EP0602201B1 - Shaped-section fine-fibre filament yarn and method of producing it - Google Patents
Shaped-section fine-fibre filament yarn and method of producing it Download PDFInfo
- Publication number
- EP0602201B1 EP0602201B1 EP93912537A EP93912537A EP0602201B1 EP 0602201 B1 EP0602201 B1 EP 0602201B1 EP 93912537 A EP93912537 A EP 93912537A EP 93912537 A EP93912537 A EP 93912537A EP 0602201 B1 EP0602201 B1 EP 0602201B1
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- European Patent Office
- Prior art keywords
- yarn
- titer
- dtex
- polyamide
- filament yarn
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- Expired - Lifetime
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Classifications
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/60—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/098—Melt spinning methods with simultaneous stretching
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/253—Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2967—Synthetic resin or polymer
- Y10T428/2969—Polyamide, polyimide or polyester
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2973—Particular cross section
Definitions
- the invention relates to a trilobal, fine-fibrillated filament yarn with a yarn viscosity RV of 40-55 and a strength of 30-45 cN / tex, in particular as a master yarn for texturing, and a method for producing the same.
- Profiled polyhexamethylene adipamide yarns are known (US-A-4801503).
- the known yarn is a smooth filament with a band-shaped fibril cross-section with a single titer of 2.8 dtex, which is suitable as a spandex substitute for the production of stockings due to its high flexural strength.
- the deep bending module is mainly attributed to the special profile.
- the well-known yarn is produced in two stages as a so-called polyamide LOY yarn.
- a polyamide LOY is to be understood as a filament which is wound up at spinning take-off speeds of up to approximately 1800 m / min; Polyamide POY is produced by spinning take-off speeds between 3700 and 5000 m / min.
- JP-A-58081609 discloses trilobal ultra-fine yarns made of polyester with a single titer ⁇ 1.5 dpf.
- the known yarns have extremely high melt viscosities and are used to produce artificial leather, for example. Production takes place at spinning speeds greater than or equal to 2500 m / min. They are unsuitable for textile use in weaving.
- a disadvantage of polyamide LOY for the planned use of the present yarn can be seen above all in the low spinning speeds, which do not guarantee economical production.
- Another disadvantage is the poorer processing (thread breaks) of polyamide LOY at high speeds.
- the thread viscosity is measured in a known manner as relative viscosity (RV) in formic acid.
- a stocking section is knitted from any number of spinning reels of a solder.
- the stocking section is in a bath with the dye Alizarin light blue 4GL from Sandoz AG, Basel stained in a known manner and, after drying, measured colorimetrically for the different remissions (brightnesses) of the sections originating from the different spinning reels.
- the coefficient of variation of the remissions is calculated in a known manner.
- the object of the invention is to provide a fine profiled original yarn for texturing or post-stretching, which is particularly suitable for warp threads in the weaving mill and does not have the dyeing disadvantages of the known profile threads.
- Another object is to provide a filament yarn which in the finished textile fabric does not have a gloss known as "greasy” and has an improved, very soft feel.
- the object is achieved according to the invention with a profile thread, by means of a single fibril titer ⁇ 1.5 dtex, a high color uniformity (coefficient of variation) of ⁇ 2 and a width / length ratio B / L of the fibril cross section of 0.5 to 0.7.
- the width / length ratio of the filament cross section from 0.5 to 0.7, in particular around 0.6, is also particularly suitable for the textile requirements with regard to gloss and feel.
- filament yarn with a trilobal profile.
- threads with a generally flat profile can also be used.
- Polyhexamethylene adipamide granules with a relative viscosity of 41.5 are melted in a known manner in an extruder and added via a spinneret plate with 52 capillary openings per thread and a cross-sectional area of 0.1 mm 2 per capillary with a capillary length of 1.2 mm and a trilobal capillary cross-section a temperature of the spinneret plate of 276 ° C.
- the throughput through the nozzle plate is set so that the thread has a POY titer of 100 dtex, corresponding to a nominal titer of 78 dtex, which gives a fibril titer of 1.5 dtex.
