EP0489191B1 - Procédé et appareillage de mercerisage en continu - Google Patents
Procédé et appareillage de mercerisage en continu Download PDFInfo
- Publication number
- EP0489191B1 EP0489191B1 EP90123294A EP90123294A EP0489191B1 EP 0489191 B1 EP0489191 B1 EP 0489191B1 EP 90123294 A EP90123294 A EP 90123294A EP 90123294 A EP90123294 A EP 90123294A EP 0489191 B1 EP0489191 B1 EP 0489191B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- yarns
- assembly
- bath
- vessel
- vessels
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000009992 mercerising Methods 0.000 title claims abstract description 40
- 238000000034 method Methods 0.000 title claims abstract description 37
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 66
- 235000011121 sodium hydroxide Nutrition 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 230000006641 stabilisation Effects 0.000 claims abstract description 16
- 238000006386 neutralization reaction Methods 0.000 claims abstract description 13
- 238000005470 impregnation Methods 0.000 claims abstract description 11
- 238000000429 assembly Methods 0.000 claims abstract description 9
- 230000000712 assembly Effects 0.000 claims abstract description 9
- 238000001035 drying Methods 0.000 claims abstract description 8
- 238000005406 washing Methods 0.000 claims abstract description 7
- 239000004094 surface-active agent Substances 0.000 claims abstract description 5
- 239000002253 acid Substances 0.000 claims abstract description 3
- 238000007654 immersion Methods 0.000 claims abstract 10
- 230000005540 biological transmission Effects 0.000 claims description 5
- 238000012545 processing Methods 0.000 claims description 3
- 238000011084 recovery Methods 0.000 claims description 2
- 230000001105 regulatory effect Effects 0.000 claims description 2
- 238000004804 winding Methods 0.000 claims description 2
- 238000012544 monitoring process Methods 0.000 claims 1
- 239000008237 rinsing water Substances 0.000 claims 1
- 229920000742 Cotton Polymers 0.000 description 7
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000011105 stabilization Methods 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B7/00—Mercerising, e.g. lustring by mercerising
- D06B7/04—Mercerising, e.g. lustring by mercerising of yarns, threads or filaments
Definitions
- This invention concerns a method for the continuous mercerising of cotton yarns and other suitable yarns.
- the invention concerns a method suitable to carry out mercerising treatment of a plurality of yarns being unwound continuously from at least one feeder beam.
- the invention concerns also an apparatus which employs the above method.
- the state of the art covers a plurality of methods and apparatuses for mercerising fabrics and yarns, especially cotton fabrics and yarns.
- mercerising is a treatment employing caustic soda, which is applied to yarns for instance, and we shall refer to yarns in the description that follows, the yarns being subjected to a suitable tension to cause them to obtain a lustre like that of silk.
- the mercerising process is applied above all to yarns intended for knitting by hand or machine, yarns for shirts and embroidery and sewing threads.
- a mercerised cotton can be dyed much more intensely than a non-mercerised cotton, thus entailing a smaller consumption of dyestuffs in the dyehouse.
- the known mercerising methods and apparatuses are of two types, namely discontinuous and continuous.
- discontinuous treatment is employed everywhere nowadays and is carried out in successive steps on yarns generally wound in hanks. These steps arrange that the yarn is impregnated with the mercerising liquid, is then drawn, freed of caustic soda, rinsed and lastly neutralized.
- US 3,789,469 and its equivalent FR 2.213.997 disclose in particular a system suitable to unwind a plurality of yarns from a beam positioned to feed a continuous mercerising plant.
- the method provides for the plurality of yarns to be divided into groups by being tied with a lease yarn.
- This system enables the plurality of yarns to be guided and kept in the right position while being unwound from the beam and undergoing the mercerising treatment.
- GB 1,218,260 discloses a continuous mercerising device consisting substantially of a pair of tapered rolls on which the yarn to be mercerised is wound.
- the taper of the rolls causes tensioning of the yarn, which undergoes the mercerising action while being wound on the rolls.
- This device is suitable to treat one single yarn coming from a yarn package.
- GB 2,051,156 discloses a continuous mercerising device used especially for filament yarns and consisting of a vessel which contains assemblies of rolls that can be positioned in relation to each other so as to be able to vary the path of the textile material.
- DE 1.610.882 discloses a mercerising process comprising in particular a bath to bleach the textile material, which is passed through this bath after the mercerising and washing steps.
- JP-B-51022559 and JP-B-51014638 disclose continuous mercerising processes whereby the textile material is immersed in succession in a plurality of caustic soda solutions so as to obtain its final strength value gradually.
- the present applicant has the purpose of obtaining a continuous mercerising method and apparatus which are suitable for achieving a process which can be employed on an industrial scale at modest costs with high-quality technological results.
- the method according to the invention provides for the continuous treatment of a plurality of yarns being unwound parallel to each other from at least one feeder beam. This plurality of yarns undergoes substantially six mercerising treatment steps:
- the yarns are taken up advantageously in separate groups on a plurality of beams having smaller dimensions than the feeder beam or beams.
- the above mercerising steps are carried out in a plurality of vessels which can be made movable so as to enable the yarns to be readily passed through, and inserted into, the operational assemblies arranged within such vessels. This becomes necessary upon each change of the lots being processed or owing to maintenance work or the like.
- Each vessel or each group of vessels is equipped advantageously with its own motor and control means governed by a central processor unit which sets the various working parameters from time to time.
- the apparatus of the invention may be equipped also with a system to monitor all the physical values entailed in the treatment so as to optimise every operational step, particularly from a technological or energy-consumption point of view.
- the yarns may be tied crosswise to their direction of feed in the apparatus at pre-set intervals so as to ensure the advance of each yarn along the whole path of the treatment, even in the event of any breakages. These lease ties may be removed before the yarns are wound onto their take-up beams.
- Figs.1 and 2 give a diagram of the embodiment of a mercerising apparatus 10 according to the invention.
- the apparatus 10 is fed with a plurality of yarns 11 being unwound from at least one beam 12 packaged on a warping machine.
- the feed consists of two beams 112 and 212 to feed separately two sides having an identical configuration 110-210 into which the mercerising apparatus 10 can be divided.
- the apparatus 10 may not be divided in this way.
- the speed of unwinding of the yarns 11 from the beam 12 can reach 60 metres per minute or more and will ensure at the same time the required level of quality of the product thus treated.
- the yarns 11 unwound from the beam 12 are fed to a pre-wash assembly 13 consisting in this example of three equal vessels 14, through which the yarns 11 are passed in succession.
- a plurality of vessels 14 comprised also in assemblies located downstream of the pre-wash assembly 13 is employed in the mercerising apparatus 10.
- this vessel 14 comprises a container 15 for trteatment liquid, a pair of upper transverse rolls 16 at the entry and exit of the vessel 14, a pair of lower transverse rolls 17 positioned at the bottom of the vessel 14 and an intermediate transverse transmission roll 18.
- Thrust means 19 to press on the yarns 11 in correspondence at least with the upper rolls 16 may also be included.
- Actuation means 20 to drive the rolls are positioned above the vessel 14 and may cooperate with one single vessel 14 or with groups of vessels 14.
- the intermediate transmission roll 18 is equipped advantageously with its own motor, which can move the roll 18 crosswise to the direction of feed of the yarns 11; the purpose of this is to be able to ensure correct positioning of the plurality of yarns 11 during their movement of feed through the apparatus 10; the position of the yarns 11 is monitored by control means, such as photoelectric cells cooperating with the motor of the intermediate transmission roll 18.
- Each vessel 14 can displace its container 15 within the apparatus 10 so as to free the upper, lower and intermediate rolls 16-17-18 for the purpose of enabling an easy insertion and passage of the yarns 11 during operations for changes of lots or other operational requrements.
- the containers 15 can be lowered to the position shown with lines of dashes in Fig.3.
- the quantity and temperature of the water and its content of surface active agents may be checked advantageously by means of suitable sensors in the vessels 14; these sensors will be linked to centralised control systems for automatic management of the operations. This feature is included also in any other operational assembly which will be described hereinafter.
- Water to top up the vessels 14 of the pre-wash assembly 13 can be prepared in a separate tank and heated by means of heat exchangers, independently or with the water coming from the recovery of caustic soda, as we shall detail later.
- the yarns 11 in the embodiment shown take about 10 to 11 seconds to pass through the pre-wash assembly 13 fully according to experiments conducted by the present applicant.
- the yarns 11 pass from the pre-wash assembly 13 to an assembly 21 which performs impregnation with caustic soda and in this example consists of two vessels 14.
- the temperature of the bath is kept at about 40°C, while the metering and heating of the caustic soda can be carried out and checked in a supplementary container.
- the yarns 11 pass from the impregnation assembly 21 to a stabilization and tensioning assembly 22 consisting of a stabilization and tensioning chamber 23 equipped with a plurality of upper rolls 24 and coordinated lower rolls 25.
- the stabilization phase in the above conditions lasts for a period of about 36 to 38 seconds.
- the yarns 11 are drawn by tensioning, for instance by a length equal to 4% of the initial length, during a period of about 3 to 4 seconds.
- All the lower rolls 25 in the chamber 23 are advantageously partly immersed in caustic soda to prevent possible oxidation of the yarns 11.
- the step of neutralization of the yarns 11 consists of a first washing stage, a second actual neutralization stage and a third rinsing stage.
- the washing stage is performed by a wash assembly 26 consisting of two groups each formed of two vessels 14, each vessel 14 containing water at a temperature of about 80°C.
- the actual neutralization stage is carried out by a neutralization assembly 27 consisting of two vessels 14 containing an acid bath to neutralize the pH.
- the rinsing stage is performed by a rinsing assembly 28 consisting of three vessels 14 containing water at a temperature of about 40°C.
- the vessels 14 in the wash assembly 26 and rinse assembly 28 are equipped with an inlet and outlet for the water, which is fed continuously so as to flow in the opposite direction to the feed of the yarns 11 to be treated.
- the water passes advantageously from one vessel 14 to the next wthin each of the above assemblies 26-28 by an overflow system.
- the water collected at the outlets of the wash assembly 26 and rinse assembly 28 can be processed to recover caustic soda by evaporation of the water.
- the thermal energy made available during the processing can be employed to heat the water used in the upstream steps.
- the yarns 11 pass from the rinse assembly 28 to a drier assembly 29 consisting of an oven 30 in which the yarns 11 undergo a series of passes about upper rolls 31 and lower rolls 32.
- the oven 30 may advantageously be of a type with a circulation of a forced draught of air heated by a submerged combustion system, as described in IT-B-1239264 in the name of the present applicant.
- the yarns 11 undergo firstly a water removal process that brings the value of relative humidity down to about 70%; thereafter they are passed through the oven 30 in contact with air heated to a temperature between 90° and 120°C and then leave the oven 30 with a relative humidity of about 7 to 8%.
- the yarns 11 leaving the drier assembly 29 are taken up on a beam or advantageously a plurality of small beams 33, each of which will hold an aliquot part of the yarns 11 held on the feeder beam 12 or feeder beams 112-212. These small take-up beams 33 will be used to feed a suitable unwinding-winding machines thereafter.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatment Of Fiber Materials (AREA)
Claims (22)
- Procédé de mercerisation en continu qui est conçu pour appliquer un traitement de mercerisation à une pluralité de fils déroulés en continu et parallèlement l'un à l'autre d'un (12) ou de plusieurs (112-212) faisceaux appliqués, la pluralité de fils (11) subissant successivement les étapes fonctionnelles suivantes :- un prélavage par immersion dans de l'eau chaude ;- une imprégnation par immersion dans la soude caustique chauffée ;- un lavage à chaud par immersion dans un bain d'eau chaude, une neutralisation par immersion dans un bain d'acide et un rinçage par immersion dans un bain d'eau ;- un séchage ;- un enroulement en un ou plusieurs faisceaux de sortie ;
le procédé étant caractérisé en ce que le bain de prélavage contient des agents actifs de surface et en ce que sa température est d'environ 90°C, tandis que le bain de l'étape d'imprégnation dans la soude caustique est à une température de 40°C environ ;- après l'étape d'imprégnation dans la soude caustique, les fils (11) subissent une étape de stabilisation qui contrôle le rétrécissement des fils (11) dans une chambre de stabilisation et de tension (23), à l'intérieur de laquelle les fils (11) sont partiellement placés en contact avec un bain de soude caustique et puis subissent une étape de tension et d'étirage. - Procédé selon la revendication 1, dans lequel la température du bain de l'étape de lavage à chaud est d'environ 80°C et dans laquelle l'eau circule dans une direction opposée au mouvement des fils.
- Procédé selon l'une quelconque des revendications précédentes, dans lequel la température du bain au cours de l'étape de rinçage est d'environ 40°C et dans lequel l'eau circule dans la direction opposée au mouvement des fils.
- Procédé selon l'une quelconque des revendications précédentes, dans lequel l'étape de séchage se fait dans une étuve (30) à circulation d'air, la température de l'air étant maintenue entre 90° et 120°C.
- Procédé selon l'une quelconque des revendications précédentes, dans lequel les fils (11) sortant de l'étape de séchage ont une humidité relative d'environ 7 à 8 %.
- Procédé selon l'une quelconque des revendications précédentes, dans lequel la tension des fils (11) peut être régulée au cours de l'étape de stabilisation.
- Procédé selon l'une quelconque des revendications précédentes, dans lequel les fils (11) sont essorés immédiatement en aval de l'étape de stabilisation et cet essorage peut être effectué avec une pression variable.
- Procédé selon l'une quelconque des revendications précédentes, dans lequel la valeur de l'étirage des fils (11) au cours de l'étape de tension et d'étirage correspond à environ 4 % de la longueur initiale des fils (11).
- Procédé selon l'une quelconque des revendications précédentes, dans lequel l'eau de lavage et de rinçage de l'étape de neutralisation est traitée pour récupérer la soude caustique.
- Procédé selon l'une quelconque des revendications précédentes, dans lequel l'énergie thermique libérée pendant la récupération de la soude caustique sert au cours d'une ou plusieurs étapes du procédé lui-même.
- Procédé selon l'une quelconque des revendications précédentes dans lequel la vitesse de mercerisation peut être de 60 mètres par minute ou plus.
- Procédé selon l'une quelconque des revendications précédentes, dans lequel les fils (11) qui sont déroulés du faisceau (12) ou des faisceaux (112-212) appliqués sont attachés dans la direction transversale à intervalle prédéterminés.
- Procédé selon l'une quelconque des revendications précédentes, dans lequel chaque étape du procédé de mercerisation est commandée par une unité centrale de traitement qui commande et régule les paramètres de fonctionnement.
- Procédé selon l'une quelconque des revendications précédentes, qui comprend un système de surveillance pour vérifier toutes les grandeurs physiques du traitement.
- Appareil de mercerisation en continu qui est conçu pour appliquer un traitement de mercerisation à une pluralité de fils déroulés en continu et parallèlement l'un à l'autre d'un (12) ou de plusieurs (112-212) faisceaux appliqués, l'appareil appliquant le procédé des revendications précédentes, les ensembles fonctionnels suivants étant disposés l'un après l'autre :- un ensemble de prélavage (13)- un ensemble d'imprégnation (21)- un ensemble de lavage (26)- un ensemble de neutralisation (27) ;- un ensemble de rinçage (28)- un ensemble de séchage (29) ;- un système preneur de fils (11) comprenant une pluralité de faisceaux preneurs (33), l'appareil étant caractérisé en ce que :- entre l'ensemble d'imprégnation (21) et l'ensemble de lavage (26) est monté un ensemble de stabilisation et de tension (22) comprenant une chambre de stabilisation et de tension (23) équipée d'une pluralité de rouleaux supérieurs (24) et de rouleaux inférieurs (25) tour contrôler le rétrécissement et l'étirage des fils (11) les fils (11) étant enroulés en continu entre ces rouleaux (24-25) ;- l'ensemble de séchage (29) comprend une cuve dans laquelle circule de l'air chaud à une température comprise entre 90 et 120°C ;et les autres ensembles comprennent au moins une cuve (14) de type normalisé, chaque cuve (14) comprenant un récipient (15) dans lequel est placé le bain, une paire de rouleaux supérieurs transverses (16), une paire de rouleaux inférieurs transverses (17) et un rouleau intermédiaire transverse de transmission (18), l'appareil (10) comprenant des moyens pour animer d'un mouvement transversal le rouleau intermédiaire transversal de transmission (18), le récipient (15) pouvant être déplacé verticalement par rapport aux rouleaux (16-17-18), l'appareil (10) étant géré par un système de commande centrale informatisé.
- Appareil (10) selon la revendication 15, qui comporte deux cotés identiques fonctionnant en parallèle (110-210).
- Appareil (10) selon la revendication 15 ou 16, dans lequel des moyens de poussée (19) pour comprimer les fils (11) coopèrent avec les rouleaux supérieurs (16) des cuves (14).
- Appareil (10) selon la revendication 15, 16 ou 17, dans lequel le rouleau transversal (18) coopère avec des moyens qui surveillent la position des fils (11) pendant leur mouvement en avant dans la direction longitudinale.
- Appareil (10) selon l'une quelconque des revendications 15 à 18 incluse, dans lequel les cuves (14) sont équipées de capteurs pour surveiller les paramètres de positionnement.
- Appareil (10) selon l'une quelconque des revendications 15 à 19 incluse, dans lequel l'ensemble de prélavage (13) est connecté à une disposition supplémentaire qui chauffe l'eau d'appoint.
- Appareil (10) selon l'une quelconque des revendications 15 à 20 incluse, dans lequel l'ensemble d'imprégnation (21) est relié à un dispositif supplémentaire qui chauffe la soude caustique.
- Appareil (10) selon l'une quelconque des revendications 15 à 21 incluses, dans lequel les rouleaux inférieurs (25) de la chambre de stabilisation et de tension (23) sont partiellement immergés dans une cuve contenant de la soude caustique.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT90123294T ATE139812T1 (de) | 1990-12-05 | 1990-12-05 | Verfahren und vorrichtung zum kontinuierlichen mercerisieren |
EP90123294A EP0489191B1 (fr) | 1990-12-05 | 1990-12-05 | Procédé et appareillage de mercerisage en continu |
DE69027605T DE69027605T2 (de) | 1990-12-05 | 1990-12-05 | Verfahren und Vorrichtung zum kontinuierlichen Mercerisieren |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP90123294A EP0489191B1 (fr) | 1990-12-05 | 1990-12-05 | Procédé et appareillage de mercerisage en continu |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0489191A1 EP0489191A1 (fr) | 1992-06-10 |
EP0489191B1 true EP0489191B1 (fr) | 1996-06-26 |
Family
ID=8204796
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP90123294A Expired - Lifetime EP0489191B1 (fr) | 1990-12-05 | 1990-12-05 | Procédé et appareillage de mercerisage en continu |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP0489191B1 (fr) |
AT (1) | ATE139812T1 (fr) |
DE (1) | DE69027605T2 (fr) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1262155B (it) * | 1993-06-30 | 1996-06-19 | Gesma Spa | Procedimento di mercerizzo in continuo di fibre di poliestere e relativo impianto |
IT1267288B1 (it) * | 1994-08-31 | 1997-01-28 | Gesma Spa | Vasca per il trattamento in continuo in bagno liquido di filati in fasci di fili |
CN101525826B (zh) * | 2009-03-10 | 2012-05-09 | 东华大学 | 一种纱线束状连续回流丝光的方法 |
CN102926149B (zh) * | 2012-11-12 | 2013-12-18 | 无锡市天然绿色纤维科技有限公司 | 一种辫子连续丝光机及其加工方法 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1350199A (fr) * | 1962-01-29 | 1964-01-24 | Hermann Windel | Perfectionnements apportés aux installations de mercerisage |
DE1805119B2 (de) * | 1968-10-25 | 1976-08-26 | Vepa Ag, Riehen Bei Basel (Schweiz) | Verfahren und vorrichtung zum kontinuierlichen merzerisieren von textilgut |
CH554446A (de) * | 1973-02-14 | 1974-09-30 | Heberlein & Co Ag | Vorrichtung zur verbesserung der faserstruktur von cellulosefasern enthaltendem textilgut. |
DE3021783C2 (de) * | 1980-06-10 | 1984-03-15 | Ivanovskij naučno-issledovatel'skij eksperimental'no-konstruktorskij mašinostroitel'nyj institut, Ivanovo | Verfahren zur Behandlung von Baumwollrohgewebe aus Zwirn und Anlage zur Durchführung des Verfahrens |
DE3341272A1 (de) * | 1983-11-15 | 1985-05-23 | Babcock Textilmaschinen GmbH, 2105 Seevetal | Verfahren und anlage zum abkochen von textilen warenbahnen oder dergl. |
-
1990
- 1990-12-05 DE DE69027605T patent/DE69027605T2/de not_active Expired - Fee Related
- 1990-12-05 AT AT90123294T patent/ATE139812T1/de not_active IP Right Cessation
- 1990-12-05 EP EP90123294A patent/EP0489191B1/fr not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE69027605D1 (de) | 1996-08-01 |
DE69027605T2 (de) | 1996-10-31 |
EP0489191A1 (fr) | 1992-06-10 |
ATE139812T1 (de) | 1996-07-15 |
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Legal Events
Date | Code | Title | Description |
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PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
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