EP0454056A1 - Aluminium cathode-plate for the electrowinning of zinc - Google Patents

Aluminium cathode-plate for the electrowinning of zinc Download PDF

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Publication number
EP0454056A1
EP0454056A1 EP91106515A EP91106515A EP0454056A1 EP 0454056 A1 EP0454056 A1 EP 0454056A1 EP 91106515 A EP91106515 A EP 91106515A EP 91106515 A EP91106515 A EP 91106515A EP 0454056 A1 EP0454056 A1 EP 0454056A1
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Prior art keywords
polyolefin
strip
cathode sheet
cathode
plate
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EP91106515A
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German (de)
French (fr)
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EP0454056B1 (en
EP0454056B2 (en
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Herbert Dr. Meissner
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Austria Metall AG
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Austria Metall AG
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
    • C25C7/02—Electrodes; Connections thereof

Definitions

  • the invention relates to a cathode sheet for the electrolytic production of zinc, with a plate made of aluminum and an insulating strip made of plastic melted on at least one edge of the plate surrounding it.
  • insulating strips are arranged at the edges. This is necessary in order to prevent the zinc deposited on the cathode surfaces from growing in the direction of the anode plate or electrolyte trough and thereby producing a short circuit. These insulation strips are either snapped onto the edges of the cathode sheet or pressed on. Versions with screwed insulation strips are also known. These insulation strips themselves are made of plastic, rubber or wood.
  • a cathode plate of the type mentioned is known from DE-A-3 219 300.
  • the cathode sheets are immersed in sulfuric acid, which is used as the electrolyte, the aluminum corrodes. This corrosion occurs preferentially under the strips. This is because the acid penetrates between the sheets and the insulation strips and causes the aluminum to corrode very quickly. There is therefore an early failure of the cathode sheet, since the edges erode, the strip loses its grip on the sheet and thus there is a short circuit when the insulation strip between the growing zinc and the anode plate or electrolyte tray breaks away.
  • copolymeric polyolefin / aluminum proves to be particularly liquid-tight against the aggressive sulfuric acid electrolyte.
  • the insulation strip on the sheet metal side comprises a layer of the copolymeric polyolefin and, moreover, it consists of ordinary polyolefin.
  • This design is very inexpensive because less of the expensive copolymeric polyolefin is required.
  • the insulation strip consists entirely of the highly adhesive polyolefin.
  • the manufacturing process used for this purpose is carried out according to the invention in such a way that the insulation strip is extruded and after the extrusion on the surfaces to be adhered to the cathode sheet metal strip in the heat (at temperatures between 100 and 200 ° C., preferably 160 and 180 ° C. for 1 to 5 min), the sheets are cut to size and then brackets are welded to the narrow side surfaces of the cathode sheet, which connect the narrow side surfaces provided with an insulation strip.
  • the extrusion of the bar is carried out by co-extruding highly adhesive copolymeric polyolefin and normal polyolefin.
  • highly adhesive copolymeric polyolefin and normal polyolefin are advantageously used, as a result of which the cathode sheet metal according to the invention is produced becomes cheaper.
  • the heat required for the extrusion is optimally used.
  • the production can take place continuously, whereby large quantities of such cathode sheet metal strips can be produced. Afterwards, these can only be cut and the brackets required for the current introduction and suspension arranged on them.
  • cathode sheets in such a way that a layer of adhesive copolymeric polyolefin is arranged on the surfaces to be insulated and a part of ordinary polyolefin, which makes up the last body in its essential volume, is pushed onto this layer.
  • copolymeric polyolefins are copolymers of olefin and adhesive additives for metal surfaces.
  • These adhesive additives are usually aliphatic carboxylic acids in an amount of 1 to 10%, for example acrylic acid or its derivatives.
  • esters such as. B. vinyl acetates may be present.
  • Vinyl acetate can also be present at the same time as acrylic acid, as are other terpolymers.
  • those hot melt adhesives based on polyolefin are suitable which have sufficient corrosion resistance is guaranteed.
  • a cathode sheet with a plate 1 made of aluminum is arranged in an electrolyte 2 in a trough 3 on busbars 4, 4 'with its holder 5 and has insulation strips 6, 6' made of polyolefin fastened on both vertical narrow sides.
  • Fig. 2 shows an embodiment of the cathode sheet, in which on the side edge of the aluminum plate 1, a uniformly made of highly adhesive copolymeric polyolefin insulation strip is melted.
  • the insulation strip can be extruded and melted using the extrusion heat.
  • a layer 7 of adhesive copolymeric polyolefin is arranged on the aluminum plate 1 of the cathode sheet, and a U-shaped rail 8, which mainly forms the body of the insulation strip, is pushed over this.
  • the slide-on takes place in the heat, preferably using extrusion heat.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Laminated Bodies (AREA)
  • Prevention Of Electric Corrosion (AREA)

