EP0500925A1 - New structure and method for fabricating indium phosphide/indium gallium arsenide phosphide buried heterostructure semiconductor lasers - Google Patents

New structure and method for fabricating indium phosphide/indium gallium arsenide phosphide buried heterostructure semiconductor lasers

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Publication number
EP0500925A1
EP0500925A1 EP91918807A EP91918807A EP0500925A1 EP 0500925 A1 EP0500925 A1 EP 0500925A1 EP 91918807 A EP91918807 A EP 91918807A EP 91918807 A EP91918807 A EP 91918807A EP 0500925 A1 EP0500925 A1 EP 0500925A1
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EP
European Patent Office
Prior art keywords
layer
semiconductor
wafer
active layer
cap
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP91918807A
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German (de)
French (fr)
Other versions
EP0500925A4 (en
Inventor
Roger P. Holmstrom
Edmund Meland
William Powazinik
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Verizon Laboratories Inc
Original Assignee
GTE Laboratories Inc
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Publication of EP0500925A1 publication Critical patent/EP0500925A1/en
Publication of EP0500925A4 publication Critical patent/EP0500925A4/en
Withdrawn legal-status Critical Current

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00—Semiconductor lasers
    • H01S5/20—Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers
    • H01S5/22—Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers having a ridge or stripe structure
    • H01S5/227—Buried mesa structure ; Striped active layer
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/302—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
    • H01L21/306—Chemical or electrical treatment, e.g. electrolytic etching
    • H01L21/30604—Chemical etching
    • H01L21/30612—Etching of AIIIBV compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/302—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
    • H01L21/306—Chemical or electrical treatment, e.g. electrolytic etching
    • H01L21/30604—Chemical etching
    • H01L21/30612—Etching of AIIIBV compounds
    • H01L21/30621—Vapour phase etching
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00—Semiconductor lasers
    • H01S5/06—Arrangements for controlling the laser output parameters, e.g. by operating on the active medium
    • H01S5/062—Arrangements for controlling the laser output parameters, e.g. by operating on the active medium by varying the potential of the electrodes
    • H01S5/06226—Modulation at ultra-high frequencies
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00—Semiconductor lasers
    • H01S5/20—Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers
    • H01S5/22—Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers having a ridge or stripe structure
    • H01S5/227—Buried mesa structure ; Striped active layer
    • H01S5/2275—Buried mesa structure ; Striped active layer mesa created by etching
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00—Semiconductor lasers
    • H01S5/20—Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers
    • H01S5/22—Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers having a ridge or stripe structure
    • H01S5/227—Buried mesa structure ; Striped active layer
    • H01S5/2275—Buried mesa structure ; Striped active layer mesa created by etching
    • H01S5/2277—Buried mesa structure ; Striped active layer mesa created by etching double channel planar buried heterostructure [DCPBH] laser
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00—Semiconductor lasers
    • H01S5/30—Structure or shape of the active region; Materials used for the active region
    • H01S5/32—Structure or shape of the active region; Materials used for the active region comprising PN junctions, e.g. hetero- or double- heterostructures
    • H01S5/323—Structure or shape of the active region; Materials used for the active region comprising PN junctions, e.g. hetero- or double- heterostructures in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser
    • H01S5/3235—Structure or shape of the active region; Materials used for the active region comprising PN junctions, e.g. hetero- or double- heterostructures in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser emitting light at a wavelength longer than 1000 nm, e.g. InP-based 1300 nm and 1500 nm lasers
    • H01S5/32391—Structure or shape of the active region; Materials used for the active region comprising PN junctions, e.g. hetero- or double- heterostructures in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser emitting light at a wavelength longer than 1000 nm, e.g. InP-based 1300 nm and 1500 nm lasers based on In(Ga)(As)P