- the cooled fibril bundle is converged and, at the same time, provided with a spin finish in a known manner, swirled and wound up directly at a spinning speed of 4200 m / min.
- the thread produced has a strength of 33 cN / tex with an elongation at break of 73%. Its relative viscosity is 44; the titer regularity is 0.8 U%. The coefficient of variation in dyeability is 1.02.
- Example 2 differs from Example 1 by the use of a spinneret plate with 68 capillary openings per thread, with a nominal titer of 78 dtex, a fibril titer of 1.14 dtex results.
- the resulting strength is 32 cN / tex with an elongation at break of 72%. RV and regularity of titer are the same.
- Example 3 differs from Example 1 by the use of a spinneret plate with 34 capillary openings per thread, a POY titer of 56 dtex being set. This corresponds to a nominal titer of 44 dtex.
- the fibril titer is 1.29 dtex.
- the resulting strength is 32.7 cN / tex with an elongation at break of 69%.
- the spun thread has a relative viscosity of 40.9.
- the coefficient of variation in dyeability is 0.9.
- the titer regularity achieved is 0.8 U%.
- Fig. 1 shows the cross section of a capillary, where B is the width of a leg and L is the length of the leg of the capillary.
- Fig. 2 shows the cross section of a fibril, where B is the width of a leg and L is the length of the leg of the fibril.
- the filament yarn according to the invention has good textile properties in the fabric and also serves as an original yarn for texturing according to the false twist and Taslan processes, but also for drawing into a plain yarn. It is particularly suitable for use in weaving as warp yarn with its high dyeing requirements.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Artificial Filaments (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Inorganic Fibers (AREA)
Abstract
Description
Die Erfindung betrifft ein trilobales, feinfibrilliges Filamentgarn mit einer Fadenviskosität RV von 40-55 und einer Festigkeit von 30-45 cN/tex, insbesondere als Vorlagegarn zum Texturieren, sowie ein Verfahren zur Herstellung desselben.The invention relates to a trilobal, fine-fibrillated filament yarn with a yarn viscosity RV of 40-55 and a strength of 30-45 cN / tex, in particular as a master yarn for texturing, and a method for producing the same.
Profilierte Polyhexamethylenadipamidgarne sind bekannt (US-A-4801503). Bei dem bekannten Garn handelt es sich um ein glattes Filament mit bandförmigem Fibrillenquerschnitt mit einem Einzeltiter von 2.8 dtex, welches wegen seiner hohen Biegefestigkeit als Spandexersatz zur Herstellung von Strümpfen geeignet ist. Der tiefe Biegemodul wird vor allem auf die besondere Profilierung zurückgeführt. Das bekannte Garn wird als sogenanntes Polyamid LOY-Garn zweistufig hergestellt.Profiled polyhexamethylene adipamide yarns are known (US-A-4801503). The known yarn is a smooth filament with a band-shaped fibril cross-section with a single titer of 2.8 dtex, which is suitable as a spandex substitute for the production of stockings due to its high flexural strength. The deep bending module is mainly attributed to the special profile. The well-known yarn is produced in two stages as a so-called polyamide LOY yarn.
Unter einem Polyamid LOY ist ein Filament zu verstehen, welches bei Spinn-Abzugsgeschwindigkeiten bis etwa 1800 m/min aufgewickelt wird; Polyamid POY ist durch Spinn-Abzugsgeschwindigkeiten zwischen 3700 und 5000 m/min erzeugt.A polyamide LOY is to be understood as a filament which is wound up at spinning take-off speeds of up to approximately 1800 m / min; Polyamide POY is produced by spinning take-off speeds between 3700 and 5000 m / min.
Aus der JP-A-58081609 sind trilobale ultrafeine Garne aus Polyester mit einem Einzeltiter < 1.5 dpf bekannt. Die bekannten Garne weisen extrem hohe Schmelzeviskositäten auf, dienen zur Herstellung von beispielsweise künstlichem Leder. Die Herstellung erfolgt bei Spinngeschwindigkeiten grösser gleich 2500 m/min. Sie sind für den textilen Einsatz in der Weberei ungeeignet.JP-A-58081609 discloses trilobal ultra-fine yarns made of polyester with a single titer <1.5 dpf. The known yarns have extremely high melt viscosities and are used to produce artificial leather, for example. Production takes place at spinning speeds greater than or equal to 2500 m / min. They are unsuitable for textile use in weaving.
