EP0537063B1 - Procédé de dépôt électrophorétique de poudre métallique pour rechargememt de pièces par brasage-diffusion et bain utilisé - Google Patents
Procédé de dépôt électrophorétique de poudre métallique pour rechargememt de pièces par brasage-diffusion et bain utilisé Download PDFInfo
- Publication number
- EP0537063B1 EP0537063B1 EP92402728A EP92402728A EP0537063B1 EP 0537063 B1 EP0537063 B1 EP 0537063B1 EP 92402728 A EP92402728 A EP 92402728A EP 92402728 A EP92402728 A EP 92402728A EP 0537063 B1 EP0537063 B1 EP 0537063B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- coating
- deposition
- metal powder
- agar
- workpieces
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000843 powder Substances 0.000 title claims description 16
- 238000000034 method Methods 0.000 title claims description 13
- 238000009792 diffusion process Methods 0.000 title claims description 12
- 238000000151 deposition Methods 0.000 title claims description 11
- 229910052751 metal Inorganic materials 0.000 title claims description 9
- 239000002184 metal Substances 0.000 title claims description 9
- 239000011248 coating agent Substances 0.000 title claims description 7
- 238000000576 coating method Methods 0.000 title claims description 7
- 239000000203 mixture Substances 0.000 claims description 21
- 230000008021 deposition Effects 0.000 claims description 10
- 239000000243 solution Substances 0.000 claims description 9
- 239000007864 aqueous solution Substances 0.000 claims description 8
- 238000001652 electrophoretic deposition Methods 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 8
- 238000001962 electrophoresis Methods 0.000 claims description 5
- 229910000601 superalloy Inorganic materials 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 4
- 230000005684 electric field Effects 0.000 claims description 4
- 229920001206 natural gum Polymers 0.000 claims description 4
- 229920001817 Agar Polymers 0.000 claims description 3
- 241000206672 Gelidium Species 0.000 claims description 3
- 235000010419 agar Nutrition 0.000 claims description 3
- 239000011230 binding agent Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 2
- 238000005219 brazing Methods 0.000 claims 2
- 239000008367 deionised water Substances 0.000 claims 1
- 229910021641 deionized water Inorganic materials 0.000 claims 1
- 239000002923 metal particle Substances 0.000 claims 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 239000013528 metallic particle Substances 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 238000007605 air drying Methods 0.000 description 2
- 238000007596 consolidation process Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229910000599 Cr alloy Inorganic materials 0.000 description 1
- 229920000715 Mucilage Polymers 0.000 description 1
- 229920002494 Zein Polymers 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000000788 chromium alloy Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000005019 zein Substances 0.000 description 1
- 229940093612 zein Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D13/00—Electrophoretic coating characterised by the process
- C25D13/02—Electrophoretic coating characterised by the process with inorganic material
Definitions
- the invention relates to a method of electrophoretic deposition of metal powders. Said method is specially adapted for producing thick deposits used for reloading of parts, in particular made of nickel-based superalloy and in particular intended for aeronautical or turbomachine applications, said reloading being obtained using brazing-diffusion techniques.
- the invention also relates to a product composition to be deposited in the form of a deposit mixture dispersed in an aqueous solution.
- the object of the invention is to propose an alternative solution for setting up the supply before carrying out the heat treatment of brazing-diffusion which is carried out according to the techniques previously used and known per se, with a view to obtaining the reload sought.
- GB-A-1 466 204 also discloses a process for producing an anti-corrosion coating on superalloy parts comprising an electrophoretic deposition of a mixture of aluminum powder and of a chromium alloy powder. aluminum obtained from a suspension of these powders in an organic dielectric based on isopropyl alcohol, nitromethane and zein and a diffusion heat treatment.
- FR-A-2 308 704 describes a process for coating a metal surface by electrophoresis from an aqueous dispersion of aluminum powder and a thermosetting acrylic resin.
- composition of the deposit mixture is Composition of the deposit mixture.
- Anodic type deposition is carried out by placing the substrate in the anode position.
- a stainless alloy cathode having the profile of a grid is used.
- the inter-electrode distance is 10 to 80 mm.
- the continuous electric field applied is between 5 and 30 V / cm.
- the current density is 0.2 to 2 A / dm2
- the deposition is carried out at ambient temperature, ie approximately 20 ° C.
- Deposition thicknesses between 0.1 and 2 mm are thus obtained depending on the deposition time and the parameter values applied.
- the deposits obtained are perfectly uniform and adherent.