Definitions

  • This invention pertains to semiconductor lasers and more particularly to high modulation bandwidth single transverse mode semiconductor lasers.
  • Background Art As fiber optic communication systems continue to push to even higher data rates and larger bandwidths, the availability of reproducible and reliable high-speed lasers becomes increasingly important. This is particularly true for microwave modulation schemes like subcarrier multiplexing, where low relative intensity noise (RIN) is very important, or for phase modulated systems, where the avoidance of phase noise is crucial. In both of these modulation schemes it is very important to avoid operating near the resonance peak of the laser, where RIN peaks and a phase shift occurs. Both of these phenomena have a deleterious effect on the noise performance of the system. The further below the resonance peak the fiber optic system can be designed to operate, the better its noise performance will be. Clearly, demands on the system designer are reduced by the availability of lasers with higher resonance frequencies and modulation bandwidths.
  • Fabrication of single transverse mode semiconductor lasers with modulation bandwidth in excess of 15 GHz depends heavily upon both the accurate control of the active layer doping, width, and thickness, and upon providing a lateral optical cladding of the active layer which minimizes surface recombination and carrier leakage while not affecting the single transverse modal properties of the laser.
  • a low capacitance and low series resistance structure is required to minimize electrical parasitics.
  • High frequency single transverse mode semiconductor lasers have been achieved by constricted mesa (Bowers, et al., "High-speed InGaAsP constricted mesa lasers", IEEE J. Quantum Electron., Vol. QE-22, pp. 833-884, June 1986), mass transport (Liau, et al., "A novel technique for GalnAsP/InP buried heterostructure fabrication", Appl. Phys. Lett., Vol. 40, pp.568-570, Apr. 1982) and vapor phase regrowth (Su, et al. , "Ultra-high frequency modulation of InGaAsP lasers", Tech. Dig. Conf. Optical Fiber Communication, pp. 90-91, Feb.
  • an indium phosphide-based semiconductor laser is produced such that the epitaxial layer configurations (composition, thickness and doping) are appropriate for high frequency laser applications. This is accomplished by sandwiching a thin, narrow active layer of small bandgap material between thicker, larger bandgap material and filling the interstices on each side of the active layer with a semi-insulating layer in such manner that the sidewalls of the device form a smooth surface, thereby reducing the homojunction capacitance and carrier leakage.
  • the method of fabrication of a 1.3 ⁇ InGaAsP laser with three dB bandwidth of 24 GHz and intrinsic resonance frequencies uses a dry-etched vapor phase regrowth structure to fabricate lasers from LPE-grown, 1.3 ⁇ double heterostructure material, or any suitable epitaxial growth technique, i.e., (VPE, MOCVD, and MBE) that will produce InGaAsP/InP double heterostructure material.
  • the method comprises the steps of dry-etching channels, followed by selective etching to undercut the active layer, then InP regrowth on the sidewalls in a halide vapor phase system.
  • SiO-, and the p- and n-contact metallizations are alloyed ZnAu and SnAu, respectively, using a flood exposure technique.
  • FIG. 1 is a cross-sectional view of a semiconductor wafer from which an embodiment of the laser of the present invention can be formed;
  • FIGS. 2a through 2f are cross-sectional views of a portion of the wafer during various stages of fabrication of the embodiment of Fig. 1;
  • FIGS. 3a and 3b are cross-sectional views of a portion of the wafer during various stages of fabrication of the embodiment of Fig. 1;
  • FIGS. 4a through 4d are cross-sectional views of a portion of the wafer during various stages of fabrication of the embodiment of Fig. 1;
  • FIG. 5 is a perspective view in cross-section showing the structure of the injection type semiconductor laser embodiment of the present invention
  • FIGS. 6, 7, 8, and 9 are diagrams illustrating operating characteristics of an embodiment of a laser in accordance with the present invention. Best Mode for Carrying out the Invention
  • An injection type semiconductor laser device embodying the present invention will now be described in detail by reference to a laser device of a InGaAsP-InP double heterostructure as an example.
  • FIG. 1 A typical wafer as an initial starting point in the fabrication process is illustrated in FIG. 1.
  • the substrate is typically composed of crystalline InP and is covered by a buffer layer of n-InP of about 1-2 microns thick.
  • the active layer is composed of In _._ Galois As 6 _ P ., deliberately and has a thickness ideally of 0.2 microns.
  • On top of the active layer is a cladding layer of InP approximately 1 micron thick.
  • the fourth layer comprises a cap layer of In g0 Ga 2 n As 0 P 60 ° ⁇ from 0.2-0.3 microns in thickness.
  • the initial step to produce the laser of the present invention is to define the mesa.
  • the mesa width is deter ⁇ mined by the desired final active layer width, the desired amount of regrowth on both sides of the active layer and any processing variables encountered in the photolithographic, dry etching and wet etching steps.
  • the initial mask for the mesa would be in the order of 2.0 ; microns.
  • the first step is to deposit a mask material, for example, 0.3 microns of SiO ⁇ , on the epitaxial cap layer that is compatible with said layer and with the dry and wet processing chemistries used in defining the mesa.
  • the next step is to apply a layer of photoresist material using standard photolithographic techniques.
  • the next step is to align and delineate stripes in the photoresist along the (110) crystallographic direction of the InP material, as shown in Fig. 2a.
  • the exposed mask material is then plasma etched in accordance with well known plasma etching techniques, for example utilizing CF. , to expose the underlying InGaAsP cap material.
  • plasma etching in accordance with well known plasma etching techniques, for example C ForceH_/H_ , to etch through the InGaAsP cap layer and stopping in the InP cladding layer in regions not protected by the SiO ⁇ mask, resulting in a wafer as shown in Fig. 2b.
  • the wafer is then subjected to a wet chemical etch of a 1:9 ratio of HC1 and H_P0 4 acid mixture to selectively and anisotropically remove the InP cladding layer, using the InGaAsP cap layer as a mask, resulting in a wafer having the appearance as shown in Fig. 2c.
  • the wafer is again subjected to a plasma etch with the SiOgon, the cap and the cladding layer now acting as a mask to etch through the InGaAsP active layer, stopping in the InP buffer layer, resulting in a wafer as shown in Fig. 2d.
  • the wafer is again subjected to a wet chemical etch using the aforementioned HC1 and H_PO. acid mixture for a time sufficient to remove a portion, approximately one-half, of the exposed InP buffer layer, using the InGaAsP active layer as a mask, as shown in Fig. 2e.
  • the wafer is again exposed to wet chemical etching, this time in a solution of K_Fe(CN) fi :KOH:H 0, which is well known, to selectively etch the InGaAsP cap and active layers laterally as shown in Fig. 2f.
  • the solution etches the active layer at about twice the rate of the cap layer. Since the amount of lateral etching required is only on the order of 0.4 microns or less, the resulting active layer is very uniform across the entire wafer.
  • the SiOtude mask is removed by hydrofluoric acid.
  • the Wafer is then exposed to vapor phase epitaxial growth of an overlayer of semi-insulating InP as shown in FIG. 3A.
  • the amount of regrowth is limited to minimize intentional diffusion of dopants into and out of the various device layers thus degrading the quality of the devices.
  • the exact amount and uniformity of regrowth is critical only to the extent that the undercut regions be completely filled laterally.
  • the wafer is again etched in the 1:9 hydrochloric and phosphoric acid mixture, leaving an unetched amount of regrowth cladding on the side, wall of the active layer, the lateral dimension of this cladding being determined solely by the relative undercutting of the active layer with respect to the cap layer, and in view of the relative etch rate of the lateral etching and the amount of etching of the active layer (i.e. about 0.3-0.4 microns) the width of the cladding will be about 0.1-0.2 micron uniformly along the active layer.
  • This technique automatically controls the width of the regrown InP and symmetrically aligns the regrown material around the active layer.
  • the active layer width is poorly controlled due to oversized mesa and/or the amount of regrowth is relatively large (e.g. greater than 1 micron) or highly non-uniform for regrowth of less than 0.5 microns.
  • the advantage of achieving a thin regrown region is that it reduces homojunction capacitance and carrier leakage.
  • a dielectric material for example approximately 0.4 microns SiO_, is deposited on the mesa side of the wafer, conforming to and encapsulating the mesa, the channels and covering the cap layer.
  • This dielectric serves a number of purposes; it defines the p-contact using localized flood exposure, as disclosed in the cross-referenced application; it acts as a diffusion barrier during the diffusion step; it electrically isolates the p-metal overlay from the cap layer and is intrinsic to the reduction of the electrical parasitics of the device.
  • the contact openings are formed by using the localized flood exposure described in the copending application filed of even date herewith and assigned to the same assignee as the present application and is incorporated herein by reference thereto.
  • the entire mesa top and an appreciable amount of the mesa sidewall is bared as is shown in FIG. 4a.
  • Diffusion of an acceptor dopant, such as zinc, to p-type epitaxial layers can be performed as shown in FIG. 4b so that the entire exposed surface is electrically modified to yield a higher differential gain, lower resistivity and lower contact resistance.
  • the active layer can be heavily doped beyond the levels possible in as-grown epitaxial layers, a necessity for achieving high frequency operation.
  • Ohmic contact metal may then be deposited over the entire exposed surface such that the largest area of contact possible in this structure is achieved as shown in FIG.
  • the substrate, or bottom, side of the wafer is thinned to facilitate cleaving.
  • An electrode is formed on the bottom of the wafer, opposite to the ohmic contact on the top of the mesa structure, the wafer is divided into chips and made into laser devices as illustrated in FIG. 5 in a manner /well known in the art.
  • the intrinsic resonance of a semiconductor laser is proportional to the product of the total loss, the differential gain ⁇ g/ ⁇ N, and the photon density. If these parameters are optimized, it is then necessary to minimize electrical parasitics (i.e., the RC time constant) to fully exploit the modulation capabilities of the laser.
  • This invention utilizes a dry-etched, vapor-phase regrowth structure to fabricate lasers from LPE-grown, 1.3 ⁇ m double heterostructure material. This technique is a modification of the wet-etched, vapor-phase-regrowth technique previously used.
  • SiO_ is used as a mask and for electrical isola- tion, and the p- and n-contact metallizations are alloyed ZnAu and SnAu, respectively.
  • the dry-etched perpendicular sidewalls result in two improvements compared to previously wet-etched vapor-phase-regrown lasers: 1) well-controlled regrowth widths of about 0.2 ⁇ m per side.
  • a third improvement was aimed at increasing the photon density in the laser cavity. Because of the perpendicular mesa sidewalls and the minimized regrowth, it was possible to accurately control the width of the emitting region to 0.9 ⁇ 0.1 ⁇ m. This dimension, coupled with active layer thicknesses of about 0.2 ⁇ m and cavity lengths of 100 to 130 ⁇ m, resulted in extremely high photon densities in a single spatial mode, even at moderate drive currents.
  • Lasers made in accordance with this invention have achieved a modulation bandwidth of 24 GHz at room tempera ⁇ ture and intrinsic resonance frequencies in excess of 22 GHz. The lasers are also characterized by a linear power- current curve, resulting in excellent modulation efficien- cies even at 24 GHz.
  • the swept frequency response (S-,-) is shown in FIG. 6 of a laser with a 3-dB bandwidth of 24 GHz.
  • the 3-dB bandwidths for lasers according to this invention ranged from 18 to 24 GHz for lasers with cavity lengths of about 130 microns.
  • FIG. 6 shows that the modulation efficiency at 24 GHz has dropped only 3 dB with a 100 mA bias current compared to its low-frequency, low-bias values.
  • the intrinsic resonance frequency, f of the lasers was found from the measured relative intensity noise (RIN) spectral density.
  • the RIN spectrum shown in FIG.7, indi ⁇ cates that even at bias currents as low as 60 mA the response peak is beyond 18 GHz.
  • These data, together with the S ? -. data of FIG. 6, indicate that the intrinsic resonance of this laser is in excess of 22 GHz.
  • the resonance frequency, f , and damping rate, ⁇ are accurately determined, free of any electrical parasitics.
  • the maximum achievable bandwidth in the absence of parasitics i.e. limited only by damping
  • FIG. 8 shows the fitted . ⁇ versus fo for the same laser. From the slope, K is found to be 0.19 ns, while more typical values are approximately 0.3 ns. These values of K suggest that the maximum damping-limited bandwidth could be as high as 44 GHz.
  • the intrinsic resonance frequency is plotted as a function of the square root of the optical power in FIG.
  • a record modulation bandwidth of 24 GHz at room-temperature is reported for 1.3 ⁇ m lasers fabricated using a dry-etched, vapor phase regrowth technique. This and other dynamic characteristics are significantly better than the previous record of 22 GHz set by 1.3 ⁇ m VPR-BH lasers, and the 15 to 18 GHz bandwidths which are more typical for high-frequency InGaAsP laser structures. Furthermore, we observe intrinsic resonance frequencies in excess of 22 GHz, the highest yet obtained for either conventional double heterostructure or quantum well InGaAsP lasers. These improvements are accomplished by using a dry-etched, vapor phase regrowth technique. These lasers exhibit reduced leakage currents and electrical parasitics, and are characterized by a linear power-current curve, resulting in excellent modulation efficiencies even at 24 GHz.

