EP0462779A2 - Method of making steel useful in springs - Google Patents
Method of making steel useful in springs Download PDFInfo
- Publication number
- EP0462779A2 EP0462779A2 EP91305456A EP91305456A EP0462779A2 EP 0462779 A2 EP0462779 A2 EP 0462779A2 EP 91305456 A EP91305456 A EP 91305456A EP 91305456 A EP91305456 A EP 91305456A EP 0462779 A2 EP0462779 A2 EP 0462779A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- plate
- cold
- steel
- rolled strip
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/02—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for springs
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/02—Hardening by precipitation
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
- C21D8/0273—Final recrystallisation annealing
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/24—Ferrous alloys, e.g. steel alloys containing chromium with vanadium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/26—Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/34—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of silicon
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0236—Cold rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
- C21D8/0263—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
Definitions
- the present invention relates to a method of making steel which is useful in springs, such as the diaphragm spring component in clutches for motor vehicles.
- the diaphragm spring is made of carbon tool steel such as SK5 (Japanese Industrial Standard). However, springs of carbon steel can relax quickly, in that they may become inoperative when the temperature thereof reaches or exceeds the high environmental temperature of 150°C.
- An object of the present invention is to provide a method of making steel having a property resisting high temperature, whereby a spring made of the steel is more resistant to relaxation at relatively high temperatures.
- Another object of the present invention is to provide steel which may be quickly quenched at a low temperature, thereby preventing significant endurance reduction in the steel.
- the method for making steel comprises hot-rolling steel material consisting essentially by weight of from 0.4 % to 0.8 % carbon, from 0.5 % to 2.5 % silicon, from 0.3 % to 2.0 % manganese, from 0.1 % to 1.5 % chromium, from 0.1 % to 0.5 % molybdenum, and the remainder iron and inevitable impurities to form a plate, annealing the hot-rolled plate, cold-rolling the annealed hot-rolled plate at rolling reduction of 10 % to 80 %, annealing the cold-rolled plate at a temperature below Ac1 critical point, heating the annealed cold-rolled plate at a temperature above Ac3 critical point for a time sufficient to austenitize carbide, cooling the heated cold-rolled plate at a speed higher than a lower critical cooling speed, heating the cooled cold-rolled plate for a time necessary for precipitating carbide and then cooling it to a room temperature.
- the lower critical cooling speed is a speed above which the austenite is fully transformed to the martensite.
- molybdenum carbide is finely precipitated, thereby preventing the dislocation migration which causes the relaxation of the spring at high temperature.
- the heating is preferably performed at a temperature between 450°C and 600°C for a time sufficient to precipitate the carbide.
- the silicon content and chromium content are preferably selected so as to satisfy the equation: -7 ⁇ 4xSi(%)-10xCr(%) ⁇ 5.
- the heating of the cooled cold-rolled plate is preferably performed so as to provide an annealed hardness between HV400 and HV550.
- the annealing of the cold-rolled plate is preferably performed at a temperature between 550°C and 730°C, thereby providing carbide having an average grain diameter less than 2 ⁇ m.
- the figure is a graph showing relationship between heating temperature and hardness of steel.
- Carbon is effective in increasing the strength of steel. In order to obtain a strength necessary for the the spring, carbon content of 0.4 % or more by weight must be included. However, if carbon is included in excess of 0.8 %, quenching crack and reduction of toughness of steel occur. Therefore the carbon is included in the range 0.4 % to 0.8 % by weight.
- the material is tempered at high temperature. Silicon is added to prevent the strength from reducing due to the high temperature tempering. It is necessary to add silicon of 0.5 % or more by weight. If the silicon content exceeds 2.5 %, internal oxidation and decarburization which are unfavourable to the spring occur, and graphitization is enhanced in the hot rolling and annealing.
- Manganese is effective in deoxidizing steel and in increasing the hardenability of the steel, if the manganese is included at 0.3 % or more by weight. If the manganese content exceeds 2.0 %, toughness of the steel reduces significantly after quenching and tempering.
- Chromium acts to restrict the graphitization and the internal oxidation which are enhanced by silicon, and is effective in increasing the hardenability as is effected by manganese, if chromium is included at 0.1 % or more by weight. If the chromium content exceeds 1.5 %, toughness of the steel reduces after quenching and tempering.
- Si content and Cr content are most preferably determined to satisfy the following equation, thereby preventing decarburization and graphitization. -7 ⁇ 4xSi(%)-10xCr(%) ⁇ 5 (1)
- the molybdenum included in the steel of the present invention forms carbide in the steel after cold rolling and annealing.
- the carbon becomes solid solution in austenite when the steel is heated over the Ac3 critical point. Consequently, the austenite is transformed into martensite after quenching, and carbide separates finely upon tempering at high temperature, thereby significantly increasing endurance whilst withstanding against relaxation.
- it is necessary to include molybdenum of at least 0.1 % but no more than 0.5 % by weight. If the molybdenum content exceeds 0.5 %, a large amount of carbide remains without becoming solid solution in austenite when the steel is heated above the Ac3 critical point.
- vanadium and niobium if included in the steel of the present invention become carbide after the cold rolling and annealing thereof. Remaining vanadium and niobium without becoming solid solution in austenite act to prevent austenite grain from growing.
- solid solution of vanadium and niobium in austenite are in solid solution in martensite when quenching, and precipitate finely as carbide when tempering, thereby enhancing endurance whilst withstanding against relaxation.