Ein Nachteil von Polyamid LOY für den geplanten Einsatz des vorliegenden Garns ist vor allem in den niedrigen Spinngeschwindigkeiten zu sehen, welche eine wirtschaftliche Herstellung nicht gewährleistet. Ein weiterer Nachteil ist die schlechtere Weiterverarbeitung (Fadenbrüche) von Polyamid LOY bei hohen Geschwindigkeiten.A disadvantage of polyamide LOY for the planned use of the present yarn can be seen above all in the low spinning speeds, which do not guarantee economical production. Another disadvantage is the poorer processing (thread breaks) of polyamide LOY at high speeds.
Es ist auch bekannt, dass es bisher nicht gelungen ist, feinere, profilierte Filamente, mit ausreichender Anfärbehomogenität im textilen Flächengebilde mit annehmbarer Titerregelmässigkeit ( U%) herzustellen. Die Herstellung von profilierten Filamenten im Titerbereich von glatten Strumpfgarnen mit Feinheiten von dtex 22 f 8, d. h. einem Einzeltiter von etwa dtex 2.8 bereitet keine Schwierigkeiten .It is also known that so far it has not been possible to produce finer, profiled filaments with sufficient dye homogeneity in the textile fabric with an acceptable titer regularity (U%). The production of profiled filaments in the titer range of smooth hosiery yarns with finenesses of dtex 22 f 8, d. H. a single titer of around dtex 2.8 is no problem.
Hingegen bietet die Herstellung eines feinfibrilligen profilierten Vorlagegarnes aus Polyhexamethylenadipamid (Nylon 66) POY erhebliche Schwierigkeiten. Das mag daran liegen, dass ein runder Fibrillenquerschnitt energetisch einen Idealzustand darstellt, von welchem man sich beim Profilspinnen erheblich entfernt. Mit steigender Feinfibrilligkeit wird beim Schmelzspinnen der Fadenbildungsprozess instabiler. Dies äussert sich vor allem darin, dass die Titerregelmässigkeit stark abnimmt und am fertigen Flächengebilde eine ungleichmässige Anfärbbarkeit resultiert. Diese Nachteile treten verstärkt beim Schmelzspinnen von Polyamid-POY auf.On the other hand, the production of a fine-fibrillated profiled yarn from polyhexamethylene adipamide (nylon 66) POY presents considerable difficulties. This may be due to the fact that a round cross section of the fibril represents an ideal energy condition, from which one considerably moves away during profile spinning. With increasing fine fibrillation, the thread formation process becomes more unstable during melt spinning. This manifests itself above all in the fact that the titer regularity decreases sharply and that the finished fabric results in an uneven dyeability. These disadvantages are more common in melt spinning polyamide POY.
Die Fadenviskosität wird in bekannter Weise als relative Viskosität (RV) in Ameisensäure gemessen.The thread viscosity is measured in a known manner as relative viscosity (RV) in formic acid.
Zur Bestimmung der Farbgleichmässigkeit wird aus mehreren beliebigen Spinnwickeln eines Lots ein Strumpfabschnitt gestrickt. Der Strumpfabschnitt wird in einem Bad mit dem Farbstoff Alizarinlichtblau 4GL der Firma Sandoz AG, Basel in bekannter Weise angefärbt und nach dem Trocknen kolorimetrisch auf die unterschiedlichen Remissionen (Helligkeiten) der von den verschiedenen Spinnwickeln stammenden Abschnitte gemessen. Von den Remissionen wird in bekannter Weise der Variationskoeffizient berechnet.To determine the color uniformity, a stocking section is knitted from any number of spinning reels of a solder. The stocking section is in a bath with the dye Alizarin light blue 4GL from Sandoz AG, Basel stained in a known manner and, after drying, measured colorimetrically for the different remissions (brightnesses) of the sections originating from the different spinning reels. The coefficient of variation of the remissions is calculated in a known manner.
