EP0591348A1 - Dispositifs de protection de circuits. - Google Patents

Dispositifs de protection de circuits.

Info

Publication number
EP0591348A1
EP0591348A1 EP92913589A EP92913589A EP0591348A1 EP 0591348 A1 EP0591348 A1 EP 0591348A1 EP 92913589 A EP92913589 A EP 92913589A EP 92913589 A EP92913589 A EP 92913589A EP 0591348 A1 EP0591348 A1 EP 0591348A1
Authority
EP
European Patent Office
Prior art keywords
sheet
electrodes
ptc
conductive members
devices
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP92913589A
Other languages
German (de)
English (en)
Other versions
EP0591348B1 (fr
Inventor
Gilles Remy Gozlan
Shou-Mean Fang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Commscope Connectivity Belgium BVBA
Raychem SA
Original Assignee
Raychem NV SA
Raychem SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Raychem NV SA, Raychem SA filed Critical Raychem NV SA
Publication of EP0591348A1 publication Critical patent/EP0591348A1/fr
Application granted granted Critical
Publication of EP0591348B1 publication Critical patent/EP0591348B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01C—RESISTORS
    • H01C7/00—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material
    • H01C7/02—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material having positive temperature coefficient
    • H01C7/027—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material having positive temperature coefficient consisting of conducting or semi-conducting material dispersed in a non-conductive organic material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00—Metal working
    • Y10T29/49—Method of mechanical manufacture
    • Y10T29/49002—Electrical device making
    • Y10T29/49082—Resistor making
    • Y10T29/49085—Thermally variable