Abstract

Aluminium cathode plates for the electrowinning of zinc, which have insulation strips at least at the edges which form two mutually approximately parallel narrow-side surfaces with the electrode surfaces and which have holding devices for the purpose of suspension in the electrolysis bath and for current collection at one narrow-side surface joining said narrow-side surfaces. The insulation strips consist, at least in the parts adjoining the plate, of copolymeric polyolefin and are fused on around the edges formed by the side surfaces with the electrode surfaces. <IMAGE>

Description

Die Erfindung bezieht sich auf ein Kathodenblech für die elektrolytische Gewinnung von Zink, mit einer Platte aus Aluminium und einer auf mindestens einem Rand der Platte diesen umgebend aufgeschmolzenen Isolationsleiste aus Kunststoff.The invention relates to a cathode sheet for the electrolytic production of zinc, with a plate made of aluminum and an insulating strip made of plastic melted on at least one edge of the plate surrounding it.

Bei heute bekannten Kathodenblechen für die elektrolytische Gewinnung von Zink sind an den Rändern Isolierungsleisten angeordnet. Dies ist deswegen notwendig, um das an den Kathodenflächen abgeschiedene Zink daran zu hindern, in Richtung der Anodenplatte bzw. Elektrolytwanne zu wachsen und dadurch einen Kurzschluß zu erzeugen. Diese Isolierungsleisten sind entweder an den Rändern des Kathodenblechs aufgeschnappt oder aufgepreßt. Es sind aber auch Versionen mit angeschraubten Isolationsleisten bekannt. Diese Isolationsleisten selbst bestehen aus Kunststoff, Gummi oder Holz. Ein Kathodenblech der eingangs genannten Art ist aus DE-A-3 219 300 bekannt.In today's known cathode sheets for the electrolytic production of zinc, insulating strips are arranged at the edges. This is necessary in order to prevent the zinc deposited on the cathode surfaces from growing in the direction of the anode plate or electrolyte trough and thereby producing a short circuit. These insulation strips are either snapped onto the edges of the cathode sheet or pressed on. Versions with screwed insulation strips are also known. These insulation strips themselves are made of plastic, rubber or wood. A cathode plate of the type mentioned is known from DE-A-3 219 300.

Da die Kathodenbleche im Betrieb mit Schwefelsäure, die als Elektrolyt verwendet wird, getaucht sind, kommt es zur Korrosion des Aluminiums. Diese Korrosion tritt bevorzugt unter den Leisten auf. Dies deshalb, da die Säure zwischen den Blechen und den Isolationsleisten eindringt und dort ein sehr schnelles Korrodieren des Aluminiums bewirkt. Es erfolgt somit ein frühzeitiger Ausfall des Kathodenblechs, da die Ränder ausfressen, die Leiste an Halt am Blech verliert und somit es zu einem Kurzschluß beim Wegbrechen der Isolationsleiste zwischen anwachsendem Zink und der Anodenplatte bzw. Elektrolytwanne kommt.Since the cathode sheets are immersed in sulfuric acid, which is used as the electrolyte, the aluminum corrodes. This corrosion occurs preferentially under the strips. This is because the acid penetrates between the sheets and the insulation strips and causes the aluminum to corrode very quickly. There is therefore an early failure of the cathode sheet, since the edges erode, the strip loses its grip on the sheet and thus there is a short circuit when the insulation strip between the growing zinc and the anode plate or electrolyte tray breaks away.

Dieser ungünstige Effekt dieser Korrosion wird erfindungsgemäß dadurch verhindert, daß die Isolationsleisten aus copolymerem Polyolefin bestehen, welche um die Kanten, die die Schmalseitenflächen mit den Elektrodenflächen bilden, aufgeschmolzen sind.This adverse effect of this corrosion is invented thereby preventing the insulation strips from being made of copolymeric polyolefin, which are melted around the edges which form the narrow side surfaces with the electrode surfaces.

Die Paarung copolymeres Polyolefin/Aluminium erweist sich dabei als besonders flüssigkeitsdicht gegenüber dem aggressiven schwefelsaueren Elektrolyten.The combination of copolymeric polyolefin / aluminum proves to be particularly liquid-tight against the aggressive sulfuric acid electrolyte.

