EP0476496B1 - Procédé de fabrication d'une pièce de fonderie bimétallique et pièce d'usure réalisée par ce procédé - Google Patents
Procédé de fabrication d'une pièce de fonderie bimétallique et pièce d'usure réalisée par ce procédé Download PDFInfo
- Publication number
- EP0476496B1 EP0476496B1 EP91115332A EP91115332A EP0476496B1 EP 0476496 B1 EP0476496 B1 EP 0476496B1 EP 91115332 A EP91115332 A EP 91115332A EP 91115332 A EP91115332 A EP 91115332A EP 0476496 B1 EP0476496 B1 EP 0476496B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- inserts
- casting
- insert
- roller
- mould
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000005266 casting Methods 0.000 title claims abstract description 25
- 238000000034 method Methods 0.000 title claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 title claims description 13
- 230000008569 process Effects 0.000 title abstract description 12
- 239000000463 material Substances 0.000 claims abstract description 27
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 8
- 230000002093 peripheral effect Effects 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 4
- 230000004888 barrier function Effects 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 238000005336 cracking Methods 0.000 claims description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- 230000002035 prolonged effect Effects 0.000 claims 2
- 229910052742 iron Inorganic materials 0.000 claims 1
- 238000000227 grinding Methods 0.000 abstract description 9
- 229910001018 Cast iron Inorganic materials 0.000 description 8
- 230000008901 benefit Effects 0.000 description 7
- 229910001141 Ductile iron Inorganic materials 0.000 description 6
- 238000005299 abrasion Methods 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 239000002131 composite material Substances 0.000 description 6
- 230000035939 shock Effects 0.000 description 6
- 229910052804 chromium Inorganic materials 0.000 description 5
- 239000011651 chromium Substances 0.000 description 5
- 238000003780 insertion Methods 0.000 description 4
- 230000037431 insertion Effects 0.000 description 4
- 238000003754 machining Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 3
- 238000003466 welding Methods 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- 238000005219 brazing Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 230000001174 ascending effect Effects 0.000 description 1
- 238000005524 ceramic coating Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 229910000734 martensite Inorganic materials 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 230000001902 propagating effect Effects 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D19/00—Casting in, on, or around objects which form part of the product
- B22D19/08—Casting in, on, or around objects which form part of the product for building-up linings or coverings, e.g. of anti-frictional metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C13/00—Disintegrating by mills having rotary beater elements ; Hammer mills
- B02C13/26—Details
- B02C13/28—Shape or construction of beater elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C15/00—Disintegrating by milling members in the form of rollers or balls co-operating with rings or discs
- B02C15/004—Shape or construction of rollers or balls
- B02C15/005—Rollers or balls of composite construction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C4/00—Crushing or disintegrating by roller mills
- B02C4/28—Details
- B02C4/30—Shape or construction of rollers
- B02C4/305—Wear resistant rollers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D19/00—Casting in, on, or around objects which form part of the product
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D19/00—Casting in, on, or around objects which form part of the product
- B22D19/06—Casting in, on, or around objects which form part of the product for manufacturing or repairing tools
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28D—WORKING STONE OR STONE-LIKE MATERIALS
- B28D1/00—Working stone or stone-like materials, e.g. brick, concrete or glass, not provided for elsewhere; Machines, devices, tools therefor
- B28D1/18—Working stone or stone-like materials, e.g. brick, concrete or glass, not provided for elsewhere; Machines, devices, tools therefor by milling, e.g. channelling by means of milling tools
- B28D1/181—Working stone or stone-like materials, e.g. brick, concrete or glass, not provided for elsewhere; Machines, devices, tools therefor by milling, e.g. channelling by means of milling tools using cutters loosely mounted on a turning tool support
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C2210/00—Codes relating to different types of disintegrating devices
- B02C2210/02—Features for generally used wear parts on beaters, knives, rollers, anvils, linings and the like
Definitions
- the present invention relates to a process for manufacturing a bimetallic foundry part as well as to a wear part produced by this process, in particular shredder frets.
- the part exposed to abrasion consists of chromium cast iron with high abrasion resistance supported by a more ductile steel core. This reduces wear on the part, while allowing machining of the core and avoiding breakage. In addition, it is possible to reduce its manufacturing cost by a judicious choice of its components.
- patent LU-64303 proposes a process for manufacturing composite parts by successive castings of materials with different or complementary properties.
- this technique has two constraints. First, the process necessarily implies the existence of a horizontal separation surface between the two cast metals. In addition, the room must be relatively massive to allow the two metals to flow successively while obtaining a correct metallurgical bond between them.
- Brazing at high temperature offers mechanical properties comparable to welding, but it requires careful operating precautions and the use of special ovens, especially vacuum ovens, in order to obtain a reliable assembly. This results in a relatively high manufacturing cost.
- Patent US-4,099,988 proposes the implementation of the technique of inserts for the production of bimetallic armor plates for blast furnaces.
- inserts are first poured into first molds, these inserts are then placed in a second mold in which the part is cast around the inserts so as to form a metallurgical bond between the inserts and the support material.
- This process has the disadvantage that the inserts undergo thermal shocks during the casting of the parts. These thermal shocks generate internal tensions and cracks which propagate, not only through the inserts but, because of the metallurgical bond, also through the support.
- the aim of the present invention is to provide a new method for manufacturing a bimetallic foundry part with a high insertion rate, the properties of which result not only from the properties specific to each component, but also from a useful synergistic effect generated. by the juxtaposition of the two components and due either to the morphology, or to the dimensioning, or to the choice of the materials of the components.
- the present invention provides a method of manufacturing a bimetallic foundry part according to claim 1.
- This preparation can for example consist, when the massiveness of the inserts is not too high, in a simple heat treatment.
- the massivity increases, it is possible to provide the inserts with a refractory coating forming a thermal barrier.
- the massivity is very high, one can even consider providing the inserts with a ceramic coating.
- the process allows, by a judicious choice of the nature and morphology of the two components, to generate, in service, a wear profile which will maintain or optimize the work of the part.
- Each insert may comprise a part of substantially parallelepiped shape constituting a wear part extended radially towards the center of the hoop by a longitudinal constriction with a section in the form of a "dovetail” forming the zone of mechanical connection with ductile iron. .
- the "dovetail” section can also be replaced by fluted sections.
- the spacing between the adjacent inserts can be determined by projecting radial ribs provided on the longitudinal sides of the inserts.
- the inserts extend from one of the bases of the hoop and end before the opposite base to define there a peripheral ring of ductile iron.
- the grinding rollers are, in general, constituted by a frustoconical or cylindrical annular hoop, mounted on a hub. On the one hand, they must have sufficient resistance to wear caused by grinding and, at the same time, be able to be machined to be mounted on the hub.
- the known hoops are generally cast in Ni-hard cast iron or in chrome cast iron and then machined with great precision (internal diameter with H6 tolerance in certain cases) before being mounted on their hub.
- the profile of the working surfaces changes and the backlash adjustment system no longer makes it possible to restore optimal grinding conditions.
- the sliding between the material to be ground and the surface of the hoop accelerates wear and reduces the flow rate, especially if the material to be ground is wet.
- the present invention proposes, in its application to the crusher, to produce the hoops with inserts as shown in FIG. 3.
- a hoop therefore consists of an annular support 42 of ductile and machinable cast iron, in which peripheral inserts 44 are embedded in a material with high abrasion resistance, for example in chromium cast iron and forming the working and wearing surface of the hoop.
- the inserts 44 are first cast separately in suitable molds. These inserts 44 advantageously have the shape shown in perspective in Figure 4. They consist of an outer part 46 of substantially parallelepiped shape with slightly frustoconical section along the radius of curvature of the hoop. This part is extended towards the base, or inside the hoop, by a strangled longitudinal foot 48 with a radial section in the form of a "dovetail" and forming the connection zone with the support 42. Each insert 44 comprises on at least one of its longitudinal sides of the part 46, in the embodiment shown, two projecting ribs 50.
- the inserts 44 are then placed in the mold for the casting of the frets so as to fill the entire periphery of the mold.
- the inserts 44 are juxtaposed so that their ribs 50 are in mutual contact to define between two juxtaposed inserts a space 52 more or less wide depending on the size of the ribs 50.
- the purpose of these ribs 50 is to cause, during casting of support 42, a spreading of the ductile iron in the spaces 52 to form between all of the neighboring inserts 44 a thin radial fin made of ductile iron.