- vanadium and/or niobium each in an amount of 0.05 % or more are necessary. If the individual content of either or both exceeds 0.5 %, the quantity of undissolved carbide in austenite increases when the steel is heated above Ac3 point, thereby reducing fatigue strength of the steel.
- the steel spring is fatigued by repeated bending or twisting.
- Existence of hard inclusions such as aluminum aggravates this fatigue.
- the aluminium content of the steel is preferably less than 0.020 weight percent.
- the annealing after the cold rolling is performed at a temperature above 730°C (Ac1 critical point), spheroidized grain of carbide becomes coarse. Consequently, it takes a long time to transform the carbide to austenite, resulting in increase of decarburization causing deterioration of spring characteristic. Therefore, the annealing after the cold rolling is carried out at a temperature below the Ac1 point. If the annealing temperature is lower than 550°C, the hardness increases, so that the formability of the material reduces. Therefore, the annealing temperature is between 550°C and 730°C.
- the average grain diameter of carbide after the annealing is less than 2 ⁇ m, carbide is easily dissolved austenite at quenching. Therefore, it is necessary to maintain the average grain diameter of carbide to a value smaller than 2 ⁇ m for effectively performing the quenching.
- the strip is heated at a temperature higher than the critical point Ac3 for a time sufficient for austenitizing the spheroidal carbide, after which it is cooled at a speed higher than a lower critical cooling speed, namely quenching. Thereafter, the strip is heated at a temperature between 450°C and 600°C for a time to precipitate fine carbide and cooled to a room temperature (that is tempering). At the quenching, the parent material is austenitized by heating it over the Ac3 point, and then carbon and other elements are dissolved to martensite by cooling at a speed higher than the lower critical cooling speed.
- Table 1 shows contents of steels.
- a to F are steels of the present invention
- G to L are comparative steels.
- Each of the steels A to F is made into a hot-rolled plate of 3.5 mmt by ordinary hot rolling and then the plate is annealed and cold rolled at a rolling reduction between 5 % and 90 %. Thereafter, the steel is annealed at 700°C below the Ac1 point for 10 hours, and is soaked at 900°C above the Ac3 point for a period necessary to provide remaining carbide ratio below 1 % by weight. Thereafter, the steel is quenched into oil.
- Table 2 shows results of tests for edge crack and depth of decarburization.
- edge crack occurs. If the rolling reduction is smaller than 10 %, carbide becomes coarse. Consequently, it takes a long time to dissolve carbide into austenite, so that the depth of decarburization increases significantly.
- Each of the steels A to F is made into a hot-rolled plate of 3.5 mmt by ordinary hot rolling and annealed and cold rolled at rolling reduction of 35 % to form a cold rolled plate of 2.3 mm. Thereafter, the steel is annealed once at 700°C for 10 hours, and is heated at a temperature between 850°C and 900°C for 10 minutes. Thereafter, the steel is quenched into oil and tempered at a temperature between 420°C and 630°C for 30 minutes.
- a relaxation test was performed in order to estimate endurance against relaxation. The test was carried out at 350°C, initial 1.0 % strain, holding time of 12 hours. Load reduction after the test was regarded as relaxation rate.
- Table 3 shows the result of the relaxation test. Since comparative example G is smaller than the present invention in carbon content, comparative example 1 is smaller in silicon content, comparative example J is in manganese content, and K is in chromium content, each of these steels has low strength so that the relaxation rate thereof is high. Although the comparative example H has a large carbon content, the relaxation rate is not largely reduced. Since the comparative example L has no molybdenum, the carbide of which is effective to increase the endurance, relaxation rate is very high. Although each of comparative examples A', D' and F' has the same ingredient content as the present invention, the tempering temperature is out of the range of the present invention. Consequently, the relaxation rate is not largely reduced.
- each steel according to the present invention has a very low relaxation rate comparing with the comparative examples, which means that the steel has a high endurance withstanding against the relaxation.
- Embodiments A to G in Table 4 are steels of the present invention and H to L are comparative steels.
- Each of the steels in the table was hot-rolled to provide a hot-rolled plate having a thickness of 3.5 mmt, and then annealing the hot-rolled plate.
- the plate was cold rolled at rolling reduction of 35 % to prepare a cold-rolled plate of 2.3 mmt thickness.
- the cold-rolled plate was annealed at a temperature between 650°C and 750°C for 10 hours to provide a test piece.
- Hardenability test was performed in such a manner that the test piece was rapidly heated to 850°C at the rate of 140C o /sec, heated from 850°C to a test temperature between 900°C and 1100°C at the rate of 30C o /sec, and then rapidly cooled immediately after the heating without taking a holding time. The hardenability was estimated by the hardness of the test piece after the quenching. Results of the test are shown in the attached figure.
- the test piece A having ingredient contents according to the present invention has an average grain diameter of carbide less than 2 ⁇ m when annealed at 650°C and 700°C. Even if the test piece A is heated to the lowest temperature 900°C, the hardness becomes the higher value. However, if it is annealed at 750°C so that the average grain diameter exceeds 2 ⁇ m, the hardness does not reach the highest value unless the quenching temperature is elevated up to 950°C.
- the comparative example H has a SICR value of -7.42 out of the range of the present invention. Consequently a large amount of chromium remains in carbide after the annealing. Accordingly, the steel must be heated up to 1000°C in order to obtain the higher hardness, although the average grain diameter is smaller than 2 ⁇ m.
- Fatigue test and relaxation test piece are estimated as follows.
- the cold-rolled plate having 2.3 mm thickness is annealed at 680°C for 10 hours, and then heated at 900°C and quenched. Thereafter, a plurality of the plates are tempered at various temperatures for 30 minutes.
- the fatigue test was performed in alternating plane bending fatigue. The result of the test is shown in Table 5.
- the steel A of the present invention has a hardness approximately equal to the comparative example I, the steel A is superior to the comparative example I in fatigue strength. This is caused by the fact that the aluminum content of the steel A is less than 0.020 weight percent, which means hard inclusion causing fatigue fracture is small.
- the steel G has the same fatigue characteristic as steel A.
- the comparative steel J has a small Cr content compared with Si content, so that SICR value is 7.50 out of the range of the present invention, producing graphite at annealing.
- SICR value is 7.50 out of the range of the present invention, producing graphite at annealing.
- decarburization increased.
- the fatigue characteristic is inferior to the steels A and G.
- a to G are steels of the present invention
- H to L are comparative steels.
- Each of the steels in the table was hot rolled to provide a hot-rolled plate having a thickness of 3.5 mmt, and the hot-rolled plate was then annealed.
- the plate was cold rolled at rolling reduction of 35 % to prepare a cold-rolled plate of 2.3 mmt thickness.
- the cold-rolled plate was annealed at 680°C for 10 hours, and then heated at a temperature between 850°C and 900°C for 10 minutes and quenched into oil. All plates were tempered at various temperatures for 30 minutes.
- the fatigue test was performed in alternating plane bending fatigue. The result of the test is shown in Table 8.
- the steel E of the present invention has a hardness approximately equal to the comparative example I, the steel E is superior to the comparative example I in fatigue strength due to the lower aluminium content.
- the fatigue strength may reduce if the annealed hardness exceeds HV550.
- Test temperature was 350°C, initial strain 1.0 %, and holding time 12 hours. Table 9 shows the test results.
- Comparative steels H and J have small C content and Si content, and hence they have high relaxation rates, respectively. Since comparative steel K has no Mo, it has a high relaxation rate. Even if each of steels A, D, E and G include components within the present invention, the relaxation rate is not significantly reduced if the tempering temperature increases and hardness is lower than an annealed hardness of HV400, as shown in comparative examples II.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Heat Treatment Of Steel (AREA)
- Heat Treatment Of Articles (AREA)
Abstract
Description
- The present invention relates to a method of making steel which is useful in springs, such as the diaphragm spring component in clutches for motor vehicles.
- In recent years, the environmental temperature of the spring used in a machine has increased with increase of the output power of the machine. For example, clutch torque developed in motor vehicle clutches can increase due to increase of the engine power of the vehicle, particularly in four-wheel drive vehicles. As a result, the environmental temperature of the clutch increases up to 250-350°C from the ordinary maximum of 150°C found in conventional motor vehicle clutch springs.
- The diaphragm spring is made of carbon tool steel such as SK5 (Japanese Industrial Standard). However, springs of carbon steel can relax quickly, in that they may become inoperative when the temperature thereof reaches or exceeds the high environmental temperature of 150°C.
- It is known that if the silicon content of steel is increased, endurance of the spring, that is a property of the spring resisting heat without settling, increases. However, conventional steels which include a large silicon content can be liable to relax at a high temperature.
- An object of the present invention is to provide a method of making steel having a property resisting high temperature, whereby a spring made of the steel is more resistant to relaxation at relatively high temperatures.
- Another object of the present invention is to provide steel which may be quickly quenched at a low temperature, thereby preventing significant endurance reduction in the steel.
- It has now been surprisingly found that steel having better or even excellent endurance against high temperature relaxation of springs made therefrom could be made by properly controlling solid solution and precipitation of carbide in steel which includes carbon (C), silicon (Si), manganese (Mn), chromium (Cr), molybdenum (Mo) and optionally others.
- According to the present invention, the method for making steel comprises hot-rolling steel material consisting essentially by weight of from 0.4 % to 0.8 % carbon, from 0.5 % to 2.5 % silicon, from 0.3 % to 2.0 % manganese, from 0.1 % to 1.5 % chromium, from 0.1 % to 0.5 % molybdenum, and the remainder iron and inevitable impurities to form a plate, annealing the hot-rolled plate, cold-rolling the annealed hot-rolled plate at rolling reduction of 10 % to 80 %, annealing the cold-rolled plate at a temperature below Ac1 critical point, heating the annealed cold-rolled plate at a temperature above Ac3 critical point for a time sufficient to austenitize carbide, cooling the heated cold-rolled plate at a speed higher than a lower critical cooling speed, heating the cooled cold-rolled plate for a time necessary for precipitating carbide and then cooling it to a room temperature.
- The lower critical cooling speed is a speed above which the austenite is fully transformed to the martensite.
- In the last heating process, molybdenum carbide is finely precipitated, thereby preventing the dislocation migration which causes the relaxation of the spring at high temperature. The heating is preferably performed at a temperature between 450°C and 600°C for a time sufficient to precipitate the carbide.
-
- The heating of the cooled cold-rolled plate is preferably performed so as to provide an annealed hardness between HV400 and HV550.
- Furthermore, the annealing of the cold-rolled plate is preferably performed at a temperature between 550°C and 730°C, thereby providing carbide having an average grain diameter less than 2µm.
- In order that the invention may be readily appreciated and carried into effect, embodiments thereof will now be described by way of example only, and with reference to the accompanying drawing.
- The figure is a graph showing relationship between heating temperature and hardness of steel.
- Quantity of each component in the steel, preparation conditions and factors for their numerical limitation are now described.
- Carbon is effective in increasing the strength of steel. In order to obtain a strength necessary for the the spring, carbon content of 0.4 % or more by weight must be included. However, if carbon is included in excess of 0.8 %, quenching crack and reduction of toughness of steel occur. Therefore the carbon is included in the range 0.4 % to 0.8 % by weight.
- In the method of the present invention, the material is tempered at high temperature. Silicon is added to prevent the strength from reducing due to the high temperature tempering. It is necessary to add silicon of 0.5 % or more by weight. If the silicon content exceeds 2.5 %, internal oxidation and decarburization which are unfavourable to the spring occur, and graphitization is enhanced in the hot rolling and annealing.
- Manganese is effective in deoxidizing steel and in increasing the hardenability of the steel, if the manganese is included at 0.3 % or more by weight. If the manganese content exceeds 2.0 %, toughness of the steel reduces significantly after quenching and tempering.
- Chromium acts to restrict the graphitization and the internal oxidation which are enhanced by silicon, and is effective in increasing the hardenability as is effected by manganese, if chromium is included at 0.1 % or more by weight. If the chromium content exceeds 1.5 %, toughness of the steel reduces after quenching and tempering.
-
- The molybdenum included in the steel of the present invention forms carbide in the steel after cold rolling and annealing. The carbon becomes solid solution in austenite when the steel is heated over the Ac3 critical point. Consequently, the austenite is transformed into martensite after quenching, and carbide separates finely upon tempering at high temperature, thereby significantly increasing endurance whilst withstanding against relaxation. In order to obtain such an effect, it is necessary to include molybdenum of at least 0.1 % but no more than 0.5 % by weight. If the molybdenum content exceeds 0.5 %, a large amount of carbide remains without becoming solid solution in austenite when the steel is heated above the Ac3 critical point.
- vanadium and niobium if included in the steel of the present invention become carbide after the cold rolling and annealing thereof. Remaining vanadium and niobium without becoming solid solution in austenite act to prevent austenite grain from growing. On the other hand, solid solution of vanadium and niobium in austenite are in solid solution in martensite when quenching, and precipitate finely as carbide when tempering, thereby enhancing endurance whilst withstanding against relaxation. In order to attain these effects, vanadium and/or niobium each in an amount of 0.05 % or more are necessary. If the individual content of either or both exceeds 0.5 %, the quantity of undissolved carbide in austenite increases when the steel is heated above Ac3 point, thereby reducing fatigue strength of the steel.
- The steel spring is fatigued by repeated bending or twisting. Existence of hard inclusions such as aluminum aggravates this fatigue. To reduce the influence of any such hard inclusion, the aluminium content of the steel is preferably less than 0.020 weight percent.
- Preferred manufacturing conditions are now described, for steel plate or strip.
- In the cold rolling, when rolling reduction is smaller than 10 %, the grain size of carbide becomes coarse when annealed below the critical point Ac1. Consequently, a long time is required for transforming the carbide to austenite when heated above the Ac3 critical point, which causes an increase in decarburization and hence spring characteristic is deteriorated. When the rolling reduction is larger than 80 %, work hardening due to the cold rolling is remarkably increased, causing deformation such as edge crack. Therefore, an upper limit is 80 %.
- If the annealing after the cold rolling is performed at a temperature above 730°C (Ac1 critical point), spheroidized grain of carbide becomes coarse. Consequently, it takes a long time to transform the carbide to austenite, resulting in increase of decarburization causing deterioration of spring characteristic. Therefore, the annealing after the cold rolling is carried out at a temperature below the Ac1 point. If the annealing temperature is lower than 550°C, the hardness increases, so that the formability of the material reduces. Therefore, the annealing temperature is between 550°C and 730°C.
- If the average grain diameter of carbide after the annealing is less than 2µm, carbide is easily dissolved austenite at quenching. Therefore, it is necessary to maintain the average grain diameter of carbide to a value smaller than 2µm for effectively performing the quenching.
- In order to increase the strength of the steel made by the cold rolling and annealing to a value necessary for the spring, the strip is heated at a temperature higher than the critical point Ac3 for a time sufficient for austenitizing the spheroidal carbide, after which it is cooled at a speed higher than a lower critical cooling speed, namely quenching. Thereafter, the strip is heated at a temperature between 450°C and 600°C for a time to precipitate fine carbide and cooled to a room temperature (that is tempering). At the quenching, the parent material is austenitized by heating it over the Ac3 point, and then carbon and other elements are dissolved to martensite by cooling at a speed higher than the lower critical cooling speed. By tempering the material at a temperature higher than 450°C, carbide of Mo, V and Nb is finely precipitated from the martensite, thereby increasing the endurance withstanding against the relaxation. If the tempering is carried out at a higher temperature than 600°C, a carbide of Mo, V and Nb becomes coarse which can not prevent the dislocation migration. In addition, the strength of the steel largely reduces. Therefore, the tempering is performed at a temperature below 600°C.
- Table 1 shows contents of steels. In the table, A to F are steels of the present invention, and G to L are comparative steels.
- Each of the steels A to F is made into a hot-rolled plate of 3.5 mmt by ordinary hot rolling and then the plate is annealed and cold rolled at a rolling reduction between 5 % and 90 %. Thereafter, the steel is annealed at 700°C below the Ac1 point for 10 hours, and is soaked at 900°C above the Ac3 point for a period necessary to provide remaining carbide ratio below 1 % by weight. Thereafter, the steel is quenched into oil.