Definitions

  • the present invention relates to electrical devices, for example circuit protection devices, and to their methods of manufacture.
  • the devices comprise material that has a positive temperature coefficient of resistance (PTC) and that undergoes a significant and sharp increase in resistance at a specified temperature or over a specified narrow temperature range above ambient temperature.
  • PTC positive temperature coefficient of resistance
  • PTC materials which may be polymeric or ceramic, are known for use in electrical devices such as heaters, and also for protecting eiectricai circuits against excessive current or temperature.
  • the excessive temperature may itself arise simply from current flowing through the device, or may be due to an increase in the ambient temperature beyond a desired value. Details of developments relating to conductive polymer PTC compositions and devices comprising them, are given for example in U.S. Pat. Nos. 4,017,715, 4,177,376, 4,246,468, 4,237,441 , 4,238,812, 4,329,726, 4,255,698, 4,272,471 , 4,445,026, and 4,327,351 , and GB 2,038,549.
  • the present invention is concerned particularly, though not exclusively, with electrical devices comprising PTC material, preferably polymeric, for use in circuit protection, and US Patent Nos. 4,238,812 and 4,329,726 referred to above for example, disclose such devices.
  • PTC circuit protection devices are such that under normal operating conditions, determined by the current and temperature rating of the PTC material, they exhibit very low resistance to the flow of current therethrough. Under fault conditions, of excessive current and/or temperature, the PTC material heats up, significantly increases its resistance and thus switches off the flow of current therethrough, thereby protecting an associated electrical circuit. The higher the resistance of the material after passing through the switching transition, the lower is the residual current that can flow through the device, and thus the more effectively is the device in protecting its circuit.
  • Products embodying these principles are presently sold by Raychem Corporation under its tradename POLYSWITCH. Some of such products are formed from a substantially homogeneous sheet of polymeric PTC material. The sheet is coated over each of its major surfaces with electrically conductive material, to act as electrodes, and disc, rectangular, or other, shaped devices are stamped therefrom.
  • the resistivity of the PTC material of POLYSWITCH devices typically does not exceed 10 ohm-cm, and taking a typical value of 5 ohm-cm and a disc configuration with typical dimensions of diameter 2 cm and thickness 0.05 cm, the resistance at room temperature (ie. about 20° C) of the device is typically 0.08 ohm.
  • the resistance values provided by devices that are of a size that can conveniently be handled manually do not vary significantly from the values given above. If it is desired to make such devices of different resistance, then this can be arranged in various ways: (a) a different PTC material having a different resistivity can be employed.
  • the difficulty encountered is that of providing, by extrusion for example, a relatively thick sheet of a polymeric material that is highly loaded, for example by as much as 50% of its volume, with fillers such as carbon black, in which the composition of the material is homogeneous throughout.
  • a typical width of extruded sheet is 30 cm; and (c) The diameter (or other planar) dimension of the stamped product can be varied.
  • Below a certain size it becomes very difficult physically to handle the individual devices, so again there is a problem with producing devices of higher resistance. For these practical reasons therefore it is difficult to make such devices having a resistance greater than say about 5 ohms.
  • EP-A-0 087 884 discloses a further polymeric PTC circuit protection device in which a cylindrical element of PTC material is mounted within an enclosure between cup-shaped electrodes at each end thereof.
  • PTC circuit protection devices particularly though not exclusively of polymeric material, can be made of higher resistance reproducibly using known sheet PTC material and applying conductive material (for formation of electrodes) at selected spaced apart locations on one side of the sheet. Current flow between the electrodes is thus substantially parallel to the major (usually planar) surfaces, and thus along the length, of the sheet and not directly through its thickness.
  • a greater range of resistances in devices can thus be produced from a sheet of material that itself has a given resistivity and thickness.
  • Such devices can be made of easily handieable size whilst still having the desired high resistance.
  • PTC material preferably polymeric
  • a method of manufacturing a plurality of electrical devices comprising:
  • substantially homogeneous sheet of material is meant a sheet throughout whose entire volume the composition of the material is substantially homogeneous.
  • the devices of the invention are formed from a sheet of material, preferably in a planar configuration, the devices themselves either by manufacture or by use need not be planar.
  • the PTC material comprises polymeric material.
  • the sheet is produced by extrusion.
  • the electrically conductive members are located on the sheet of PTC material, at suitable locations, before the sheet is cut to produce the plurality of individual electrical devices.
  • the PTC sheet may be cut into individual portions and the electrically conductive members subsequently appropriately located thereon.
  • the conductive members may be located on one only or on both of the major surfaces of the PTC material.
  • the cutting of the sheet may result in devices that themselves have conductive members on one or both of their major surfaces.
  • the conductive members may be applied in discrete form to the PTC sheet and may or may not be themselves cut by the cutting step (c).
  • a conductive member may be applied as one or more continuous strips, for example along an edge of the sheet, and may be cut in step (c) so as to provide conductive members, serving as electrodes, for a plurality of devices.
  • Conductive material may be applied as a continuous layer, for example by deposition, or a photo-resist method, to one or both major surfaces of the sheet.
  • part of the layer may be removed from the sheet, for example by etching, so as to provide a plurality of conductive members thereon.
  • a conductive sheet or foil for example of 0.025 mm thickness, is hot-pressed on to the PTC material.
  • conductive material may be applied to the sheet of PTC material by a continuous deposition process. This could conveniently involve the use of a mask such that discrete electrodes are deposited.
  • the deposited layer could be a film of thickness about 25 micrometers, which could be built up, into a thicker film if necessary, by successive depositions.
  • the electrical devices formed from a single sheet by the method of the invention may be generally rectangular or circular, or have any other required shape.
  • the devices are particularly applicable for use in circuit protection devices, the conductive members acting as electrodes.
  • the resultant conductive members of each device are such that, in use, current flow is substantially parallel to the major surfaces of the device, and it is specifically required that substantially no current at all flow transversely thereof (since this would give rise to a lower resistance path that would reduce the effectiveness of the device since the current at which the device would protect an associated circuit would be higher).
  • the thickness of the sheet of PTC material is less than about 2 mm, and may be about 1 mm, and preferably is less than about 0.5 mm, whilst its resistivity is as high as can conveniently and reliably be achieved, typically being up to about 10 ohm-cm.