- the hoop is cast in such a way as to avoid a metallurgical connection between the support 42 and the inserts 44.
- the inserts 44 can undergo a prior preparation, for example a heat treatment to reduce the risk of cracking. If the massiveness of the inserts 44 is relatively large compared to the support 42 it is inter alia possible to coat the inserts 44 before the casting of the hoop, with a refractory coating intended to form a thermal barrier.
- the temperature of the material forming the support 42 must therefore no longer be as high, during the casting of the hoop, compared to the case of a casting with the formation of a metallurgical bond. This has the advantage of reducing the thermal shocks that the inserts 44 undergo during this casting. These are therefore less exposed to the risks of crack formation. If, despite this precaution, a crack should form in an insert 44, this crack would only propagate through the insert since the absence of metallurgical bond prevents its progression through the material of the support 42. In other words , the method proposed by the invention reduces the risk of cracks occurring in the inserts 44 and also prevents their progression in the support.
- the purpose of the fins 52 is to cause, by the work of the roller, preferential wear of the ductile alloy and the formation of grooves between the inserts 44 for the purpose of gripping the material to be ground. In order to have the optimum yield, it is therefore necessary to choose the spacing between the inserts 44 as a function of the friction characteristics of the material used, of its particle size and of its angularity.
- the morphology and the shape of the inserts 44 is therefore dictated by several criteria. Their width and spacing must allow a circumferential pitch providing optimal training of the material used.
- the profile of the part 48 of each insert 44 allows an excellent mechanical connection between the inserts 44 and the support 42 with a minimum of tension concentration in the chromium cast iron of the inserts.
- the radial height of the inserts 44 allows a large usable thickness and a good mechanical connection until the end of the service life.
- the ribs 50 allow easy adjustment and positioning of the inserts 44 in the mold.
- a hoop produced with inserts as described above has several advantages over known frets.
- the machining and hooping operation is less delicate and less costly because of the ductility of the support 42. This ductility also reduces the risk of sudden rupture over the entire section of the part following static stresses of hooping and fatigue in service. It is possible to use castings with a high chromium content, that is to say of very high hardness (greater than 65 Rc), the machining of which is extremely difficult and expensive. At the same time, the manufacturing process allows a better utilization rate of the expensive chrome cast iron.
- the combination of these materials generates a synergistic effect offering other advantages.
- This compression of the working surface has a positive effect on the resistance to fatigue and also, in certain cases, on abrasion resistance.
- the hoops produced according to the proposed method offer increased wear resistance, increased mechanical reliability and increased flow during their period of use.
- the hoop 60 has inserts 62 which do not extend over the entire length of the generator so as to leave a peripheral nose 64a forming part of the support 64 in the outer edge of the rollers.
- ductile iron We therefore deliberately cause wear in this region of the roller faster to compensate for the fact that this region normally wears less quickly.
- Figure 7 shows the evolution of the wear of such a hoop 60.
- the profile identified by A represents the outer periphery of the hoop 60 in the unused new state.
- Line B represents the evolution of the wear profile when the hoop has a uniform hardness over the entire length of the generator
- dashed line C represents the evolution of the wear profile as corrected by a hoop according to Figure 6 with an outer edge 64a more ductile.
- the particular shape of the inserts 44 especially their dovetail shape 48 contributes to consolidating the mechanical connection between the inserts 44 and the support 42.
- the inserts are relatively massive, it is possible, to increase the contact surface while avoiding having to make cuts that are too deep to form the dovetail shapes, to provide inserts as shown in FIG. 8.
- Such an insert 64 is comparable to the inserts 44 of FIG. 4, with the difference that the inner part 66 has on its two longitudinal sides corrugations or grooves 68 forming a sort of multiple dovetail.
- the mechanical connection zone is therefore separate and is, in fact, behind the wear zone, which avoids a certain number of drawbacks at the end of life compared to the simple dovetail flush with the work surface.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Food Science & Technology (AREA)
- Manufacturing & Machinery (AREA)
- Mining & Mineral Resources (AREA)
- Crushing And Grinding (AREA)
- Component Parts Of Construction Machinery (AREA)
- Earth Drilling (AREA)
- Adornments (AREA)
- Crushing And Pulverization Processes (AREA)
- Lubricants (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE9000895A BE1004573A4 (fr) | 1990-09-20 | 1990-09-20 | Procede de fabrication d'une piece de fonderie bimetallique et piece d'usure realisee par ce procede. |
BE9000895 | 1990-09-20 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0476496A1 EP0476496A1 (fr) | 1992-03-25 |
EP0476496B1 true EP0476496B1 (fr) | 1995-03-01 |
Family
ID=3884932
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP91115332A Expired - Lifetime EP0476496B1 (fr) | 1990-09-20 | 1991-09-11 | Procédé de fabrication d'une pièce de fonderie bimétallique et pièce d'usure réalisée par ce procédé |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP0476496B1 (pt) |
JP (1) | JP2799250B2 (pt) |
KR (1) | KR0149031B1 (pt) |
AT (1) | ATE119092T1 (pt) |
BE (1) | BE1004573A4 (pt) |
CA (1) | CA2051221C (pt) |
DE (1) | DE69107746T2 (pt) |
DK (1) | DK0476496T3 (pt) |
ES (1) | ES2069156T3 (pt) |
PT (1) | PT99013B (pt) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100425348C (zh) * | 2004-03-03 | 2008-10-15 | 马格托国际股份有限公司 | 用于垂直粉碎机的粉碎滚轮 |
CN107552767A (zh) * | 2017-08-24 | 2018-01-09 | 昆明理工大学 | 一种新型耐磨斗齿的制作工艺 |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
LU88246A1 (fr) * | 1993-04-14 | 1994-12-01 | Magotteaux Int | Procédé de fabrication de pièces d'usure composite et pièces réalisées par ce procédé |
LU88549A1 (fr) * | 1994-10-24 | 1995-02-01 | Magotteaux Int | Procédé de fabrication d'un galet de broyage bimétallique et galet de broyage obtenu par la mise en oeuvre de ce procédé |
DE19528512C2 (de) * | 1995-08-03 | 2001-02-22 | Swb Stahlformgusgmbh | Verschleißteile und Verfahren zu deren Herstellung |
KR19990076793A (ko) * | 1995-12-26 | 1999-10-15 | 아더 이. 푸리어 2세 | 석탄 분쇄용 고효율 연마롤 |
LU88753A1 (fr) * | 1996-04-30 | 1996-10-04 | Magotteaux Int | Piste pour broyeurs |
JP2001504036A (ja) | 1996-10-01 | 2001-03-27 | ユベール フランソワ | 複合耐摩耗部品 |
EP0838288A1 (fr) * | 1996-10-01 | 1998-04-29 | Hubert Francois | Pièce d'usure composite |
LU90006B1 (fr) * | 1997-01-15 | 1997-08-21 | Magotteaux Int | Insert pour pièces d'usure composites procédé de fabrication d'une pièce d'usure à l'aide de tels inserts et pièce d'usure ainsi réalisée |
CA2468352C (en) | 2001-12-04 | 2010-06-15 | Claude Poncin | Cast parts with enhanced wear resistance |
SE532815C2 (sv) * | 2007-11-09 | 2010-04-13 | Combi Wear Parts Ab | Självskärpande, autosignalerande slitdel |
BE1018129A3 (fr) | 2008-09-19 | 2010-05-04 | Magotteaux Int | Impacteur composite pour concasseurs a percussion. |
CN103056343B (zh) * | 2012-12-21 | 2014-11-26 | 佳木斯大学 | 三金属复合铸造破碎机锤头生产工艺方法 |
BE1021839B1 (fr) * | 2014-04-23 | 2016-01-21 | Magotteaux International S.A. | Galet de broyage comportant des inserts a massivite elevee |
CN103977864A (zh) * | 2014-06-11 | 2014-08-13 | 南京凯盛国际工程有限公司 | 一种新型立磨辊套 |
CN105413804A (zh) * | 2015-12-03 | 2016-03-23 | 中钢集团安徽天源科技股份有限公司 | 一种高压辊磨机辊面结构及制作方法 |
CN111112583B (zh) * | 2020-01-06 | 2021-09-24 | 南通高欣耐磨科技股份有限公司 | 一种低成本、可修复式陶瓷合金复合磨辊的制造方法 |
CN111408702A (zh) * | 2020-04-07 | 2020-07-14 | 聂章银 | 一种方便移动的双金属铸造模具 |
CN111571121B (zh) * | 2020-04-22 | 2021-09-21 | 南通高欣耐磨科技股份有限公司 | 一种易拆卸、可修复高耐磨陶瓷合金复合磨辊的制造方法 |
CN111590053B (zh) * | 2020-04-22 | 2021-09-03 | 南通高欣耐磨科技股份有限公司 | 一种易加工、可修复高耐磨金属陶瓷复合磨辊的制造方法 |
CN111618277B (zh) * | 2020-04-22 | 2021-09-21 | 南通高欣耐磨科技股份有限公司 | 一种易拆卸、易加工、可修复、高耐磨陶瓷合金复合磨辊的制造方法 |
CN113368959A (zh) * | 2021-06-11 | 2021-09-10 | 郑州机械研究所有限公司 | 一种不伤害母体的耐磨结构及其制备方法 |
CN114950636B (zh) * | 2022-06-06 | 2024-04-26 | 唐山迁西大方科技有限公司 | 铠甲钉辊套及其制备方法 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2155215A (en) * | 1936-02-27 | 1939-04-18 | Beament Thomas Geoffrey | Method of producing composite wear-resisting bodies |
LU64303A1 (pt) * | 1971-11-22 | 1971-12-05 | ||
US4099988A (en) * | 1976-02-26 | 1978-07-11 | Kawasaki Jukogyo Kabushiki Kaisha | Composite material having wear- and impact-resisting surface and process for producing same |
AT375035B (de) * | 1979-12-13 | 1984-06-25 | Ver Edelstahlwerke Ag | Verfahren zur herstellung von metallischen hartguss-formteilen |
JPS63143949A (ja) * | 1986-12-09 | 1988-06-16 | アイエヌジ商事株式会社 | 粉砕機に使用される破砕面部材 |
DE3814433A1 (de) * | 1988-04-28 | 1989-11-09 | Krupp Polysius Ag | Walzenmuehle sowie verfahren zur beschichtung einer walze |
-
1990
- 1990-09-20 BE BE9000895A patent/BE1004573A4/fr not_active IP Right Cessation
-
1991
- 1991-01-31 JP JP3032033A patent/JP2799250B2/ja not_active Expired - Fee Related
- 1991-09-11 DK DK91115332.8T patent/DK0476496T3/da active
- 1991-09-11 AT AT91115332T patent/ATE119092T1/de not_active IP Right Cessation
- 1991-09-11 ES ES91115332T patent/ES2069156T3/es not_active Expired - Lifetime
- 1991-09-11 EP EP91115332A patent/EP0476496B1/fr not_active Expired - Lifetime
- 1991-09-11 DE DE69107746T patent/DE69107746T2/de not_active Expired - Fee Related
- 1991-09-12 CA CA002051221A patent/CA2051221C/en not_active Expired - Fee Related
- 1991-09-19 KR KR1019910016444A patent/KR0149031B1/ko not_active IP Right Cessation
- 1991-09-19 PT PT99013A patent/PT99013B/pt not_active IP Right Cessation
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100425348C (zh) * | 2004-03-03 | 2008-10-15 | 马格托国际股份有限公司 | 用于垂直粉碎机的粉碎滚轮 |
CN107552767A (zh) * | 2017-08-24 | 2018-01-09 | 昆明理工大学 | 一种新型耐磨斗齿的制作工艺 |
Also Published As
Publication number | Publication date |
---|---|
DE69107746T2 (de) | 1995-06-29 |
KR920006061A (ko) | 1992-04-27 |
ATE119092T1 (de) | 1995-03-15 |
CA2051221A1 (en) | 1992-03-21 |
JP2799250B2 (ja) | 1998-09-17 |
EP0476496A1 (fr) | 1992-03-25 |
KR0149031B1 (ko) | 1998-11-16 |
PT99013A (pt) | 1993-10-29 |
ES2069156T3 (es) | 1995-05-01 |
PT99013B (pt) | 1999-02-26 |
DK0476496T3 (da) | 1995-07-17 |
CA2051221C (en) | 1999-03-30 |
JPH04231164A (ja) | 1992-08-20 |
DE69107746D1 (de) | 1995-04-06 |
BE1004573A4 (fr) | 1992-12-15 |
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