EP0602201B2 - Shaped-section fine-fibre filament yarn and method of producing it - Google Patents
Shaped-section fine-fibre filament yarn and method of producing it Download PDFInfo
- Publication number
- EP0602201B2 EP0602201B2 EP93912537A EP93912537A EP0602201B2 EP 0602201 B2 EP0602201 B2 EP 0602201B2 EP 93912537 A EP93912537 A EP 93912537A EP 93912537 A EP93912537 A EP 93912537A EP 0602201 B2 EP0602201 B2 EP 0602201B2
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- European Patent Office
- Prior art keywords
- yarn
- titer
- dtex
- polyamide
- filament yarn
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Classifications
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/60—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/098—Melt spinning methods with simultaneous stretching
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/253—Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2967—Synthetic resin or polymer
- Y10T428/2969—Polyamide, polyimide or polyester
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2973—Particular cross section
Definitions
- the invention relates to a trilobal, fine fibrillated filament yarn with a thread viscosity RV of 40-55 and a strength of 30-45 cN / tex, especially as a master yarn for texturing, as well as a method for manufacturing thereof.
- Profiled polyhexamethylene adipamide games are known (US-A-4801503).
- Gam is a smooth filament with ribbon-shaped Fibril cross-section with a one-time titer of 2.8 dtex, which because of its high flexural strength as Spandex replacement suitable for the production of stockings is.
- the deep bending module is mainly due to the special Profiling traced.
- the well-known gam becomes a so-called polyamide LOY-Gam in two stages manufactured.
- a polyamide LOY is a filament which at spinning take-off speeds is wound up to about 1800 m / min; Polyamide POY is between by spinning take-off speeds 3700 and 5000 m / min generated.
- JP-A-58081609 are trilobal ultrafine Game made of polyester with a single titer ⁇ 1.5 dpf known.
- the known yarns are extremely high Melt viscosities serve for the production of for example artificial leather.
- the production takes place at spinning speeds greater than or equal to 2500 m / min. They are for textile use in weaving not suitable.
- a disadvantage of polyamide LOY for the planned one Use of the present chamois is mainly in the low spinning speeds to see which one economic production not guaranteed.
- Another disadvantage is the poorer processing (Thread breaks) of polyamide LOY at high speeds.
- a method is known from WO 91/19839 for the production of a trilobal polyamide filament yarn known.
- the yarn is made from a polyamide 6.6 made with a RV ron ⁇ 50.
- the obtained thread has a titer of 55/17 on.
- the thread viscosity is known in a known manner as relative Viscosity (RV) measured in formic acid.
- the object of the invention is a fine profiled Original yarn for texturing or post-stretching To make available, especially in the weaving mill is suitable for warp threads and the dyeing disadvantages does not have the known profile threads.
- Another task is to use a filament yarn To provide that in the finished textile fabric no gloss known as "greasy", one has an improved very soft feel.
- the object is achieved according to the invention with a profile thread solved by a single fibril titer ⁇ 1.5 dtex, high color uniformity (coefficient of variation) of ⁇ 2 and a width / length ratio B / L of the fibril cross section from 0.5 to 0.7.
- a profile thread with a single fibril titer of ⁇ 1.5 dtex surprisingly shows no visible bears Irregularities such as streakiness in the colored fabric.
- a fine fibril titer with a POY starting material produce a color uniformity with a coefficient of variation of ⁇ 2 and a titer regularity of Uster% ⁇ 1.
- the width / length ratio of the filament cross section of 0.5 up to 0.7, especially around 0.6, is for the textile requirements particularly suitable in terms of gloss and grip.
- For numerical recording of the profile characteristics serves the ratio of width and length B / L, at trilobal threads measured from the beginning of the leg.
- Filament yarn is particularly useful to be provided with a trilobal profile.
- Texturing / stocking can also be made with threads generally flat profile can be used.
