EP0472608A1 - Method for simultaneous control of cleaning and hygiene and agent for use when carrying out the method - Google Patents

Method for simultaneous control of cleaning and hygiene and agent for use when carrying out the method

Info

Publication number
EP0472608A1
EP0472608A1 EP19900908195 EP90908195A EP0472608A1 EP 0472608 A1 EP0472608 A1 EP 0472608A1 EP 19900908195 EP19900908195 EP 19900908195 EP 90908195 A EP90908195 A EP 90908195A EP 0472608 A1 EP0472608 A1 EP 0472608A1
Authority
EP
European Patent Office
Prior art keywords
cleaning
hygiene
agent
dye
dyes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP19900908195
Other languages
German (de)
English (en)
French (fr)
Inventor
Per Bruun Famme
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ISOLINE AS
Original Assignee
ISOLINE AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ISOLINE AS filed Critical ISOLINE AS
Publication of EP0472608A1 publication Critical patent/EP0472608A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40Dyes ; Pigments
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/84Systems specially adapted for particular applications
    • G01N21/88Investigating the presence of flaws or contamination
    • G01N21/91Investigating the presence of flaws or contamination using penetration of dyes, e.g. fluorescent ink

Definitions

  • the present invention relates to a method for simultaneous control of cleaning and hygiene, so-called prophylactic cleaning, in particular for use in the food industry, hospitals and other places where hygiene requirements are high.
  • the invention further relates to an agent for use when carrying out the method.
  • Bacteriological methods can only be used for determining live microorganisms (e.g. bacteria and fungi), but not for determining the total amount of organic contaminations which may give rise to bacteria growth. This entails that by bacteriological methods only the bacteriological hygiene state is determined, whereas no impression of the overall hygiene is obtained.
  • live microorganisms e.g. bacteria and fungi
  • Bacteriological methods as an expression of the over ⁇ all hygiene state further entail that inadequate hygiene can be masked as a result of efficient disinfection. This entails the risk that a build-up of organic contaminations which have not been measured or detected may give rise to growth of microorganisms, in particular microorganisms of resistant or pathogenic nature.
  • an otherwise non-colouring cleaning agent contains a dye or a combination of such dyes which react chemically with organic matter - only organic matter of vegetable or animal origin - and dyes the organic matter with a visible colour shade, such organic matter is made visible during the cleaning process proper.
  • organic contaminations of any kind including hard to see or even invisible contaminations, are made visible and markedly distinguishable form the background as such, whereby places at which the required cleaning has been inadequate are immediately revealed.
  • the invention thus relates to a method for simultaneous control of cleaning and hygiene, so-called prophylactic cleaning, in particular for use in the food industry and hospitals, and the method of the present invention is characterized in that an aqueous solution of a cleaning agent containing a dye or a combination of such dyes which bind on and colour organic matter of animal origin is applied onto the surfaces to be cleaned when performing the cleaning, whereby contamination, if any, of the surfaces shows itself by colouring thereof.
  • US patent specification No. 4 745 797 discloses a method of detecting leaks by which a dye solution is applied onto the object to be detected.
  • the organic material in particular mineral oil fractions, seeping through the leak will subsequently evoke a colour reaction and consequently reveal the leak.
  • the method is particularly useful for leak control of fuel tanks in aircrafts.
  • Such a dye method may also be used for revealing unevenness or cracks in a surface, e.g. as disclosed in DE public disclosure No. 1 773 270. This is an indirect (not immediately visible) colour reaction with specific substances which call for detection with UV-light in order to be labeled.
  • prophylactic cleaning is understood a method which in conjunction with any kind of cleaning process and any cleaning agent can visualize even the tiniest occurrence of dirt during the cleaning process proper.
  • Any person can - without special qualifications and without using any kind of aids - quickly, in a simple way and reliably evaluate the course and result of a cleaning solely based on the presence or absence of colour on the cleaned surface.
  • Any cleaning parameter including choice of agents, equipment and method can be evaluated objectively during the cleaning proper. Hereby it is made possible to optimize all cleaning parameters in view of obtaining the desired hygiene at a minimum of economical, environmental and human costs.
  • the dye used in the method of the present invention may be any dye or a specific combination of such dyes which can bind on organic materials of any animal and vegetable kind, such as proteins, lipids and carbohydrates, and in the process colour these materials if the dye is stable in the selected combination with the cleaning agent.
  • a variety of dyes have this capability, and the invention is thus not limited to any particular dye or any particular cleaning agent.
  • the method of the invention is extremely usable in slaughterhouses and other food producing and processing industries it is in practice preferred to use dyes which are already known - and approved - in connection with food.
  • Examples of food dyes which are approved in the EEC-countries are Ponceau 4R (E124), Carraoisine (E122), Amaranth (E123), Erythrosine BS (E127), Ponceau 6R (E126) and Scarlet GN (E125), all of which are red dyes.
  • Yellow and orange dyes may be Orange GGN (Elll), Tartrazine (E102), Sunset Yellow FCF (E110), Acid Yellow (E105), Quinoline Yellow (E104) and Chrysoine S (E103).
  • Green, blue, violet and black dyes are also known, e.g. Brilliant Green BS (E142), Indigo Carmine (E132), Patent Blue V (E131) and Black BN (E151).
  • Erythrosine BS (E127), a red dye which is well-known for use in connection with colouring of sausages.
  • the substance which is marketed by Pointing Ltd., Northhumberland, England, under the trade name "Hexacol Erythrosine Supra” is- the disodium salt of the compound 2,4,5,7-tetraiodofluorescein, having the formula
  • This dye is preferred because it is extremely well-suited for the use. It thus reacts very quickly and has an intensive colour effect. Further it exhibits negligent toxicity, and it is already widely used in the food industry and other areas within which the present method is usable.
  • Erythrosine BS (E127) has been used within odontology, where it is administered in tablets for control of toothbrushing, in particular with children. Also here advantage is taken of the marked colour effect and the negligent toxicity.
  • the selected dye has been added to the concentrated cleaning agent, whereby the dye is applied onto the surfaces during cleaning.
  • the method according to the invention is applicable in connection with all kinds of cleaning, such as foam cleaning, manual cleaning, circulation cleaning, in washing machines, when cleaning containers etc.
  • the preferred dye E127 When using the preferred dye E127 preferably 1 g E127 per kg cleaning agent is added. As the cleaning agent is typically used in concentrations of 0.2-2,0% (w/w), the dye concentration used will be 2-20 mg per 1 end solution.
  • measuring or evaluation of the cleaning quality and the hygiene standard can be performed in various ways: -
  • Samples of the coloured surfaces can be taken out by scraping and a chemical/technical measurement of the dye concentration performed, e.g. spectrophotometric- ally.
  • the cleaning consists such as mechanial processing, the efficiency of the cleaning agent and the like.
  • the method may also be used to ensure that during flushing all traces of the cleaning agent have been removed.
  • the prophylactic cleaning agent has optimal technical efficiency:
  • the product provides the desired foam formation and foam stability. - the product colours and makes visible all dirt occurences in the course of approx. 5 min.
  • the prophylactic cleaning agent results in optimal hygiene:
  • the prophylactic cleaning agent causes none of the traditional nuisances to the user:

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Detergent Compositions (AREA)
  • Cleaning By Liquid Or Steam (AREA)
  • Cleaning In General (AREA)
  • Dental Tools And Instruments Or Auxiliary Dental Instruments (AREA)
EP19900908195 1989-05-17 1990-05-16 Method for simultaneous control of cleaning and hygiene and agent for use when carrying out the method Withdrawn EP0472608A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DK2395/89 1989-05-17
DK239589A DK239589D0 (da) 1989-05-17 1989-05-17 Fremgangsmaade til simultan rengoerings- og hygiejnekontrol samt middel til brug ved fremgangsmaaden

Publications (1)

Publication Number Publication Date
EP0472608A1 true EP0472608A1 (en) 1992-03-04

Family

ID=8112079

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19900908195 Withdrawn EP0472608A1 (en) 1989-05-17 1990-05-16 Method for simultaneous control of cleaning and hygiene and agent for use when carrying out the method

Country Status (11)

Country Link
EP (1) EP0472608A1 (fi)
JP (1) JPH05504979A (fi)
AU (1) AU640662B2 (fi)
CA (1) CA2057008A1 (fi)
DK (1) DK239589D0 (fi)
FI (1) FI915382A0 (fi)
HU (1) HU208740B (fi)
IS (1) IS3577A7 (fi)
PL (1) PL164408B1 (fi)
PT (1) PT94076A (fi)
WO (1) WO1990014591A1 (fi)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU669163B2 (en) * 1992-03-20 1996-05-30 Unilever Plc Aqueous cleaning composition containing protein binding dye
EP0715713B1 (de) * 1993-08-23 1997-05-14 HENKEL-ECOLAB GmbH & CO. OHG Verfahren zur differenzierung von organischen lebensmittelrückständen auf harten oberflächen
WO2001036663A2 (en) * 1999-11-15 2001-05-25 Chemclean Corporation Bio-burden visualization system
DE10055557C2 (de) * 2000-11-09 2002-09-26 Ecolab Gmbh & Co Ohg Verfahren zur gleichzeitigen Erfassung mehrerer Rückstandsarten
WO2007054238A1 (en) * 2005-11-08 2007-05-18 Unilever N.V. Hygiene indicator device
US9372142B2 (en) * 2012-02-27 2016-06-21 Wisconsin Alumni Research Foundation Liquid crystal device and method for screening protein stabilizing agents or optimal protein concentrations to prevent unfolding
CN102830098A (zh) * 2012-07-20 2012-12-19 江苏广播电视大学 一种测定苦味酸含量的荧光传感器及其制备方法
CN105592696B (zh) 2013-07-22 2019-05-17 埃梅卡泰克有限责任公司 用于有效抑制蝇种群的系统
US9170205B2 (en) * 2013-09-18 2015-10-27 Metrex Research, LLC Disinfection and cleaning confirmation system
US20180000093A1 (en) * 2015-01-16 2018-01-04 Emekatech, Llc Systems, methods and compositions for effective insect population suppression

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1219175A (en) * 1968-04-03 1971-01-13 Electroflor Inc Process for fluorescence detection of estremely thin tracer films
US3386920A (en) * 1965-10-04 1968-06-04 James R. Alburger Process for fluorescence detection of extremely small flaws
US3915886A (en) * 1974-02-21 1975-10-28 Rockwell International Corp Water washable dye penetrant composition and method for utilizing same
CA1052244A (en) * 1975-05-23 1979-04-10 Orlando G. Molina Water washable dye penetrant composition and method of application
US4069419A (en) * 1975-09-08 1978-01-17 Rockwell International Corporation Dry developer composition for dye penetrant inspection and method for employing same
EP0061297A3 (en) * 1981-03-19 1983-11-30 Brent Chemicals International Plc Penetrant inspection methods and compositions
US4745797A (en) * 1984-05-07 1988-05-24 Lockheed Corporation Method and apparatus for detecting hydrocarbon fuel leaks
US4858465A (en) * 1988-06-21 1989-08-22 Rockwell International Corporation Water washable contaminant detection and labeling compositions and method for utilizing same

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9014591A1 *

Also Published As

Publication number Publication date
CA2057008A1 (en) 1990-11-18
WO1990014591A1 (en) 1990-11-29
DK239589D0 (da) 1989-05-17
IS3577A7 (is) 1990-11-18
JPH05504979A (ja) 1993-07-29
PL285229A1 (en) 1991-01-28
HUT60038A (en) 1992-07-28
FI915382A0 (fi) 1991-11-14
PL164408B1 (pl) 1994-07-29
PT94076A (pt) 1991-01-08
HU904246D0 (en) 1992-02-28
HU208740B (en) 1993-12-28
AU5738990A (en) 1990-12-18
AU640662B2 (en) 1993-09-02

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