can either be self-supporting with respect to the tensioning forces in the case of manufacturing of prestressed concrete products, or non-bearing with respect to said forces in the case of the manufacture of reinforced concrete products . In the latter case shown by way of example in FIG.
- said core fixed in its support shell, firstly ensures the pouring on edge of two face panels to-face and several head to head and secondly ensures the heat treatment TT of the concrete over the entire rotary travel of 360 ° of said battery so that arrived again at the top of the barrel, it is in a third time taken load by a specific installation of type 4 easements, which ensures in the outward stroke the initial demoulding D1 and the evacuation E of said hardened panels and, in the return stroke, the positioning MP of the armatures (being hung on said core instead of evacuated panels).
- the type 7 multi-function barrel shown in FIG. 11, firstly comprises a lightened rotary structure, formed using a membrane 33, in particular cylindrical, provided with two bearing rings 3 and reinforced by several rings 70, by two head sections 4 and by a series of longitudinal beams 71, beams provided with a few mold support chairs 72 and a few mold blocking parts 73 with elastic contact, and secondly comprises mold batteries bm7 allowing the casting side by side of prestressed or reinforced concrete products as by example of poles 74 for power lines, batteries produced individually using, on the one hand, an open type support shell cs7 having a common bottom 75 and two tilting and heating side walls 76, shell provided with a few reservation parts 77, elastic supports 24 and vibrators 26, and with the help, on the other hand, of a removable multifunctional core na7 which is self-supporting or not with respect to the stressing efforts of the reinforcements.
- the self-supporting type core is formed in the form of a very rigid removable assembly, using a welded shell of thick sheet metal 78 reinforced by two eardrums 79 for closing the head and by a series of anti-buckling gussets 80, shell provided on the one hand with reserve parts 77 and a steam distribution pipe 27 and on the other hand with two self-supporting head screens 81, so that by fixing this core in the support shell cs7 is finding it cleaned and oiled at the top of the barrel and closing the side walls 76, it first ensures the side-by-side pouring of two posts and in a second step of intensive heat treatment TT of the concrete well enclosed using lids insulating ç_7, throughout its rotary travel of 360 *, and so that at the end of said path, when the core returns from top barrel having a pole stuck on each side, it is supported by a SETUP specific ion of type 5 and moved through the main work stations arranged outside the barrel either longitudinally or preferably transversely (FIG. 11)
- the type 1 single-function barrel shown in FIG. 12, comprises, on the one hand, a light rotary structure, constituted by means of a membrane 33 provided with two bearing rings 3, two head eardrums 4 and of a few beams-rail 82 assembled two in pairs by means of support gussets 83, structure provided with a rotary device 84 for distributing the steam, and comprises, on the other hand, a series of heated or, preferably dismountable, peripheral niches made up of using radial walls 85 provided with own fixing means 86 and using heat-insulated peripheral covers 87 also provided with own fixing means, recesses closed at one end by a heat-insulating screen and at the other end by a door also insulated , so that by closing off the spaces between the peripheral covers with a few sealing strips 88, an independent installation of intensive heat treatment TTI can be obtained which can be mounted in the open air on four small foundations 89 , installation having the extraction station and reintroduction of the molds provided with rollers 90 preferably at the top of the barrel.
- the type 2 single-function barrel shown in FIG. 13, comprises a rotary structure incorporating heating niches - ⁇ 2, a structure formed using, on the one hand, two peripheral rings 91 linked by a series of beams longitudinal 92 reinforced by gussets 93 and provided with rollers 94, and using, on the other hand, a tubular beam 95 arranged in the axis of the barrel and provided with a rotary device 84 for distributing steam, so that by connecting radially two by two the longitudinal beams 92 to the tubular beam 95 using a few removable walls 96 in particular in "V", walls reinforced by gussets 97 and provided with some connecting parts 98, and so that by closing said structure with thermally insulated walls at the top 99 and by peripheral thermally insulated walls 100, a series of heating niches is obtained, usually higher than wide nZ, integrated into the structure rotating to the point of forming with it a independent installation of intensive heat treatment preferably having the extraction station and reintroduction of the molding means (molds or batteries
- the type 3 single-function barrel shown in FIGS. 14 and 15, comprises, on the one hand, a rotary structure produced using two or more box rings 101 mounted outside of a cylinder 102, of so as to be able to place between said rings heating and removable niches Q3., preferably wider than high, niches which can receive and carry, in their step-by-step rotation of 360 * , molds (or batteries of molds) provided rollers 90, allowing the horizontal pouring of products having a structure and / or a special shape such as for example: decorative panels, sandwich panels, segments for the construction of tunnels, etc.
