JPS6333590A - Method for insulating and coating peripheral edge part of electrolytic cathode - Google Patents

Method for insulating and coating peripheral edge part of electrolytic cathode

Info

Publication number
JPS6333590A
JPS6333590A JP17689786A JP17689786A JPS6333590A JP S6333590 A JPS6333590 A JP S6333590A JP 17689786 A JP17689786 A JP 17689786A JP 17689786 A JP17689786 A JP 17689786A JP S6333590 A JPS6333590 A JP S6333590A
Authority
JP
Japan
Prior art keywords
cathode plate
cathode
peripheral edge
insulator
insulating material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP17689786A
Other languages
Japanese (ja)
Other versions
JPH0515795B2 (en
Inventor
Hideki Nagata
秀樹 永田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Akita Seiren KK
Original Assignee
Akita Seiren KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Akita Seiren KK filed Critical Akita Seiren KK
Priority to JP17689786A priority Critical patent/JPS6333590A/en
Publication of JPS6333590A publication Critical patent/JPS6333590A/en
Publication of JPH0515795B2 publication Critical patent/JPH0515795B2/ja
Granted legal-status Critical Current

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  • Electrolytic Production Of Metals (AREA)

Abstract

PURPOSE:To easily release an electrodeposited metal from a cathode by coating a double polyolefin plastic on the peripheral edge part of the cathode to be used in the electrolytic refining of various metals as an insulating material to prevent the connection of the metals electrodeposited on both surfaces of the cathode at the peripheral part. CONSTITUTION:When the metals such as Zn, Cu, Pb, and Ni are deposited on the surface of the cathode plate by electrolysis, the metals deposited on both surfaces of the cathode plate connect with each other and are hardly released. To prevent this phenomenon, a polyethylene plastic 2 having an ultrahigh mean mol.wt. of 1X10<6>-5X10<6> and having excellent resistance to wear, impact, and chemicals is provided on the peripheral edge part of the cathode plate main body 1 as an electrical insulating material, and a polyethylene plastic sheet 3 having a comparatively low mol.wt. of 2X10<4> is interposed between the cathode 1 and the plastic 2. The materials are pressed and adhered to each other, and the sheet 3 is heated and melted to firmly fix the insulating material 2 to the cathode plate 1. The electrodeposited metal is made easily releasable in this way, and a cathode for electrolytic metal refining with the durable insulating material and cathode is obtained.

Description

【発明の詳細な説明】 (イ)技術分野 本発明は、金属の電解精錬に用いられる陰極板において
、電着物が該陰極板の板面前後でつながらないよいうに
して電着物の剥取りを容易とするために、rk、極板の
板面周縁部を帯状絶縁物で絶縁被覆する方法に関するも
のである。
Detailed Description of the Invention (a) Technical field The present invention provides a cathode plate used for electrolytic refining of metals, in which the electrodeposit can be easily removed by preventing the electrodeposit from connecting on the front and back surfaces of the cathode plate. The present invention relates to a method of insulating and covering the peripheral edge of the plate surface of an electrode plate with a band-shaped insulating material in order to achieve this.

(ロ)従来技術 従来、陰極板の電着物の剥取りを容易とするために、陰
極板の左右両側縁部さらに場合によっては下縁部にもゴ
ム製又はプラスチック製の断面コ字形の帯状絶縁物を嵌
合挾持する方法が一般的に行なわれている(第1図参照
)。
(b) Prior art Conventionally, in order to facilitate the removal of electrodeposit from the cathode plate, band-shaped insulators made of rubber or plastic and having a U-shaped cross section were installed on both left and right edges of the cathode plate, and in some cases also on the lower edge. A commonly used method is to fit and hold objects (see Figure 1).

更に、これら絶縁物を陰極板の使用条件に適合した接着
剤を用いて陰極板に固定する方法、あるいは予め陰極板
周縁部の適当な位置に複数個の透孔を穿孔しておいてポ
リエチレン等のプラスチックの断面コ字形の帯状成形品
を該陰極板周縁部に嵌合せしめた後、適当な手段で加熱
、加圧操作を行なうことにより、ヒ記穿孔部を介して部
分的に陰極板前後板面のプラスチックどうしを溶着し、
陰極板に絶縁部を形成する方法も行なわれている。
Furthermore, there is a method of fixing these insulators to the cathode plate using an adhesive that is compatible with the usage conditions of the cathode plate, or a method of drilling a plurality of through holes in advance at appropriate positions on the periphery of the cathode plate and using polyethylene, etc. After fitting a plastic band-shaped molded product with a U-shaped cross section to the peripheral edge of the cathode plate, heat and pressurize it by appropriate means to partially cut the front and back of the cathode plate through the perforated part. Weld the plastic plates together,
Another method is to form an insulating part on the cathode plate.

しかしながら、まず第1の嵌合挾持による方法は、絶縁
物として使用している材料の経年劣化や、電解液が絶縁
物と陰極板の隙間に浸透することによる陰極板周縁部の
陰極板本体に対する優先的腐食による経年的な消耗によ
り、帯状絶縁物の陰極板に対するグリップ力が次第に減
衰し、またハンドリング中に陰極板が他器材に接触する
際の外力等により帯状絶縁物が陰極板から脱落する頻度
が多くて1円滑な操業の妨げとなっているばかりでなく
、陰極板本体の寿命が陰極板周縁部の寿命に限定されて
しまい、これが大きな欠点となっていた。
However, the first method using fitting and clamping does not prevent damage to the cathode plate body at the peripheral edge of the cathode plate due to age-related deterioration of the material used as the insulator or electrolyte permeating into the gap between the insulator and the cathode plate. Due to wear and tear over time due to preferential corrosion, the gripping force of the insulator strip on the cathode plate gradually decreases, and the insulator strip may fall off from the cathode plate due to external force when the cathode plate comes into contact with other equipment during handling. Not only does this occur frequently, impeding smooth operation, but the lifespan of the cathode plate itself is limited to that of the periphery of the cathode plate, which is a major drawback.

次に、第2の接着剤を用いる方法は、異質な材質すなわ
ち金属とゴムあるいは金属とプラスチックの接着となる
ので、その接着強度ならびに接着剤自体の経年劣化とい
う点で、比較的厳しい陰極板の使用条件において満足で
きる組合せを見つけだすことが至難であるほか、被着体
である絶縁物と陰極板両方の接着前の前処理を適切に実
施しなければならない面倒があった。
Next, the method using the second adhesive involves adhering dissimilar materials, ie, metal and rubber or metal and plastic, so it is relatively difficult to adhere to the cathode plate in terms of adhesive strength and deterioration of the adhesive itself over time. In addition to being extremely difficult to find a combination that satisfies the usage conditions, there is also the hassle of having to properly pre-treat both the insulator and the cathode plate before bonding.

また、7iTj3のプラスチックの熱溶着方法において
は、金属とプラスチックの溶着強度が充分でないという
大きな欠点を補うために前記の如く帯状プラスチック絶
縁物が取りつけられる陰極板周縁部の適当位置に複数個
の孔をあけ、この孔を介して部分的にプラスチックどう
しを溶着させる方法がとられているが、これも全体とし
ては確実な方法ではなく、しかも孔の加工に手間がかか
り、改善すべきところが多い。
In addition, in the 7iTj3 plastic heat welding method, in order to compensate for the major drawback that the welding strength between metal and plastic is insufficient, a plurality of holes are formed at appropriate positions on the periphery of the cathode plate to which the strip-shaped plastic insulator is attached as described above. The method used is to drill a hole and partially weld the plastic pieces together through this hole, but this is not a reliable method as a whole, and the hole machining is time-consuming, and there are many improvements that need to be made.

(ハ)発明の開示 本発明は、帯状絶縁物を陰極板の板面周縁部に被覆固着
するのに、接着剤を用いずにプラスチックの熱溶着によ
る方法を採り、しかも従来のような孔あけ加工を必要と
しないで充分な溶着強度が得られてハンドリング中に脱
落することもない簡便な方法を提案するものである。
(C) Disclosure of the Invention The present invention adopts a method of heat welding plastic without using adhesive to cover and fix a band-shaped insulator to the peripheral edge of the plate surface of a cathode plate, and in addition, it does not require the conventional method of drilling holes. The present invention proposes a simple method that provides sufficient welding strength without requiring processing and that does not fall off during handling.

ここに、陰極板周縁部とは、陰極板本体の板面両側縁部
および下縁部のほか、液面よりやや下の位置からヘッド
バーよりも下側の板面部を包含する(第1図および第3
図参照)。
Here, the peripheral edge of the cathode plate includes both side edges and the lower edge of the plate surface of the cathode plate body, as well as the plate surface portion from a position slightly below the liquid level to below the head bar (see Fig. 1). and third
(see figure).

プラスチック類のうちポリオレフィン系のポリエチレン
あるいはポリプロピレン等は、一般の水溶液電解精錬に
おける陰極板の使用条件において例えば耐熱性、化学的
安定性、電気絶縁性などの材料特性については充分に満
足できるものであり、そのコストパフォーマンスが比較
的優れているため、陰極板の板面周縁部の絶縁物の材料
としてしばしば用いられて来た。
Among plastics, polyolefin-based polyethylene, polypropylene, etc. have sufficient material properties such as heat resistance, chemical stability, and electrical insulation under the conditions of use of cathode plates in general aqueous electrolytic refining. Because of its relatively good cost performance, it has often been used as an insulating material for the peripheral edge of the cathode plate.

しかし、従来からポリオレフィン系プラスチックの異質
な材料への接着が困難であることは周知のところであり
、これが大きな欠点とされている。
However, it has been well known that it is difficult to adhere polyolefin plastics to different materials, and this has been considered a major drawback.

一方、数あるエンジニアリングプラスチックのうちで超
高分子量ポリエチレンは、平均分子量が100万〜50
0万と一般の高密度ポリエチレンの平均分子?2万〜3
0万に比べてSわめて大きく、そのため一般の高密度ポ
リエチレンや他のエンジニアリングプラスチックに比べ
て、特に耐摩耗性、#衝撃性、目己循滑性、耐薬品性に
優れ。
On the other hand, among the many engineering plastics, ultra-high molecular weight polyethylene has an average molecular weight of 1 million to 50
00,000 and the average molecule of general high-density polyethylene? 20,000 to 3
0,000,000,000,000,000,000,000,000,000,000,000,000,000,000,000,000,000,000,000,000,000,000,000,000,000,000,000,000,000,000,000.

これらの物性を活かした用途に広く使われているのは周
知である。
It is well known that they are widely used in applications that take advantage of these physical properties.

しかし、ケタ違いに大きな平均分子量を有するために溶
融粘度が高く、流動性が悪いなど加工面で欠点をもって
おり、材料そのものはエンジニアプラスチックのなかで
も比較的安いにもかかわらず、接着の困難さもあり、用
途が限定されているのが実状であった・ また、超高分子量ポリエチレンは、このほかにも耐候性
、耐水性、′Fj、気特性など従来のポリエチレンが持
つ特性を備えており、接着の困難さを除けばその材料特
性としては陰極板の板面周縁部の絶縁物の材料としては
最適なものといえる。
However, it has disadvantages in terms of processing, such as high melt viscosity and poor fluidity due to its unusually large average molecular weight, and although the material itself is relatively cheap among engineering plastics, it is difficult to bond. In addition, ultra-high molecular weight polyethylene has other properties that conventional polyethylene has, such as weather resistance, water resistance, 'Fj, and air properties. With the exception of the difficulty of the process, its material properties can be said to be optimal as an insulating material for the peripheral edge of the cathode plate.

本発明者等は、ポリオレフィン系プラスチック、好まし
くは超高分子量ポリエチレンのこうした優れた材料特性
に目を向け、鋭意調査、研究。
The present inventors focused on these excellent material properties of polyolefin plastics, preferably ultra-high molecular weight polyethylene, and conducted extensive investigation and research.

試験を重ねた結果、本発明に至ったものである。As a result of repeated tests, we have arrived at the present invention.

本発明においては、陰極板の板面周縁部の絶縁材料とし
て、平均分子を−の高いポリオレフィン系プラスチック
、好ましくは超高分子量ポリエチレンを用い、これを陰
極板の板面周縁部に固定するのに、該絶縁物と陰極板と
の間に該絶縁物より平均性−トにの低いポリオレフィン
系プラスチックのシートをはさみ、このシートと絶縁物
を陰極板の周縁にしっかりと保持するために、適当な治
具で均一にプレスした状態で、均一加熱炉内で中間のに
記シートが軟化溶融する温度でしかも外側の絶縁物がそ
の形状を維持できるような温度範囲に適当時間保持する
という簡便な方法により、軟化溶融した中間シートを介
して該絶縁物を陰極板に強固に溶着するものである。
In the present invention, a polyolefin plastic with a high average molecular weight, preferably ultra-high molecular weight polyethylene, is used as the insulating material for the peripheral edge of the cathode plate, and this is fixed to the peripheral edge of the negative electrode plate. A sheet of polyolefin plastic with a lower average hardness than the insulator is sandwiched between the insulator and the cathode plate, and a suitable material is used to firmly hold the sheet and the insulator around the periphery of the cathode plate. A simple method is to press the sheet uniformly with a jig and hold it in a uniform heating furnace for an appropriate period of time at a temperature at which the middle sheet softens and melts, and at which the outer insulator maintains its shape. The insulator is firmly welded to the cathode plate via the softened and melted intermediate sheet.