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Abstract

On fabrique un laser à semi-conducteurs ayant une largeur de bande à modulation élevée en utilisant une couche supérieure InGaAsP (14) et une couche active InGaAsP (12) dont les structures cristallines sont différentes. Des gorges (21 et 22) sont formées par attaque à l'acide par procédé anisotrope dans les couches supérieure (14), de placage (13) et active (12) et partiellement dans la couche intermédiaire (11). Les couches active (12) et supérieure (14) sont attaquées latéralement et un matériau semi-isolant (30) est déposé sur les parois latérales. Une autre attaque à l'acide ne laisse qu'une mince paroi (31 et 32) de matériau semi-isolant autour de la couche active (12). On a fabriqué avec succès à l'aide de ce procédé des lasers InGaAsp 1,3 mum avec des largeurs de bandes 3 dB de 24 GHz et des fréquences de résonance intrinsèque dépassant 22 GHz. Il s'agit de la plus grande largeur de bande jamais enregistrée pour un laser à semi-conducteurs et de la plus importante fréquence de résonance pour des lasers InGaAsP. On a observé d'excellentes efficacités de modulation à des fréquences élevées.A semiconductor laser having a high modulation bandwidth is manufactured using an InGaAsP upper layer (14) and an InGaAsP active layer (12) with different crystal structures. Grooves (21 and 22) are formed by acid attack by an anisotropic process in the upper (14), plating (13) and active (12) layers and partially in the intermediate layer (11). The active (12) and upper (14) layers are attacked laterally and a semi-insulating material (30) is deposited on the side walls. Another acid attack leaves only a thin wall (31 and 32) of semi-insulating material around the active layer (12). Using this process, 1.3 mum InGaAsp lasers have been successfully manufactured with 3 dB bandwidths of 24 GHz and intrinsic resonance frequencies exceeding 22 GHz. It is the largest bandwidth ever recorded for a semiconductor laser and the highest resonant frequency for InGaAsP lasers. Excellent modulation efficiencies have been observed at high frequencies.