- the niches are, on the one hand, made up of covers 103, conforming to the curvature of said segments, said covers being welded to a frame comprising beams 104, gussets 105, and angles 106 for mounting said frame between two rings, and are, on the other hand, provided with rails 107, allowing the extraction and reintroduction of the molds, devices 108 for blocking the molds in said rails and some lifting devices 109 , preferably with hydraulic cylinders 110, which lift the molds after their introduction, so that the free face of the concrete matches the covers 103 during the intensive heat treatment TTI over the entire course of 360 * .
- the ten types of barrels described are advantageously served by one or more of the ten types of specific easement installations presented below.
- the specific type 1 installation shown in FIG. 1, comprises a device for handling sli covers consisting of a horizontal beam 111, overhanging the upper face of the barrel served in its longitudinal axial plane, and two electropalans 112 provided with prehensile means 113, preferably with clamps, electropalans suspended from said beam with a spacing of 0.54 1 ("1" being the length of the covers), so that the moment of deflection of the covers with regard to their length is considerably reduced, resulting in a significant reduction in their weight and in the power of the electropalans.
- the specific type 2 installation represented in FIG. 1, comprises at least two removable gripping devices 114, provided with gripping means preferably with suction cups 115, for the hardened products, and gripping means preferably with pliers for the armatures, devices suspended by means of a high inertia beam 116 from an apparatus 117 for vertical lifting and horizontal translation overhanging the upper part of the barrel served so that this installation performs or facilitates:
- the specific installation of type 3, represented in FIGS. 4 and 5, comprises a tilting beam us, provided with two head axes 119, with a device 120 for tilting at 180 * , with prehensile means for the covers 121, and removable prehensile means 122 for hardened products and armatures, beam mounted on a suspended carriage 123 overhanging the upper part of the barrel served, carriage provided with a vertical displacement device 124, and a device for horizontal displacement 125, so that this installation ensures or facilitates:
- the specific installation of type 4, represented in FIG. 10, comprises a multi-purpose carriage 126 overhanging the upper part of the barrel served, cha ⁇ riot integrating means of horizontal displacement 127, means of vertical displacement 128 thus as prehensile means for the cores 129, so that this installation ensures or facilitates:
- the specific installation of type 5, represented in FIG. 11, comprises a tool-holder framework 130, provided with a central row 131 of fixed prehensile means for the cores and two lateral rows 132 of removable prehensile means for the hardened products, frame suspended from a traveling beam 133, movable above the cylinder served, preferably transversely with respect to it, so that this installation successively ensures:
- the specific installation of type 6, shown in FIG. 11, comprises, on the one hand, a device for opening and closing the side walls of the battery of molds arriving at the top of the barrel served, preferably made up of using of several main cylinders 134 coupled to secondary cylinders 135, and comprises, on the other hand, a final release device
- a device located at the far left of the floor overhanging the barrel, a device mainly consisting of a support frame 136, equipped with double-acting cylinders 137 linked to movable arms 138 provided with suction cups 139 and in some cases vibrators, so that by placing on said framework a multi-purpose core na7, loaded with two posts, these are automatically taken care of by the movable arms 138 which separate them and separate them from the core, thus carrying out the final phase of deferred demolding.
- the specific installation of type 7, represented in FIG. 4, comprises a circular thermal screen 140 mounted in a fixed position all around the barrel des ⁇ served with the aid of a few parts 141 connecting it to an optimized structure, screen equipped with a series of electric or gas radiators 142 over approximately a quarter of its circumference, in the initial part thereof relative to the direction of rotation of the barrel served.
- the specific installation of type 8, shown in FIGS. 5 and 6, is a secondary barrel known as a service barrel disposed outside the main barrel served, preferably in its axial longitudinal plane, comprising in the first place a rotary framework modular 143 having the same step-by-step rate of rotation as that of the main barrel, frame provided with several support chairs 144 in turn provided with a few rotary arms 145 ensuring the blocking of hardened products £, whether or not fitted with screens freestanding from head 39, during their tilting 180 °, comprising second transfer means to the vertical 146 and horizontal transfer means 147 of the cured products, and finally having thirdly ergonomic preparation workstation PA fittings, so that this installation successively ensures:
- the specific installation of type 9, shown in FIG. 1, comprises two ergonomic walkways produced using a series of arms 148, preferably in "Z" shape, arms having their low horizontal part formed in the form of a heat-insulating floor 149 and their upper horizontal part provided with either means 150 ensuring their tilting, or means ensuring their sliding (vertical or horizontal), so that at each stop of a molding means (mold or battery of molds), at the top of the barrel served, said gangways tilt or slide one to the left and the other to the right of the molding means, thus facilitating access for workers, and so that once the molding means are filled and closed, the two gateways disappear, allowing the barrel to rotate by one step, during which time said gateways act as a guardrail.