- Polyhexamethylene adipamide granules with a relative viscosity of 41.5 are melted in a known manner in an extruder and added via a spinneret plate with 52 capillary openings per thread and a cross-sectional area of 0.1 mm 2 per capillary with a capillary length of 1.2 mm and a trilobal capillary cross-section clamp a temperature of the spinneret plate of 276 ° C.
- the throughput through the nozzle plate is set so that the thread has a POY titer of 100 dtex, corresponding to a nominal titer of 78 dtex, which gives a fibril titer of 1.5 dtex.
- the cooled fibril bundle is converged and at the same time provided with a spin finish in a known manner, swirled and wound up directly at a spinning speed of 4200 m / min.
- the thread produced has a strength of 33 cN / tex with an elongation at break of 73%. Its relative Viscosity is 44; the titer regularity is 0.8 U%. The coefficient of variation of dyeability is 1.02.
- Example 1 differs from Example A by the use of a spinneret plate with 68 capillary openings per thread, with a nominal titer of 78 dtex, the fibril titer is 1.14 dtex.
- the resulting one Strength is 32 cN / tex with an elongation at break of 72%. RV and titer regularity are equal.
- Example 2 differs from Example A by the use of a spinneret plate with 34 capillary openings per thread, with a POY titer of 56 dtex is set. This corresponds to a nominal titer of 44 dtex.
- the fibril titer is 1.29 dtex.
- the resulting strength is 32.7 cN / tex at one Elongation at break of 69%.
- the spun thread has one relative viscosity of 40.9.
- the coefficient of variation the dyeability is 0.9.
- the titer regularity achieved is 0.8 U%.
- Fig. 1 shows the cross section of a capillary, wherein B the width of a leg and L the length of the Mean leg of the capillary.
- Fig. 2 shows the cross section of a fibril, wherein B the width of a leg and L the length of the leg the fibril mean.
- the filament yarn according to the invention has good textile properties in the fabric and also serves as a template game for texturing after the false swimming and the Taslan procedure, but also for stretching to a plain yarn. It is particularly suitable for use in weaving as a warp yarn with its high dyeing requirements.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Artificial Filaments (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Inorganic Fibers (AREA)
Abstract
Description
Die Erfindung betrifft ein trilobales, feinfibrilliges Filamentgarn mit einer Fadenviskosität RV von 40-55 und einer Festigkeit von 30-45 cN/tex, insbesondere als Vorlagegarn zum Texturieren, sowie ein Verfahren zur Herstellung desselben.The invention relates to a trilobal, fine fibrillated filament yarn with a thread viscosity RV of 40-55 and a strength of 30-45 cN / tex, especially as a master yarn for texturing, as well as a method for manufacturing thereof.
Profilierte Polyhexamethylenadipamidgame sind bekannt (US-A-4801503). Bei dem bekannten Gam handelt es sich um ein glattes Filament mit bandförmigem Fibrillenquerschnitt mit einem Einzeititer von 2.8 dtex, welches wegen seiner hohen Biegefestigkeit als Spandexersatz zur Herstellung von Strümpfen geeignet ist. Der tiefe Biegemodul wird vor allem auf die besondere Profilierung zurückgeführt. Das bekannte Gam wird als sogenanntes Polyamid LOY-Gam zweistufig hergestellt.Profiled polyhexamethylene adipamide games are known (US-A-4801503). With the well-known Gam it is a smooth filament with ribbon-shaped Fibril cross-section with a one-time titer of 2.8 dtex, which because of its high flexural strength as Spandex replacement suitable for the production of stockings is. The deep bending module is mainly due to the special Profiling traced. The well-known gam becomes a so-called polyamide LOY-Gam in two stages manufactured.