- the composition of the deposit is that of the electrophoretic bath.
- the gross electrophoresis deposit is hydrated in a proportion of 20 to 40%.
- An air drying treatment removes the water either after 24 hours at room temperature or 2 hours at 120 ° C.
- the mechanical resistance of the deposits is sufficient to allow manipulation and the carrying out of a brazing-diffusion heat treatment which makes it possible to obtain the consolidation of the deposit and a reloading having the desired mechanical and metallurgical characteristics.
- the operating conditions and the parameter values are known per se and determined for each application as a function of the particular material of the part to be recharged or substrate and of the filler material retained.
- the process of electrophoresis deposition of metal powders for reloading of parts by heat treatment of brazing-diffusion can be used to effect reloading in repairing parts and / or in manufacturing new parts.
- the part In the case where the part must be coated on two faces, when the electrophoretic deposition is carried out, the part is arranged between two shaped electrodes located at an equal distance, according to the criteria defined above.
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Powder Metallurgy (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9112409A FR2682401B1 (fr) | 1991-10-09 | 1991-10-09 | Procede de depot electrophoretique de poudre metallique pour rechargement de pieces par brasage-diffusion et bain utilise. |
FR9112409 | 1991-10-09 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0537063A1 EP0537063A1 (fr) | 1993-04-14 |
EP0537063B1 true EP0537063B1 (fr) | 1995-12-06 |
Family
ID=9417733
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP92402728A Expired - Lifetime EP0537063B1 (fr) | 1991-10-09 | 1992-10-07 | Procédé de dépôt électrophorétique de poudre métallique pour rechargememt de pièces par brasage-diffusion et bain utilisé |
Country Status (5)
Country | Link |
---|---|
US (2) | US5336382A (ja) |
EP (1) | EP0537063B1 (ja) |
JP (1) | JP2761330B2 (ja) |
DE (1) | DE69206568T2 (ja) |
FR (1) | FR2682401B1 (ja) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5976337A (en) * | 1997-10-27 | 1999-11-02 | Allison Engine Company | Method for electrophoretic deposition of brazing material |
FR2827311B1 (fr) * | 2001-07-12 | 2003-09-19 | Snecma Moteurs | Procede de reparation locale de pieces revetues d'une barriere thermique |
DE10335406A1 (de) * | 2003-08-01 | 2005-02-17 | Mtu Aero Engines Gmbh | Verfahren zum Reparieren von Wärmedämmschichten mit lokalen Beschädigungen |
JP6093523B2 (ja) * | 2011-09-29 | 2017-03-08 | 電化皮膜工業株式会社 | 着色アルミニウム製品または着色アルミニウム合金製品の製造方法 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3067120A (en) * | 1960-09-02 | 1962-12-04 | Pearlstein Fred | Addition agents for improving electrophoretic deposition of aluminum from organic suspensions |
US3795601A (en) * | 1971-12-27 | 1974-03-05 | Ford Motor Co | Electrodiffused protective coating system |
FR2381591A1 (fr) * | 1977-02-24 | 1978-09-22 | Snecma | Procede de liaison par brasage-diffusion de pieces en acier ou superalliage |
EP0002109B1 (en) * | 1977-11-15 | 1981-12-02 | Imperial Chemical Industries Plc | A method for the preparation of thin photoconductive films and of solar cells employing said thin photoconductive films |
FR2511908A1 (fr) * | 1981-08-26 | 1983-03-04 | Snecma | Procede de brasage-diffusion destine aux pieces en superalliages |
FR2516526B1 (fr) * | 1981-11-16 | 1987-05-22 | Rhone Poulenc Spec Chim | Compositions a base de gommes hydrosolubles, leur preparation et leur utilisation |
DE3247756A1 (de) * | 1982-12-23 | 1984-06-28 | Herberts Gmbh, 5600 Wuppertal | Waessriges ueberzugsmittel |
AU3742185A (en) * | 1983-11-22 | 1985-03-04 | Udviklingsselskabet A F 31 10 1983 ApS | Paint |
US4869421A (en) * | 1988-06-20 | 1989-09-26 | Rohr Industries, Inc. | Method of jointing titanium aluminide structures |
GB0200819D0 (en) * | 2002-01-15 | 2002-03-06 | Cole Polytechnique Federale De | Microscopy imaging apparatus and method for generating an image |
-
1991
- 1991-10-09 FR FR9112409A patent/FR2682401B1/fr not_active Expired - Fee Related
-
1992
- 1992-10-06 JP JP4267400A patent/JP2761330B2/ja not_active Expired - Fee Related
- 1992-10-07 US US07/957,166 patent/US5336382A/en not_active Expired - Fee Related
