EP0425441A3 - Photoempfindliches Gemisch - Google Patents

Photoempfindliches Gemisch Download PDF

Info

Publication number
EP0425441A3
EP0425441A3 EP19900810803 EP90810803A EP0425441A3 EP 0425441 A3 EP0425441 A3 EP 0425441A3 EP 19900810803 EP19900810803 EP 19900810803 EP 90810803 A EP90810803 A EP 90810803A EP 0425441 A3 EP0425441 A3 EP 0425441A3
Authority
EP
European Patent Office
Prior art keywords
meth
weight
gew
von
eines
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP19900810803
Other languages
English (en)
French (fr)
Other versions
EP0425441B1 (de
EP0425441A2 (de
Inventor
Max Dr. Hunziker
Manfred Dr. Hofmann
Adrian Dr. Schulthess
Paul Dr. Bernhard
Bernd Dr. Klingert
Rolf Dr. Wiesendanger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huntsman Advanced Materials Switzerland GmbH
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Publication of EP0425441A2 publication Critical patent/EP0425441A2/de
Publication of EP0425441A3 publication Critical patent/EP0425441A3/de
Application granted granted Critical
Publication of EP0425441B1 publication Critical patent/EP0425441B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/027Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds

Landscapes

  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Physics & Mathematics (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Flüssige Gemische, enthaltend
  • a) 5-25 Gew.-% eines monomeren aliphatischen oder cycloaliphatischen Di(meth)acrylats mit einem Molekulargewicht (MG) von höchstens 800,
  • b) 0-15 Gew.-% eines monomeren Poly(meth)acrylats mit einer Funktionalität von mindestens 3 und einem MG von höchstens 600,
  • c) 0-20 Gew.-% eines Mono(meth)acrylats oder einer Mono-N-vinylverbindung mit einem MG von höchstens 500,
  • d) 20-60 Gew.-% eines Urethan(meth)acrylats mit einer Funktionalität von 2 bis 4 und einem MG von 500 bis 10000,
  • e) 10-50 Gew.-% eines monomeren oder oligomeren Di(meth)acrylats auf Basis von Bisphenol A oder Bisphenol F,
  • f) 0,1-10 Gew.-% eines Photoinitiators und
  • g) 0-5 Gew.-% üblicher Additive, wobei der Anteil der Komponenten a) bis g) zusammen 100 Gew.-% beträgt, stellen photoempfindliche Gemische dar, die mittels aktinischer Bestrahlung polymerisiert werden können und sich vorzugsweise zur Herstellung von dreidimensionalen Gegenständen mittels des stereolithographischen Verfahrens eignen.
  • EP90810803A 1989-10-27 1990-10-19 Photoempfindliches Gemisch Expired - Lifetime EP0425441B1 (de)

    Applications Claiming Priority (4)

    Application Number Priority Date Filing Date Title
    CH390289 1989-10-27
    CH3902/89 1989-10-27
    CH966/90 1990-03-23
    CH96690 1990-03-23

    Publications (3)

    Publication Number Publication Date
    EP0425441A2 EP0425441A2 (de) 1991-05-02
    EP0425441A3 true EP0425441A3 (de) 1991-06-26
    EP0425441B1 EP0425441B1 (de) 1995-12-27

    Family

    ID=25686242

    Family Applications (1)

    Application Number Title Priority Date Filing Date
    EP90810803A Expired - Lifetime EP0425441B1 (de) 1989-10-27 1990-10-19 Photoempfindliches Gemisch

    Country Status (5)

    Country Link
    EP (1) EP0425441B1 (de)
    JP (1) JP3243565B2 (de)
    KR (1) KR0163588B1 (de)
    CA (1) CA2028541C (de)
    DE (1) DE59010008D1 (de)

    Families Citing this family (21)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    EP0506616B1 (de) * 1991-03-27 1998-01-21 Ciba SC Holding AG Photoempfindliches Gemisch auf Basis von Acrylaten
    EP0525578A1 (de) * 1991-08-02 1993-02-03 E.I. Du Pont De Nemours And Company Photopolymerzusammensetzung zur Herstellung von dreidimensionalen Objekten
    TW311923B (de) * 1992-01-27 1997-08-01 Ciba Sc Holding Ag
    TW418346B (en) * 1993-03-05 2001-01-11 Ciba Sc Holding Ag Photopolymerisable compositions containing tetraacrylates
    ES2127365T5 (es) * 1993-08-26 2002-08-16 Vantico Ag Composicion liquida reticulable por radiacion, destinada en especial a la estereolitografia.
    GB9504995D0 (en) * 1995-03-11 1995-04-26 Zeneca Ltd Compositions
    GB9504996D0 (en) * 1995-03-11 1995-04-26 Zeneca Ltd Compositions
    GB9522656D0 (en) * 1995-11-04 1996-01-03 Zeneca Ltd Mould
    JP3786480B2 (ja) * 1996-10-14 2006-06-14 Jsr株式会社 光硬化性樹脂組成物
    JP3626302B2 (ja) * 1996-12-10 2005-03-09 Jsr株式会社 光硬化性樹脂組成物
    JP3765896B2 (ja) 1996-12-13 2006-04-12 Jsr株式会社 光学的立体造形用光硬化性樹脂組成物
    JP4839525B2 (ja) 2000-09-29 2011-12-21 大日本印刷株式会社 感光性樹脂組成物および液晶ディスプレイ用カラーフィルタ
    DE10328302A1 (de) * 2003-06-23 2005-01-27 Dreve Otoplastik Gmbh Niedrigviskose, strahlungshärtbare Formulierung, insbesondere für die Stereolithographie, zum Einsatz in der Medizintechnik, insbesondere zur Herstellung von Ohrstücken
    DE102004050868A1 (de) * 2004-10-18 2006-04-20 Dreve Otoplastik Gmbh Niedrigviskose, strahlungshärtbare Formulierung zur Herstellung von Ohrpassstücken
    KR100810998B1 (ko) * 2005-03-30 2008-03-11 주식회사 코오롱 프리즘 필름 및 그 제조방법
    US20110144271A1 (en) 2005-06-16 2011-06-16 Jsr Corporation Radioactive ray-curable liquid resin composition for use in optical stereolithography, and optically shaped article produced by curing the composition
    JP2008201913A (ja) 2007-02-20 2008-09-04 Fujifilm Corp 光重合性組成物
    RU2761204C2 (ru) 2017-02-10 2021-12-06 Басф Се Мономеры на основе акрилата для применения в качестве реакционноспособных разбавителей в составах для печати
    WO2018146259A1 (en) 2017-02-10 2018-08-16 Basf Se Acrylate-based monomers for use as reactive diluents in printing formulations
    CN112272680B (zh) * 2018-06-25 2023-09-01 科巨希化学股份有限公司 三维造形用光固化性树脂组合物及三维造形方法、三维造形物
    US20230002631A1 (en) 2019-11-07 2023-01-05 Basf Se Water-washable compositions for use in 3d printing

    Citations (2)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    EP0171069A2 (de) * 1984-08-08 1986-02-12 3D SYSTEMS, INC. (a California corporation) Stereolithographische Vorrichtung und Verfahren zur Herstellung von dreidimensionalen Gegenständen
    US4789620A (en) * 1986-03-03 1988-12-06 Mitsubishi Rayon Co. Ltd. Liquid photosensitive resin composition containing carboxylated epoxy acrylates or methacrylates

    Patent Citations (2)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    EP0171069A2 (de) * 1984-08-08 1986-02-12 3D SYSTEMS, INC. (a California corporation) Stereolithographische Vorrichtung und Verfahren zur Herstellung von dreidimensionalen Gegenständen
    US4789620A (en) * 1986-03-03 1988-12-06 Mitsubishi Rayon Co. Ltd. Liquid photosensitive resin composition containing carboxylated epoxy acrylates or methacrylates