Unter einem Polyamid LOY ist ein Filament zu verstehen, welches bei Spinn-Abzugsgeschwindigkeiten bis etwa 1800 m/min aufgewickelt wird; Polyamid POY ist durch Spinn-Abzugsgeschwindigkeiten zwischen 3700 und 5000 m/min erzeugt.A polyamide LOY is a filament which at spinning take-off speeds is wound up to about 1800 m / min; Polyamide POY is between by spinning take-off speeds 3700 and 5000 m / min generated.
Aus der JP-A-58081609 sind trilobale ultrafeine Game aus Polyester mit einem Einzeltiter < 1.5 dpf bekannt. Die bekannten Garne weisen extrem hohe Schmelzeviskositäten auf, dienen zur Herstellung von beispielsweise künstlichem Leder. Die Herstellung erfolgt bei Spinngeschwindigkeiten grösser gleich 2500 m/min. Sie sind für den textilen Einsatz in der Weberei ungeeignet.JP-A-58081609 are trilobal ultrafine Game made of polyester with a single titer <1.5 dpf known. The known yarns are extremely high Melt viscosities serve for the production of for example artificial leather. The production takes place at spinning speeds greater than or equal to 2500 m / min. They are for textile use in weaving not suitable.
Ein Nachteil von Polyamid LOY für den geplanten Einsatz des vorliegenden Gams ist vor allem in den niedrigen Spinngeschwindigkeiten zu sehen, welche eine wirtschaftliche Herstellung nicht gewährleistet. Ein weiterer Nachteil ist die schlechtere Weiterverarbeitung (Fadenbrüche) von Polyamid LOY bei hohen Geschwindigkeiten.A disadvantage of polyamide LOY for the planned one Use of the present chamois is mainly in the low spinning speeds to see which one economic production not guaranteed. On Another disadvantage is the poorer processing (Thread breaks) of polyamide LOY at high speeds.
Aus der WO 91/19839 ist ein Verfahren zur Herstellung eines trilobalen Polyamidfilamentgarn bekannt.A method is known from WO 91/19839 for the production of a trilobal polyamide filament yarn known.
Nach Beispiel 6 (S69), wird der Faden mit einer Aufspulgeschwindigkeit von 3909 mpm aufgewickelt.According to example 6 (S69), the thread with a winding speed wound up from 3909 mpm.
Das Garn wird aus einem Polyamid 6.6 mit einer RV ron ∼50 hergestellt. Der erhaltene Faden weist einen Titer von 55/17 den auf.The yarn is made from a polyamide 6.6 made with a RV ron ∼50. The obtained thread has a titer of 55/17 on.
Es ist auch bekannt, dass es bisher nicht gelungen ist, feinere, profilierte Filamente, mit ausreichender Anfärbehomogenität im textilen Flächengebilde mit annehmbarer Titerregelmässigkeit (U%) herzustellen. Die Herstellung von profilierten Filamenten im Titerbereich von glatten Strumpfgamen mit Feinheiten von dtex 22 f 8, d. h. einem Einzeltiter von etwa dtex 2.8 bereitet keine Schwierigkeiten.It is also known that so far it has not been successful is, finer, profiled filaments, with sufficient coloring homogeneity in the textile fabric with acceptable Establish titer regularity (U%). The Production of profiled filaments in the titer range of smooth hosiery with subtleties of dtex 22 f 8, d. H. a single titer of about dtex 2.8 does not Trouble.
Hingegen bietet die Herstellung eines feinfibrilligen profilierten Vorlagegarnes aus Polyhexametliylenadipamid (Nylon 66) POY erhebliche Schwierigkeiten. Das mag daran liegen, dass ein runder Fibrillenquersehnitt energetisch einen Idealzustand darstellt, von welchem man sich beim Profifspinnen erheblich entfemt. Mit steigender Feinfibrilfigkeit wird beim Schmelzspinnen der Fadenbildungsprozess instabiler. Dies äussert sich vor allem darin, dass die Trterregelmässigkeit stark abnimmt und am fertigen Flächengebilde eine ungleichmässige Anfärbbarkeit resultiert. Diese Nachteile treten verstärkt beim Schmelzspinnen von Polyamid-POY auf.In contrast, the production of a fine fibrillated profiled master yarn made of polyhexamethylene adipamide (Nylon 66) POY considerable difficulty. The may be due to the fact that a round cross section of the fibril energetically represents an ideal state of which one strays away considerably in professional spinning. With increasing Fine fibrility is the result of melt spinning Thread formation process more unstable. This manifests itself all in the fact that the regularity of the treadle decreases strongly and an uneven one on the finished fabric Dyeability results. These disadvantages occur reinforced when melt spinning polyamide POY.