- a semi-circular thermal screen made up of a resistance framework 151, a heat-insulated envelope 152, two gutters 153 and a few sealing strips 1 154, so that by placing several screens 155 on this screen on the rings of a single-function cylinder, it ensures, in addition to weather protection, the automatic closing of the heating niches of the cylinder served and the melting instant snow, while being very light and inexpensive.
- the first preferred association represented in FIG. 1, integrates a multifunctional barrel of type 1, two ordinary installations of easements (one of supply-distribution of concrete and one of cleaning-oiling of molds) and three specific installations of easements of type 1, 2 and 9, using an optimized type 1 structure, comprising four fully removable main parts including:
- the first part is a multi-function framework having at least two gantries 156 linked, on the one hand, by two strong beams 157, provided with rails 158, so as to form a common track both for the two ordinary installations of above mentioned easements for the specific type 2 installation, linked, on the other hand, by two beams 159 supporting the cladding 160 and by two beams 161 supporting a light roof 162, a roof which includes the support beam 111 of the installation type 1 specific, and finally linked by two multipurpose beams 163, of preferably tubular, cantilevered using a few high inertia brackets 164, the latter beams being provided, on the one hand, with support pieces-walls 165, support pieces-platforms 166, support pieces curtain 167 and sealing parts 168 and, on the other hand, ventilation means 169, and / or heat recovery 170;
- the second part consists of a few head platforms mounted directly on the aforementioned gantry cranes and two lateral platforms 171, preferably insulated, console mounted on the multi-purpose beams 163, so that these latter platforms can support on their ends overhanging the barrel the specific installation of type 9;
- the third part consists, on the one hand, of two side walls in a semi-warhead 172 mounted between the multi-purpose beams and the support-cladding beams 159 and, on the other hand, of some front walls 173 mounted, with or without doors and / or windows, on the ogival walls 172;
- the fourth part consists of two lateral closing devices comprising some curtains 174 with counterweight 175, mounted on reels 176, suspended with the help of some bearings 177 on the multipurpose beams by means of said curtain support pieces 167 of so as to facilitate the opening and closing of the two lateral spaces 178 used for the storage of coils 179, molds, etc.
- the multifunctional framework is preassembled on the ground and placed vertically in one piece, except for the two multipurpose beams which are subsequently assembled already fitted with said lateral platforms 171 and said curtain devices 174 to 177.
- the second privileged association represented in FIGS. 4, 5 and 6, integrates a type 2 multi-function barrel, two ordinary installations for easements (one for feeding the concrete and one for cleaning and oiling the molds) and three specific installations for easements of type 3, 7 and 8, using an optimized type 2 structure, comprising two main parts including:
- the first part is the main frame having two rows of posts 180 provided with a series of small mounting brackets 181, rows linked in the first place by two longitudinal beams 182 provided with several gussets 183 having, welded to their ends ⁇ moths, a few curved plates 184 which firstly assemble the lower part (about a third) of the heat shield 140 which is the subject of the specific installation of type 7 and secondly the two parts lateral of said screen, rows linked secondly by two transverse box beams 185, so as to ensure the mounting of the barrel via two preset bearings 186, rows linked thirdly by two longitudinal beams 187 ensuring the mounting of five work and / or passage platforms including two head platforms 188, a central platform 189 arranged between the main barrel and the secondary barrel and two platforms 190 arranged laterally with respect to the secondary barrel, rows linked in the fourth place by two longitudinal beams 191 provided with gussets 192, having on the one hand plates (184), which ensure the mounting of the two lateral parts of the specific installation of
- the third preferred association incorporates, in the form of a floating workshop, a type 6 multifunctional barrel, all or part of the ordinary installations of above-mentioned easements and a specific installation of easements of type 4 to using an optimized type 3 structure, comprising two main parts, of which: - the first part is a ship hull 203 reinforced by transverse ribs 204 and longitu ⁇ dinales 205, hull first provided with a framework of multifunctional bottom having transverse beams 206 and longitudinal beams 207 welded to the desired height on the transverse ribs 204 so that said framework simultaneously supports the support frames 208 for lifting and rotating the barrel, supporting the floor of the barrel the machine room (generator, hydraulic group, compressor, boiler, etc.) located at one end of the barrel , the support of the floor of the main ⁇ tenance room and various storage located at the other end of the barrel, the raising of said frames and floors to keep them out of possible infiltration water, the bracing of the hull, uniform distribution of loads transmitted by equipment
- the second part is a frame added in arc 211, the bases of which bear on the side walls of the hull and the upper part of which incorporates a running track common to the two ordinary concrete supply-distribution and cleaning-oiling installations molds, and common to a specific type 4 installation, a track which is advantageously made up of two beams 212 joined together and to the arched frame by gussets 213 so as to ensure transverse stiffening at the same time and the longitudinal bracing of said frame equipped with fixed or mobile covering elements 214.
- a technical floor 216 with a strong framework distinguished by its level overhanging the barrel, by an opening of dimensions greater than those of the battery of molds open at the top of the barrel, by the support of a track 217 mounted on the longitudinal edges of said opening in the floor and by its function of the ceiling of room 218 available for fitting out many ordinary installations of easements;
- a heat shield 140 the two upper parts of which are integral with the technical floor 216 and the posts 215 and the lower part of which rests on supports 220.
- the methods, factories and workshops with barrels according to the invention relate to the manufacture of moldable products and in particular those of molded concrete which is diffused, with a significant increase in productivity and quality.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Moulds, Cores, Or Mandrels (AREA)
- On-Site Construction Work That Accompanies The Preparation And Application Of Concrete (AREA)
- Moulding By Coating Moulds (AREA)
- Devices For Post-Treatments, Processing, Supply, Discharge, And Other Processes (AREA)
- Manufacturing Of Tubular Articles Or Embedded Moulded Articles (AREA)
Abstract
L'invention concerne la fabrication de produits moulables caractérisée par l'intégration de moyens de moulage (bm1) à des structures rotatives optimisées (1, 5, 7, 9, 12) sous la forme de barillets modulaires ayant au moins deux pans, barillets dotés de et/ou associés à des moyens qui assurent le regroupement des principaux postes de travail (MP, MT, B, D, NH) de manière à affecter au durcissement du matériau moulé un parcours rotatif supérieur à 270° et de préférence égal à 360°, avec ou sans recours à tout moyen d'accélération dudit durcissement. L'invention concerne particulièrement la fabrication de produits en béton avec démoulage différé.The invention relates to the manufacture of moldable products characterized by the integration of molding means (bm1) in optimized rotary structures (1, 5, 7, 9, 12) in the form of modular barrels having at least two sides, barrels provided with and / or associated with means which ensure the regrouping of the main work stations (MP, MT, B, D, NH) so as to assign to the hardening of the molded material a rotary path greater than 270 ° and preferably equal to 360 °, with or without recourse to any means of acceleration of said hardening. The invention relates particularly to the manufacture of concrete products with deferred mold release.
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9200124 | 1992-01-08 | ||
FR9200124A FR2685885B1 (en) | 1992-01-08 | 1992-01-08 | PROCESS, WORKSHOPS AND BARREL FACTORIES, SERVICING PLANTS AND ASSEMBLY STRUCTURES FOR THE MANUFACTURE OF MOLDABLE PRODUCTS, PARTICULARLY CONCRETE BASED. |
PCT/FR1993/000004 WO1993013924A1 (en) | 1992-01-08 | 1993-01-05 | Method, barrel subunits and units, service installations and assembly structures for the fabrication of mouldable products, particularly based on concrete |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0621822A1 true EP0621822A1 (en) | 1994-11-02 |
EP0621822B1 EP0621822B1 (en) | 1995-11-29 |
Family
ID=9425465
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP93914495A Expired - Lifetime EP0621822B1 (en) | 1992-01-08 | 1993-01-05 | Method, barrel subunits and units, service installations and assembly structures for the fabrication of mouldable products, particularly based on concrete |
Country Status (10)
Country | Link |
---|---|
US (1) | US5728327A (en) |
EP (1) | EP0621822B1 (en) |
AU (1) | AU660071B2 (en) |
CA (1) | CA2126991C (en) |
DE (1) | DE69300912T2 (en) |
ES (1) | ES2080622T3 (en) |
FR (1) | FR2685885B1 (en) |
HK (1) | HK1007985A1 (en) |
RO (1) | RO112597B1 (en) |
WO (1) | WO1993013924A1 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6910289B2 (en) * | 2003-02-27 | 2005-06-28 | Cj Moyna + Sons, Inc. | Scraping device and a system and a method for collecting materials |
US7980282B2 (en) * | 2007-10-02 | 2011-07-19 | Caterpillar Inc. | Tire system for an off-highway machine |
US7640996B2 (en) | 2007-10-02 | 2010-01-05 | Caterpillar Inc. | Walking beam and tire system for an earthmoving scraping device |
US10493656B2 (en) * | 2017-01-31 | 2019-12-03 | William M. Del Zotto | Devices and processes for making concrete articles |
CN114872177B (en) * | 2022-05-16 | 2023-12-12 | 江西科技学院 | Production forming device of permeable concrete brick and application method thereof |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR964131A (en) * | 1950-08-07 | |||
US3568272A (en) * | 1967-09-12 | 1971-03-09 | Leo D Zmania | Apparatus for producing masonry blocks and the like |
FR2060445A5 (en) * | 1969-07-25 | 1971-06-18 | Borcoman Mircea | |
FR2060447A5 (en) * | 1969-08-29 | 1971-06-18 | Borcoman Mircea | |
FR2062090A5 (en) * | 1969-10-10 | 1971-06-25 | Borcoman Mirdea | |
CA997536A (en) * | 1973-05-04 | 1976-09-28 | Andre Pilish | Mobile concrete manufacturing plant |
FR2305284A1 (en) * | 1975-03-27 | 1976-10-22 | Borcoman Mircea | SINGLE-BLOCK PLANT OR PLANT FOR THE MANUFACTURING OF CONCRETE PRODUCTS, IN PARTICULAR PRE-STRESSED CONCRETE AND / OR REINFORCED CONCRETE |
JPS5421415A (en) * | 1977-07-19 | 1979-02-17 | Mitsubishi Heavy Ind Ltd | Barge for making iron reinforced concrete products |
FR2387750A1 (en) * | 1978-08-07 | 1978-11-17 | Camus Raymond | Mobile plant for making precast concrete panels - is barge chain with concrete making, casting, reinforcing and crane barges |
FR2442116A1 (en) * | 1978-11-22 | 1980-06-20 | Borcoman Mircea | ROTARY DRUM FACTORIES FOR THE MANUFACTURE OF REINFORCED CONCRETE AND PRE-STRESSED CONCRETE PRODUCTS |
DE2950661A1 (en) * | 1979-12-15 | 1981-06-19 | Gerhard 5272 Wipperfürth Hering | Brick hardening and drying unit - has rotary drum with platforms for bricks operating continuously |
US4266916A (en) * | 1980-02-14 | 1981-05-12 | Lubavs Arnold A | Mobile block production plant |
FR2498976A1 (en) * | 1981-02-04 | 1982-08-06 | Borcoman Mircea | METHOD, DEVICES, MOLD-SUPPORTING STRUCTURES AND FACILITIES FOR IMPROVING THE EFFICIENCY OF PROCESSES FOR THE MANUFACTURE OF PRE-STRESSED CONCRETE PRODUCTS |
-
1992
- 1992-01-08 FR FR9200124A patent/FR2685885B1/en not_active Expired - Fee Related
-
1993
- 1993-01-05 EP EP93914495A patent/EP0621822B1/en not_active Expired - Lifetime
- 1993-01-05 ES ES93914495T patent/ES2080622T3/en not_active Expired - Lifetime
- 1993-01-05 AU AU34552/93A patent/AU660071B2/en not_active Ceased
- 1993-01-05 RO RO94-01165A patent/RO112597B1/en unknown
- 1993-01-05 CA CA002126991A patent/CA2126991C/en not_active Expired - Fee Related
- 1993-01-05 DE DE69300912T patent/DE69300912T2/en not_active Expired - Fee Related
- 1993-01-05 WO PCT/FR1993/000004 patent/WO1993013924A1/en active IP Right Grant
-
1994
- 1994-07-08 US US08/275,212 patent/US5728327A/en not_active Expired - Fee Related
-
1998
- 1998-06-26 HK HK98107092A patent/HK1007985A1/en not_active IP Right Cessation
Non-Patent Citations (1)
Title |
---|
See references of WO9313924A1 * |
Also Published As
Publication number | Publication date |
---|---|
AU3455293A (en) | 1993-08-03 |
DE69300912D1 (en) | 1996-01-11 |
FR2685885A1 (en) | 1993-07-09 |
AU660071B2 (en) | 1995-06-08 |
CA2126991C (en) | 2002-06-11 |
DE69300912T2 (en) | 1996-06-13 |
FR2685885B1 (en) | 1994-03-25 |
RO112597B1 (en) | 1997-11-28 |
US5728327A (en) | 1998-03-17 |
CA2126991A1 (en) | 1993-07-22 |
WO1993013924A1 (en) | 1993-07-22 |
EP0621822B1 (en) | 1995-11-29 |
ES2080622T3 (en) | 1996-02-01 |
HK1007985A1 (en) | 1999-04-30 |
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