    Also Published As

    Publication number Publication date
    EP0425441B1 (de) 1995-12-27
    JP3243565B2 (ja) 2002-01-07
    KR910008491A (ko) 1991-05-31
    KR0163588B1 (ko) 1998-12-15
    EP0425441A2 (de) 1991-05-02
    CA2028541A1 (en) 1991-04-28
    CA2028541C (en) 2000-05-16
    JPH03160013A (ja) 1991-07-10
    DE59010008D1 (de) 1996-02-08

    Similar Documents

    Publication Publication Date Title
    EP0425441A3 (de) Photoempfindliches Gemisch
    CA2063982A1 (en) Photosensitive composition based on acrylates
    ES2054977T3 (es) Masas dentales endurecibles con luz visible.
    DE69033676D1 (de) Zusammensetzungen, die von pflanzen produzierte glykopolypeptidmultimere enthalten, sowie verfahren zu deren herstellung
    ATA258390A (de) Mischung aus vorwiegend einem polyhydroxyalkanoat und einer verbindung, die mindestens zwei reaktive gruppen wie säure- und/oder alkoholgruppen enthält und ein durch schmelzen der mischung hergestelltes polymerisat
    ES430643A1 (es) Procedimiento para la obtencion de masas endurecibles por luz ultravioleta.
    DE69123880D1 (de) Verfahren zur Herstellung von Eicosapentaensäure oder von einem Esterderivat davon
    DE2406557B2 (de) Hydroxyl-gruppen enthaltende diester von acrylsaeuren und diese enthaltendes zahnfuellungsmaterial
    EP0023685A3 (de) Dentalmassen
    ATE3774T1 (de) Beclomethason-ester-solvate, verfahren zu ihrer herstellung und herstellung einer formulierung.
    KR950005820A (ko) 우레탄기를 함유하는 (메트)아클릴레이트
    KR870007977A (ko) 저 굴절률의 플루오르-함유 수지 조성물
    ATE40644T1 (de) Fotopolymerisierbare zusammenstellungen.
    ATE134504T1 (de) Durch einwirkung von schwingungen herstellbare und verarbeitbare dentalmassen und verfahren zu ihrer herstellung
    DK487785A (da) Vulkaniserbar gummiblanding og fremgangsmaade til vulkanisering deraf
    JPS5313692A (en) Polymerizable material by ultraviolet
    EP0243595A3 (de) Schlagzähe Polyamid-Formmassen
    KR100263033B1 (ko) 디아크릴레이트와 디메타크릴레이트
    EP0213099A3 (de) Mittel mit antiphlogistischer, immunstimulierender und zytoprotektiver Wirkung, ihre Herstellung und pharmazeutische Verwendungen
    AU568608B2 (en) Radiation curable urethane acrylate compositions
    BE887316A (fr) Composition antigingivite non colorante a base d'acide trans-4-(aminomethyl)cyclohexane-1-carboxylique
    GB1450288A (en) Photopolymerizable compositon
    BR8807437A (pt) Composicao endurecivel a base de um produto de adicao michael,processo para sua preparacao bem como sua aplicacao
    DE2437379A1 (de) Schnell erhaertender klebstoff mit grossem haftvermoegen
    JPS56100817A (en) Photosetting resin composition

    Legal Events

    Date Code Title Description
    PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

    Free format text: ORIGINAL CODE: 0009012

    17P Request for examination filed

    Effective date: 19901022

    AK Designated contracting states

    Kind code of ref document: A2

    Designated state(s): BE CH DE FR GB IT LI NL SE

    PUAL Search report despatched

    Free format text: ORIGINAL CODE: 0009013

    AK Designated contracting states

    Kind code of ref document: A3

    Designated state(s): BE CH DE FR GB IT LI NL SE

    17Q First examination report despatched

    Effective date: 19930730

    GRAA (expected) grant

    Free format text: ORIGINAL CODE: 0009210

    ITF It: translation for a ep patent filed
    AK Designated contracting states

    Kind code of ref document: B1

    Designated state(s): BE CH DE FR GB IT LI NL SE

    REF Corresponds to:

    Ref document number: 59010008

    Country of ref document: DE

    Date of ref document: 19960208

    GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

    Effective date: 19960222

    ET Fr: translation filed
    REG Reference to a national code

    Ref country code: CH

    Ref legal event code: PUE

    Owner name: CIBA-GEIGY AG TRANSFER- CIBA SC HOLDING AG

    PLBE No opposition filed within time limit

    Free format text: ORIGINAL CODE: 0009261

    STAA Information on the status of an ep patent application or granted ep patent

    Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

    26N No opposition filed
    BECN Be: change of holder's name

    Effective date: 19961129

    NLS Nl: assignments of ep-patents

    Owner name: CIBA SC HOLDING AG

    REG Reference to a national code

    Ref country code: CH

    Ref legal event code: PFA

    Free format text: CIBA SC HOLDING AG TRANSFER- CIBA SPECIALTY CHEMICALS HOLDING INC.

    REG Reference to a national code

    Ref country code: GB

    Ref legal event code: 732E

    NLT1 Nl: modifications of names registered in virtue of documents presented to the patent office pursuant to art. 16 a, paragraph 1

    Owner name: CIBA SPECIALTY CHEMICALS HOLDING INC.

    REG Reference to a national code

    Ref country code: FR

    Ref legal event code: TP

    REG Reference to a national code

    Ref country code: CH

    Ref legal event code: PUE

    Owner name: CIBA SPECIALTY CHEMICALS HOLDING INC. TRANSFER- VA

    REG Reference to a national code

    Ref country code: GB

    Ref legal event code: 732E

    NLS Nl: assignments of ep-patents

    Owner name: VANTICO AG

    REG Reference to a national code

    Ref country code: GB

    Ref legal event code: IF02

    PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

    Ref country code: SE

    Payment date: 20021004

    Year of fee payment: 13

    PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

    Ref country code: FR

    Payment date: 20021008

    Year of fee payment: 13

    PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

    Ref country code: GB

    Payment date: 20021016

    Year of fee payment: 13

    REG Reference to a national code

    Ref country code: FR

    Ref legal event code: TP

    PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

    Ref country code: DE

    Payment date: 20021024

    Year of fee payment: 13

    PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

    Ref country code: NL

    Payment date: 20021031

    Year of fee payment: 13

    PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

    Ref country code: CH

    Payment date: 20021101

    Year of fee payment: 13

    PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

    Ref country code: BE

    Payment date: 20021219

    Year of fee payment: 13

    REG Reference to a national code

    Ref country code: GB

    Ref legal event code: 746

    Effective date: 20030116

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: GB

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20031019

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: SE

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20031020

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: LI

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20031031

    Ref country code: CH

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20031031

    Ref country code: BE

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20031031

    BERE Be: lapsed

    Owner name: *VANTICO A.G.

    Effective date: 20031031

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: NL

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20040501

    Ref country code: DE

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20040501

    EUG Se: european patent has lapsed
    GBPC Gb: european patent ceased through non-payment of renewal fee

    Effective date: 20031019

    REG Reference to a national code

    Ref country code: CH

    Ref legal event code: PL

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: FR

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20040630

    NLV4 Nl: lapsed or anulled due to non-payment of the annual fee

    Effective date: 20040501

    REG Reference to a national code

    Ref country code: FR

    Ref legal event code: ST

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: IT

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES;WARNING: LAPSES OF ITALIAN PATENTS WITH EFFECTIVE DATE BEFORE 2007 MAY HAVE OCCURRED AT ANY TIME BEFORE 2007. THE CORRECT EFFECTIVE DATE MAY BE DIFFERENT FROM THE ONE RECORDED.

    Effective date: 20051019