EP0462447A1 - Utilisation de colorants azoiques pour l'impression par transfert thermique - Google Patents
Utilisation de colorants azoiques pour l'impression par transfert thermique Download PDFInfo
- Publication number
- EP0462447A1 EP0462447A1 EP91109225A EP91109225A EP0462447A1 EP 0462447 A1 EP0462447 A1 EP 0462447A1 EP 91109225 A EP91109225 A EP 91109225A EP 91109225 A EP91109225 A EP 91109225A EP 0462447 A1 EP0462447 A1 EP 0462447A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alkyl
- omega
- alkyl group
- azo dyes
- nr7r8
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
- B41M5/385—Contact thermal transfer or sublimation processes characterised by the transferable dyes or pigments
- B41M5/388—Azo dyes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/913—Material designed to be responsive to temperature, light, moisture
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/914—Transfer or decalcomania
Definitions
- the main heat source used is a thermal head with which short heating impulses lasting a fraction of a second can be emitted.
- a transfer sheet which contains the dye to be transferred together with one or more binders, a carrier material and possibly other auxiliaries such as release agents or crystallization-inhibiting substances is heated from the rear by the thermal head.
- the dye diffuses from the transfer sheet into the surface coating of the substrate, e.g. into the plastic layer of a coated paper.
- the main advantage of this method is that the amount of color transferred and thus the color gradation can be specifically controlled via the energy to be delivered to the thermal head.
- Thermal transfer printing generally uses the three subtractive primary colors yellow, magenta and cyan, possibly also black, whereby the dyes used for optimum color recording must have the following properties: easy thermal transferability, low tendency to migrate within or from the surface coating of the recording medium at room temperature , high thermal and photochemical stability as well as resistance to moisture and chemicals, no tendency to crystallize when storing the transfer sheet, a suitable color for the subtractive color mixture, a high molar absorption coefficient and easy technical accessibility.
- the azo dyes I themselves are known per se or can be obtained by known methods (EP-B-111 236).
- the invention was therefore based on the object of finding suitable yellow dyes for thermal transfer printing which come closer to the required property profile than the dyes known hitherto.
- a method for transferring azo dyes by diffusion from a support onto a plastic-coated substrate using a thermal head was found, which is characterized in that a support is used for this purpose, on which one or more of the azo dyes I defined at the outset are located.
- radicals R 1 defined by definition ethyl and propyl and especially methyl are preferred.
- radicals R2 by definition, acetyl and cyano are particularly suitable.
- the C chain of said alkyl radicals R3 can be interrupted by one or two non-adjacent links -CO-, -O-CO-, -CO-O- or especially -O- and can have up to two substituents such as bromine and chlorine, hydroxy , Methyl, ethyl, phenyl or cyclohexyl; Examples include: - (CH2) 4-CO- (CH2) 4-O- (CH2) 3-O-Ph; - (CH2) 4-O-CO- (CH2) 3-O-Ph, - (CH2) 3-O-CO- (CH2) 6-O-C6H11; - (CH2) 4-CO-O- (CH2) 8-O-Ph and - (CH2) 3-CO-O- (CH2) 6-O-CH2-Ph; particularly preferred - (CH2) 3-O- (CH2) 2-O-Ph, - (CH2) 3-O- (CH2) 2-O-Ph-2-CH3, - (CH2) 3-O- (CH2) 2-O-
- Residues R4 or R5 can be especially hydrogen, chlorine and cyano, but also fluorine, bromine, nitro and trihalomethyl groups such as trifluoromethyl and trichloromethyl.
- R4 or R5 have the formulas -CO-H, -CO-R6, -O-CO-R6, -CO-OR6, -SO-OR6, -O-SO-OR6, -CO-NR7R8, -O -CO-NR7R8, -SO2-NR7R8 or -O-SO2-NR7R8; those of the formula -CO-OR6 are particularly preferred.
- the rest R6 is one of the above-listed C1-C12-alkyl groups or ⁇ -phenoxy, ⁇ -tolyloxy, ⁇ -benzyloxy or ⁇ -cyclohexyloxy-C1-C12-alkyl groups, the C chain of which each has one or two oxygen atoms can be interrupted in ether function.