Description

NEW STRUCTURE AND METHOD FOR FABRICATING INDIUM PHOSPHIDE/INDIUM GALLIUM ARSENIDE PHOSPHIDE BURIED HETEROSTRUCTURE SEMICONDUCTOR LASERS
This application is related to an application entitled "Processing Method for Fabricating Electrical Contacts to Mesa Structures in Semiconductor Devices,"
Serial No. filed simultaneously by the same applicant. Technical Field
This invention pertains to semiconductor lasers and more particularly to high modulation bandwidth single transverse mode semiconductor lasers. Background Art As fiber optic communication systems continue to push to even higher data rates and larger bandwidths, the availability of reproducible and reliable high-speed lasers becomes increasingly important. This is particularly true for microwave modulation schemes like subcarrier multiplexing, where low relative intensity noise (RIN) is very important, or for phase modulated systems, where the avoidance of phase noise is crucial. In both of these modulation schemes it is very important to avoid operating near the resonance peak of the laser, where RIN peaks and a phase shift occurs. Both of these phenomena have a deleterious effect on the noise performance of the system. The further below the resonance peak the fiber optic system can be designed to operate, the better its noise performance will be. Clearly, demands on the system designer are reduced by the availability of lasers with higher resonance frequencies and modulation bandwidths.
Fabrication of single transverse mode semiconductor lasers with modulation bandwidth in excess of 15 GHz depends heavily upon both the accurate control of the active layer doping, width, and thickness, and upon providing a lateral optical cladding of the active layer which minimizes surface recombination and carrier leakage while not affecting the single transverse modal properties of the laser. In addition, a low capacitance and low series resistance structure is required to minimize electrical parasitics.
High frequency single transverse mode semiconductor lasers have been achieved by constricted mesa (Bowers, et al., "High-speed InGaAsP constricted mesa lasers", IEEE J. Quantum Electron., Vol. QE-22, pp. 833-884, June 1986), mass transport (Liau, et al., "A novel technique for GalnAsP/InP buried heterostructure fabrication", Appl. Phys. Lett., Vol. 40, pp.568-570, Apr. 1982) and vapor phase regrowth (Su, et al. , "Ultra-high frequency modulation of InGaAsP lasers", Tech. Dig. Conf. Optical Fiber Communication, pp. 90-91, Feb. 1986) techniques. These structures have broad mesa tops so as to reduce series resistance and facilitate the formation of ohmic contacts. In order to achieve this structure, the processes reported to date require selective wet chemical etching of the active layer of 4 microns or more to reduce its width and/or the epitaxial growth of thick layers of high quality p-doped, semi-insulating, or pn blocking layer configurations. These regrown materials are subject to unintentional doping to and from the p-type device structure layers during the regrowth process and tend to be electrically leaky which severely limits the achievable output power and bandwidth. (Ohtoshi, et al. , "Current leakage mechanism in InGaAsP/InP buried heterostructure lasers", 11th IEEE International Semiconductor Laser Conference, Boston, Mass., 1988). In addition, wet chemical etching through dielectric masks, used to form the initial mesa structure, is inherently non-uniform so that control of active layer width, a necessity for high bandwidth single transverse mode operation, is very diffi¬ cult resulting in low yield and non-reproducible results. Alternatively, the fabrication of narrow mesa tops leads to the additional problems of high series resistance and difficulty in photolithographically defining and forming ohmic contacts. Disclosure of Invention
In a first aspect of the invention, an indium phosphide-based semiconductor laser is produced such that the epitaxial layer configurations (composition, thickness and doping) are appropriate for high frequency laser applications. This is accomplished by sandwiching a thin, narrow active layer of small bandgap material between thicker, larger bandgap material and filling the interstices on each side of the active layer with a semi-insulating layer in such manner that the sidewalls of the device form a smooth surface, thereby reducing the homojunction capacitance and carrier leakage.
In a second aspect of the invention, the method of fabrication of a 1.3μ InGaAsP laser with three dB bandwidth of 24 GHz and intrinsic resonance frequencies uses a dry-etched vapor phase regrowth structure to fabricate lasers from LPE-grown, 1.3μ double heterostructure material, or any suitable epitaxial growth technique, i.e., (VPE, MOCVD, and MBE) that will produce InGaAsP/InP double heterostructure material. The method comprises the steps of dry-etching channels, followed by selective etching to undercut the active layer, then InP regrowth on the sidewalls in a halide vapor phase system. SiO-, and the p- and n-contact metallizations are alloyed ZnAu and SnAu, respectively, using a flood exposure technique.
Brief Description of the Drawings In the drawings:
FIG. 1 is a cross-sectional view of a semiconductor wafer from which an embodiment of the laser of the present invention can be formed; FIGS. 2a through 2f are cross-sectional views of a portion of the wafer during various stages of fabrication of the embodiment of Fig. 1;
FIGS. 3a and 3b are cross-sectional views of a portion of the wafer during various stages of fabrication of the embodiment of Fig. 1;
FIGS. 4a through 4d are cross-sectional views of a portion of the wafer during various stages of fabrication of the embodiment of Fig. 1; FIG. 5 is a perspective view in cross-section showing the structure of the injection type semiconductor laser embodiment of the present invention;
FIGS. 6, 7, 8, and 9 are diagrams illustrating operating characteristics of an embodiment of a laser in accordance with the present invention. Best Mode for Carrying out the Invention
An injection type semiconductor laser device embodying the present invention will now be described in detail by reference to a laser device of a InGaAsP-InP double heterostructure as an example.
A typical wafer as an initial starting point in the fabrication process is illustrated in FIG. 1. The substrate is typically composed of crystalline InP and is covered by a buffer layer of n-InP of about 1-2 microns thick. The active layer is composed of In _._ Ga „ As 6_ P .,„ and has a thickness ideally of 0.2 microns. On top of the active layer is a cladding layer of InP approximately 1 micron thick. The fourth layer comprises a cap layer of In g0 Ga 2nAs 0P 60 °^ from 0.2-0.3 microns in thickness. A wafer of such composition and structure can be made by techniques well known in the art by chemical vapor deposition (CVD), liquid phase epitaxy (LPE) or a combination thereof and, and include all compositions of In., Ga As P._ that would produce high frequency lasers emitting at λ = 1.25 μm to λ = 1.58 μm and all wavelengths between. The initial step to produce the laser of the present invention is to define the mesa. The mesa width is deter¬ mined by the desired final active layer width, the desired amount of regrowth on both sides of the active layer and any processing variables encountered in the photolithographic, dry etching and wet etching steps. As an example, if a one-micron 0.1 micron active layer width with 0.1 - 0.2 microns of regrowth per side was desired, the initial mask for the mesa would be in the order of 2.0 ; microns. The first step is to deposit a mask material, for example, 0.3 microns of SiO~, on the epitaxial cap layer that is compatible with said layer and with the dry and wet processing chemistries used in defining the mesa. The next step is to apply a layer of photoresist material using standard photolithographic techniques. The next step is to align and delineate stripes in the photoresist along the (110) crystallographic direction of the InP material, as shown in Fig. 2a. The exposed mask material is then plasma etched in accordance with well known plasma etching techniques, for example utilizing CF. , to expose the underlying InGaAsP cap material. After the photoresist is removed, the wafer is subjected to plasma etching in accordance with well known plasma etching techniques, for example C„H_/H_ , to etch through the InGaAsP cap layer and stopping in the InP cladding layer in regions not protected by the SiO^ mask, resulting in a wafer as shown in Fig. 2b. The wafer is then subjected to a wet chemical etch of a 1:9 ratio of HC1 and H_P04 acid mixture to selectively and anisotropically remove the InP cladding layer, using the InGaAsP cap layer as a mask, resulting in a wafer having the appearance as shown in Fig. 2c. The wafer is again subjected to a plasma etch with the SiO„, the cap and the cladding layer now acting as a mask to etch through the InGaAsP active layer, stopping in the InP buffer layer, resulting in a wafer as shown in Fig. 2d. The wafer is again subjected to a wet chemical etch using the aforementioned HC1 and H_PO. acid mixture for a time sufficient to remove a portion, approximately one-half, of the exposed InP buffer layer, using the InGaAsP active layer as a mask, as shown in Fig. 2e.
The wafer is again exposed to wet chemical etching, this time in a solution of K_Fe(CN)fi:KOH:H 0, which is well known, to selectively etch the InGaAsP cap and active layers laterally as shown in Fig. 2f. In view of the difference in composition of the active layer and the cap layer, the solution etches the active layer at about twice the rate of the cap layer. Since the amount of lateral etching required is only on the order of 0.4 microns or less, the resulting active layer is very uniform across the entire wafer. With the mesa, the active layer width and the cap width now defined, the SiO„ mask is removed by hydrofluoric acid.