Die Fadenviskosität wird in bekannter Weise als relative Viskosität (RV).in Ameisensäure gemessen.The thread viscosity is known in a known manner as relative Viscosity (RV) measured in formic acid.
Zur Bestimmung der Farbgleichmässigkeit wird aus mehreren beliebigen Spinnwickeln eines Lots ein Strumpfabschnitt gestrickt. Der Strumpfabschnitt wird in einem Bad mit dem Farbstoff Alizarinlichtblau 4GL der Firma Sandoz AG, Basel in bekannter Weise angefärbt und nach dem Trocknen kolorimetrisch auf die unterschiedlichen Remissionen (Helligkeiten) der von den verschiedenen Spinnwickeln stammenden Abschnitte gemessen. Von den Remissionen wird in bekannter Weise der Variationskoeffizient berechnet.To determine the color uniformity, several arbitrary spinning reels of a solder Stocking section knitted. The stocking section is in a bath with the 4GL alizarin light blue dye Sandoz AG, Basel stained in a known manner and after drying colorimetrically on the different Remissions (brightness) of the different sections originating from spinning reels measured. Of the remissions is known in Way the coefficient of variation is calculated.
Aufgabe der Erfindung ist es, ein feines profiliertes Vorlagegarn zum Texturieren oder Nachverstrecken zur Verfügung zu stellen, welches vor allem in der Weberei für Kettfäden geeignet ist und die färberischen Nachteile der bekannten Profilfäden nicht aufweist.The object of the invention is a fine profiled Original yarn for texturing or post-stretching To make available, especially in the weaving mill is suitable for warp threads and the dyeing disadvantages does not have the known profile threads.
Eine weitere Aufgabe ist es, ein Filamentgarn zur Verfügung zu stellen, das im fertigen textilen Flächengebilde keinen als "speckig" bekannten Glanz, einen verbesserten sehr weichen Griff aufweist.Another task is to use a filament yarn To provide that in the finished textile fabric no gloss known as "greasy", one has an improved very soft feel.
Die Aufgabe wird mit einem Profilfaden erfindungsgemäss gelöst, durch einen Einzelfibrillentiter < 1,5 dtex, einer hohen Farbgleichmässigkeit (Variationskoeffizient) von < 2 und ein Breiten/Längenverhältnis B/L des Fibrillenquerschnitts von 0,5 bis 0,7.The object is achieved according to the invention with a profile thread solved by a single fibril titer <1.5 dtex, high color uniformity (coefficient of variation) of <2 and a width / length ratio B / L of the fibril cross section from 0.5 to 0.7.