Aufgabe der Erfindung ist es, ein feines profiliertes Vorlagegarn zum Texturieren oder Nachverstrecken zur Verfügung zu stellen, welches vor allem in der Weberei für Kettfäden geeignet ist und die färberischen Nachteile der bekannten Profilfäden nicht aufweist.The object of the invention is to provide a fine profiled original yarn for texturing or post-stretching, which is particularly suitable for warp threads in the weaving mill and does not have the dyeing disadvantages of the known profile threads.
Eine weitere Aufgabe ist es, ein Filamentgarn zur Verfügung zu stellen, das im fertigen textilen Flächengebilde keinen als "speckig" bekannten Glanz, einen verbesserten sehr weichen Griff aufweist.Another object is to provide a filament yarn which in the finished textile fabric does not have a gloss known as "greasy" and has an improved, very soft feel.
Die Aufgabe wird mit einem Profilfaden erfindungsgemäss gelöst, durch einen Einzelfibrillentiter < 1,5 dtex, einer hohen Farbgleichmässigkeit (Variationskoeffizient) von < 2 und ein Breiten/Längenverhältnis B/L des Fibrillenquerschnitts von 0,5 bis 0,7.The object is achieved according to the invention with a profile thread, by means of a single fibril titer <1.5 dtex, a high color uniformity (coefficient of variation) of <2 and a width / length ratio B / L of the fibril cross section of 0.5 to 0.7.
Ein Profilfaden, mit einem Einzelfibrillentiter von < 1,5 dtex, zeigt in überraschender Weise keine sichtbaren Unregelmässigkeiten wie beispielsweise Streifigkeit im gefärbten Flächengebilde. Es ist erstmals gelungen, einen so feinen Fibrillentiter, mit einem POY-Ausgangsmaterial herzustellen, der eine Farbgleichmässigkeit mit einem Variationskoeffizienten von < 2 und einer Titerregelmässigkeit von Uster% < 1 aufweist. Auch das Breiten-/Längenverhältnis des Filamentquerschnitts von 0,5 bis 0,7, insbesondere um 0,6, ist für die textilen Anforderungen bezüglich Glanz und Griff besonders geeignet. Zur zahlenmässigen Erfassung der Profilausprägung dient das Verhältnis aus Breite und Länge B/L, bei trilobalen Fäden gemessen vom Beginn des Schenkels.A profile thread, with a single fibril titer of <1.5 dtex, surprisingly shows no visible irregularities, such as streakiness in the colored fabric. It was possible for the first time to produce such a fine fibril titer with a POY starting material that has a color uniformity with a coefficient of variation of <2 and a titer regularity of Uster% <1. The width / length ratio of the filament cross section from 0.5 to 0.7, in particular around 0.6, is also particularly suitable for the textile requirements with regard to gloss and feel. The ratio of width and Length B / L, measured from the beginning of the leg for trilobal threads.
Es ist besonders zweckmässig das Filamentgarn mit einem trilobalen Profil zu versehen. Im Einsatzgebiet Texturierung/Strumpf können aber auch Fäden mit einem allgemein flachen Profil verwendet werden.It is particularly useful to provide the filament yarn with a trilobal profile. In the field of texturing / stocking, threads with a generally flat profile can also be used.
Bei der Herstellung des profilierten Polyamid-Filamentgarns mit einer Festigkeit von 30-45 cN/tex, wird mit Spritzgeschwindigkeiten von 8-14 m/min, insbesondere von 8,5-10 m/min, bevorzugt 12m/min, gearbeitet. Sie tragen wesentlich zu einer verbesserten Garnsauberkeit bei.In the production of the profiled polyamide filament yarn with a strength of 30-45 cN / tex, spray speeds of 8-14 m / min, in particular 8.5-10 m / min, preferably 12m / min, are used. They contribute significantly to improved yarn cleanliness.
Die Erfindung soll anhand von Beispielen näher erläutert werden.The invention will be explained in more detail by means of examples.
Polyhexamethylenadipamid-Granulat mit einer relativen Viskosität von 41,5 wird in bekannter Weise in einem Extruder aufgeschmolzen und über eine Spinndüsenplatte mit 52 Kapillaröffnungen pro Faden und einer Querschnittsfläche von 0,1mm2 pro Kapillare bei einer Kapillarlänge von 1,2mm und einem trilobalem Kapillarquerschnitt bei einer Temperatur der Spinndüsenplatte von 276°C versponnen. Der Durchsatz durch die Düsenplatte ist so eingestellt, dass der Faden einen POY-Titer von 100 dtex, entsprechend einem Nominaltiter von 78 dtex aufweist, was einen Fibrillentiter von 1,5 dtex ergibt. Das abgekühlte Fibrillenbündel wird konvergiert und gleichzeitig in bekannter Weise mit einer Spinnpräparation versehen, verwirbelt und mit einer Spinngeschwindigkeit von 4200 m/min direkt aufgespult.Polyhexamethylene adipamide granules with a relative viscosity of 41.5 are melted in a known manner in an extruder and added via a spinneret plate with 52 capillary openings per thread and a cross-sectional area of 0.1 mm 2 per capillary with a capillary length of 1.2 mm and a trilobal capillary cross-section a temperature of the spinneret plate of 276 ° C. The throughput through the nozzle plate is set so that the thread has a POY titer of 100 dtex, corresponding to a nominal titer of 78 dtex, which gives a fibril titer of 1.5 dtex. The cooled fibril bundle is converged and, at the same time, provided with a spin finish in a known manner, swirled and wound up directly at a spinning speed of 4200 m / min.
Der hergestellte Faden weist eine Festigkeit von 33 cN/tex bei einer Bruchdehnung von 73% auf. Seine relative Viskosität beträgt 44; die Titerregelmässigkeit liegt bei 0,8 U%. Der Variationskoeffizient der Anfärbbarkeit liegt bei 1,02.The thread produced has a strength of 33 cN / tex with an elongation at break of 73%. Its relative viscosity is 44; the titer regularity is 0.8 U%. The coefficient of variation in dyeability is 1.02.
Beispiel 2 unterscheidet sich von Beispiel 1 durch die Verwendung einer Spinndüsenplatte mit 68 Kapillaröffnungen pro Faden, bei einem Nominaltiter von 78 dtex ergibt sich ein Fibrillentiter von 1,14 dtex. Die resultierende Festigkeit beträgt 32 cN/tex bei einer Bruchdehnung von 72%. RV und Titerregelmässsigkeit sind gleich.Example 2 differs from Example 1 by the use of a spinneret plate with 68 capillary openings per thread, with a nominal titer of 78 dtex, a fibril titer of 1.14 dtex results. The resulting strength is 32 cN / tex with an elongation at break of 72%. RV and regularity of titer are the same.
Beispiel 3 unterscheidet sich von Beispiel 1 durch die Verwendung einer Spinndüsenplatte mit 34 Kapillaröffnungen pro Faden, wobei ein POY-Titer von 56 dtex eingestellt ist. Dies entspricht einem Nominaltiter von 44 dtex. Es ergibt sich ein Fibrillentiter von 1,29 dtex. Die resultierende Festigkeit beträgt 32,7 cN/tex bei einer Bruchdehnung von 69%. Der gesponnene Faden hat eine relative Viskosität von 40,9. Der Variationskoeffizient der Anfärbbarkeit liegt bei 0,9. Die erreichte Titerregelmässsigkeit ist 0,8 U%.Example 3 differs from Example 1 by the use of a spinneret plate with 34 capillary openings per thread, a POY titer of 56 dtex being set. This corresponds to a nominal titer of 44 dtex. The fibril titer is 1.29 dtex. The resulting strength is 32.7 cN / tex with an elongation at break of 69%. The spun thread has a relative viscosity of 40.9. The coefficient of variation in dyeability is 0.9. The titer regularity achieved is 0.8 U%.
Zur Erläuterung der Kapillar- und Filamentform die Zeichnung dienen. Es zeigen
- Fig.1
- die Kapillarform
- Fig.2
- die Fibrillenform
- Fig. 1
- the capillary shape
- Fig. 2
- the fibril shape
Fig. 1 zeigt den Querschnitt einer Kapillare, wobei B die Breite eines Schenkels und L die Länge des Schenkels der Kapillare bedeuten.Fig. 1 shows the cross section of a capillary, where B is the width of a leg and L is the length of the leg of the capillary.
Fig. 2 zeigt den Querschnitt einer Fibrille, wobei B die Breite eines Schenkels und L die Länge des Schenkels der Fibrille bedeuten.Fig. 2 shows the cross section of a fibril, where B is the width of a leg and L is the length of the leg of the fibril.
Das erfindungsgemässe Filamentgarn, dtex 100(78) f 52, weist im Flächengebilde gute textile Eigenschaften auf und dient auch als Vorlagegarn zum Texturieren nach dem Falschzwirn- und dem Taslanverfahren, aber auch zum Verstrecken zu einem Glattgarn. Es ist besonders zum Einsatz in der Weberei als Kettgarn mit seinen hohen färberischen Anforderungen geeignet.The filament yarn according to the invention, dtex 100 (78) f 52, has good textile properties in the fabric and also serves as an original yarn for texturing according to the false twist and Taslan processes, but also for drawing into a plain yarn. It is particularly suitable for use in weaving as warp yarn with its high dyeing requirements.
Claims (2)
- Trilobal low-dpf filament yarn composed of a polyamide POY having a thread viscosity RV of 40 to 55 and a tenacity of 30-45 cN/tex, especially for use as texturizing feed yarn, characterized by an individual filament linear density < 1.5 dtex, based on the nominal linear density, a colour uniformity having a coefficient of variation of < 2 and a width/length ratio B/L of the filament cross-section of 0.5 to 0.7.
- Process for producing a trilobal low-dpf polyamide filament yarn having a tenacity of 30-45 cN/tex, characterized in that the polyamide melt is extruded at an ejection rate of 8-14 m/min through a die having a capillary area of 0.05 to 0.1 mm2 and the solidified filaments are wound up at between 3700 and 5000 m/min.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH2109/92 | 1992-07-03 | ||
CH210992 | 1992-07-03 | ||
CH210992 | 1992-07-03 | ||
PCT/CH1993/000168 WO1994001603A1 (en) | 1992-07-03 | 1993-07-01 | Shaped-section fine-fibre filament yarn and method of producing it |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0602201A1 EP0602201A1 (en) | 1994-06-22 |
EP0602201B1 true EP0602201B1 (en) | 1997-10-15 |
EP0602201B2 EP0602201B2 (en) | 2004-01-28 |
Family
ID=4226085
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP93912537A Expired - Lifetime EP0602201B2 (en) | 1992-07-03 | 1993-07-01 | Shaped-section fine-fibre filament yarn and method of producing it |
Country Status (9)
Country | Link |
---|---|
US (1) | US5432002A (en) |
EP (1) | EP0602201B2 (en) |
AT (1) | ATE159303T1 (en) |
BR (1) | BR9305568A (en) |
CA (1) | CA2116779C (en) |
DE (1) | DE59307545D1 (en) |
DK (1) | DK0602201T4 (en) |
ES (1) | ES2110095T5 (en) |
WO (1) | WO1994001603A1 (en) |
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CN102069676B (en) * | 2009-11-20 | 2012-07-18 | 江苏华佳丝绸有限公司 | Production method of silkworm planar silk painting material |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5486417A (en) * | 1993-09-28 | 1996-01-23 | Basf Corporation | Mixed cross-section carpet yarn |