The Wafer is then exposed to vapor phase epitaxial growth of an overlayer of semi-insulating InP as shown in FIG. 3A. The amount of regrowth is limited to minimize intentional diffusion of dopants into and out of the various device layers thus degrading the quality of the devices. The exact amount and uniformity of regrowth is critical only to the extent that the undercut regions be completely filled laterally. The wafer is again etched in the 1:9 hydrochloric and phosphoric acid mixture, leaving an unetched amount of regrowth cladding on the side, wall of the active layer, the lateral dimension of this cladding being determined solely by the relative undercutting of the active layer with respect to the cap layer, and in view of the relative etch rate of the lateral etching and the amount of etching of the active layer (i.e. about 0.3-0.4 microns) the width of the cladding will be about 0.1-0.2 micron uniformly along the active layer. This technique automatically controls the width of the regrown InP and symmetrically aligns the regrown material around the active layer. This is in contrast to the other techniques where either the active layer width is poorly controlled due to oversized mesa and/or the amount of regrowth is relatively large (e.g. greater than 1 micron) or highly non-uniform for regrowth of less than 0.5 microns. The advantage of achieving a thin regrown region is that it reduces homojunction capacitance and carrier leakage.
A dielectric material, for example approximately 0.4 microns SiO_, is deposited on the mesa side of the wafer, conforming to and encapsulating the mesa, the channels and covering the cap layer. This dielectric serves a number of purposes; it defines the p-contact using localized flood exposure, as disclosed in the cross-referenced application; it acts as a diffusion barrier during the diffusion step; it electrically isolates the p-metal overlay from the cap layer and is intrinsic to the reduction of the electrical parasitics of the device. The contact openings are formed by using the localized flood exposure described in the copending application filed of even date herewith and assigned to the same assignee as the present application and is incorporated herein by reference thereto. In accordance with this method, the entire mesa top and an appreciable amount of the mesa sidewall is bared as is shown in FIG. 4a. Diffusion of an acceptor dopant, such as zinc, to p-type epitaxial layers can be performed as shown in FIG. 4b so that the entire exposed surface is electrically modified to yield a higher differential gain, lower resistivity and lower contact resistance. By controlling the amount of exposed sidewall, a feature of this technique, and the diffusion time and temperature, the active layer can be heavily doped beyond the levels possible in as-grown epitaxial layers, a necessity for achieving high frequency operation. Ohmic contact metal may then be deposited over the entire exposed surface such that the largest area of contact possible in this structure is achieved as shown in FIG. 4c and thus the lowest possible contact resistance in this structure is achieved without increasing the parasitic junction capaci- tance. In addition, this ohmic metal contact process results in thermal properties that are superior to the other structures. A variety of other process techniques such a ■ thick dielectrics to reduce parasitic chip capacitance to permit "epi down" mounting are performed. A resulting structure is shown in FIG. 4d.
The substrate, or bottom, side of the wafer is thinned to facilitate cleaving. An electrode is formed on the bottom of the wafer, opposite to the ohmic contact on the top of the mesa structure, the wafer is divided into chips and made into laser devices as illustrated in FIG. 5 in a manner /well known in the art.
The intrinsic resonance of a semiconductor laser is proportional to the product of the total loss, the differential gain Δg/ΔN, and the photon density. If these parameters are optimized, it is then necessary to minimize electrical parasitics (i.e., the RC time constant) to fully exploit the modulation capabilities of the laser. Past work on ultra-high-frequency diode lasers has been plagued by the difficulty of fabricating lasers with very small active areas, low leakage, and low electrical parasitics. This invention utilizes a dry-etched, vapor-phase regrowth structure to fabricate lasers from LPE-grown, 1.3 μm double heterostructure material. This technique is a modification of the wet-etched, vapor-phase-regrowth technique previously used.
Basically, it consists of dry etching channels, followed by selective etching to undercut the active layer, then InP regrowth on the sidewalls in a halide vapor phase system. SiO_ is used as a mask and for electrical isola- tion, and the p- and n-contact metallizations are alloyed ZnAu and SnAu, respectively. The dry-etched perpendicular sidewalls result in two improvements compared to previously wet-etched vapor-phase-regrown lasers: 1) well-controlled regrowth widths of about 0.2 μm per side. Since this regrowth forms the p-n blocking homojunctions, limiting this width reduces homojunction leakage (thus improving the linearity of the power-current curves) and minimizes diffusion capacitance (thus extending the RC limit); 2) the entire top of the mesa was contacted, using a flood exposure technique, thus reducing the contact and series resistance of the device.
A third improvement was aimed at increasing the photon density in the laser cavity. Because of the perpendicular mesa sidewalls and the minimized regrowth, it was possible to accurately control the width of the emitting region to 0.9±0.1μm. This dimension, coupled with active layer thicknesses of about 0.2 μm and cavity lengths of 100 to 130μm, resulted in extremely high photon densities in a single spatial mode, even at moderate drive currents. Lasers made in accordance with this invention have achieved a modulation bandwidth of 24 GHz at room tempera¬ ture and intrinsic resonance frequencies in excess of 22 GHz. The lasers are also characterized by a linear power- current curve, resulting in excellent modulation efficien- cies even at 24 GHz. The swept frequency response (S-,-) is shown in FIG. 6 of a laser with a 3-dB bandwidth of 24 GHz. The 3-dB bandwidths for lasers according to this invention ranged from 18 to 24 GHz for lasers with cavity lengths of about 130 microns. FIG. 6 shows that the modulation efficiency at 24 GHz has dropped only 3 dB with a 100 mA bias current compared to its low-frequency, low-bias values.
The intrinsic resonance frequency, f , of the lasers was found from the measured relative intensity noise (RIN) spectral density. The RIN spectrum, shown in FIG.7, indi¬ cates that even at bias currents as low as 60 mA the response peak is beyond 18 GHz. These data, together with the S?-. data of FIG. 6, indicate that the intrinsic resonance of this laser is in excess of 22 GHz. By fitting the RIN data to the standard single-mode rate equation solution, the resonance frequency, f , and damping rate, τ, are accurately determined, free of any electrical parasitics. The maximum achievable bandwidth in the absence of parasitics (i.e. limited only by damping) can then be estimated, as shown by Olshansky, et al., IEEE J. Quan. Electron. QE 23, p. 1410 (1987), using the relationship where K= τ/f o . FIG. 8 shows the fitted . τ versus fo for the same laser. From the slope, K is found to be 0.19 ns, while more typical values are approximately 0.3 ns. These values of K suggest that the maximum damping-limited bandwidth could be as high as 44 GHz.
The intrinsic resonance frequency is plotted as a function of the square root of the optical power in FIG.
9. The slope of this line is 8.9 GHz/mW ' . We believe this to be the highest value ever reported for a semiconductor laser, more typical values of this slope are
1/2 5 to 6 GHz/mW for semiconductor lasers. Because of the extremely high value of this slope, large bandwidths are obtained at relatively low operating currents. Specifically, a 3 dB bandwidth of 20 GHz is achieved with as little as 55 mA of drive current. This may result in improved long-term reliability compared to previous high-frequency lasers.
A record modulation bandwidth of 24 GHz at room-temperature is reported for 1.3 μm lasers fabricated using a dry-etched, vapor phase regrowth technique. This and other dynamic characteristics are significantly better than the previous record of 22 GHz set by 1.3 μm VPR-BH lasers, and the 15 to 18 GHz bandwidths which are more typical for high-frequency InGaAsP laser structures. Furthermore, we observe intrinsic resonance frequencies in excess of 22 GHz, the highest yet obtained for either conventional double heterostructure or quantum well InGaAsP lasers. These improvements are accomplished by using a dry-etched, vapor phase regrowth technique. These lasers exhibit reduced leakage currents and electrical parasitics, and are characterized by a linear power-current curve, resulting in excellent modulation efficiencies even at 24 GHz.
We have demonstrated 1.3 μm lasers with intrinsic resonance frequencies in excess of 22 GHz, and 3dB band- widths of up to 24 GHz. This is a significant improvement over the previous record of 22 GHz for the 3 dB bandwidth. These advances were achieved primarily by increasing the photon density in the lasing cavity (to increase the intrinsic resonance frequency), and by minimizing electrical parasitics. It is expected that these devices will play an important role in the realization of extremely broadband fiber optic systems in general, and in microwave multiplexed systems such as subcarrier systems in particular.

