EP0374062B1 - Procédé et appareil de séchage de l'isolant de papier d'un dispositif électrotechnique à haute tension et applicateur d'énergie des micro-ondes à cet effet - Google Patents
Procédé et appareil de séchage de l'isolant de papier d'un dispositif électrotechnique à haute tension et applicateur d'énergie des micro-ondes à cet effet Download PDFInfo
- Publication number
- EP0374062B1 EP0374062B1 EP89420493A EP89420493A EP0374062B1 EP 0374062 B1 EP0374062 B1 EP 0374062B1 EP 89420493 A EP89420493 A EP 89420493A EP 89420493 A EP89420493 A EP 89420493A EP 0374062 B1 EP0374062 B1 EP 0374062B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- coaxial
- microwave
- transmission line
- water
- dielectric insulation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000009413 insulation Methods 0.000 title claims abstract description 51
- 238000001035 drying Methods 0.000 title claims description 34
- 238000000034 method Methods 0.000 title claims description 6
- 239000004020 conductor Substances 0.000 claims abstract description 78
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 68
- 230000005540 biological transmission Effects 0.000 claims abstract description 61
- 230000007704 transition Effects 0.000 claims description 23
- 230000001902 propagating effect Effects 0.000 claims description 9
- 239000003989 dielectric material Substances 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 230000009466 transformation Effects 0.000 claims description 3
- 230000005484 gravity Effects 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 238000007789 sealing Methods 0.000 claims 2
- 230000000644 propagated effect Effects 0.000 abstract 1
- 239000012212 insulator Substances 0.000 description 30
- 230000000712 assembly Effects 0.000 description 5
- 238000000429 assembly Methods 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 3
- 230000006978 adaptation Effects 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B6/00—Heating by electric, magnetic or electromagnetic fields
- H05B6/64—Heating using microwaves
- H05B6/80—Apparatus for specific applications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B2206/00—Aspects relating to heating by electric, magnetic, or electromagnetic fields covered by group H05B6/00
- H05B2206/04—Heating using microwaves
- H05B2206/046—Microwave drying of wood, ink, food, ceramic, sintering of ceramic, clothes, hair
Definitions
- the present invention relates to a method of drying, by microwave, a multi-layer paper insulator, forming part of a high-voltage electrotechnical device, such as a transformer bushing.
- the invention also relates to a microwave energy applicator and a dryer containing such an applicator, the latter as well as the dryer being intended for carrying out the method.
- bushings pass through the metal casing, in order to allow a connection, from the outside, with the winding terminals.
- One such crossing includes a conductor wrapped in multi-layer paper insulation.
- the paper insulation, as well as part of the conductor, are housed inside a cylindrical ceramic envelope, hermetically sealed and filled with oil. The paper insulation is therefore moistened with this oil.
- the main object of the present invention is therefore to provide a quick and inexpensive means of drying the paper insulation of the bushings, of the type mentioned above, by means of microwaves.
- Microwave drying of the insulation of an electrotechnical device is quick and inexpensive, so that it becomes more advantageous to recondition the electrotechnical device by drying its dielectric insulator , rather than replacing it.
- the two apparatuses for drying a paper insulator each have a microwave energy applicator 1 .
- the applicator 1 has a first end which is connected to a first microwave window 2 and a second end which is connected to a second microwave window 3 .
- FIGS. 2A, 2B and 2C The structure of the applicator 1 and of the windows 2 and 3 appears in detail in FIGS. 2A, 2B and 2C .
- the applicator 1 first comprises a tubular metallic element 4 , electrically conductive, namely a circular cylinder in cross section, in which is mounted the bushing whose insulator is to be dried.
- the bushing 5 is designed to be used in a high voltage transformer.
- a crossing 5 comprises a metallic conductor 6 , namely a hollow elongated tube whose ends are threaded externally to allow an electrical connection.
- the conductor 6 is straight and cylindrical, that is to say circular in cross section. It is, on the other hand, insulated by means of a dielectric insulator 7 of multi-layer paper, enveloping said conductor 6 .
- a dielectric insulator 7 of multi-layer paper enveloping said conductor 6 .
- one end of the insulator 7 of multi-layer paper is perpendicular to the conductor 6 , while the other end of the insulator is conical.
- the bushing 5 has been removed from its ceramic envelope and, as said above, its paper insulation is impregnated with oil, but also contains water which has got there. infiltrated.