- Table 2 shows results of tests for edge crack and depth of decarburization. When the rolling reduction exceeds 80 %, edge crack occurs. If the rolling reduction is smaller than 10 %, carbide becomes coarse. Consequently, it takes a long time to dissolve carbide into austenite, so that the depth of decarburization increases significantly.
- Each of the steels A to F is made into a hot-rolled plate of 3.5 mmt by ordinary hot rolling and annealed and cold rolled at rolling reduction of 35 % to form a cold rolled plate of 2.3 mm. Thereafter, the steel is annealed once at 700°C for 10 hours, and is heated at a temperature between 850°C and 900°C for 10 minutes. Thereafter, the steel is quenched into oil and tempered at a temperature between 420°C and 630°C for 30 minutes.
- A relaxation test was performed in order to estimate endurance against relaxation. The test was carried out at 350°C, initial 1.0 % strain, holding time of 12 hours. Load reduction after the test was regarded as relaxation rate.
- Table 3 shows the result of the relaxation test. Since comparative example G is smaller than the present invention in carbon content, comparative example 1 is smaller in silicon content, comparative example J is in manganese content, and K is in chromium content, each of these steels has low strength so that the relaxation rate thereof is high. Although the comparative example H has a large carbon content, the relaxation rate is not largely reduced. Since the comparative example L has no molybdenum, the carbide of which is effective to increase the endurance, relaxation rate is very high. Although each of comparative examples A', D' and F' has the same ingredient content as the present invention, the tempering temperature is out of the range of the present invention. Consequently, the relaxation rate is not largely reduced.
-
-
- Each of the steels in the table was hot-rolled to provide a hot-rolled plate having a thickness of 3.5 mmt, and then annealing the hot-rolled plate. The plate was cold rolled at rolling reduction of 35 % to prepare a cold-rolled plate of 2.3 mmt thickness. The cold-rolled plate was annealed at a temperature between 650°C and 750°C for 10 hours to provide a test piece. Hardenability test was performed in such a manner that the test piece was rapidly heated to 850°C at the rate of 140Co/sec, heated from 850°C to a test temperature between 900°C and 1100°C at the rate of 30Co/sec, and then rapidly cooled immediately after the heating without taking a holding time. The hardenability was estimated by the hardness of the test piece after the quenching. Results of the test are shown in the attached figure.
- As is seen from the graph, the test piece A having ingredient contents according to the present invention has an average grain diameter of carbide less than 2µm when annealed at 650°C and 700°C. Even if the test piece A is heated to the
lowest temperature 900°C, the hardness becomes the higher value. However, if it is annealed at 750°C so that the average grain diameter exceeds 2µm, the hardness does not reach the highest value unless the quenching temperature is elevated up to 950°C. - The comparative example H has a SICR value of -7.42 out of the range of the present invention. Consequently a large amount of chromium remains in carbide after the annealing. Accordingly, the steel must be heated up to 1000°C in order to obtain the higher hardness, although the average grain diameter is smaller than 2µm.
- From the comparisons it will be seen that the carbide is rapidly dissolved into austenite at a lower temperature in accordance with the present invention.
- Fatigue test and relaxation test piece are estimated as follows. The cold-rolled plate having 2.3 mm thickness is annealed at 680°C for 10 hours, and then heated at 900°C and quenched. Thereafter, a plurality of the plates are tempered at various temperatures for 30 minutes.
-
- From the table, it will be seen that although the steel A of the present invention has a hardness approximately equal to the comparative example I, the steel A is superior to the comparative example I in fatigue strength. This is caused by the fact that the aluminum content of the steel A is less than 0.020 weight percent, which means hard inclusion causing fatigue fracture is small. The steel G has the same fatigue characteristic as steel A.
- The comparative steel J has a small Cr content compared with Si content, so that SICR value is 7.50 out of the range of the present invention, producing graphite at annealing. In addition, since a long time was required for austenitization, decarburization increased. As a result, the fatigue characteristic is inferior to the steels A and G.
-
-
- Each of the steels in the table was hot rolled to provide a hot-rolled plate having a thickness of 3.5 mmt, and the hot-rolled plate was then annealed. The plate was cold rolled at rolling reduction of 35 % to prepare a cold-rolled plate of 2.3 mmt thickness. The cold-rolled plate was annealed at 680°C for 10 hours, and then heated at a temperature between 850°C and 900°C for 10 minutes and quenched into oil. All plates were tempered at various temperatures for 30 minutes.
-
- From the table, it will be seen that although the steel E of the present invention has a hardness approximately equal to the comparative example I, the steel E is superior to the comparative example I in fatigue strength due to the lower aluminium content.
- Even if the steel components are within the range of the present invention, the fatigue strength may reduce if the annealed hardness exceeds HV550.
-
- Comparative steels H and J have small C content and Si content, and hence they have high relaxation rates, respectively. Since comparative steel K has no Mo, it has a high relaxation rate. Even if each of steels A, D, E and G include components within the present invention, the relaxation rate is not significantly reduced if the tempering temperature increases and hardness is lower than an annealed hardness of HV400, as shown in comparative examples II.
- While presently preferred embodiments of the present invention have been shown and described, it is to be understood that such disclosure is only for illustration and that various changes and modifications may be made without departing from the scope of the invention as set forth in the appended claims.