US5558826A (en) * | 1995-02-07 | 1996-09-24 | E. I. Du Pont De Nemours And Company | High speed process for making fully-oriented nylon yarns |
US7165963B2 (en) | 2003-10-31 | 2007-01-23 | Invista North America S.A.R.L. | Spinneret for producing circular cross section yarn and process for making the same |
CN104928773A (en) * | 2015-07-08 | 2015-09-23 | 福建凯邦锦纶科技有限公司 | Nylon 6 deeply-dyed drawn yarn and production technology thereof |
CN111041651B (en) * | 2019-12-29 | 2021-08-13 | 江苏恒力化纤股份有限公司 | Preparation method of bandage cloth |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2939201A (en) † | 1959-06-24 | 1960-06-07 | Du Pont | Trilobal textile filament |
US3508390A (en) * | 1968-09-30 | 1970-04-28 | Allied Chem | Modified filament and fabrics produced therefrom |
AR204352A1 (en) † | 1974-04-03 | 1975-12-22 | Du Pont | POLYHEXAMETHYLENADIPAMIDE THREAD WITHOUT STRETCHING VAPORIZED AND PROCEDURE FOR OBTAINING IT |
DE3036683C2 (en) * | 1980-09-29 | 1985-01-24 | Davy McKee AG, 6000 Frankfurt | Process for melt spinning synthetic polymers |
JPS5881609A (en) † | 1981-11-04 | 1983-05-17 | Nippon Ester Co Ltd | Melt spinning method of ultrafine modified cross section yarn |
US4801530A (en) * | 1984-02-29 | 1989-01-31 | Rockefeller University | Nucleotide hybridization assay for protozoan parasites |
US5223197A (en) * | 1986-01-30 | 1993-06-29 | E. I. Du Pont De Nemours And Company | Process of making mixed filament yarn |
DD293379A5 (en) † | 1990-03-29 | 1991-08-29 | Veb Chemiefaserkombinat Schwarza "Wilhelm Pieck",De | METHOD FOR PRODUCING OVERALL OR FULLY ORIENTED PROFILED POLYAMIDE FAEDES |
TW200534B (en) † | 1990-06-21 | 1993-02-21 | Du Pont | |
US5208106A (en) * | 1991-08-27 | 1993-05-04 | E. I. Du Pont De Nemours And Company | Trilobal and tetralobal filaments exhibiting low glitter and high bulk |
FR2691985B1 (en) † | 1992-06-05 | 1996-03-29 | Rhone Poulenc Fibres | MULTILOBE YARNS AND PROCESS FOR OBTAINING SAME. |
-
1993
- 1993-07-01 AT AT93912537T patent/ATE159303T1/en not_active IP Right Cessation
- 1993-07-01 DE DE59307545T patent/DE59307545D1/en not_active Expired - Fee Related
- 1993-07-01 CA CA002116779A patent/CA2116779C/en not_active Expired - Fee Related
- 1993-07-01 WO PCT/CH1993/000168 patent/WO1994001603A1/en active IP Right Grant
- 1993-07-01 DK DK93912537T patent/DK0602201T4/en active
- 1993-07-01 ES ES93912537T patent/ES2110095T5/en not_active Expired - Lifetime
- 1993-07-01 BR BR9305568A patent/BR9305568A/en not_active IP Right Cessation
- 1993-07-01 EP EP93912537A patent/EP0602201B2/en not_active Expired - Lifetime
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1994
- 1994-02-28 US US08/204,148 patent/US5432002A/en not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102069676B (en) * | 2009-11-20 | 2012-07-18 | 江苏华佳丝绸有限公司 | Production method of silkworm planar silk painting material |
Also Published As
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ES2110095T3 (en) | 1998-02-01 |
DK0602201T4 (en) | 2004-04-05 |
DK0602201T3 (en) | 1998-06-02 |
DE59307545D1 (en) | 1997-11-20 |
EP0602201A1 (en) | 1994-06-22 |
BR9305568A (en) | 1995-12-26 |
CA2116779A1 (en) | 1994-01-20 |
US5432002A (en) | 1995-07-11 |
WO1994001603A1 (en) | 1994-01-20 |
ATE159303T1 (en) | 1997-11-15 |
EP0602201B2 (en) | 2004-01-28 |
CA2116779C (en) | 2003-06-17 |
ES2110095T5 (en) | 2004-07-16 |
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