Gemäß einer bevorzugten Ausgestaltung der Erfindung umfaßt die Isolationsleiste blechseitig eine Lage aus dem copolymeren Polyolefin und im übrigen besteht sie aus gewöhnlichem Polyolefin. Diese Bauweise ist sehr preisgünstig, weil weniger von dem teueren copolymeren Polyolefin notwendig ist.According to a preferred embodiment of the invention, the insulation strip on the sheet metal side comprises a layer of the copolymeric polyolefin and, moreover, it consists of ordinary polyolefin. This design is very inexpensive because less of the expensive copolymeric polyolefin is required.

Es ist weiters in einer Ausgestaltung der Erfindung eine solche Bauweise vorgesehen, daß die Isolationsleiste insgesamt aus dem hochhaftenden Polyolefin besteht.It is further provided in one embodiment of the invention such a construction that the insulation strip consists entirely of the highly adhesive polyolefin.

Bei dieser Bauweise kann bei großen Stückzahlen herzustellender Bleche besonders kostengünstig, weil einfach, gefertigt werden.With this construction method, sheet metal to be produced in large quantities can be manufactured particularly cost-effectively because it is simple.

Es hat sich gezeigt, daß das dazu verwendende Herstellungsverfahren erfindungsgemäß so durchgeführt wird, daß die Isolationsleiste extrudiert wird und nach der Extrusion an den anzuhaftenden Flächen des Kathodenblechbandes in der Wärme (bei Temperaturen zwischen 100 und 200 °C, vorzugsweise 160 und 180 °C, für 1 bis 5 min) angedrückt wird, die Bleche zugeschnitten und danach Halterungen an den Schmalseitenflächen des Kathodenblechs angeschweißt werden, die die mit einer Isolationsleiste versehenen Schmalseitenflächen verbinden.It has been shown that the manufacturing process used for this purpose is carried out according to the invention in such a way that the insulation strip is extruded and after the extrusion on the surfaces to be adhered to the cathode sheet metal strip in the heat (at temperatures between 100 and 200 ° C., preferably 160 and 180 ° C. for 1 to 5 min), the sheets are cut to size and then brackets are welded to the narrow side surfaces of the cathode sheet, which connect the narrow side surfaces provided with an insulation strip.

Es ist dabei in einer weiteren Ausgestaltung der Erfindung günstig, daß die Extrusion der Leiste durch Koextrusion von hochhaftendem copolymerem Polyolefin und normalem Polyolefin erfolgt. Dadurch wird weniger von dem teueren und nur blechseitig erforderlichen hochhaftenden Polyolefin verwendet, wodurch die Herstellung des erfindungsgemäßen Kathodenblechs günstiger wird.It is advantageous in a further embodiment of the invention that the extrusion of the bar is carried out by co-extruding highly adhesive copolymeric polyolefin and normal polyolefin. As a result, less of the expensive high-adhesion polyolefin, which is only required on the sheet metal side, is used, as a result of which the cathode sheet metal according to the invention is produced becomes cheaper.

Durch die Extrusion des Profils mit nachfolgendem Aufschmelzen auf den Kathodenblechbändern wird die für die Extrusion notwendige Wärme optimal genützt. Die Produktion kann kontinuierlich erfolgen, wodurch große Mengen an solchen Kathodenblechbändern hergestellt werden können. Diese sind nachher nur mehr zu schneiden und an ihnen die für die Stromeinleitung und Aufhängung benötigten Halterungen anzuordnen.By extruding the profile with subsequent melting on the cathode sheet metal strips, the heat required for the extrusion is optimally used. The production can take place continuously, whereby large quantities of such cathode sheet metal strips can be produced. Afterwards, these can only be cut and the brackets required for the current introduction and suspension arranged on them.

Es ist in einer Ausgestaltung der Erfindung günstig, Kathodenbleche so herzustellen, daß eine Schicht aus haftendem copolymerem Polyolefin auf den zu isolierenden Flächen angeordnet wird und auf diese Schicht ein Teil aus gewöhnlichem Polyolefin, der den Leistenkörper in seinem wesentlichen Volumen ausmacht, aufgeschoben wird.It is advantageous in one embodiment of the invention to produce cathode sheets in such a way that a layer of adhesive copolymeric polyolefin is arranged on the surfaces to be insulated and a part of ordinary polyolefin, which makes up the last body in its essential volume, is pushed onto this layer.

Dadurch, daß dieses gut haftende Polyolefin dicht mit dem Kathodenblech verbunden ist, kann kein Elektrolyt in die Verbindung eindringen und die eigentliche Isolationsleiste braucht lediglich warm aufgeschoben zu werden. Die Haftung, die zwischen der Schicht Polyolefin und der übrigen Isolationsleiste vorhanden ist, reicht beim Betrieb des Kathodenblechs zur Befestigung aus. Dieses Verfahren ist besonders dann wirtschaftlich, wenn nur wenige Kathodenbleche erzeugt werden sollen, was bei Reparaturen und bei der Wartung einer Elektrolyseanlage häufig der Fall ist.Because this well-adhering polyolefin is tightly connected to the cathode sheet, no electrolyte can penetrate the connection and the actual insulation strip only needs to be pushed on warm. The adhesion that exists between the polyolefin layer and the rest of the insulation strip is sufficient for fastening when the cathode sheet is in operation. This process is particularly economical if only a few cathode sheets are to be produced, which is often the case for repairs and for the maintenance of an electrolysis system.

Copolymere Polyolefine im Sinne der Erfindung sind Mischpolymerisate von Olefin und Haftzusätzen für Metalloberflächen. Diese Haftzusätze sind in der Regel aliphatische Carbonsäuren in einer Menge von 1 bis 10 %, beispielsweise Acrylsäure oder deren Derivate. Statt der Acrylsäure können auch Ester wie z. B. Vinylacetate vorhanden sein. Vinylacetat kann auch gleichzeitig mit Acrylsäure vorhanden sein, ebenso kommen auch andere Terpolymere in Frage. Geeignet sind letzlich diejenigen Schmelzkleber auf Polyolefinbasis, bei welchen eine ausreichende Korrosionsbeständigkeit gewährleistet ist.For the purposes of the invention, copolymeric polyolefins are copolymers of olefin and adhesive additives for metal surfaces. These adhesive additives are usually aliphatic carboxylic acids in an amount of 1 to 10%, for example acrylic acid or its derivatives. Instead of acrylic acid, esters such as. B. vinyl acetates may be present. Vinyl acetate can also be present at the same time as acrylic acid, as are other terpolymers. Ultimately, those hot melt adhesives based on polyolefin are suitable which have sufficient corrosion resistance is guaranteed.

Die Erfindung wird anhand der nachstehenden Zeichnungen beschrieben. Es zeigt:

  • Fig. 1 eine Gesamtansicht eines erfindungsgemäßen Kathodenblechs,
  • Fig. 2 ein Detail eines erfindungsgemäßen Kathodenblechs im Horizontalschnitt in vergrößerter Ansicht,
  • Fig. 3 ein Detail eines weiteren erfindungsgemäßen Kathodenblechs.
The invention will be described with reference to the drawings below. It shows:
  • 1 is an overall view of a cathode sheet according to the invention,
  • 2 shows a detail of a cathode sheet according to the invention in horizontal section in an enlarged view,
  • Fig. 3 shows a detail of a further cathode sheet according to the invention.

Ein Kathodenblech mit einer Platte 1 aus Aluminium ist in einem Elektrolyten 2 in einer Wanne 3 an Stromschienen 4, 4' mit seiner Halterung 5 angeordnet und hat auf beiden vertikalen Schmalseiten Isolationsleisten 6, 6' aus Polyolefin befestigt.A cathode sheet with a plate 1 made of aluminum is arranged in an electrolyte 2 in a trough 3 on busbars 4, 4 'with its holder 5 and has insulation strips 6, 6' made of polyolefin fastened on both vertical narrow sides.

Fig. 2 zeigt eine Ausführungsform des Kathodenblechs, bei welcher auf dem seitlichen Rand der Aluminiumplatte 1 eine einheitlich aus hochhaftendem copolymerem Polyolefin bestehende Isolationsleiste aufgeschmolzen ist. Die Isolationsleiste kann extrudiert und unter Ausnutzung der Extrusionshitze aufgeschmolzen sein.Fig. 2 shows an embodiment of the cathode sheet, in which on the side edge of the aluminum plate 1, a uniformly made of highly adhesive copolymeric polyolefin insulation strip is melted. The insulation strip can be extruded and melted using the extrusion heat.

In der Fig. 3 ist auf der Aluminiumplatte 1 des Kathodenblechs eine Schicht 7 haftendes copolymeres Polyolefin angeordnet und über diese eine den Körper der Isolationsleiste hauptsächlich ausmachende U-förmige Schiene 8 aufgeschoben. Das Aufschieben erfolgt in der Wärme, vorzugsweise unter Ausnutzung von Extrusionshitze.In FIG. 3, a layer 7 of adhesive copolymeric polyolefin is arranged on the aluminum plate 1 of the cathode sheet, and a U-shaped rail 8, which mainly forms the body of the insulation strip, is pushed over this. The slide-on takes place in the heat, preferably using extrusion heat.

Claims (5)

Kathodenblech für die eletkrolytische Gewinnung von Zink, mit einer Platte (1) aus Aluminium und einer auf mindestens einem Rand der Platte diesen umgebend aufgeschmolzenen Isolationsleiste (6) aus Kunststoff, dadurch gekennzeichnet, daß die Isolationsleiste (6) mindestens in einem an die Platte (1) anschließenden Teil aus einem copolymeren Polyolefin besteht.Cathode sheet for the electrolytic extraction of zinc, with a plate (1) made of aluminum and an insulating strip (6) made of plastic melted on at least one edge of the plate, characterized in that the insulating strip (6) is attached to the plate (6) in at least one 1) subsequent part consists of a copolymeric polyolefin. Kathodenblech nach Anspruch 1, dadurch gekennzeichnet, daß die Isolationsleiste (6) aus einer an das Blech (1) anschließenden Lage (7) aus copolymerem Polyolefin und einer darüber befindlichen Lage (8) aus gewöhnlichem Polyolefin aufgebaut ist.Cathode sheet according to claim 1, characterized in that the insulation strip (6) is constructed from a layer (7) of copolymeric polyolefin adjoining the sheet (1) and a layer (8) located above it from ordinary polyolefin. Verfahren zur Herstellung eines Kathodenblechs nach Anspruch 1, dadurch gekennzeichnet, daß die Isolationsleiste (6) in an sich bekannter Weise extrudiert wird und nach der Extrusion im noch heißen Zustand an den Rändern eines Kathodenblechbandes angedrückt wird, das mit Isolationsleisten versehene Blechband nachfolgend zu Kathodenblechen zugeschnitten wird und danach an einem zwischen zwei mit Isolationsleisten versehenen Rändern verlaufenden Rand Halterungen (5) angeschweißt werden.A process for producing a cathode sheet according to claim 1, characterized in that the insulation strip (6) is extruded in a manner known per se and, after the extrusion, is pressed onto the edges of a cathode sheet strip while it is still hot, and the sheet strip provided with insulation strips is subsequently cut into cathode sheets and then brackets (5) are welded to an edge running between two edges provided with insulation strips. Verfahren zur Herstellung eines Kathodenblechs nach Anspruch 3, dadurch gekennzeichnet, daß die Extrusion der Isolationsleiste (6) durch Koextrusion von copolymerem Polyolefin und normalem Polyolefin erfolgt.A method for producing a cathode sheet according to claim 3, characterized in that the extrusion of the insulation strip (6) is carried out by co-extrusion of copolymeric polyolefin and normal polyolefin. Verfahren zur Herstellung eines Kathodenblechs nach Anspruch 2, dadurch gekennzeichnet, daß eine Schicht aus copolymerem Polyolefin auf den zu isolierenden Flächen angeordnet wird und über diese Schicht eine Leiste aus normalem Polyolefin geschoben wird.A method for producing a cathode sheet according to claim 2, characterized in that a layer of copolymeric polyolefin is arranged on the surfaces to be insulated and a strip of normal polyolefin is pushed over this layer.
EP91106515A 1990-04-23 1991-04-23 Aluminium cathode-plate for the electrowinning of zinc Expired - Lifetime EP0454056B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
AT936/90 1990-04-23
AT0093690A AT395722B (en) 1990-04-23 1990-04-23 ALUMINUM CATHODE SHEETS FOR ELECTROLYTIC PRODUCTION OF ZINC
AT93690 1990-04-23

Publications (3)

Publication Number Publication Date
EP0454056A1 true EP0454056A1 (en) 1991-10-30
EP0454056B1 EP0454056B1 (en) 1996-09-11
EP0454056B2 EP0454056B2 (en) 1999-12-15

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EP91106515A Expired - Lifetime EP0454056B2 (en) 1990-04-23 1991-04-23 Aluminium cathode-plate for the electrowinning of zinc

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EP (1) EP0454056B2 (en)
JP (1) JP2596648B2 (en)
AT (2) AT395722B (en)
CA (1) CA2041055C (en)
DE (1) DE59108156D1 (en)
ES (1) ES2030645T5 (en)
FI (1) FI97305C (en)
NO (1) NO304658B1 (en)

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ES2067411A1 (en) * 1993-06-18 1995-03-16 Asturiana De Zinc Sa A cathode for the electrolytic deposition of non-ferrous metals.
WO1997021851A1 (en) * 1995-12-08 1997-06-19 Outokumpu Wenmec Oy Method for producing a mother plate for electrolytic cleaning and a mother plate produced according to said method
WO2001085382A1 (en) * 2000-05-08 2001-11-15 Nippon Light Metal Company, Ltd. Method of manufacturing conductive structure
EP1182277A2 (en) * 2000-08-16 2002-02-27 KM Europa Metal AG Cathode sheet
WO2010023101A1 (en) * 2008-08-29 2010-03-04 EMS Elektro Metall Schwanenmühle GmbH Cathode for the electrolytic deposition of zinc or the like from an electrolyte bath
CN114703507A (en) * 2022-03-15 2022-07-05 洛阳双瑞精铸钛业有限公司 Titanium aluminium titanium electrolysis zinc negative plate

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AT404035B (en) * 1996-06-17 1998-07-27 Fehrer Ernst Apparatus for needling a pre-consolidated nonwoven web
DE102006046879B3 (en) * 2006-10-04 2007-11-22 Thyssenkrupp Vdm Gmbh Cathode plate for electrolytic zinc recovery, comprises carrier rod connected to main body of aluminum with external coating of copper applied by hot deformation
CN103668341A (en) * 2013-11-22 2014-03-26 云南和美佳科贸有限公司 Negative plate with insulating sealed edge

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FR2406008A1 (en) * 1977-10-11 1979-05-11 Noranda Mines Ltd ELECTRODE FOR THE ELECTROLYTIC DEPOSIT OF METALS
GB2040311A (en) * 1979-02-05 1980-08-28 Copper Refineries Pty Ltd Cathode for use in the electrolytic refining of copper

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2067411A1 (en) * 1993-06-18 1995-03-16 Asturiana De Zinc Sa A cathode for the electrolytic deposition of non-ferrous metals.
WO1997021851A1 (en) * 1995-12-08 1997-06-19 Outokumpu Wenmec Oy Method for producing a mother plate for electrolytic cleaning and a mother plate produced according to said method
US5928482A (en) * 1995-12-08 1999-07-27 Outokumpu Wenmec Oy Method for producing a mother plate for electrolytic cleaning and a mother plate produced according to said method
EA000778B1 (en) * 1995-12-08 2000-04-24 Оутокумпу Венмек Ой Method for producing a mother plate for electrolytic cleaning and a mother plate produced according to said method
CN1063237C (en) * 1995-12-08 2001-03-14 奥托昆普温麦克公司 Method for producing mother plate for electrolytic cleaning and mother plate produced according to said method
WO2001085382A1 (en) * 2000-05-08 2001-11-15 Nippon Light Metal Company, Ltd. Method of manufacturing conductive structure
EP1182277A2 (en) * 2000-08-16 2002-02-27 KM Europa Metal AG Cathode sheet
EP1182277A3 (en) * 2000-08-16 2002-03-06 KM Europa Metal AG Cathode sheet
WO2010023101A1 (en) * 2008-08-29 2010-03-04 EMS Elektro Metall Schwanenmühle GmbH Cathode for the electrolytic deposition of zinc or the like from an electrolyte bath
CN114703507A (en) * 2022-03-15 2022-07-05 洛阳双瑞精铸钛业有限公司 Titanium aluminium titanium electrolysis zinc negative plate

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FI97305C (en) 1997-09-09
ES2030645T3 (en) 1996-12-01
AT395722B (en) 1993-02-25
DE59108156D1 (en) 1996-10-17
FI911967A (en) 1991-10-24
CA2041055C (en) 2004-03-02
NO911552D0 (en) 1991-04-19
JP2596648B2 (en) 1997-04-02
ATE142715T1 (en) 1996-09-15
ATA93690A (en) 1992-07-15
EP0454056B1 (en) 1996-09-11
ES2030645T1 (en) 1992-11-16
CA2041055A1 (en) 1991-10-24
FI911967A0 (en) 1991-04-23
NO911552L (en) 1991-10-24
ES2030645T5 (en) 2000-05-01
EP0454056B2 (en) 1999-12-15
FI97305B (en) 1996-08-15
NO304658B1 (en) 1999-01-25
JPH06293989A (en) 1994-10-21

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