Claims (10)
- A method for making steel comprising:
hot-rolling steel material consisting essentially by weight of from 0.4 % to 0.8 % carbon, from 0.5 % to 2.5 % silicon, from 0.3 % to 2.0 % manganese, from 0.1 % to 1.5 % chromium, from 0.1 % to 0.5 % molybdenum,the remainder substantially iron and inevitable impurities to form a strip or plate;
annealing the hot-rolled strip or plate;
cold-rolling the annealed hot-rolled strip or plate at a rolling reduction between 10 % and 80 %;
annealing the cold-rolled strip or plate at a temperature below Ac1 critical point;
heating the annealed cold-rolled strip or plate at a temperature above Ac3 critical point for a time sufficient to austenitize carbide;
cooling the heated cold-rolled strip or plate;
heating the cooled cold-rolled strip or plate for a time necessary for precipitating carbide and then cooling it to a room temperature. - A method according to claim 1 wherein the steel material further comprises
0.05 % to 0.5 % by weight of vanadium and/or 0.05 % to 0.5 % by weight of niobium. - A method according to claim 1 or 2 wherein the steel material further includes no more than 0.020 % by weight of aluminium.
- A method according to any preceding claim claim wherein heating of the cooled cold-rolled stripp or plate is performed at a temperature of 450°C to 600°C.
- A method according to any preceding claim wherein the cooling of the heated cold-rolled strip or plate is performed at a speed higher than a lower critical cooling speed.
- A method according to any preceding claim wherein heating of the cooled cold-rolled strip or plate is performed to provide an annealed hardness of HV400 to HV550.
- A method according to any preceding claim wherein annealing of the cold-rolled strip or plate performed at a temperature of 550°C to 730°C, such as to provide carbide having an average grain diameter less than 2µm.
- A spring constructed of a steel consisting essentially by weight of 0.4 % to 0.8 % carbon, 0.5 % to 2.5 % silicon, 0.3 % to 2.0 % manganese, 0.1 % to 1.5 % chromium, from 0.1 % to 0.5 % molybdenum, the remainder substantially iron and inevitable impurities, optionally including 0.05% to 0.5% vandadium and/or 0.05% to 0.5% niobium and/or no more than 0.020% of aluminium.
- Use of a steel material obtained by a method as claimed in any one of claims 1 to 8 in the production of a diaphragm spring for a motor vehicle clutch.
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP158790/90 | 1990-06-19 | ||
JP15879090A JP2961666B2 (en) | 1990-06-19 | 1990-06-19 | Manufacturing method of spring steel with excellent resistance to warm set |
JP25077/91 | 1991-01-28 | ||
JP2507791A JP2823965B2 (en) | 1991-01-28 | 1991-01-28 | Manufacturing method of steel for diaphragm spring |
JP25076/91 | 1991-01-28 | ||
JP2507691A JP2952862B2 (en) | 1991-01-28 | 1991-01-28 | Manufacturing method of spring steel with excellent hardenability and warm set resistance |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0462779A2 true EP0462779A2 (en) | 1991-12-27 |
EP0462779A3 EP0462779A3 (en) | 1993-09-01 |
EP0462779B1 EP0462779B1 (en) | 1996-09-11 |
Family
ID=27284887
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP91305456A Expired - Lifetime EP0462779B1 (en) | 1990-06-19 | 1991-06-17 | Method of making steel useful in springs |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0462779B1 (en) |
KR (1) | KR930012177B1 (en) |
AU (1) | AU633737B2 (en) |
CA (1) | CA2044639C (en) |
DE (1) | DE69121982T2 (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0672761A2 (en) * | 1994-02-17 | 1995-09-20 | Uddeholm Strip Steel Aktiebolag | Use of a steel alloy |
GB2352726A (en) * | 1999-08-04 | 2001-02-07 | Secr Defence | A steel and a heat treatment for steels |
EP1347072A1 (en) * | 2000-12-20 | 2003-09-24 | Kabushiki Kaisha Kobe Seiko Sho | Steel wire rod for hard drawn spring, drawn wire rod for hard drawn spring and hard drawn spring, and method for producing hard drawn spring |
EP1491647A1 (en) * | 2002-04-02 | 2004-12-29 | Kabushiki Kaisha Kobe Seiko Sho | Steel wire for hard drawn spring excellent in fatigue strength and resistance to settling, and hard drawn spring |
WO2005021190A1 (en) * | 2003-08-28 | 2005-03-10 | Toyota Jidosha Kabushiki Kaisha | Iron-based sintered alloy and manufacturing method thereof |
EP1612287A1 (en) * | 2003-03-28 | 2006-01-04 | Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) | Steel for spring being excellent in resistance to setting and fatigue characteristics |
EP2028285A1 (en) * | 2006-06-09 | 2009-02-25 | Kabushiki Kaisha Kobe Seiko Sho | Steel for high-cleanliness spring with excellent fatigue characteristics and high-cleanliness spring |
EP2682493A1 (en) * | 2011-03-04 | 2014-01-08 | NHK Spring Co.,Ltd. | Spring and manufacturing method thereof |
CN106202937A (en) * | 2016-01-28 | 2016-12-07 | 西北工业大学 | Carbide size Forecasting Methodology in M50 steel forging tissue |