- 1992-10-07 DE DE69206568T patent/DE69206568T2/de not_active Expired - Fee Related
- 1992-10-07 EP EP92402728A patent/EP0537063B1/fr not_active Expired - Lifetime
-
1994
- 1994-04-04 US US08/222,713 patent/US5411582A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE69206568D1 (de) | 1996-01-18 |
DE69206568T2 (de) | 1996-05-15 |
US5336382A (en) | 1994-08-09 |
JPH05247690A (ja) | 1993-09-24 |
FR2682401B1 (fr) | 1993-11-26 |
FR2682401A1 (fr) | 1993-04-16 |
JP2761330B2 (ja) | 1998-06-04 |
EP0537063A1 (fr) | 1993-04-14 |
US5411582A (en) | 1995-05-02 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6485780B1 (en) | Method for applying coatings on substrates | |
CA1335439C (fr) | Pieces de machine thermique en alliage comportant un revetement protecteur metalloceramique | |
EP0368753B1 (fr) | Dépôt électrophorétique anti-usure du type métallo-céramique consolidé par nickelage électrolytique | |
US8501273B2 (en) | Mixture and technique for coating an internal surface of an article | |
JPH0788564B2 (ja) | 超合金基体上への白金−ケイ素−添加拡散アルミニド被膜の形成法 | |
CN101033545A (zh) | 热障涂层组合物、施加它的方法和涂有它的制品 | |
EP0537063B1 (fr) | Procédé de dépôt électrophorétique de poudre métallique pour rechargememt de pièces par brasage-diffusion et bain utilisé | |
US3620693A (en) | Ductile, high-temperature oxidation-resistant composites and processes for producing same | |
CA2356305C (fr) | Formation d'un revetement aluminiure incorporant un element reactif, sur un substrat metallique | |
EP2459781B1 (fr) | Méthode de fabrication d'une barrière thermique | |
EP0354822A1 (fr) | Compositions nouvelles de primaire d'adhérence pour revêtement fluoré à base de résines époxydes et méthacryliques, leur application pour le revêtement de substrats métalliques et procédé de fabrication desdits revêtements | |
FR2669397A1 (fr) | Reservoir metallique notamment bouteille ou citerne a gaz. | |
WO2002070617A1 (en) | Method of application of a protective coating to a substrate | |
CN107177813A (zh) | 一种在M-Al金属间化合物上直接热生长α-Al2O3的方法及应用 | |
US3761301A (en) | Processes for producing ductile high temperature oxidation resistant composites | |
US20100055434A1 (en) | Method to signficantly increase electrophoretic coating thickness and/or to provide a conductive electrophoretically coated surface | |
EP4423323A1 (fr) | Procede de formation d'un revetement de protection cathodique sur une piece de turbomachine | |
FR3108633A1 (fr) | Procédé de dépôt d’un revêtement sur une pièce métallique et pièce métallique obtenue selon un tel procédé | |
EP4436940A1 (fr) | Procédé de revêtement par électrophorèse d'une pièce en matériau composite à matrice céramique par une barrière environnementale | |
CZ20003057A3 (cs) | Způsob nanášení povlaků na substrát | |
BE471533A (ja) | ||
WO1998008907A1 (fr) | Revetement protecteur, en particulier pour substrat metallique, obtention et applications | |
EP0922074A1 (fr) | Revetement protecteur, en particulier pour substrat metallique, obtention et applications |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 19921019 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): DE FR GB NL |
|
17Q | First examination report despatched |
Effective date: 19950308 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): DE FR GB NL |
|
REF | Corresponds to: |
Ref document number: 69206568 Country of ref document: DE Date of ref document: 19960118 |
|
GBT | Gb: translation of ep patent filed (gb section 77(6)(a)/1977) |
Effective date: 19960122 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed | ||
REG | Reference to a national code |
Ref country code: GB Ref legal event code: IF02 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20030922 Year of fee payment: 12 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20031001 Year of fee payment: 12 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 20031031 Year of fee payment: 12 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20031219 Year of fee payment: 12 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20041007 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20050501 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20050503 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20041007 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20050630 |
|
NLV4 | Nl: lapsed or anulled due to non-payment of the annual fee |
Effective date: 20050501 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST |