EP0619365A1 - Cleaning composition and process therefor - Google Patents
Cleaning composition and process therefor Download PDFInfo
- Publication number
- EP0619365A1 EP0619365A1 EP94105386A EP94105386A EP0619365A1 EP 0619365 A1 EP0619365 A1 EP 0619365A1 EP 94105386 A EP94105386 A EP 94105386A EP 94105386 A EP94105386 A EP 94105386A EP 0619365 A1 EP0619365 A1 EP 0619365A1
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- EP
- European Patent Office
- Prior art keywords
- cleaning agent
- agent according
- cleaning
- mixture
- substances
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
Definitions
- the invention relates to a cleaning agent and a manufacturing method.
- cleaning agent is a collective name for mixtures of suitable substances that are used in particular for the surface cleaning of objects of all kinds. Cleaning agents are used on a large scale in industry, in commercial companies and in the household.
- Alkaline cleaning agents are known which mostly consist of strongly alkaline substances, such as sodium hydroxide solution and soda, and also often contain polyphosphates as softeners and silicates to improve the dirt-carrying capacity.
- washing-active substances such as, for example, fatty alcohol sulfates and disinfectants, for example chlorine bleach, can also be present.
- acidic cleaning agents are also common, e.g. Contain amidosulfonic acid and suitable detergent substances.
- Turpentine, benzene and benzine are also used as cleaning agents and solvents in the commercial sector.
- the main constituents of powdered or liquid household cleaning agents are mostly washing-active substances and polyphosphates, to which stabilizers, skin protection agents as well as colors and fragrances are added.
- mechanical abrasives consisting of finely ground quartz sand, chalk, diatomaceous earth or pumice stone in grain sizes smaller than 0.1 mm are common, which contain additives of alkalis, polyphosphates, washing-active and disinfectant substances.
- orange peel oil is a very good fat solvent.
- Orange peel oil is a purely biological substance with a high cleaning ability, which is also deodorising and mildly disinfecting and which does not create any ecological problems when it comes to disposal. There is only a germicidal effect up to a concentration of 1: 10,000, at a lower concentration, such as occurs in the disposal, essential orange peel oil is broken down very quickly and decomposed into unproblematic components.
- the object of the invention is to improve a cleaning agent based on orange peel oil with regard to the cleaning action and handling.
- an all-purpose cleaner is created which is suitable for a large number of applications both in the industrial and commercial sectors and in the household.
- the cleaner can be used as a concentrate, for example for removing stains, as well as in dilution with water, for example for house cleaning, in car washes, in canteen kitchens, etc.
- the degree of dilution depends on the type and extent of contamination.
- the cleaning agent is either added directly to the cleaning water or the cleaning agent is applied and washed off with water after the cleaning process.
- the use of the cleaning agent according to the invention is simple, easy and convenient, with no streaks, cleaning strips, etc., as residues.
- the cleaning effect is high even with economical dosing, which in connection with the high environmental compatibility and the quick degradation does not lead to disposal problems.
- the cold-pressed orange peel oil is an essential oil of 96.7% limonene; 1.9% myrcene; 0.6% ⁇ -pinene; 0.2% ⁇ -pinene and 0.1% phellandrene.
- the substance citrus phenene D-limone is obtained by distillation from orange peel as a mixture of predominantly monocyclic terpenes of the empirical formula C10H16, the 96% to 98% D-limonene; Contains 1% to 2% myrcene and 0.5% camphene.
- the cleaning effect and handling is optimized in particular by the mixture of cold-pressed orange peel oil and orange peel oil obtained by distillation.
- a known emulsifier of the composition mono- / diglycerides - polyoxyethylene (20) sorbitan monostearate is used, as is also used in the food sector. This eliminates a toxic effect and ensures good degradability.
- dilution with water in a ratio of 1:10 to 1: 500 can be used with good cleaning results.
- substances a) and b) and possibly d) are mixed in a first process step.
- the emulsifier is heated to 35 ° C. to 50 ° C. in accordance with c) and incorporated into the mixture by stirring.
- the citric acid may be added in a further process step.
- Claim 9 proposes to produce the required dilution by slowly and uniformly adding water and then to homogenize the mixture in order to counteract segregation.
- a preferred application in the household sector is that the cleaning agent is filled into a commercially available pump-spray bottle in the required dilution.
- the objects to be cleaned such as window panes, mirrors, sinks, tiles, etc., are sprayed with a thin film. Then wipe over with a damp cloth.
- the diluted detergent can also be applied directly to the cloth.
- almost all stains in the household such as crusts, oil stains, tar, shoe polish, wax stains, chewing gum, are loosened and removed.
- the cleaning agent according to the invention is well suited for cleaning carpets and carpets and for cleaning upholstery.
- the fabrics are also sprayed and then rubbed off with terry towels to remove dirt.
- the towels can be easily cleaned in the washing machine. Good cleaning results are also achieved with chrome cleaning, e.g. in car and engine care.
- the invention provides an inexpensive, ecologically well tolerated, effective cleaning agent which is suitable for a large number of applications.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Die Erfindung betrifft ein Reinigungsmittel und ein Herstellungsverfahren.The invention relates to a cleaning agent and a manufacturing method.
Der Begriff Reinigungsmittel steht als Sammelbezeichnung für Gemische geeigneter Substanzen, die insbesondere zur Oberflächenreinigung von Gegenständen verschiedenster Art verwendet werden. Reinigungsmittel werden in großem Umfang in der Industrie, in gewerblichen Betrieben und im Haushalt eingesetzt.The term cleaning agent is a collective name for mixtures of suitable substances that are used in particular for the surface cleaning of objects of all kinds. Cleaning agents are used on a large scale in industry, in commercial companies and in the household.
Es sind alkalische Reinigungsmittel bekannt, die meist aus stark alkalisch reagierenden Substanzen, wie Natronlauge und Soda, bestehen und außerdem oft Polyphosphate als Enthärter und Silicate zur Verbesserung des Schmutztragevermögens enthalten. Zudem können auch waschaktive Substanzen, wie z.B. Fettalkoholsulfate und Desinfektionsmittel, z.B. Chlorbleichlauge, enthalten sein.Alkaline cleaning agents are known which mostly consist of strongly alkaline substances, such as sodium hydroxide solution and soda, and also often contain polyphosphates as softeners and silicates to improve the dirt-carrying capacity. In addition, washing-active substances, such as, for example, fatty alcohol sulfates and disinfectants, for example chlorine bleach, can also be present.
Außer den alkalischen Reinigungsmitteln sind auch sauere Reinigungsmittel gebräuchlich, die z.B. Amidosulfonsäure und geeignete waschaktive Substanzen enthalten.In addition to the alkaline cleaning agents, acidic cleaning agents are also common, e.g. Contain amidosulfonic acid and suitable detergent substances.
Im gewerblichen Bereich sind auch Terpentin, Benzol und Waschbenzin als Reinigungs- und Lösungsmittel eingesetzt.Turpentine, benzene and benzine are also used as cleaning agents and solvents in the commercial sector.
Hauptbestandteile der pulverförmigen oder flüssigen Haushaltsreinigungsmittel sind meist waschaktive Substanzen und Polyphosphate, denen Stabilisatoren, Hautschutzmittel sowie Farb- und Duftstoffe zugegeben sind.The main constituents of powdered or liquid household cleaning agents are mostly washing-active substances and polyphosphates, to which stabilizers, skin protection agents as well as colors and fragrances are added.
Weiter sind mechanisch wirkende Scheuermittel, bestehend aus fein gemahlenem Quarzsand, Kreide, Kieselgur oder Bimsstein in Korngrößen kleiner 0,1 mm verbreitet, die Zusätze an Alkalien, Polyphosphaten, waschaktiven und desinfizierenden Substanzen enthalten.Furthermore, mechanical abrasives consisting of finely ground quartz sand, chalk, diatomaceous earth or pumice stone in grain sizes smaller than 0.1 mm are common, which contain additives of alkalis, polyphosphates, washing-active and disinfectant substances.