SE1950679A1 (en) * | 2019-06-07 | 2020-12-08 | Voestalpine Prec Strip Ab | Steel strip for flapper valves |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2932943B2 (en) * | 1993-11-04 | 1999-08-09 | 株式会社神戸製鋼所 | High corrosion resistance and high strength steel for springs |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1290235A (en) * | 1961-02-28 | 1962-04-13 | Ct Tech De L Ind Horlogere | Method of manufacturing springs or materials for steel springs and springs or materials obtained by this method, in particular springs for watch movements |
US4770721A (en) * | 1981-08-11 | 1988-09-13 | Aichi Steel Works, Ltd. | Process of treating steel for a vehicle suspension spring to improve sag-resistance |
JPH02240240A (en) * | 1989-03-10 | 1990-09-25 | Aisin Seiki Co Ltd | Diaphragm spring of clutch for automobile use |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5827955A (en) * | 1981-08-11 | 1983-02-18 | Aichi Steel Works Ltd | Spring steel with superior hardenability and wear resistance |
AU547648B2 (en) * | 1981-09-30 | 1985-10-31 | Aichi Steel Works Ltd. | Steel for a vehicle suspension spring |
-
1991
- 1991-06-13 AU AU78373/91A patent/AU633737B2/en not_active Ceased
- 1991-06-14 CA CA002044639A patent/CA2044639C/en not_active Expired - Fee Related
- 1991-06-17 DE DE69121982T patent/DE69121982T2/en not_active Expired - Fee Related
- 1991-06-17 EP EP91305456A patent/EP0462779B1/en not_active Expired - Lifetime
- 1991-06-19 KR KR1019910010243A patent/KR930012177B1/en not_active IP Right Cessation
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1290235A (en) * | 1961-02-28 | 1962-04-13 | Ct Tech De L Ind Horlogere | Method of manufacturing springs or materials for steel springs and springs or materials obtained by this method, in particular springs for watch movements |
US4770721A (en) * | 1981-08-11 | 1988-09-13 | Aichi Steel Works, Ltd. | Process of treating steel for a vehicle suspension spring to improve sag-resistance |
JPH02240240A (en) * | 1989-03-10 | 1990-09-25 | Aisin Seiki Co Ltd | Diaphragm spring of clutch for automobile use |
Non-Patent Citations (1)
Title |
---|
PATENT ABSTRACTS OF JAPAN vol. 14, no. 559 (C-787)12 December 1990 & JP-A-02 240 240 ( AISIN SEIKI ) 25 September 1990 * |
Cited By (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0672761A3 (en) * | 1994-02-17 | 1995-11-08 | Uddeholm Steel Strip | Use of a steel alloy. |
EP0672761A2 (en) * | 1994-02-17 | 1995-09-20 | Uddeholm Strip Steel Aktiebolag | Use of a steel alloy |
US6884306B1 (en) | 1999-08-04 | 2005-04-26 | Qinetiq Limited | Baintic steel |
GB2352726A (en) * | 1999-08-04 | 2001-02-07 | Secr Defence | A steel and a heat treatment for steels |
EP1347072A1 (en) * | 2000-12-20 | 2003-09-24 | Kabushiki Kaisha Kobe Seiko Sho | Steel wire rod for hard drawn spring, drawn wire rod for hard drawn spring and hard drawn spring, and method for producing hard drawn spring |
EP1347072A4 (en) * | 2000-12-20 | 2005-08-31 | Kobe Steel Ltd | Steel wire rod for hard drawn spring, drawn wire rod for hard drawn spring and hard drawn spring, and method for producing hard drawn spring |
US7597768B2 (en) | 2002-04-02 | 2009-10-06 | Kabushiki Kaisha Kobe Seiko Sho | Steel wire for hard drawn spring excellent in fatigue strength and resistance to settling, and hard drawn spring and method of making thereof |
US7763123B2 (en) | 2002-04-02 | 2010-07-27 | Kabushiki Kaisha Kobe Seiko Sho | Spring produced by a process comprising coiling a hard drawn steel wire excellent in fatigue strength and resistance to setting |
EP1491647A4 (en) * | 2002-04-02 | 2005-07-06 | Kobe Steel Ltd | Steel wire for hard drawn spring excellent in fatigue strength and resistance to settling, and hard drawn spring |
EP1491647A1 (en) * | 2002-04-02 | 2004-12-29 | Kabushiki Kaisha Kobe Seiko Sho | Steel wire for hard drawn spring excellent in fatigue strength and resistance to settling, and hard drawn spring |
EP1612287A1 (en) * | 2003-03-28 | 2006-01-04 | Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) | Steel for spring being excellent in resistance to setting and fatigue characteristics |
EP1612287A4 (en) * | 2003-03-28 | 2007-11-21 | Kobe Steel Ltd | Steel for spring being excellent in resistance to setting and fatigue characteristics |
US7615186B2 (en) | 2003-03-28 | 2009-11-10 | Kobe Steel, Ltd. | Spring steel excellent in sag resistance and fatigue property |
WO2005021190A1 (en) * | 2003-08-28 | 2005-03-10 | Toyota Jidosha Kabushiki Kaisha | Iron-based sintered alloy and manufacturing method thereof |
US7749298B2 (en) | 2003-08-28 | 2010-07-06 | Toyota Jidosha Kabushiki Kaisha | Iron-based sintered alloy and manufacturing method thereof |
US8613809B2 (en) | 2006-06-09 | 2013-12-24 | Kobe Steel, Ltd. | High cleanliness spring steel and high cleanliness spring excellent in fatigue properties |
EP2028285A4 (en) * | 2006-06-09 | 2011-04-20 | Kobe Steel Ltd | Steel for high-cleanliness spring with excellent fatigue characteristics and high-cleanliness spring |
EP2028285A1 (en) * | 2006-06-09 | 2009-02-25 | Kabushiki Kaisha Kobe Seiko Sho | Steel for high-cleanliness spring with excellent fatigue characteristics and high-cleanliness spring |
EP2682493A1 (en) * | 2011-03-04 | 2014-01-08 | NHK Spring Co.,Ltd. | Spring and manufacturing method thereof |