- the bushing 5 is held in position inside the cylinder 4 by means of two annular end supports 8 and 9 , interposed between the paper insulation 7 and the internal surface of the cylinder 4 .
- the two supports 8 and 9 are made of a dielectric material permeable to microwaves and are provided with passages, such as 9 ′ in FIG. 2B , passing right through each support when the supports 8 and 9 are inserted between the cylinder 4 and the paper insulator 7 of the bushing.
- the metal cylinder 4 and the conductor 6 form a coaxial microwave transmission line, capable of propagating the microwaves. More precisely, the conductor 6 constitutes the internal conductor of the line, the cylinder 4 , the external conductor of the same line and the paper insulator 7 acts as a dielectric in the coaxial transmission line.
- the cylinder 4 is provided with an upper and vertical exhaust duct 10 , two lower and vertical exhaust ducts 11 and 12 and as well as two collar end fittings 13 and 14 .
- the microwave energy applicator 1 comprises, in in addition, two sets of coaxial-to-coaxial transition 15 and 16 provided at their respective ends.
- Each of the transition assemblies 15 , 16 comprises a tapered waveguide section 17 , 18 (external conductor), of circular cross section and a conical internal conductor 19 , 20 coaxial with the waveguide section 17 , 18 and, also, of circular cross section.
- the waveguide section 17 is provided with a collar connection 21 at its close end and another collar connection 26 at its remote end, the two connections being conventional.
- the waveguide section 18 is provided with a flange connection 23 at its close end and with another flange connection 24 at its remote end, the two connections being conventional.
- the collar fittings 13 and 21 are fixed together to form an airtight seal between them.
- An airtight seal is also obtained between the collar connections 14 and 23 of the cylinder 4 and of the waveguide section 18 .
- the production of such seals is well known to those skilled in the art and it is therefore not necessary to specify further.
- the internal conductor 19 is provided with a pin 19 ′, at its close end, this pin 19 ′ being inserted under pressure into the corresponding end of the hollow tube 6 .
- the internal conductor 20 is provided with a pin 20 ′, at its close end, which pin 20 ′ is also inserted under pressure into the other end of the hollow tube 6 .
- the internal conductors 19 and 20 are mounted on the hollow tube 6 , which conducts electricity.
- the microwave window 2 comprises a section 27 of standard 50 ⁇ waveguide, of circular cross section which comprises, at its close end, a standard collar connector 28 , fixed to the collar connector 26 , to make a airtight seal between fittings 26 and 28 .
- the waveguide section 27 further includes a standard flange connection 29 at its remote end.
- the microwave window 3 comprises a section 30 of standard circular waveguide of 50 ⁇ having a standard collar connection 31 , at its close end, attached to collar fitting 24 . Also, an airtight seal is formed between the collar fittings 24 and 31 .
- the waveguide section 30 obviously has a standard collar connection 32 at its remote end.
- Each of the two microwave windows 2 , 3 also has an internal central conductor 33 , 34 coaxial with the section 27 , 30 of waveguide and of circular and constant cross section.
- the hollow end, brought closer to each conductor 33 , 34 is forced inside a coaxial hole dug in the end remote from the internal conical conductors 19 , 20 , so that the conductor 33 , 34 is fixed to the conductor 19 , 20 .
- Each window 2 , 3 comprises, in addition, an annular stop 35 , 36 , made of a dielectric material permeable to microwaves.
- Each stop 35 , 36 can be slid longitudinally inside the waveguide section 27 , 30 and thus around the internal conductor 33 , 34 .
- a first O-ring 37 , 38 seals the seal between the stop 35 , 36 and the bore of the waveguide section 27 , 30
- a second O-ring 39 , 40 seals the seal between the stop 35 , 36 and the internal conductor 33 , 34 .
- the stop 35 , 36 keeps the conductor 33 , 34 coaxial with the waveguide section 27 , 30 and its position inside the waveguide section is adjusted so as to obtain an optimal reflection coefficient which is as low as possible.
- the window 2 , the transition assembly 15 , the cylinder 4 , the conductor 6 , the transition assembly 16 and the window 3 constitute, overall, a coaxial microwave transmission line, capable to propagate microwaves whose external conductor is constituted by the coaxial sections of waveguide 27 and 17 , the cylinder 4 and the sections 18 and 30 of waveguide and whose internal conductor is constituted by conductors 33 , 19 , 6 , 20 and 34 aligned on a common axis.
- the function of the transition assembly 15 is to adapt the impedance of window 2 to the impedance of the coaxial line of transition formed by cylinder 4 and conductor 6 .
- the internal diameter of the waveguide section 17 gradually increases from the internal diameter of the waveguide section 27 to the internal diameter of the cylinder 4 , while the internal conical conductor 19 sees its external diameter increase gradually, from that of driver 33 to that of driver 6 .
- the transition assembly 16 likewise adapts the impedance of the coaxial transmission line formed by the cylinder 4 and the conductor 6 to that of the microwave window 3 .
- the internal diameter of the waveguide section 18 decreases gradually from the internal diameter of the cylinder 4 to the internal diameter of the waveguide section 30 , while the internal conical conductor 20 also sees its external diameter gradually decrease, from that of conductor 6 to that of conductor 34 .
- Impedance matching using transition assemblies 15 and 16 , prevents the formation of a standing wave in the coaxial microwave transmission line that includes window 2 , transition assembly 15 , cylinder 4 , the conductor 6 , the transition assembly 16 and the window 3 , due to the reflections that would cause the absence of such an adaptation of impedances.
- a standing wave of this nature has maximums and minimums and would cause uneven heating of the water in the paper insulation.
- the windows 2 and 3 , the transition assemblies 15 and 16 , the cylinder 4 and the conductor 6 define an airtight annular enclosure.
- the paper insulation drying apparatus comprises a high power source 41 of microwaves, advantageously constituted by a magnetron generator.
- the microwaves, coming from the source 41 are transmitted to the window 2 by means of a conventional waveguide-to-coaxial transition device (not illustrated), connected to the standard collar connection 29 of the guide section. wave 27 ( fig. 2A ).
- the microwaves, coming from the source 41 pass through the window 2 , the applicator 1 and the window 3 and are transmitted to a suitable load 42 through a conventional coaxial-to-waveguide transition device (not illustrated). ) attached to standard fitting 32 ( fig. 2A ).
- the load 42 being adapted, there is no reflection, since the load then absorbs all the energy of the microwaves which propagate through the windows 2 and 3 and through the applicator 1 , without being absorbed by the water itself. It follows that a standing wave does not form in the applicator 1 , so that the water is heated uniformly throughout the paper insulator 7 , due to a uniform distribution of the electric field in the transmission line.
- the high power microwave source 41 transmits microwaves to window 2 , through a circulator 45 connected to window 2 , by means of a waveguide-to-coaxial transition device (not shown) which is fixed to the standard flange connection 29 ( fig. 2A ).
- the microwaves propagate through the window 2 , the applicator 1 and the window 3 and are transmitted to an adjustable short circuit 47 connected to the collar connection 32 ( FIG. 2A ) of the waveguide section 30 , using a conventional coaxial-to-waveguide transition device (not shown).
- the microwaves which reach the short circuit 47 are reflected and transmitted to a suitable load 46 through the window 3 , the applicator 1 , the window 2 and the circulator 45 .
- a standing wave with maximums and minimums is therefore produced inside the coaxial line formed by the cylinder 4 and the conductor 6 .
- the short circuit 47 is displaced to move the minimums and maximums of the standing wave in the applicator 1 , in order to obtain a heating of the water which is uniform in the insulator 7 of paper.
- the energy of the microwaves, reaching the appropriate charge 46 is absorbed by the latter, without significant reflection of the microwaves.
- the microwaves which propagate through the coaxial transmission line formed by the cylinder 4 and the conductor 6 , cause the water molecules to oscillate in the paper insulator 7 .
- the water is thus heated and transformed into water vapor.
- a vacuum pump 43 sucks the water vapor thus produced through the upper exhaust duct 10 of FIG. 2A , in order to improve and speed up the drying process, by forcing the evacuation of water vapor from the airtight enclosure. It is therefore important that the O-rings 37 , 38 , 39 and 40 and the pairs of collar fittings 26 , 28 ; 13 , 21 ; 14 , 23 and 24 , 31 create airtight seals, in order to obtain an airtight enclosure which is discussed above.
- the oil which permeates the paper insulator 7 , is also heated by microwaves and by steam, so that its fluidity increases and that it flows by gravity towards an oil trap 44 , by means of two lower exhaust pipes 11 and 12 , this being true for the two embodiments of FIGS. 1 and 3 .
- the vacuum pump 43 can be replaced by a cryogenic trap using liquid nitrogen ( N2 ) or carbon dioxide ( CO2 ), such a cryogenic trap being, of course, well known in the art.