Claims

CLAIMS :
1. A semiconductor device having a semiconductor assembly for generating laser beams comprising: a substrate for crystal growth, said substrate having a first semiconductor layer on a first major surface serving as a buffer layer; a second semiconductor layer formed directly on said first layer by crystal growth so that said second layer is in direct contact with said first semiconductor layer, and serves as an active layer; a third semiconductor layer formed on said second layer, said first and third layers having a smaller refractive index and having a broader band gap than said second layer, and serving as a cladding layer; a fourth semiconductor layer formed on said third semiconductor layer, said fourth layer serving as a cap layer and* being a such composition as to act as a mask layer while etching selected portions of said first three layers; a first electrode on the upper surface of said assem¬ bly; a second electrode on the lower surface of the said assembly; and means for providing optical feedback so as to generate said laser beams, wherein, in a cross-section of said semiconductor material assembly perpendicular to the direction of said laser beams, said second layer is narrower than said other three layers and the interstitial space on either side of the active layer is filled with a semi-insulating material.
2. A semiconductor laser device as set forth in claim 1, wherein said second semiconductor layer is between 0.15 to 0.25 microns thick and between 1.5 and 1.7 microns wide.
3. A semiconductor laser device as set forth in claim 1 or 2, wherein the width of said semi-insulating material filling the interstitial space on either side of the active layer is 0.15 to 0.35 microns.
4. A semiconductor laser device as set forth in claim 1 or 2, wherein said second semiconductor layer is composed of In 7_ Ga ?„ As ,._, P _„ and said fourth semiconductor layer is composed of In „ Ga _ As . P fi.
5. A semiconductor laser device as set forth in claim 1 or 2, wherein said first semiconductor layer is composed of n-InP and said third semiconductor layer is composed of p-InP.
6. A semiconductor laser device as set forth in claim 1 or 2, wherein said first semiconductor layer is composed of p-InP and said third semiconductor layer is composed of n-InP.
7. A semiconductor laser device as set forth in claim 1 or 2. wherein said semi-insulating material filling the interstitial space on each side of said active layer is InP.
8. A method of fabricating a semiconductor laser having an epitaxial layer wafer configuration comprising a substrate layer, a buffer layer, an active layer, a cladding layer, and a cap layer, wherein said wafer configuration is fabricated for high frequency laser applications, comprising the steps of: a. depositing on said cap layer of said wafer a layer of mask material compatible with said cap layer; b. applying a layer of photoresist material on said mask layer; c. delineating stripes in said photoresist layer along a particular crystallographic direction of one of said wafer layers, thereby exposing window stripes of said mask layer; d. plasma etching said exposed windows of said mask layer to expose said underlying cap layer to form exposed window stripes of said cap layer; . removing said photoresist; g. subjecting regions of said wafer not protected by said mask material to plasma etching to completely etch said exposed cap layer windows and to partially etch through said cladding layer; h. subjecting said wafer to a wet chemical etch mixture to selectively and anistropically remove the exposed material of said cladding layer, using said cap layer as an effective mask, whereby window stripes of said active layer are exposed; i. subjecting said wafer to a plasma etch mixture wherein said mask material, cap layer, and cladding layer serve as an effective mask to etch through said active layer and partially etch through said buffer layer; j. subjecting said wafer to a wet chemical etch for a time sufficient to remove a selected portion of the exposed buffer layer, using said active layer as an effective mask; k. exposing said wafer to a wet chemical etching mixture to selectively and concurrently etch exposed regions of said cap layer and said active layer in a lateral direction to create spaces in sidewalls of said cap and active layer, wherein said etching mixture etches said active layer at a known faster rate than said cap layer; 1. removing said mask layer; m. exposing said entire wafer to an epitaxial growth of an overlayer of a semi-insulating material; n. etching said wafer to leave an unetched amount of regrowth cladding only in the lateral side wall spaces of said active layer wherein a lateral dimension of said regrowth cladding is determined by the relative undercutting of said active layer with respect to said cap layer; o. depositing on the mesa side of said wafer a dielectric material which conforms to and encapsulates said mesa and a channel covering said cap layer; p. forming contact openings on said wafer by performing localized flood exposure of said wafer to controllably remove said dielectric material from the top of said mesa and from a substantial portion of the mesa sidewall; q. diffusing an appropriate dopant into said contact openings; r. depositing ohmic contact metal over the entirety of said contact openings; s. thinning said substrate layer; and t. forming an electrode on said thinned substrate layer.
9. A method of making a semiconductor device as set forth in claim 8, wherein said second layer is composed of
Inx Ga.1-x AsyP1-,-y in which x = .73 and y J = .67 and said fourth layer is composed of In Ga1_ As. Pη_t in which s = .8 and t = .4.
10. A method of making a semiconductor laser device as set forth in claim 8 or 9, in which the lateral etching of said second and fourth layers is accomplished by a solution of K~Fe(CN)6 :K0H:H20.
EP19910918807 1990-09-14 1991-09-12 New structure and method for fabricating indium phosphide/indium gallium arsenide phosphide buried heterostructure semiconductor lasers Withdrawn EP0500925A4 (en)

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Families Citing this family (51)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0513881A (en) * 1990-11-28 1993-01-22 Matsushita Electric Ind Co Ltd Manufacture of semiconductor laser
US5755752A (en) * 1992-04-24 1998-05-26 Segal; Kim Robin Diode laser irradiation system for biological tissue stimulation
USRE35512F1 (en) * 1992-07-20 1998-08-04 Presstek Inc Lithographic printing members for use with laser-discharge imaging
AU674518B2 (en) * 1992-07-20 1997-01-02 Presstek, Inc. Lithographic printing plates for use with laser-discharge imaging apparatus
US5379698A (en) * 1992-07-20 1995-01-10 Presstek, Inc. Lithographic printing members for use with laser-discharge imaging
US5351617A (en) * 1992-07-20 1994-10-04 Presstek, Inc. Method for laser-discharge imaging a printing plate
US5339737B1 (en) * 1992-07-20 1997-06-10 Presstek Inc Lithographic printing plates for use with laser-discharge imaging apparatus
US5353705A (en) * 1992-07-20 1994-10-11 Presstek, Inc. Lithographic printing members having secondary ablation layers for use with laser-discharge imaging apparatus
KR100303279B1 (en) * 1994-08-27 2001-12-01 윤종용 Semiconductor laser diode and manufacturing method therefor
US5877038A (en) * 1996-11-27 1999-03-02 The Regents Of The University Of California Method of making a vertical cavity laser
US6167072A (en) * 1997-06-06 2000-12-26 University Of Florida Modulated cap thin p-clad semiconductor laser
US7058112B2 (en) 2001-12-27 2006-06-06 Finisar Corporation Indium free vertical cavity surface emitting laser
US6975660B2 (en) 2001-12-27 2005-12-13 Finisar Corporation Vertical cavity surface emitting laser including indium and antimony in the active region
US7257143B2 (en) * 1998-12-21 2007-08-14 Finisar Corporation Multicomponent barrier layers in quantum well active regions to enhance confinement and speed
US7095770B2 (en) 2001-12-20 2006-08-22 Finisar Corporation Vertical cavity surface emitting laser including indium, antimony and nitrogen in the active region
US7167495B2 (en) * 1998-12-21 2007-01-23 Finisar Corporation Use of GaAs extended barrier layers between active regions containing nitrogen and AlGaAs confining layers
US6922426B2 (en) 2001-12-20 2005-07-26 Finisar Corporation Vertical cavity surface emitting laser including indium in the active region
US7286585B2 (en) * 1998-12-21 2007-10-23 Finisar Corporation Low temperature grown layers with migration enhanced epitaxy adjacent to an InGaAsN(Sb) based active region
US20030219917A1 (en) * 1998-12-21 2003-11-27 Johnson Ralph H. System and method using migration enhanced epitaxy for flattening active layers and the mechanical stabilization of quantum wells associated with vertical cavity surface emitting lasers
US7435660B2 (en) * 1998-12-21 2008-10-14 Finisar Corporation Migration enhanced epitaxy fabrication of active regions having quantum wells
US7408964B2 (en) 2001-12-20 2008-08-05 Finisar Corporation Vertical cavity surface emitting laser including indium and nitrogen in the active region
US6714573B2 (en) 2000-08-22 2004-03-30 The Regents Of The University Of California Contact scheme for intracavity-contacted vertical-cavity surface-emitting laser
US6631154B2 (en) 2000-08-22 2003-10-07 The Regents Of The University Of California Method of fabricating a distributed Bragg reflector having enhanced thermal and electrical properties
US6822995B2 (en) * 2002-02-21 2004-11-23 Finisar Corporation GaAs/AI(Ga)As distributed bragg reflector on InP
US7295586B2 (en) * 2002-02-21 2007-11-13 Finisar Corporation Carbon doped GaAsSb suitable for use in tunnel junctions of long-wavelength VCSELs
CN101432936B (en) * 2004-10-01 2011-02-02 菲尼萨公司 Vertical cavity surface emitting laser having multiple top-side contacts
US7860137B2 (en) * 2004-10-01 2010-12-28 Finisar Corporation Vertical cavity surface emitting laser with undoped top mirror
US7492806B2 (en) * 2005-06-15 2009-02-17 Daylight Solutions, Inc. Compact mid-IR laser
US20100243891A1 (en) * 2005-06-15 2010-09-30 Timothy Day Compact mid-ir laser
US7535656B2 (en) * 2005-06-15 2009-05-19 Daylight Solutions, Inc. Lenses, optical sources, and their couplings
US7466734B1 (en) * 2005-06-15 2008-12-16 Daylight Solutions, Inc. Compact external cavity mid-IR optical lasers
US7535936B2 (en) * 2005-08-05 2009-05-19 Daylight Solutions, Inc. External cavity tunable compact Mid-IR laser
US7424042B2 (en) * 2006-09-22 2008-09-09 Daylight Solutions, Inc. Extended tuning in external cavity quantum cascade lasers
US7920608B2 (en) * 2007-03-12 2011-04-05 Daylight Solutions, Inc. Quantum cascade laser suitable for portable applications
US20090159798A1 (en) * 2007-12-20 2009-06-25 Daylight Solutions, Inc. Gas imaging system
US7848382B2 (en) * 2008-01-17 2010-12-07 Daylight Solutions, Inc. Laser source that generates a plurality of alternative wavelength output beams
US20100110198A1 (en) * 2008-04-01 2010-05-06 Daylight Solutions, Inc. Mid infrared optical illuminator assembly
US8306077B2 (en) 2008-04-29 2012-11-06 Daylight Solutions, Inc. High output, mid infrared laser source assembly
US8565275B2 (en) 2008-04-29 2013-10-22 Daylight Solutions, Inc. Multi-wavelength high output laser source assembly with precision output beam
US8774244B2 (en) 2009-04-21 2014-07-08 Daylight Solutions, Inc. Thermal pointer
FR2949619B1 (en) * 2009-08-28 2011-08-05 Thales Sa SEMICONDUCTOR LASER WITH ELECTRICAL MODULATION
US20110080311A1 (en) * 2009-10-05 2011-04-07 Michael Pushkarsky High output laser source assembly with precision output beam
WO2011156033A2 (en) * 2010-03-15 2011-12-15 Daylight Solutions, Inc. Laser source that generates a rapidly changing output beam
US8335413B2 (en) 2010-05-14 2012-12-18 Daylight Solutions, Inc. Optical switch
US9225148B2 (en) 2010-09-23 2015-12-29 Daylight Solutions, Inc. Laser source assembly with thermal control and mechanically stable mounting
US8467430B2 (en) 2010-09-23 2013-06-18 Daylight Solutions, Inc. Continuous wavelength tunable laser source with optimum orientation of grating and gain medium
US9042688B2 (en) 2011-01-26 2015-05-26 Daylight Solutions, Inc. Multiple port, multiple state optical switch
US9059562B2 (en) 2011-06-23 2015-06-16 Daylight Solutions, Inc. Control system for directing power to a laser assembly
US9093813B2 (en) 2011-10-11 2015-07-28 Daylight Solutions, Inc. Mounting base for a laser system
JP7145765B2 (en) * 2017-02-07 2022-10-03 古河電気工業株式会社 Optical waveguide structure
CN114256740A (en) * 2021-12-15 2022-03-29 华中科技大学 DFB semiconductor laser

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1558642A (en) * 1977-04-01 1980-01-09 Standard Telephones Cables Ltd Injection lasers
JPS56111284A (en) * 1980-02-07 1981-09-02 Nec Corp Manufacture of semiconductor laser
JPS5743428A (en) * 1980-08-28 1982-03-11 Nec Corp Mesa etching method
GB2114808B (en) * 1981-12-01 1985-10-09 Standard Telephones Cables Ltd Semiconductor laser manufacture
JPS5992591A (en) * 1982-11-18 1984-05-28 Nec Corp Semiconductor laser of low radiation angle and manufacture thereof
JPS59130492A (en) * 1983-01-17 1984-07-27 Hitachi Ltd Semiconductor laser device and manufacture thereof
JPS59155977A (en) * 1983-02-25 1984-09-05 Hitachi Ltd Manufacture of semiconductor laser element
JPS59227177A (en) * 1983-06-08 1984-12-20 Hitachi Ltd Semiconductor laser
JPS6085585A (en) * 1983-10-17 1985-05-15 Nec Corp Buried type semiconductor laser
JPS60251689A (en) * 1984-05-28 1985-12-12 Nippon Telegr & Teleph Corp <Ntt> Semiconductor laser element and manufacture thereof
GB2160823B (en) * 1984-06-28 1987-05-28 Stc Plc Semiconductor devices and their fabrication
JPS6167980A (en) * 1984-09-11 1986-04-08 Anritsu Corp Semiconductor laser
US4990465A (en) * 1985-01-22 1991-02-05 Massachusetts Institute Of Technology Method of forming a surface emitting laser
GB2175442B (en) * 1985-05-15 1989-05-24 Stc Plc Laser manufacture
DE3689809D1 (en) * 1985-06-27 1994-06-01 Nec Corp Embedded heterostructure semiconductor laser.
US4764246A (en) * 1985-08-06 1988-08-16 American Telephone And Telegraph Company, At&T Bell Laboratories Buried undercut mesa-like waveguide and method of making same
US4818722A (en) * 1986-09-29 1989-04-04 Siemens Aktiengesellschaft Method for generating a strip waveguide
JP2527190B2 (en) * 1987-07-07 1996-08-21 理想科学工業株式会社 Method for manufacturing base paper for heat-sensitive stencil printing
JPS6461081A (en) * 1987-09-01 1989-03-08 Japan Res Dev Corp Distributed-feedback type semiconductor laser and manufacture thereof
JPH01114092A (en) * 1987-10-28 1989-05-02 Hitachi Ltd Buried-type semiconductor laser
US4972238A (en) * 1987-12-08 1990-11-20 Kabushiki Kaisha Toshiba Semiconductor laser device
US4987576A (en) * 1988-11-30 1991-01-22 Siemens Aktiengesellschaft Electrically tunable semiconductor laser with ridge waveguide

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
ELECTRONICS LETTERS. vol. 24, no. 24, 24 November 1988, ENAGE GB pages 1483 - 1484 T. TANBUN-EK ET AL. 'High frequency buried heterostructure 1.5 um GaInAsP/InP lasers, grown entirely by metalorganic vapour phase epitaxy in two epitaxial growth steps' *
PROCEEDINGS OF THE THIRD INTERNATIONAL CONFERENCE ON INDIUM PHOSPHIDE AND RELATED MATERIALS, Cardiff, UK, 8-11 April 1991, IEEE, New York, USA, pages 130-133; R.P. HOLMSTROM et al.: "New fabrication method for high frequency InP/InGaAsP buried heterostructure semiconductor lasers." *
See also references of WO9205576A1 *

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