  • Particularly advantageous embodiments of device produced by the method of the present invention are rectangular in shape, and have a rectangular conductive member extending along each of two opposing edges thereof (i) both on the same surface, or (ii) on opposing surfaces of the sheet of PTC material.
  • such devices may be of length about 15 mm and width from about 2 mm to 10 mm.
  • a circuit protection device comprising a substantially homogeneous sheet that (a) is formed of material having a positive temperature coefficient of resistance, (b) has a thickness less than about 2 mm, (c) has on at least one major surface thereof two electrodes that are spaced apart such that, in use, current flow therebetween is substantially parallel to the major surfaces of the sheet, and (d) has a resistance (along the current flow path between the electrodes) at 20° C that is greater than 1 ohm.
  • the electrodes may or may not be on the same major surface of the sheet of PTC material.
  • the resistivity of the PTC material which is preferably polymeric, the thickness of the sheet, and the size and separation of the conductive members are selected such that the devices of the invention have a resistance at room temperature (that is to say at 20° C) of at least 1 ohm, preferably at least 20 ohms, and typically 100 ohms.
  • Such devices can limit trip current up to about 400mA.
  • the resistivity of the PTC material is as high as possible, and in practice is preferably greater than 1 ohm-cm.
  • the device of said another aspect of the present invention is produced by the method of said one aspect of the present invention.
  • the electrodes of the device could be applied to the PTC material as discrete components.
  • a substrate such as a printed circuit board, may be itself provided with electrodes that are arranged to clamp on to, or otherwise make good electrical contact with, the PTC strip.
  • the electrodes although preferably being bonded to the PTC material, may simply be in good physical contact therewith.
  • the method and device of the present invention are such that the device is provided with means for encouraging the formation of a local hot spot in the PTC material, so that the concentrated heating will more quickly give rise to tripping of the device.
  • the hot spot which may be linear, that is to say a hot line, should be located away from the electrodes, thus preferably halfway therebetween, so as to avoid any damage thereto.
  • the hot spot can conveniently be encouraged by locally reducing the amount of PTC material present.
  • an electrical circuit comprising at least one electrical component susceptible to excessive current and/or temperature, and a device arranged to protect the component thereagainst, wherein the protection device comprises a substantially homogeneous sheet of PTC material of thickness less than 2.0 mm, the sheet being mounted in the circuit with two spaced apart electrodes in good electrical contact therewith such that, in use, current flow between the electrodes is substantially parallel to the major surfaces of the PTC sheet and such that the resistance at 20° C of the PTC material between the electrodes is greater than 1 ohm.
  • Figure 1 shows one embodiment of a PTC sheet with nine identical devices each as shown in Figure 1 A cut therefrom;
  • Figure 2 to 4 show alternative embodiments of devices;
  • Figures 5A, 5B and 5C show three devices having different configurations for enhancing switching per ormance; and
  • Figure 6 shows a plan view of a further modification of the device of Figure 1A.
  • Figure 1 shows a plan view of a rectangular sheet 2 of polymeric PTC material of 0.5 mm thickness having a resistivity of 4 ohm- cm.
  • Conductive material, nickel, of thickness 1 mil (25 micron) is deposited on to one surface only of the sheet so as to provide a relatively narrow strip 4 along each of two opposing edges, and two relatively wide strips 6 equispaced therebetween.
  • Figure 3 shows a further embodiment of device, in which the conductive material is deposited in strips on the PTC sheet 2 alternatively on upper and lower major surfaces so that after cutting, the device has one end electrode 4A on an upper surface and an opposing end electrode 6B on a lower surface.
  • the direction of current flow through the device is substantially paraiiei to the plane of the PTC material ' .
  • the separation 8 mm of the electrodes, and their transverse dimension 4 mm determines the resistance of the device, for a PTC material of given resistivity and formed as a sheet of given thickness.
  • a 0.5 mm thick sheet of resistivity 4 ohm-cm with d - 4 mm and I ⁇ 8 mm will provide a device at room temperature having a resistance of about 80 ohms and a circuit protection current of about 30mA.
  • Figure 4 shows a device of generally circular configuration that has been stamped out of a larger sheet.
  • a central disc electrode 10 and an outer annular electrode 12 are disposed on and separated by PTC sheet material 14.
  • the separation of the electrodes across the surface of the PTC material may be as little as 0.1 mm, but typically the electrode separation would lie in the range from about 0.2 to 1.0 cm.
  • the thickness of the sheet of PTC material would typically be from about 0.25 to 1.0 mm.
  • Figures 5A (plan view), 5B (plan view) and 5C (perspective view) show respective ways of enhancing the performance of the circuit protection device of Figure 1A. It will be appreciated that in operating conditions in which the current through, and/or temperature of, the device becomes excessive thus needing it to trip to protect its associated circuit, it is desirable that the tripping, or switching, action takes place as quickly as possible. This can be enhanced in the case of overcurrent protection if the formation of a local hot spot can be encouraged.
  • Each of these Figures achieves that effect, by providing a region, for formation of a so-called hot line, of reduced PTC material, thereby locally enhancing the current density and reducing the thermal mass preferentially.
  • the device 20 of Figure 5A has holes 22 formed therethrough; the device 24 of Figure 5B has a pair of notches 26 cut in the sides thereof; and the device 28 of Figure 5C has a channel 30 in one of its major surfaces.
  • the device 32 comprises a sheet (or strip) 34 of PTC polymeric material of 0.5 mm thickness and resistivity 5 ohm-cm.
  • Three nickel electrodes A, B, C are applied to one surface thereof such that the separation of A and B is 4 mm and of B and C is 8 mm.
  • the device 32 can be arranged to have different current protection values depending on how electrical contact is made between the electrodes A, B, C and the associated electrical circuit. For example, if external conductors are attached only to the electrodes A and B, the resistance between these electrodes, 133 ohms, gives a protection current therebetween of 21 mA.
  • electrode C and the PTC material lying between electrodes B and C, is superfluous and plays no part in operation of the device.
  • conductors can be attached to electrodes B and C, giving a device with a resistance of 266 ohms and a protection current of 18mA.
  • electrodes A and C can be connected together directly by an external conductor, and conductors taken from electrodes B and C to an external circuit. This effectively results in a device formed from two PTC resistors A-B and B-C connected in parallel, giving a combined resistance of 90 ohms and a protection current value of 40mA.
  • other combinations can be made. In general, therefore, it is seen that by using a device having three, or more, electrodes thereon, and by selecting the spacing between them, a single device can be used in a variety of applications where different protection currents are required.
  • the devices may be mounted between clips on a circuit board, when the device of Figure 2 may be particularly suitable, or terminal conductors may be connected to the conductive members (electrodes) thereof, for ease of connection into an electrical circuit.

Abstract

Procédé de fabrication d'un dispositif polymère et plan de protection de circuits, selon lequel le courant entre deux électrodes (4,6) suit un trajet parallèle à la surface d'une feuille (2) de matériau polymère électroconducteur, au lieu de la traverser dans le sens de son épaisseur. On peut régler avec précision les niveaux de résistance et de courant d'excitation du dispositif, et les fixer à des niveaux comparativement peu élevés.
EP92913589A 1991-06-27 1992-06-26 Dispositifs de protection de circuits Expired - Lifetime EP0591348B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB9113888 1991-06-27
GB919113888A GB9113888D0 (en) 1991-06-27 1991-06-27 Circuit protection devices
PCT/GB1992/001162 WO1993000688A1 (fr) 1991-06-27 1992-06-26 Dispositifs de protection de circuits

Publications (2)

Publication Number Publication Date
EP0591348A1 true EP0591348A1 (fr) 1994-04-13
EP0591348B1 EP0591348B1 (fr) 1996-06-12

Family

ID=10697427

Family Applications (1)

Application Number Title Priority Date Filing Date
EP92913589A Expired - Lifetime EP0591348B1 (fr) 1991-06-27 1992-06-26 Dispositifs de protection de circuits

Country Status (8)

Country Link
US (1) US5537286A (fr)
EP (1) EP0591348B1 (fr)
JP (2) JPH06508960A (fr)
AT (1) ATE139364T1 (fr)
CA (1) CA2111844A1 (fr)
DE (1) DE69211552T2 (fr)
GB (1) GB9113888D0 (fr)
WO (1) WO1993000688A1 (fr)

Families Citing this family (9)

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JP3175102B2 (ja) * 1996-05-20 2001-06-11 株式会社村田製作所 正特性サーミスタ素体および正特性サーミスタ
FR2761204B1 (fr) * 1997-03-24 1999-05-14 Siemens Automotive Sa Dispositif de distribution d'energie electrique dans plusieurs circuits alimentes en paralleles, et procede de fabrication de ce dispositif
KR20060127854A (ko) * 2003-10-21 2006-12-13 타이코 일렉트로닉스 레이켐 케이. 케이. Ｐｔｃ 소자 및 형광등용 스타터 회로
KR100731462B1 (ko) * 2005-05-04 2007-06-21 삼성에스디아이 주식회사 이차전지
FR2891958B1 (fr) * 2005-10-11 2008-08-01 Schneider Electric Ind Sas Dispositif limiteur de courant, disjoncteur comportant un tel dispositif, et procede limiteur de courant
DE102006017796A1 (de) * 2006-04-18 2007-10-25 Epcos Ag Elektrisches Kaltleiter-Bauelement
WO2012070336A1 (fr) * 2010-11-22 2012-05-31 Tdk株式会社 Thermistance sous forme de puce et carte d'ensemble de thermistors
JP2017191856A (ja) * 2016-04-13 2017-10-19 日本特殊陶業株式会社 サーミスタ素子及びその製造方法
JP6830038B2 (ja) * 2017-06-13 2021-02-17 日本特殊陶業株式会社 センサ素子、及びそれを備えたガスセンサ

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Also Published As

Publication number Publication date
CA2111844A1 (fr) 1993-01-07
JPH06508960A (ja) 1994-10-06
JP2004006963A (ja) 2004-01-08
EP0591348B1 (fr) 1996-06-12
US5537286A (en) 1996-07-16
GB9113888D0 (en) 1991-08-14
DE69211552D1 (de) 1996-07-18
WO1993000688A1 (fr) 1993-01-07
DE69211552T2 (de) 1997-02-06
ATE139364T1 (de) 1996-06-15

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