EP2682493A4 (en) * | 2011-03-04 | 2014-08-27 | Nhk Spring Co Ltd | Spring and manufacturing method thereof |
US9341223B2 (en) | 2011-03-04 | 2016-05-17 | Nhk Spring Co., Ltd. | Spring and manufacture method thereof |
CN106202937A (en) * | 2016-01-28 | 2016-12-07 | 西北工业大学 | Carbide size Forecasting Methodology in M50 steel forging tissue |
CN106202937B (en) * | 2016-01-28 | 2018-10-19 | 西北工业大学 | M50 steel forgings make carbide size prediction technique in tissue |
SE1950679A1 (en) * | 2019-06-07 | 2020-12-08 | Voestalpine Prec Strip Ab | Steel strip for flapper valves |
WO2020246937A1 (en) * | 2019-06-07 | 2020-12-10 | Voestalpine Precision Strip Ab | Steel strip for flapper valves |
SE543422C2 (en) * | 2019-06-07 | 2021-01-12 | Voestalpine Prec Strip Ab | Steel strip for flapper valves |
EP3980571A4 (en) * | 2019-06-07 | 2023-11-22 | voestalpine Precision Strip AB | Steel strip for flapper valves |
Also Published As
Publication number | Publication date |
---|---|
KR920000959A (en) | 1992-01-29 |
DE69121982T2 (en) | 1997-01-30 |
CA2044639C (en) | 2001-08-28 |
AU7837391A (en) | 1992-01-09 |
AU633737B2 (en) | 1993-02-04 |
CA2044639A1 (en) | 1991-12-20 |
KR930012177B1 (en) | 1993-12-24 |
DE69121982D1 (en) | 1996-10-17 |
EP0462779B1 (en) | 1996-09-11 |
EP0462779A3 (en) | 1993-09-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US5108518A (en) | Method of producing thin high carbon steel sheet which exhibits resistance to hydrogen embrittlement after heat treatment | |
EP0461652A1 (en) | Flat spring hose clamp and manufacture of same | |
JP5030280B2 (en) | High carbon steel sheet with excellent hardenability, fatigue characteristics, and toughness and method for producing the same | |
EP0462779B1 (en) | Method of making steel useful in springs | |
JP3468048B2 (en) | Manufacturing method of high carbon cold rolled steel sheet with excellent formability | |
EP1183399B2 (en) | Method of production of rolling bearing steel having a surface with a lower bainitic structure | |
US6270596B1 (en) | Process for producing high strength shaft | |
JPH039168B2 (en) | ||
JP3918589B2 (en) | Steel plate for heat treatment and manufacturing method thereof | |
JPH03100142A (en) | Case hardening steel for bearing having excellent crushing property and its manufacture | |
JPH0598388A (en) | High toughness and high carbon thin steel sheet and its manufacture | |
JP2000144311A (en) | High carbon thin steel sheet | |
JPH059588A (en) | Production of high carbon steel sheet excellent in formability | |
JPH0598356A (en) | Production of tempering-free-type ti-b type high carbon steel sheet | |
JP2952862B2 (en) | Manufacturing method of spring steel with excellent hardenability and warm set resistance | |
JP3910242B2 (en) | High carbon steel sheet with small in-plane anisotropy | |
JPH0598357A (en) | Production of tempering-free-type high carbon steel sheet | |
KR102476008B1 (en) | High-carbon steel with low hardness and method of manufacturing the same | |
JPH08246051A (en) | Production of medium carbon steel sheet excellent in workability | |
KR100311785B1 (en) | Manufacturing method of alloy wire rod for cold forging | |
JPH0717944B2 (en) | Manufacturing method of bainite steel sheet with excellent spring characteristics | |
JPH0625379B2 (en) | Manufacturing method of high carbon cold rolled steel sheet with excellent toughness after heat treatment | |
JP2919642B2 (en) | Manufacturing method of high carbon steel for tempering with excellent toughness and fatigue resistance | |
JPH04116137A (en) | High toughness high carbon cold rolled steel sheet and its manufacture | |
JP4472164B2 (en) | Spring steel with excellent warm resistance |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 19910712 |
|
AK | Designated contracting states |
Kind code of ref document: A2 Designated state(s): DE FR GB |
|
PUAL | Search report despatched |
Free format text: ORIGINAL CODE: 0009013 |
|
AK | Designated contracting states |
Kind code of ref document: A3 Designated state(s): DE FR GB |
|
17Q | First examination report despatched |
Effective date: 19941108 |
|
GRAH | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOS IGRA |
|
GRAH | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOS IGRA |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): DE FR GB |
|
ET | Fr: translation filed | ||
REF | Corresponds to: |
Ref document number: 69121982 Country of ref document: DE Date of ref document: 19961017 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed | ||
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20010611 Year of fee payment: 11 Ref country code: DE Payment date: 20010611 Year of fee payment: 11 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20010613 Year of fee payment: 11 |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: IF02 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20020617 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20030101 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20020617 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20030228 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST |