EP0433309A1 - Verwendung von metallacetylacetonaten als katalysatoren für die ethoxylierung bzw. propoxylierung - Google Patents
Verwendung von metallacetylacetonaten als katalysatoren für die ethoxylierung bzw. propoxylierungInfo
- Publication number
- EP0433309A1 EP0433309A1 EP89909551A EP89909551A EP0433309A1 EP 0433309 A1 EP0433309 A1 EP 0433309A1 EP 89909551 A EP89909551 A EP 89909551A EP 89909551 A EP89909551 A EP 89909551A EP 0433309 A1 EP0433309 A1 EP 0433309A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- catalysts
- ethoxylation
- propoxylation
- acac
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/02—Preparation of ethers from oxiranes
- C07C41/03—Preparation of ethers from oxiranes by reaction of oxirane rings with hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B41/00—Formation or introduction of functional groups containing oxygen
- C07B41/04—Formation or introduction of functional groups containing oxygen of ether, acetal or ketal groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
Definitions
- metal acetylacetonates as catalysts for the ethoxylation or propoxylation.
- the invention relates to catalysts for the ethoxylation or propoxylation of compounds with active H atoms.
- fatty alcohols Guerbet alcohols, fatty acids and amines, which form non-ionic detergents during ethoxylation or propoxylation.
- a typical example of this is the reaction of fatty alcohols with usually 10 to 18 carbon atoms with ethylene oxide and / or propylene oxide in the presence of catalysts, the fatty alcohols reacting with several molecules of ethylene oxide and / or propylene oxide.
- the catalysts for the aforementioned polyalkoxylation include: the following have been used:
- Barium hydroxide (EP-B 0 115 083), basic magnesium compounds, e.g. alkoxides (EP-A 00 82 569),
- the aforementioned catalysts have i.a. the disadvantage that they are difficult to incorporate into the reaction system and / or are difficult to manufacture. Furthermore, when using alkali hydroxides and alkali alcoholates, the range of the degree of polyalkoxylation that can be achieved, i.e. the
- Acidic catalysts e.g.
- Antimony pentachloride do cause a closer
- Aluminum alcoholates and sulfuric acid can achieve a narrow homolog distribution of the alkoxylation products with good conversion in the case of linear fatty alcohols, but not with branched alcohols, e.g. the so-called
- the range or homolog distribution of the fatty alcohol polyalkoxylates depends essentially on the type of used
- Degree of ethoxylation and p mean the percentage of the adduct with certain EO degrees, which is predominantly formed. A large Q value therefore means a narrow range of homolog distribution.
- Oxethylates with a low content of free fatty alcohols have an increased degree of conversion in the production of ether carboxylic acids by reacting the oxethylates with sodium chloroacetates in the presence of alkali metal hydroxides.
- Farther are ethoxylates with restricted homolog distribution, highly effective thickeners for surfactant solutions.
- M is a metal cation from that of Al 3+ , Cr 3+ , Fe 3+ , Mn 2+ ,
- ACAC is an anion of the acetylacetonate and n is a number corresponding to the charge number of the
- Metal cations mean as catalysts for the ethoxylation or
- metal acetylacetonates of the general formula I to be used according to the invention which are known compounds and for the most part are commercially available include:
- Zinc sulfate / acetylacetone or tin (II) oxalate / acetylacetone mixtures are used, e.g. Zinc sulfate / acetylacetone or tin (II) oxalate / acetylacetone mixtures.
- Metal acetylacetonates from the above list are particularly advantageous, in which the metal cation M is selected from the groups formed by Al 3+ , Fe 3+ , Zn 2+ and Zr 4+ ; Such metal acetylacetonates are physiologically harmless and can therefore, if desired, remain in the alkoxylation products.
- the catalysts are added in an amount of 0.1 to 2% by weight, based on the end product of the ethoxylation or propoxylation.
- Tin (II) oxalate and acetylacetone (10 mmol / 30 mmol per 100 g end product of the ethoxylation).
- the fatty alcohols to be alkoxylated according to Table 1 were mixed with the specified catalysts and transferred to a suitable autoclave. After approximately 30 minutes of evacuation at 100 ° C. and flushing with nitrogen, the temperature was raised to approximately 180 ° C. and the desired amount of ethylene oxide was pressed in at a maximum of 5 bar. After a reaction time of 30 min, unreacted alkylene oxide was drawn off at 100 ° C./14 mbar.
- the OH number and the polyglycol content (PG) of the alkoxylates formed were determined; continued to be a
- fatty alcohols mentioned in the tables were commercial, technical fatty alcohol mixtures with the following composition:
- C 12/14 fatty alcohol of chain length distribution 0 - 2% C 10, 70 - 75% C 12, 20 - 30% C 14, 0 - 2% C 16; Iodine number less than 0.3, average molecular weight 194, hydroxyl number 285-293.
- C 12 fatty alcohol of the chain length distribution 0-2% C 10, at least 97% C 12, 0-3% C 14, iodine number less than 0.3, average molecular weight 188, hydroxyl number 295 - 301.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3829751 | 1988-09-01 | ||
DE3829751A DE3829751A1 (de) | 1988-09-01 | 1988-09-01 | Verwendung von metallacetylacetonaten als katalysatoren fuer die ethoxylierung bzw. propoxylierung |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0433309A1 true EP0433309A1 (de) | 1991-06-26 |
Family
ID=6362098
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89115556A Withdrawn EP0361083A1 (de) | 1988-09-01 | 1989-08-23 | Verwendung von Metallacetylacetonaten als Katalysatoren für die Ethoxylierung bzw. Propoxylierung |
EP89909551A Withdrawn EP0433309A1 (de) | 1988-09-01 | 1989-08-23 | Verwendung von metallacetylacetonaten als katalysatoren für die ethoxylierung bzw. propoxylierung |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89115556A Withdrawn EP0361083A1 (de) | 1988-09-01 | 1989-08-23 | Verwendung von Metallacetylacetonaten als Katalysatoren für die Ethoxylierung bzw. Propoxylierung |
Country Status (4)
Country | Link |
---|---|
EP (2) | EP0361083A1 (ko) |
KR (1) | KR900701695A (ko) |
DE (1) | DE3829751A1 (ko) |
WO (1) | WO1990002721A1 (ko) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4005338A1 (de) * | 1990-02-20 | 1991-08-22 | Henkel Kgaa | Verwendung von strontium- und/oder bariumacetylacetonaten als katalysatoren fuer die ethoxylierung bzw. propoxylierung von verbindungen mit aktiven h-atomen |
DE102007027372A1 (de) | 2007-06-11 | 2008-12-18 | Cognis Oleochemicals Gmbh | Verfahren zur Hydrierung von Glycerin |
DE102007027371A1 (de) | 2007-06-11 | 2008-12-18 | Cognis Oleochemicals Gmbh | Verfahren zur Herstellung einer Verbindung aufweisend mindestens eine Ester-Gruppe |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2218343B1 (ko) * | 1973-02-21 | 1977-04-29 | Ugine Kuhlmann | |
EP0034648A3 (en) * | 1980-02-04 | 1981-10-21 | Conoco Phillips Company | A method for the alkoxylation of alkanols in the presence of strontium-containing catalysts and promoters |
EP0180266B1 (en) * | 1984-10-29 | 1989-11-23 | Shell Internationale Researchmaatschappij B.V. | Alkoxylation process using bimetallic oxo catalyst |
-
1988
- 1988-09-01 DE DE3829751A patent/DE3829751A1/de not_active Withdrawn
-
1989
- 1989-08-23 WO PCT/EP1989/000987 patent/WO1990002721A1/de not_active Application Discontinuation
- 1989-08-23 EP EP89115556A patent/EP0361083A1/de not_active Withdrawn
- 1989-08-23 KR KR1019900700829A patent/KR900701695A/ko not_active Application Discontinuation
- 1989-08-23 EP EP89909551A patent/EP0433309A1/de not_active Withdrawn
Non-Patent Citations (1)
Title |
---|
See references of WO9002721A1 * |
Also Published As
Publication number | Publication date |
---|---|
DE3829751A1 (de) | 1990-03-15 |
EP0361083A1 (de) | 1990-04-04 |
WO1990002721A1 (de) | 1990-03-22 |
KR900701695A (ko) | 1990-12-04 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 19910221 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): DE FR IT |
|
17Q | First examination report despatched |
Effective date: 19911022 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN WITHDRAWN |
|
18W | Application withdrawn |
Withdrawal date: 19920507 |