- Suitable radicals R7 or R8 are the unsubstituted C1-C12 alkyl groups already mentioned.
- radicals R4 or R5 may be mentioned as examples of the radicals R4 or R5: -CO-CH3, -CO-C2H5, -CO-C6H13, -CO-C11H23, -CO- (CH2) 3-O- (CH2) 2-O-Ph, -CO- (CH2) 4-O-C3H7 and -CO- (CH2) 8-O-CH3; -O-CO-CH3, -O-CO-C4H9, -O-CO-C7H15, -O-CO- (CH2) 3-O-CH3 and -O-CO- (CH2) 4-O-C4H9; -CO-O-CH3, -CO-O-C2H5, -CO-O-C4H9, -CO-O-C6H13, -CO-O-C7H15, -CO-O- (CH2) 4-O-CH3, -CO-O-CH (CH3) -CH2-O-CH3, -CO-O- (
- Preferred azo dyes I can be found in the examples.
- the dyes I to be used according to the invention are distinguished from the yellow dyes previously used for thermal transfer printing by the following properties: easier thermal transferability despite the relatively high molecular weight, improved migration properties in the recording medium at room temperature, higher lightfastness, better resistance to moisture and chemicals, better solubility the production of the printing ink, higher color strength and easier technical accessibility.
- the azo dyes I show significantly better color purity, in particular in dye mixtures, and give improved black prints.
- the transfer sheets required as dye donors for the thermal transfer printing process according to the invention are prepared as follows:
- the azo dyes I are dissolved in an organic solvent, e.g. Isobutanol, methyl ethyl ketone, methylene chloride, chlorobenzene, toluene, tetrahydrofuran or mixtures thereof, processed with one or more binders and possibly other auxiliaries such as release agents or crystallization inhibitors to give a printing ink which preferably contains the dyes in molecularly dispersed solution.
- the printing ink is then applied to an inert support and dried.
- Suitable binders for the use of azo dyes I according to the invention are all materials which are soluble in organic solvents and which are known to serve for thermal transfer printing, i.e. Cellulose derivatives such as methyl cellulose, hydroxypropyl cellulose, cellulose acetate or cellulose acetobutyrate, especially ethyl cellulose, ethyl hydroxyethyl cellulose and cellulose acetate hydrogen phthalate, starch, alginates, alkyd resins such as polyvinyl alcohol or polyvinyl pyrrolidone, and especially polyvinyl acetate and polyvinyl butyrate.
- Cellulose derivatives such as methyl cellulose, hydroxypropyl cellulose, cellulose acetate or cellulose acetobutyrate, especially ethyl cellulose, ethyl hydroxyethyl cellulose and cellulose acetate hydrogen phthalate, starch, alginates, alkyd resins such as polyvinyl alcohol or polyvin
- polymers and copolymers of acrylates or their derivatives such as polyacrylic acid, polymethyl methacrylate or styrene acrylate copolymers, polyester resins, polyamide resins, polyurethane resins or natural resins such as e.g. Gum arabic into consideration.
- binders are often recommended, e.g. those made of ethyl cellulose and polyvinyl butyrate in a weight ratio of 2: 1.
- the weight ratio of binder to dye is usually 8: 1 to 1: 1, preferably 5: 1 to 2: 1.
- Inert carrier materials are, for example, tissue paper, blotting paper or glassine paper and films made of heat-resistant plastics such as polyesters, polyamides or polyimides, these films also being able to be metal-coated.
- the inert carrier can also be coated with a lubricant on the side facing the thermal head in order to prevent the thermal head from sticking to the carrier material.
- Suitable lubricants are, for example, silicones or polyurethanes, as are described in EP-A-216 483.
- the thickness of the dye carrier is generally 3 to 30 microns, preferably 5 to 10 microns.
- the substrate to be printed for example paper, must itself be coated with a binder that absorbs the dye during the printing process.
- a binder that absorbs the dye during the printing process.
- Polymeric materials whose glass transition temperature T g is between 50 and 100 ° C., for example polycarbonates and polyester, are preferably used for this purpose. Further details can be found in EP-A-227 094, EP-A-133 012, EP-A-133 011, JP-A-199 997/1986 or JP-A 283 595/1986.
- a thermal head which can be heated to temperatures above 300 ° C., so that the dye transfer takes place in a maximum of 15 msec.
- transfer sheets were produced in a conventional manner from 8 ⁇ m thick polyester film, which was provided with an approximately 5 ⁇ m thick transfer layer made from a binder B, each of which contained 0.25 g of azo dye I.
- the weight ratio of binder to dye was 4: 1 in each case.
- the substrate to be printed consisted of paper of approx. 120 ⁇ m thickness, which was coated with an 8 ⁇ m thick plastic layer (Hitachi Color Video Print Paper).
- the coated side of the encoder and slave was placed on top of one another, wrapped with aluminum foil and heated to a temperature between 70 and 80 ° C. for two minutes between two heating plates. With similar samples, this process was repeated three times at a higher temperature between 80 and 120 ° C.
- the amount of dye diffused into the plastic layer of the receiver is proportional to the optical density, which was determined as absorbance A photometrically after the respective heating to the temperatures given above.
- the temperature T * at which the extinction reaches the value 1 can also be taken from the application, ie the transmitted light intensity is one tenth of the incident light intensity.
- the smaller the temperature T * the better the thermal transferability of the investigated dye.
- binder B used in each case is indicated.
- EC ethyl cellulose
- PVB polyvinyl butyrate
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4019419 | 1990-06-19 | ||
DE4019419A DE4019419A1 (de) | 1990-06-19 | 1990-06-19 | Verwendung von azofarbstoffen fuer den thermotransferdurck |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0462447A1 true EP0462447A1 (fr) | 1991-12-27 |
EP0462447B1 EP0462447B1 (fr) | 1994-12-21 |
Family
ID=6408614
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP91109225A Expired - Lifetime EP0462447B1 (fr) | 1990-06-19 | 1991-06-06 | Utilisation de colorants azoiques pour l'impression par transfert thermique |
Country Status (4)
Country | Link |
---|---|
US (1) | US5204312A (fr) |
EP (1) | EP0462447B1 (fr) |
JP (1) | JPH04232781A (fr) |
DE (2) | DE4019419A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5929218A (en) * | 1996-05-08 | 1999-07-27 | Hansol Paper Co., Ltd. | Pyridone-based yellow monoazo dye for use in thermal transfer and ink compositions comprising same |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6835708B2 (en) | 2001-03-07 | 2004-12-28 | Nippon Shokubai Co., Ltd. | Graft polymer composition and its production process and uses |
JP5634019B2 (ja) * | 2008-10-14 | 2014-12-03 | キヤノン株式会社 | 色素化合物並びに該色素化合物を含有するインク |
CN105504858A (zh) * | 2016-01-27 | 2016-04-20 | 杭州福莱蒽特精细化工有限公司 | 一种单偶氮基吡啶酮染料及其制备方法和应用 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2951403A1 (de) * | 1979-12-20 | 1981-06-25 | Basf Ag, 6700 Ludwigshafen | Pyridonfarbstoffe |
EP0247737A1 (fr) * | 1986-05-27 | 1987-12-02 | Imperial Chemical Industries Plc | Impression par transfert thermique |
JPS6339380A (ja) * | 1986-08-04 | 1988-02-19 | Mitsubishi Chem Ind Ltd | 感熱転写記録用色素及び感熱転写シート |
EP0302627A2 (fr) * | 1987-08-04 | 1989-02-08 | Imperial Chemical Industries Plc | L'impression par transfert thermique |
EP0319234A2 (fr) * | 1987-12-03 | 1989-06-07 | MITSUI TOATSU CHEMICALS, Inc. | Méthode de coloration utilisant un nouveau colorant jaune et un matériau de transfer à utiliser pour le transfert thermique selon cette méthode |
EP0323259A2 (fr) * | 1987-12-29 | 1989-07-05 | Matsushita Electric Industrial Co., Ltd. | Feuilles de colorants pour l'impression par transfert thermique |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3244960A1 (de) * | 1982-12-04 | 1984-06-07 | Basf Ag, 6700 Ludwigshafen | Pyridonfarbstoffe |
CA1223154A (fr) * | 1983-07-25 | 1987-06-23 | Sadanobu Kawasaki | Feuille de thermodecalcomanie |
JPS6112393A (ja) * | 1984-06-29 | 1986-01-20 | Mitsui Toatsu Chem Inc | 黄色系熱転写用色材 |
GB8504518D0 (en) * | 1985-02-21 | 1985-03-27 | Ici Plc | Thermal transfer dyesheet |
JPH0741746B2 (ja) * | 1985-02-28 | 1995-05-10 | 大日本印刷株式会社 | 熱転写受像シート |
JPS61244595A (ja) * | 1985-04-24 | 1986-10-30 | Mitsubishi Chem Ind Ltd | 感熱転写記録用ピリドンアゾ系色素 |
JPS61262191A (ja) * | 1985-05-16 | 1986-11-20 | Sumitomo Chem Co Ltd | 昇華転写体 |
JPH0714665B2 (ja) * | 1985-06-10 | 1995-02-22 | 大日本印刷株式会社 | 被熱転写シ−ト |
GB8521327D0 (en) * | 1985-08-27 | 1985-10-02 | Ici Plc | Thermal transfer printing |
US4695286A (en) * | 1985-12-24 | 1987-09-22 | Eastman Kodak Company | High molecular weight polycarbonate receiving layer used in thermal dye transfer |
US4740496A (en) * | 1985-12-24 | 1988-04-26 | Eastman Kodak Company | Release agent for thermal dye transfer |
DE69106734T2 (de) * | 1990-02-14 | 1995-05-18 | Mitsubishi Chem Ind | Thermisches Übertragungsaufzeichnungsblatt und Tintenzusammensetzung zur Herstellung desselben. |
-
1990
- 1990-06-19 DE DE4019419A patent/DE4019419A1/de not_active Withdrawn
-
1991
- 1991-06-06 EP EP91109225A patent/EP0462447B1/fr not_active Expired - Lifetime
- 1991-06-06 DE DE59103964T patent/DE59103964D1/de not_active Expired - Lifetime
- 1991-06-12 US US07/714,021 patent/US5204312A/en not_active Expired - Fee Related
- 1991-06-18 JP JP3145742A patent/JPH04232781A/ja active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2951403A1 (de) * | 1979-12-20 | 1981-06-25 | Basf Ag, 6700 Ludwigshafen | Pyridonfarbstoffe |
EP0247737A1 (fr) * | 1986-05-27 | 1987-12-02 | Imperial Chemical Industries Plc | Impression par transfert thermique |
JPS6339380A (ja) * | 1986-08-04 | 1988-02-19 | Mitsubishi Chem Ind Ltd | 感熱転写記録用色素及び感熱転写シート |
EP0302627A2 (fr) * | 1987-08-04 | 1989-02-08 | Imperial Chemical Industries Plc | L'impression par transfert thermique |
EP0319234A2 (fr) * | 1987-12-03 | 1989-06-07 | MITSUI TOATSU CHEMICALS, Inc. | Méthode de coloration utilisant un nouveau colorant jaune et un matériau de transfer à utiliser pour le transfert thermique selon cette méthode |
EP0323259A2 (fr) * | 1987-12-29 | 1989-07-05 | Matsushita Electric Industrial Co., Ltd. | Feuilles de colorants pour l'impression par transfert thermique |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5929218A (en) * | 1996-05-08 | 1999-07-27 | Hansol Paper Co., Ltd. | Pyridone-based yellow monoazo dye for use in thermal transfer and ink compositions comprising same |
Also Published As
Publication number | Publication date |
---|---|
DE59103964D1 (de) | 1995-02-02 |
US5204312A (en) | 1993-04-20 |
JPH04232781A (ja) | 1992-08-21 |
EP0462447B1 (fr) | 1994-12-21 |
DE4019419A1 (de) | 1992-01-02 |
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