Weiter sind Spezialreinigungsmittel für spezielle Anwendungsfälle, wie Fensterreiniger, Autoreiniger, Metallputzmittel, etc., auf dem Markt, die sich je nach Verwendungszweck in ihrer Zusammensetzung unterscheiden.There are also special cleaning agents for special applications, such as window cleaners, car cleaners, metal cleaning agents, etc., which differ in their composition depending on the intended use.
Alle vorstehend genannten, bekannten Reinigungsmittel haben als gemeinsame Eigenschaft das Problem einer mehr oder weniger starken ökologischen Unverträglichkeit. Umweltschädigungen treten insbesondere dadurch auf, daß die Reinigungsmittel nach der Anwendung über die Kanalisation entsorgt werden und in den natürlichen Wasserhaushalt gelangen können. Es handelt sich meist um künstlich geschaffene Substanzen, die in der Umwelt sonst nicht vorkommen und die Pflanzen und Tiere, insbesondere die Mikroflora, direkt schädigen können. Zudem ist die biologische Abbaubarkeit oft nur über lange Zeiträume gegeben. Schädigungen können auch in biologischen Kläranlagen auftreten.All of the known cleaning agents mentioned above have the problem of a more or less strong ecological intolerance as a common property. Environmental damage occurs in particular because the cleaning agents are disposed of via the sewer system after use and can get into the natural water balance. These are mostly artificially created substances that do not otherwise occur in the environment and can directly damage plants and animals, especially the microflora. In addition, biodegradability is often only possible over long periods. Damage can also occur in biological sewage treatment plants.
Es ist bereits die Reinigungswirkung von Orangenschalenöl als ätherischem Öl bekannt. Insbesondere ist Orangenschalenöl ein sehr gutes Fettlösemittel. Orangenschalenöl ist eine rein biologische Substanz mit hohem Reinigungsvermögen, die zudem desodorierend und mild desinfizierend wirkt und das keine ökologischen Probleme bei der Entsorgung schafft. Lediglich bis zu einer Konzentration von 1:10.000 besteht eine keimtötende Wirkung, bei einer geringeren Konzentration, wie sie in der Entsorgung auftritt, wird ätherisches Orangenschalenöl sehr schnell abgebaut und in unproblematische Bestandteile zersetzt.The cleaning action of orange peel oil as an essential oil is already known. In particular, orange peel oil is a very good fat solvent. Orange peel oil is a purely biological substance with a high cleaning ability, which is also deodorising and mildly disinfecting and which does not create any ecological problems when it comes to disposal. There is only a germicidal effect up to a concentration of 1: 10,000, at a lower concentration, such as occurs in the disposal, essential orange peel oil is broken down very quickly and decomposed into unproblematic components.
Es ist kaltgepreßtes Orangenschalenöl und durch Destillation gewonnenes Orangenschalenöl bekannt.Cold-pressed orange peel oil and orange peel oil obtained by distillation are known.
Trotz der bekannten, guten Reinigungseigenschaften, der ökologischen Vorteile und eines gegenüber herkömmlichen Reinigungsmitteln eher geringeren Preises hat sich bisher der Einsatz als Reinigungsmittel in größerem Umfang nicht durchgesetzt. Der Grund dafür dürfte in Schwierigkeiten und Problemen bei der Anwendung liegen:Despite the known, good cleaning properties, the ecological advantages and a rather lower price than conventional cleaning agents, the use as a cleaning agent has so far not become widespread. The reason for this is likely to be difficulties and problems with the application:
Bei einer unspezifischen Zusammensetzung und Anwendung können, bedingt durch den Ölcharakter, nur schwer zu entfernende Schmutzränder, Schmierstreifen und Schichtbildungen auftreten. Neben diesen Anwendungsschwierigkeiten ist bei einer unspezifischen Zusammensetzung ggfs. die Reinigungswirkung gering.In the case of an unspecific composition and application, due to the oil character, it is difficult to remove dirty edges, smear strips and layers. In addition to these application difficulties, the cleaning effect may be low with an unspecific composition.
Aufgabe der Erfindung ist es demgegenüber, ein Reinigungsmittel auf Orangenschalenölbasis hinsichtlich der Reinigungswirkung und der Handhabung zu verbessern.In contrast, the object of the invention is to improve a cleaning agent based on orange peel oil with regard to the cleaning action and handling.
Diese Aufgabe wird mit den Merkmalen des Anspruchs 1 gelöst.This object is achieved with the features of claim 1.
Gemäß Anspruch 1 besteht das Reinigungsmittel aus einem Gemisch folgender Substanzen:
- a) 35 % bis 50 % kaltgepreßtes Orangenschalenöl,
- b) 35 % bis 50 % Zitrusterpene D-Limone und
- c) 5 % bis 15 % Emulgator zur Herstellung von Trennemulsionen.
- a) 35% to 50% cold-pressed orange peel oil,
- b) 35% to 50% citrus pens D-lime and
- c) 5% to 15% emulsifier for the preparation of separating emulsions.
Alle %-Angaben beziehen sich auf Volumenanteile.All percentages relate to volume fractions.
Mit einem solchen Gemisch wird ein Allzweckreiniger geschaffen, der sowohl im industriellen und gewerblichen Bereich als auch im Haushalt für eine Vielzahl von Anwendungen geeignet ist. Der Reiniger kann als Konzentrat, beispielsweise zur Fleckenentfernung, als auch in Verdünnung mit Wasser, beispielsweise für den Hausputz, in Autowaschanlagen, in Großküchen, etc., verwendet werden. Der Verdünnungsgrad richtet sich dabei nach der Art und dem Umfang der Verschmutzung. Bei der Anwendung wird das Reinigungsmittel entweder direkt dem Putzwasser zugegeben oder das Reinigungsmittel wird aufgetragen und nach dem Putzvorgang mit Wasser abgewaschen.With such a mixture, an all-purpose cleaner is created which is suitable for a large number of applications both in the industrial and commercial sectors and in the household. The cleaner can be used as a concentrate, for example for removing stains, as well as in dilution with water, for example for house cleaning, in car washes, in canteen kitchens, etc. The degree of dilution depends on the type and extent of contamination. In use, the cleaning agent is either added directly to the cleaning water or the cleaning agent is applied and washed off with water after the cleaning process.
Die Anwendung des erfindungsgemäßen Reinigungsmittels ist einfach, leicht und bequem, wobei keine Schlieren, Putzstreifen, etc., als Rückstände auftreten.The use of the cleaning agent according to the invention is simple, easy and convenient, with no streaks, cleaning strips, etc., as residues.
Die Reinigungswirkung ist auch bei sparsamer Dosierung hoch, was in Verbindung mit der hohen Umweltverträglichkeit und dem schnellen Abbau zu keinen Entsorgungsproblemen führt.The cleaning effect is high even with economical dosing, which in connection with the high environmental compatibility and the quick degradation does not lead to disposal problems.
Gemäß Anspruch 2 besteht das kaltgepreßte Orangenschalenöl als ätherisches Öl aus 96,7 % Limonen; 1,9 % Myrcen; 0,6 % α-Pinen; 0,2 % β-Pinen und 0,1 % Phellandren.According to claim 2, the cold-pressed orange peel oil is an essential oil of 96.7% limonene; 1.9% myrcene; 0.6% α-pinene; 0.2% β-pinene and 0.1% phellandrene.
Gemäß Anspruch 3 ist die Substanz Zitrusterphene D-Limone durch Destillation aus Orangenschalen gewonnen als Gemisch von vorwiegend monozyklischen Terpenen der Summenformel C₁₀H₁₆, das 96 % bis 98 % D-Limonen; 1 % bis 2 % Myrcen und 0,5 % Camphen enthält.According to claim 3, the substance citrus phenene D-limone is obtained by distillation from orange peel as a mixture of predominantly monocyclic terpenes of the empirical formula C₁₀H₁₆, the 96% to 98% D-limonene; Contains 1% to 2% myrcene and 0.5% camphene.
Die Reinigungswirkung und Handhabung wird insbesondere durch das Gemisch aus kaltgepreßtem Orangenschalenöl und durch Destillation gewonnenem Orangenschalenöl optimiert.The cleaning effect and handling is optimized in particular by the mixture of cold-pressed orange peel oil and orange peel oil obtained by distillation.
Nach Anspruch 4 wird ein an sich bekannter Emulgator der Zusammensetzung Mono-/Diglyceride - Polyoxyethylen-(20)-Sorbitanmonostearat verwendet, wie er auch im Lebensmittelbereich eingesetzt wird. Dadurch ist eine toxische Wirkung ausgeschlossen und eine gute Abbaubarkeit gewährleistet.According to claim 4, a known emulsifier of the composition mono- / diglycerides - polyoxyethylene (20) sorbitan monostearate is used, as is also used in the food sector. This eliminates a toxic effect and ensures good degradability.
Zweckmäßig wird für ein großes Anwendungsspektrum als Allzweckreiniger zusätzlich 10 % bis 15 % Isopropyl-Alkohol CH₃-CH(OH)CH₃ zugegeben, wodurch die Verteilung und die Entfernung des Reinigungsmittels mit den Schmutzresten begünstigt wird.Appropriately for a wide range of applications as an all-purpose cleaner, 10% to 15% isopropyl alcohol CH₃-CH (OH) CH₃ is added, which promotes the distribution and removal of the cleaning agent with the dirt residues.
Für spezielle Anwendungen, insbesondere im Sanitärbereich, wird eine weitere Verbesserung gemäß Anspruch 6 dadurch erreicht, daß noch 10 % Zitronensäure, bezogen auf die Gesamtmenge der übrigen Substanzen, zugesetzt werden.For special applications, in particular in the sanitary area, a further improvement is achieved in that 10% citric acid, based on the total amount of the other substances, is added.
Je nach Anwendung sowie Art und Grad der Verschmutzung ist nach Anspruch 7 eine Verdünnung mit Wasser im Verhältnis 1:10 bis 1:500 mit gutem Reinigungserfolg einsetzbar.Depending on the application and the type and degree of contamination, dilution with water in a ratio of 1:10 to 1: 500 can be used with good cleaning results.
Gemäß dem mit Anspruch 8 beanspruchten Herstellungsverfahren werden in einem ersten Verfahrensschritt die Substanzen a) und b) sowie ggfs. d) gemischt. In einem weiteren Verfahrensschritt wird der Emulgator entsprechend c) auf 35°C bis 50°C erwärmt und durch Rühren in das Gemisch eingearbeitet. Für das Reinigungsmittel mit Zitronensäure wird ggfs. in einem weiteren Verfahrensschritt die Zitronensäure zugegeben. Die Herstellung ist somit einfach und kostengünstig durchführbar. Da auch die Ausgangssubstanzen preiswert sind, ergibt sich in Verbindung mit der sparsamen Anwendungsmöglichkeit ein günstiger Preis für das Reinigungsmittel.According to the manufacturing process claimed in claim 8, substances a) and b) and possibly d) are mixed in a first process step. In a further process step, the emulsifier is heated to 35 ° C. to 50 ° C. in accordance with c) and incorporated into the mixture by stirring. For the cleaning agent with citric acid, the citric acid may be added in a further process step. The production is thus simple and inexpensive to carry out. Since the starting substances are also inexpensive, the economical use of the detergent results in a favorable price.
Mit Anspruch 9 wird vorgeschlagen, die erforderliche Verdünnung durch langsame und gleichmäßige Wasserzugabe herzustellen und anschließend das Gemisch zu homogenisieren, um einer Entmischung entgegenzuwirken.Claim 9 proposes to produce the required dilution by slowly and uniformly adding water and then to homogenize the mixture in order to counteract segregation.
Eine bevorzugte Anwendung im Haushaltsbereich besteht darin, daß das Reinigungsmittel in der erforderlichen Verdünnung in eine handelsübliche Pump-Sprüh-Flasche eingefüllt wird. Die zu reinigenden Gegenstände, wie Fensterscheiben, Spiegel, Waschbecken, Fliesen, etc., werden mit einem dünnen Film besprüht. Anschließend wird mit einem feuchten Lappen darübergewischt. Das verdünnte Reinigungsmittel kann aber auch direkt auf den Lappen gegeben werden. Weiter werden nahezu alle Flecken im Haushalt, wie Krusten, Ölflecken, Teer, Schuhcreme, Wachsflecken, Kaugummi, gelöst und abgelöst. Weiter ist das erfindungsgemäße Reinigungsmittel zur Teppich- und Teppichbodenreinigung sowie zur Polsterstoffreinigung gut geeignet. Dazu werden die Stoffe ebenfalls besprüht und anschließend mit Frotteehandtüchern zur Schmutzentfernung abgerieben. Die Handtücher können ohne Mühe in der Waschmaschine wieder gereinigt werden. Gute Reinigungsergebnisse werden auch bei der Chromreinigung, z.B. bei der Auto- und Motorpflege, erzielt.A preferred application in the household sector is that the cleaning agent is filled into a commercially available pump-spray bottle in the required dilution. The objects to be cleaned, such as window panes, mirrors, sinks, tiles, etc., are sprayed with a thin film. Then wipe over with a damp cloth. The diluted detergent can also be applied directly to the cloth. Furthermore, almost all stains in the household, such as crusts, oil stains, tar, shoe polish, wax stains, chewing gum, are loosened and removed. Furthermore, the cleaning agent according to the invention is well suited for cleaning carpets and carpets and for cleaning upholstery. The fabrics are also sprayed and then rubbed off with terry towels to remove dirt. The towels can be easily cleaned in the washing machine. Good cleaning results are also achieved with chrome cleaning, e.g. in car and engine care.
Zusammenfassend ist festzustellen, daß mit der Erfindung ein preiswertes, ökologisch gut verträgliches, wirksames und für eine Vielzahl von Anwendungsfällen geeignetes Reinigungsmittel zur Verfügung gestellt wird.In summary, it can be stated that the invention provides an inexpensive, ecologically well tolerated, effective cleaning agent which is suitable for a large number of applications.
Claims (9)
daß in einem weiteren Verfahrensschritt der Emulgator nach c) auf 35°C bis 50°C erwärmt und durch Rühren in das Gemisch eingearbeitet wird und
daß gegebenenfalls in einem weiteren Verfahrensschritt die Zitronensäure entsprechend e) zugegeben wird.Manufacturing process for the cleaning agent according to one of claims 1 to 7, characterized in that in a first process step substances a) and b) and optionally d) are mixed,
that in a further process step the emulsifier according to c) is heated to 35 ° C. to 50 ° C. and incorporated into the mixture by stirring and
that the citric acid corresponding to e) is optionally added in a further process step.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19934311409 DE4311409A1 (en) | 1993-04-07 | 1993-04-07 | Detergents and manufacturing processes |
| DE4311409 | 1993-04-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP0619365A1 true EP0619365A1 (en) | 1994-10-12 |
Family
ID=6484947
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP94105386A Withdrawn EP0619365A1 (en) | 1993-04-07 | 1994-04-07 | Cleaning composition and process therefor |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP0619365A1 (en) |
| DE (1) | DE4311409A1 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999011744A2 (en) * | 1997-09-04 | 1999-03-11 | Serefina Lamarca | Cleaning agent |
| EP0943239A1 (en) * | 1997-05-16 | 1999-09-22 | pro-pack Handels- und Vertriebsgesellschaft mbH & Co. KG | Composition comprising citrus terpenes. |
| WO2011072861A1 (en) | 2009-12-15 | 2011-06-23 | Bene-Arzneimittel Gmbh | Suppository comprising pantoprazole |
| WO2012171540A1 (en) | 2011-06-15 | 2012-12-20 | Bene-Arzneimittel Gmbh | Suppository comprising pantoprazole comprised in pellets with a cellulose core |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE180824T1 (en) * | 1994-12-09 | 1999-06-15 | Horst K Veith | METHOD FOR CLEANING AND DISINFECTING TEXTILE OBJECTS AND BIOLOGICAL DISINFECTANT AND CLEANING AGENT |
| DE10119825A1 (en) * | 2001-04-23 | 2002-11-07 | Nanogate Technologies Gmbh | Composition for producing surfactant, used for cleaning and impregnating soiled, oily area, e.g. steel, engine or printing machine roller, contains long-chain, unfluorinated silane and perfluorinated silane forming curable polysiloxane |
| DE10315304B4 (en) * | 2002-09-11 | 2014-03-13 | Karsten Püschner | Method for decontaminating an object contaminated with organochlorine biocides |
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|---|---|---|---|---|
| US4533487A (en) * | 1983-08-15 | 1985-08-06 | Pitre-Jones | Process for producing blended d-Limonene and uses of the blended product |
| JPH01272700A (en) * | 1988-04-25 | 1989-10-31 | Dai Ichi Kogyo Seiyaku Co Ltd | Detergent for hard surface and method for washing |
| EP0384292A2 (en) * | 1989-02-22 | 1990-08-29 | Joachim Koss | Cleaning agent and process for its preparation |
| JPH03243700A (en) * | 1990-02-20 | 1991-10-30 | Nippon Oil & Fats Co Ltd | Detergent composition |
| EP0512328A1 (en) * | 1991-05-06 | 1992-11-11 | Miles Inc. | Food safe cleaning composition |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USRE33210E (en) * | 1986-05-01 | 1990-05-08 | Cleaning composition of terpene hydrocarbon and a coconut oil fatty acid alkanolamide having water dispersed therein |
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1993
- 1993-04-07 DE DE19934311409 patent/DE4311409A1/en not_active Withdrawn
-
1994
- 1994-04-07 EP EP94105386A patent/EP0619365A1/en not_active Withdrawn
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|---|---|---|---|---|
| US4533487A (en) * | 1983-08-15 | 1985-08-06 | Pitre-Jones | Process for producing blended d-Limonene and uses of the blended product |
| JPH01272700A (en) * | 1988-04-25 | 1989-10-31 | Dai Ichi Kogyo Seiyaku Co Ltd | Detergent for hard surface and method for washing |
| EP0384292A2 (en) * | 1989-02-22 | 1990-08-29 | Joachim Koss | Cleaning agent and process for its preparation |
| JPH03243700A (en) * | 1990-02-20 | 1991-10-30 | Nippon Oil & Fats Co Ltd | Detergent composition |
| EP0512328A1 (en) * | 1991-05-06 | 1992-11-11 | Miles Inc. | Food safe cleaning composition |
Non-Patent Citations (2)
| Title |
|---|
| PATENT ABSTRACTS OF JAPAN vol. 014, no. 037 (C - 680) 24 January 1990 (1990-01-24) * |
| PATENT ABSTRACTS OF JAPAN vol. 016, no. 033 (C - 0905) 28 January 1992 (1992-01-28) * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0943239A1 (en) * | 1997-05-16 | 1999-09-22 | pro-pack Handels- und Vertriebsgesellschaft mbH & Co. KG | Composition comprising citrus terpenes. |
| WO1999011744A2 (en) * | 1997-09-04 | 1999-03-11 | Serefina Lamarca | Cleaning agent |
| WO1999011744A3 (en) * | 1997-09-04 | 1999-08-19 | Serefina Lamarca | Cleaning agent |
| WO2011072861A1 (en) | 2009-12-15 | 2011-06-23 | Bene-Arzneimittel Gmbh | Suppository comprising pantoprazole |
| EP2338477A1 (en) | 2009-12-15 | 2011-06-29 | bene-Arzneimittel GmbH | Suppository comprising pantoprazole |
| WO2012171540A1 (en) | 2011-06-15 | 2012-12-20 | Bene-Arzneimittel Gmbh | Suppository comprising pantoprazole comprised in pellets with a cellulose core |
Also Published As
| Publication number | Publication date |
|---|---|
| DE4311409A1 (en) | 1994-10-13 |
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