しかも、この溶着強度は陰極板の使用条件において充分
なものであるので、陰極板の使用期間中はとんど剥離す
ることがない。
Furthermore, since this welding strength is sufficient under the conditions in which the cathode plate is used, the cathode plate hardly peels off during its use.

なお、この絶縁物はプラスチック成形機による成形品で
も、あるいは素材を機械加工したものであっても何らそ
の機能に差はなく、また絶縁物および陰極板周縁部の前
処理は接着剤で接着するときのように特に気を使う必要
はなく、−船釣な脱脂、研磨程度で充分である。
Note that there is no difference in function whether this insulator is molded using a plastic molding machine or machined from raw material, and the pretreatment of the insulator and the periphery of the cathode plate is performed by adhering it with adhesive. There is no need to be particularly careful like when fishing, just degreasing and polishing is sufficient.

(ニ)実施例 絶縁物の材料として平均分子量400万の超高分子l−
ポリエチレンを用い、これを機械加工し。
(d) Ultra high polymer l- with an average molecular weight of 4 million as a material for the insulating material of the example
Machined using polyethylene.

第2図又は第4図に示すような断面形状がコ字形の帯状
の絶縁物2を製作した。
A strip-shaped insulator 2 having a U-shaped cross section as shown in FIG. 2 or 4 was manufactured.

次に、該絶縁物2の溝部とこれに挾持される陰極板1の
両側縁部との間に、ポリエチレン系の平均分子i52万
の1OOIL厚のシート3をはさみ、これら中間シート
3と絶縁物2を陰極板の両側縁部にしっかりと保持する
ために治具で均一にプレスした状態で均一加熱炉内に入
れ、中間のシート3が軟化溶融する温度で、しかも外側
の絶縁物2がその形状を維持できる温度範囲の200℃
±lO℃に約1時間保持した。
Next, a polyethylene sheet 3 having an average molecular weight of 520,000 and a thickness of 1 OOIL is sandwiched between the groove of the insulator 2 and both side edges of the cathode plate 1 held therein, and these intermediate sheets 3 and the insulator In order to firmly hold the sheet 2 on both sides of the cathode plate, it is pressed uniformly with a jig and placed in a uniform heating furnace at a temperature at which the middle sheet 3 softens and melts, and the outer insulator 2 200℃, the temperature range that allows it to maintain its shape
It was kept at ±10°C for about 1 hour.

その結果、炉から取り出した絶縁物2は、軟化溶融した
中間シート3を介して陰極板lに強固に溶着していた。
As a result, the insulator 2 taken out from the furnace was firmly welded to the cathode plate 1 via the softened and melted intermediate sheet 3.

このようにして製作した陰極板lを亜鉛の電解採取現場
操業に適用してみたところ、何ら支障はなく、従来使用
していたゴム製のはさみこみによる絶縁物に比較すると
、特に耐摩耗性、耐薬品性というその材料特性と合せて
、絶縁物および陰極板双方の寿命の延長が図られた。
When the cathode plate l manufactured in this way was applied to zinc electrowinning field operations, there were no problems at all, and compared to the conventionally used insulator made of rubber inserts, it has particularly good wear resistance and durability. Combined with the material's chemical properties, the life expectancy of both the insulator and cathode plate was extended.

さらに、操業中に帯状絶縁物2が陰極板から脱落する現
象もなくなり、円滑な操業が可能となった。また、特に
超高分子量ポリエチレンを用いた効果として、陰極板を
ワイヤブラシ等で研摩する際に絶縁物の摩耗に特に気を
使う必要がなくなったほか、電着物を陰極板から剥離す
る際に絶縁物りでの剥離用ナイフの滑りが良いため絶縁
物がナイフによって傷付くことがなくなり、しかもハン
ドリング中の他器材との接触による絶縁物の損傷もなく
なった。
Furthermore, the phenomenon of the band-shaped insulator 2 falling off the cathode plate during operation was eliminated, and smooth operation became possible. Another advantage of using ultra-high molecular weight polyethylene is that there is no need to be particularly careful about abrasion of the insulation when polishing the cathode plate with a wire brush, etc., and when removing electrodeposit from the cathode plate, the insulation is removed. Since the stripping knife slides smoothly on the handle, the insulator is not damaged by the knife, and the insulator is no longer damaged by contact with other equipment during handling.

(ホ)発明の効果 本発明法は、上述のように亜鉛、銅、鉛、コバルト、ニ
ッケル、錫など一般の水溶液電解精錬用の陰極板の周縁
部に絶縁物として優れたポリオレフィン系プラスチック
を用いて簡単な方法でこれを確実強固に固定できるもの
であり、絶縁物および陰極板の双方の寿命を陰極板本体
の経年的な消耗による寿命と同程度にまで延ばすことが
でき、材料費も安く操ズ管理も容易である等の利点を有
する。
(E) Effects of the Invention As mentioned above, the method of the present invention uses polyolefin plastic, which is excellent as an insulator, at the periphery of the cathode plate for general aqueous electrolytic refining such as zinc, copper, lead, cobalt, nickel, and tin. This can be fixed securely and firmly using a simple method, extending the life of both the insulator and the cathode plate to the same level as the life of the cathode plate due to wear and tear over time, and the material cost is low. It has advantages such as easy operation management.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明法により絶縁被覆された陰極板の一例を
示す正面図、第2図は同A−A断面図、第3図は本発明
法を適用した他の例を示す正面図、第4図は同B−B断
面図である。 符り説明 l−陰極板本体 2−絶縁物 3−シート4−ヘッドバ
ー 特 許 出 願 人 秋田製錬株式会社第1図 第3図 第2図 第4図
FIG. 1 is a front view showing an example of a cathode plate coated with insulation according to the method of the present invention, FIG. 2 is a sectional view taken along line AA of the same, and FIG. 3 is a front view showing another example to which the method of the present invention is applied. FIG. 4 is a sectional view taken along line BB. Number Description 1 - Cathode Plate Body 2 - Insulator 3 - Sheet 4 - Head Bar Patent Applicant Akita Smelting Co., Ltd. Figure 1 Figure 3 Figure 2 Figure 4

Claims (2)

【特許請求の範囲】[Claims] (1)電解用陰極板の板面周縁部を被覆する絶縁物の材
料として平均分子量の高いポリオレフィン系プラスチッ
クを用い、該絶縁物と陰極板との間に該絶縁物より平均
分子量の低いポリオレフィン系プラスチックのシートを
介在させ、該絶縁物を陰極板の板面周縁部に向けて加圧
すると共に、上記シートが軟化溶融しかつ外側の絶縁物
がその形状を維持できる温度範囲に保持することにより
該絶縁物を陰極板の板面周縁部に固定することを特徴と
する電解用陰極板周縁部の絶縁被覆方法。
(1) A polyolefin plastic with a high average molecular weight is used as the material for the insulator that covers the peripheral edge of the plate surface of the cathode plate for electrolysis, and a polyolefin plastic with a lower average molecular weight than the insulator is used between the insulator and the cathode plate. By interposing a plastic sheet and pressurizing the insulating material toward the peripheral edge of the plate surface of the cathode plate, the sheet is maintained at a temperature range in which the sheet softens and melts and the outer insulating material maintains its shape. A method for insulating the peripheral edge of a cathode plate for electrolysis, characterized by fixing an insulator to the peripheral edge of the plate surface of the cathode plate.
(2)前記絶縁物が超高分子量ポリエチレンである特許
請求の範囲第1項記載の電解用陰極板周縁部の絶縁被覆
方法。
(2) The method for insulating the peripheral edge of a cathode plate for electrolysis according to claim 1, wherein the insulator is ultra-high molecular weight polyethylene.
JP17689786A 1986-07-28 1986-07-28 Method for insulating and coating peripheral edge part of electrolytic cathode Granted JPS6333590A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP17689786A JPS6333590A (en) 1986-07-28 1986-07-28 Method for insulating and coating peripheral edge part of electrolytic cathode

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP17689786A JPS6333590A (en) 1986-07-28 1986-07-28 Method for insulating and coating peripheral edge part of electrolytic cathode

Publications (2)

Publication Number Publication Date
JPS6333590A true JPS6333590A (en) 1988-02-13
JPH0515795B2 JPH0515795B2 (en) 1993-03-02

Family

ID=16021661

Family Applications (1)

Application Number Title Priority Date Filing Date
JP17689786A Granted JPS6333590A (en) 1986-07-28 1986-07-28 Method for insulating and coating peripheral edge part of electrolytic cathode

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0681184A (en) * 1991-04-23 1994-03-22 Copper Refineries Pty Ltd Edge cover member for negative plate
US5353889A (en) * 1992-03-17 1994-10-11 Honda Giken Kogyo Kabushiki Kaisha Power transmitting device for four-wheel drive vehicle
JPH06293989A (en) * 1990-04-23 1994-10-21 Austria Metall Ag Cathode plate for electrolytic production of zinc
JP2008513608A (en) * 2004-09-13 2008-05-01 アマグ・ローリング・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング A method of attaching a protection bar to a cathode plate for obtaining a metal from an electrolyte by electrolysis
US9139922B2 (en) 2012-03-16 2015-09-22 Clim-A-Tech Industries, Inc. Cathode plate edge protector and methods of manufacture
USRE46212E1 (en) 2002-10-22 2016-11-22 William A. Ebert Edge protector systems for cathode plates and methods of making same
US9863050B2 (en) 2012-03-16 2018-01-09 Clim-A-Tech Industries, Inc. Cathode plate edge protector and methods of manufacture
JP2020147816A (en) * 2019-03-14 2020-09-17 パンパシフィック・カッパー株式会社 Method for producing metal plate
JP2020147815A (en) * 2019-03-14 2020-09-17 パンパシフィック・カッパー株式会社 Cathod and insulating material

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57123047A (en) * 1981-01-22 1982-07-31 Mitsui Petrochemical Ind Manufacture of laminated board
JPS6111230A (en) * 1984-06-27 1986-01-18 Kawasaki Heavy Ind Ltd Bonding of metal with superhigh molecular weight polyethylene resin
JPS61143137A (en) * 1984-12-18 1986-06-30 日本石油化学株式会社 Laminate consisting of ultra-high-molecular-weight polyethylene

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57123047A (en) * 1981-01-22 1982-07-31 Mitsui Petrochemical Ind Manufacture of laminated board
JPS6111230A (en) * 1984-06-27 1986-01-18 Kawasaki Heavy Ind Ltd Bonding of metal with superhigh molecular weight polyethylene resin
JPS61143137A (en) * 1984-12-18 1986-06-30 日本石油化学株式会社 Laminate consisting of ultra-high-molecular-weight polyethylene

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06293989A (en) * 1990-04-23 1994-10-21 Austria Metall Ag Cathode plate for electrolytic production of zinc
JPH0681184A (en) * 1991-04-23 1994-03-22 Copper Refineries Pty Ltd Edge cover member for negative plate
US5353889A (en) * 1992-03-17 1994-10-11 Honda Giken Kogyo Kabushiki Kaisha Power transmitting device for four-wheel drive vehicle
USRE46212E1 (en) 2002-10-22 2016-11-22 William A. Ebert Edge protector systems for cathode plates and methods of making same
JP2008513608A (en) * 2004-09-13 2008-05-01 アマグ・ローリング・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング A method of attaching a protection bar to a cathode plate for obtaining a metal from an electrolyte by electrolysis
US9139922B2 (en) 2012-03-16 2015-09-22 Clim-A-Tech Industries, Inc. Cathode plate edge protector and methods of manufacture
US9863050B2 (en) 2012-03-16 2018-01-09 Clim-A-Tech Industries, Inc. Cathode plate edge protector and methods of manufacture
JP2020147816A (en) * 2019-03-14 2020-09-17 パンパシフィック・カッパー株式会社 Method for producing metal plate
JP2020147815A (en) * 2019-03-14 2020-09-17 パンパシフィック・カッパー株式会社 Cathod and insulating material

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JPH0515795B2 (en) 1993-03-02

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