Ein Profilfaden, mit einem Einzelfibrillentiter von < 1,5 dtex, zeigt in überraschender Weise keine sichtbären Unregefmässigkeiten wie beispielsweise Streifigkeit im gefärbten Flächengebilde. Es ist erstmals gelungen, einen so feinen Fibrillentiter, mit einem POY-Ausgangsmaterial herzustellen, der eine Farbgleichmässigkeit mit einem Variationskoeffizienten von < 2 und einer Titerregelmässigkeit von Uster% < 1 aufweist. Auch das Breiten-/Längenverhältnis des Filamentquerschnitts von 0,5 bis 0,7, insbesondere um 0,6, ist für die textilen Anforderungen bezüglich Glanz und Griff besonders geeignet. Zur zahlenmässigen Erfassung der Profilausprägung dient das Verhältnis aus Breite und Länge B/L, bei trilobalen Fäden gemessen vom Beginn des Schenkels.A profile thread with a single fibril titer of < 1.5 dtex, surprisingly shows no visible bears Irregularities such as streakiness in the colored fabric. For the first time such a fine fibril titer, with a POY starting material produce a color uniformity with a coefficient of variation of <2 and a titer regularity of Uster% <1. Also the width / length ratio of the filament cross section of 0.5 up to 0.7, especially around 0.6, is for the textile requirements particularly suitable in terms of gloss and grip. For numerical recording of the profile characteristics serves the ratio of width and length B / L, at trilobal threads measured from the beginning of the leg.
Es ist besonders zweckmässig das Filamentgarn mit einem trilobalen Profil zu versehen. Im Einsatzgebiet Texturierung/Strumpf können aber auch Fäden mit einem allgemein flachen Profil verwendet werden.Filament yarn is particularly useful to be provided with a trilobal profile. In the field of application Texturing / stocking can also be made with threads generally flat profile can be used.
Bei der Herstellung des profilierten Polyamid-Filamentgarns mit einer Festigkeit von 30-45 cN/tex, wird mit Spritzgeschwindigkeiten von 8-14 m/min, insbesondere von 8,5-10 m/min, bevorzugt 12m/min, gearbeitet. Sie tragen wesentlich zu einer verbesserten Gamsauberkeit bei.In the production of the profiled polyamide filament yarn with a strength of 30-45 cN / tex with spray speeds of 8-14 m / min, in particular of 8.5-10 m / min, preferably 12m / min. They contribute significantly to an improved chamois cleanliness at.
Die Erfindung soll anhand von Beispielen näher erläutert werden.The invention will be explained in more detail by means of examples become.
Polyhexamethylenadipamid-Granulat mit einer relativen Viskosität von 41,5 wird in bekannter Weise in einem Extruder aufgeschmolzen und über eine Spinndüsenplatte mit 52 Kapillaröffnungen pro Faden und einer Querschnittsfläche von 0,1mm2 pro Kapillare bei einer Kapillarlänge von 1,2mm und einem trilobalem Kapillarquerschnitt bei einer Temperatur der Spinndüsenplatte von 276°C verspannen. Der Durchsatz durch die Düsenplatte ist so eingestellt, dass der Faden einen POY-Titer von 100 dtex, entsprechend einem Nominaltiter von 78 dtex aufweist, was einen Fibrillentiter von 1,5 dtex ergibt. Das abgekühlte Fibrillenbündel wird konvergiert und gleichzeitig in bekannter Weise mit einer Spinnpräparation versehen, verwirbelt und mit einer Spinngeschwindigkeit von 4200 m/min direkt aufgespult.Polyhexamethylene adipamide granules with a relative viscosity of 41.5 are melted in a known manner in an extruder and added via a spinneret plate with 52 capillary openings per thread and a cross-sectional area of 0.1 mm 2 per capillary with a capillary length of 1.2 mm and a trilobal capillary cross-section clamp a temperature of the spinneret plate of 276 ° C. The throughput through the nozzle plate is set so that the thread has a POY titer of 100 dtex, corresponding to a nominal titer of 78 dtex, which gives a fibril titer of 1.5 dtex. The cooled fibril bundle is converged and at the same time provided with a spin finish in a known manner, swirled and wound up directly at a spinning speed of 4200 m / min.
Der hergestellte Faden weist eine Festigkeit von 33 cN/tex bei einer Bruchdehnung von 73% auf. Seine relative Viskosität beträgt 44; die Titerregelmässigkeit liegt bei 0,8 U%. Der Variationskoeffizient der Anfärbbarkeit liegt bei 1,02.The thread produced has a strength of 33 cN / tex with an elongation at break of 73%. Its relative Viscosity is 44; the titer regularity is 0.8 U%. The coefficient of variation of dyeability is 1.02.
Beispiel 1 unterscheidet sich von Beispiel A durch die Verwendung einer Spinndüsenplatte mit 68 Kapillaröffnungen pro Faden, bei einem Nominaltiter von 78 dtex ergibt sich ein Fibrillentiter von 1,14 dtex. Die resultierende Festigkeit beträgt 32 cN/tex bei einer Bruchdehnung von 72%. RV und Titerregelmässsigkeit sind gleich.Example 1 differs from Example A by the use of a spinneret plate with 68 capillary openings per thread, with a nominal titer of 78 dtex, the fibril titer is 1.14 dtex. The resulting one Strength is 32 cN / tex with an elongation at break of 72%. RV and titer regularity are equal.
Beispiel 2 unterscheidet sich von Beispiel A durch die Verwendung einer Spinndüsenplatte mit 34 Kapillaröffnungen pro Faden, wobei ein POY-Titer von 56 dtex eingestellt ist. Dies entspricht einem Nominaltiter von 44 dtex. Es ergibt sich ein Fibrillentiter von 1,29 dtex. Die resultierende Festigkeit beträgt 32,7 cN/tex bei einer Bruchdehnung von 69%. Der gesponnene Faden hat eine relative Viskosität von 40,9. Der Variationskoeffizient der Anfärbbarkeit liegt bei 0,9. Die erreichte Titerregelmässsigkeit ist 0,8 U%.Example 2 differs from Example A by the use of a spinneret plate with 34 capillary openings per thread, with a POY titer of 56 dtex is set. This corresponds to a nominal titer of 44 dtex. The fibril titer is 1.29 dtex. The resulting strength is 32.7 cN / tex at one Elongation at break of 69%. The spun thread has one relative viscosity of 40.9. The coefficient of variation the dyeability is 0.9. The titer regularity achieved is 0.8 U%.
Zur Erläuterung der Kapillar- und Filamentform die Zeichnung dienen. Es zeigen
- Fig.1
- die Kapillarform
- Fig.2
- die Fibrillenform
- Fig.1
- the capillary shape
- Fig.2
- the fibril shape
Fig. 1 zeigt den Querschnitt einer Kapillare, wobei B die Breite eines Schenkels und L die Länge des Schenkels der Kapillare bedeuten.Fig. 1 shows the cross section of a capillary, wherein B the width of a leg and L the length of the Mean leg of the capillary.
Fig. 2 zeigt den Querschnitt einer Fibrille, wobei B die Breite eines Schenkels und L die Länge des Schenkels der Fibrille bedeuten.Fig. 2 shows the cross section of a fibril, wherein B the width of a leg and L the length of the leg the fibril mean.
Das erfindungsgemässe Filamentgarn, dtex 100 (78) f 52, weist im Flächengebilde gute textile Eigenschaften auf und dient auch als Vorlagegam zum Texturieren nach dem Falschzwim- und dem Taslanverfahren, aber auch zum Verstrecken zu einem Glattgarn. Es ist besonders zum Einsatz in der Weberei als Kettgarn mit seinen hohen färberischen Anforderungen geeignet.The filament yarn according to the invention, dtex 100 (78) f 52, has good textile properties in the fabric and also serves as a template game for texturing after the false swimming and the Taslan procedure, but also for stretching to a plain yarn. It is particularly suitable for use in weaving as a warp yarn with its high dyeing requirements.
Claims (1)
- Process for producing a trilobal low-dpf polyamide filament yarn having a thread viscosity RV of 40 to 55, a tenacity of 30-45 cN/tex, especially for use as texturizing feed yarn, having an individual filament linear density < 1.5 dtex, based on the nominal linear density, a width/length ratio B/L of the filament cross-section of 0.5 to 0.7 and a linear density uniformity of Uster % < 1, the polyamide melt wherein extruded at an ejection rate of 8-14 m/min through a die having a capillary area of 0.05 to 0.1 mm2 and the solidified filaments are wound up at between 3700 and 5000 m/min.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH210992 | 1992-07-03 | ||
CH210992 | 1992-07-03 | ||
CH2109/92 | 1992-07-03 | ||
PCT/CH1993/000168 WO1994001603A1 (en) | 1992-07-03 | 1993-07-01 | Shaped-section fine-fibre filament yarn and method of producing it |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0602201A1 EP0602201A1 (en) | 1994-06-22 |
EP0602201B1 EP0602201B1 (en) | 1997-10-15 |
EP0602201B2 true EP0602201B2 (en) | 2004-01-28 |
Family
ID=4226085
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP93912537A Expired - Lifetime EP0602201B2 (en) | 1992-07-03 | 1993-07-01 | Shaped-section fine-fibre filament yarn and method of producing it |
Country Status (9)
Country | Link |
---|---|
US (1) | US5432002A (en) |
EP (1) | EP0602201B2 (en) |
AT (1) | ATE159303T1 (en) |
BR (1) | BR9305568A (en) |
CA (1) | CA2116779C (en) |
DE (1) | DE59307545D1 (en) |
DK (1) | DK0602201T4 (en) |
ES (1) | ES2110095T5 (en) |
WO (1) | WO1994001603A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104928773A (en) * | 2015-07-08 | 2015-09-23 | 福建凯邦锦纶科技有限公司 | Nylon 6 deeply-dyed drawn yarn and production technology thereof |
CN111041651A (en) * | 2019-12-29 | 2020-04-21 | 江苏恒力化纤股份有限公司 | Preparation method of bandage cloth |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5486417A (en) * | 1993-09-28 | 1996-01-23 | Basf Corporation | Mixed cross-section carpet yarn |
US5558826A (en) * | 1995-02-07 | 1996-09-24 | E. I. Du Pont De Nemours And Company | High speed process for making fully-oriented nylon yarns |
US7165963B2 (en) | 2003-10-31 | 2007-01-23 | Invista North America S.A.R.L. | Spinneret for producing circular cross section yarn and process for making the same |
CN102069676B (en) * | 2009-11-20 | 2012-07-18 | 江苏华佳丝绸有限公司 | Production method of silkworm planar silk painting material |
Citations (6)
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US2939201A (en) † | 1959-06-24 | 1960-06-07 | Du Pont | Trilobal textile filament |
US3994121A (en) † | 1974-04-03 | 1976-11-30 | E. I. Dupont De Nemours And Company | Polyhexamethylene adipamide yarn |
JPS5881609A (en) † | 1981-11-04 | 1983-05-17 | Nippon Ester Co Ltd | Melt spinning method of ultrafine modified cross section yarn |
DD293379A5 (en) † | 1990-03-29 | 1991-08-29 | Veb Chemiefaserkombinat Schwarza "Wilhelm Pieck",De | METHOD FOR PRODUCING OVERALL OR FULLY ORIENTED PROFILED POLYAMIDE FAEDES |
WO1991019839A1 (en) † | 1990-06-21 | 1991-12-26 | E.I. Du Pont De Nemours And Company | Improvements in nylon flat yarns |
EP0573376A1 (en) † | 1992-06-05 | 1993-12-08 | Rhone-Poulenc Fibres | Multilobal yarns und process for obtaining them |
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US3508390A (en) * | 1968-09-30 | 1970-04-28 | Allied Chem | Modified filament and fabrics produced therefrom |
DE3036683C2 (en) * | 1980-09-29 | 1985-01-24 | Davy McKee AG, 6000 Frankfurt | Process for melt spinning synthetic polymers |
US4801530A (en) * | 1984-02-29 | 1989-01-31 | Rockefeller University | Nucleotide hybridization assay for protozoan parasites |
US5223197A (en) * | 1986-01-30 | 1993-06-29 | E. I. Du Pont De Nemours And Company | Process of making mixed filament yarn |
US5208106A (en) * | 1991-08-27 | 1993-05-04 | E. I. Du Pont De Nemours And Company | Trilobal and tetralobal filaments exhibiting low glitter and high bulk |
-
1993
- 1993-07-01 ES ES93912537T patent/ES2110095T5/en not_active Expired - Lifetime
- 1993-07-01 DE DE59307545T patent/DE59307545D1/en not_active Expired - Fee Related
- 1993-07-01 DK DK93912537T patent/DK0602201T4/en active
- 1993-07-01 EP EP93912537A patent/EP0602201B2/en not_active Expired - Lifetime
- 1993-07-01 CA CA002116779A patent/CA2116779C/en not_active Expired - Fee Related
- 1993-07-01 WO PCT/CH1993/000168 patent/WO1994001603A1/en active IP Right Grant
- 1993-07-01 AT AT93912537T patent/ATE159303T1/en not_active IP Right Cessation
- 1993-07-01 BR BR9305568A patent/BR9305568A/en not_active IP Right Cessation
-
1994
- 1994-02-28 US US08/204,148 patent/US5432002A/en not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2939201A (en) † | 1959-06-24 | 1960-06-07 | Du Pont | Trilobal textile filament |
US3994121A (en) † | 1974-04-03 | 1976-11-30 | E. I. Dupont De Nemours And Company | Polyhexamethylene adipamide yarn |
JPS5881609A (en) † | 1981-11-04 | 1983-05-17 | Nippon Ester Co Ltd | Melt spinning method of ultrafine modified cross section yarn |
DD293379A5 (en) † | 1990-03-29 | 1991-08-29 | Veb Chemiefaserkombinat Schwarza "Wilhelm Pieck",De | METHOD FOR PRODUCING OVERALL OR FULLY ORIENTED PROFILED POLYAMIDE FAEDES |
WO1991019839A1 (en) † | 1990-06-21 | 1991-12-26 | E.I. Du Pont De Nemours And Company | Improvements in nylon flat yarns |
EP0573376A1 (en) † | 1992-06-05 | 1993-12-08 | Rhone-Poulenc Fibres | Multilobal yarns und process for obtaining them |
Non-Patent Citations (5)
Title |
---|
BARMAG information Service Brochure No. 8/1973 † |
Encyclopaedia of Polymer Science and Engineering, John Wiley & Sons, 2nd Edition (1988), vol. 11, pages 362-364 † |
G.Koschinek and L. Riehl in Chemiefasern 1983 (9/83) pages E69-E71 † |
H. Treptow in Man-Made Fiber Year Book 1986 † |
M. Mayer in Cheniefasern 2/85 (1985) E9-E13 † |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104928773A (en) * | 2015-07-08 | 2015-09-23 | 福建凯邦锦纶科技有限公司 | Nylon 6 deeply-dyed drawn yarn and production technology thereof |
CN111041651A (en) * | 2019-12-29 | 2020-04-21 | 江苏恒力化纤股份有限公司 | Preparation method of bandage cloth |
Also Published As
Publication number | Publication date |
---|---|
DK0602201T4 (en) | 2004-04-05 |
ATE159303T1 (en) | 1997-11-15 |
US5432002A (en) | 1995-07-11 |
DK0602201T3 (en) | 1998-06-02 |
EP0602201A1 (en) | 1994-06-22 |
EP0602201B1 (en) | 1997-10-15 |
ES2110095T5 (en) | 2004-07-16 |
DE59307545D1 (en) | 1997-11-20 |
CA2116779C (en) | 2003-06-17 |
CA2116779A1 (en) | 1994-01-20 |
ES2110095T3 (en) | 1998-02-01 |
BR9305568A (en) | 1995-12-26 |
WO1994001603A1 (en) | 1994-01-20 |
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