- N2 liquid nitrogen
- CO2 carbon dioxide
- the paper insulation 7 is dried quickly by microwaves, the drying time being counted in hours rather than days, as is the case for drying in conventional ovens.
- the drying of the insulator 7 becomes economical and the restoration at low cost of the crossbeams of high voltage transformers is therefore possible.
- the frequency of the microwaves is important in that their wavelength must be close to the internal diameter of the cylinder 4 , so as to obtain a propagation according to the dominant TEM mode.
- a cylindrical metallic shield 48 illustrated in broken lines in FIG. 2A , either provided in the paper insulator 7 .
- two coaxial and parallel transmission lines are formed, the first being constituted by the conductor 6 and the shield 48 , while the second is constituted by the shield 48 and the cylinder 4 .
- the present invention can also be used to dry the multi-layer paper insulation, but an appropriate adaptation of the impedances must then be made using the transition assemblies 15 and 16 and, optionally, adjusting screws.
- the present invention can be used to dry the multi-layer paper insulation from high-voltage transformer bushings or any other high-voltage electrotechnical device, provided that they have a central internal conductor around which the paper insulation multilayer is wound and that such a conductor can be used as an internal conductor of a coaxial microwave transmission line.
- the central conductor of the electrotechnical device need not be straight. In fact, it may be somewhat curved, provided that the tubular member 4 is similarly curved to form the required coaxial microwave transmission line.
- the central conductor of the device may also exhibit discontinuities, provided that an appropriate impedance matching is carried out.
- the present invention can also be used for a dielectric insulator other than paper, provided that such an insulator is permeable to water and microwaves.
Landscapes
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Drying Of Solid Materials (AREA)
- Insulating Bodies (AREA)
- Paper (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT89420493T ATE73921T1 (de) | 1988-12-15 | 1989-12-14 | Verfahren und vorrichtung zur trocknung der papierisolation eines elektrotechnischen hochspannungsapparates und mikrowellenenergieapplikationsvorrichtung zu diesem zweck. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US284732 | 1988-12-15 | ||
| US07/284,732 US4889965A (en) | 1988-12-15 | 1988-12-15 | Microwave drying of the paper insulation of high voltage electrotechnical equipments |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0374062A2 EP0374062A2 (fr) | 1990-06-20 |
| EP0374062A3 EP0374062A3 (en) | 1990-08-08 |
| EP0374062B1 true EP0374062B1 (fr) | 1992-03-18 |
Family
ID=23091319
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP89420493A Expired - Lifetime EP0374062B1 (fr) | 1988-12-15 | 1989-12-14 | Procédé et appareil de séchage de l'isolant de papier d'un dispositif électrotechnique à haute tension et applicateur d'énergie des micro-ondes à cet effet |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4889965A (enExample) |
| EP (1) | EP0374062B1 (enExample) |
| JP (1) | JPH0610939B2 (enExample) |
| AT (1) | ATE73921T1 (enExample) |
| CA (1) | CA1317643C (enExample) |
| DE (1) | DE68901033D1 (enExample) |
| ES (1) | ES2030999T3 (enExample) |
| GR (1) | GR3004093T3 (enExample) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE465348B (sv) * | 1990-06-14 | 1991-08-26 | Nils Elander | Mikrovaagsanordning foer behandling av precessvaetskor |
| US5262610A (en) * | 1991-03-29 | 1993-11-16 | The United States Of America As Represented By The Air Force | Low particulate reliability enhanced remote microwave plasma discharge device |
| GB9309202D0 (en) * | 1993-05-05 | 1993-06-16 | Apv Corp Ltd | Microwave ovens |
| US5423260A (en) * | 1993-09-22 | 1995-06-13 | Rockwell International Corporation | Device for heating a printed web for a printing press |
| DE69622175T2 (de) * | 1995-09-20 | 2003-03-13 | Sun Microsystems, Inc. | Sorptionspaar verwendende kälteanlage |
| US5855119A (en) * | 1995-09-20 | 1999-01-05 | Sun Microsystems, Inc. | Method and apparatus for cooling electrical components |
| US5916259A (en) | 1995-09-20 | 1999-06-29 | Sun Microsystems, Inc. | Coaxial waveguide applicator for an electromagnetic wave-activated sorption system |
| US6244056B1 (en) | 1995-09-20 | 2001-06-12 | Sun Microsystems, Inc. | Controlled production of ammonia and other gases |
| US5873258A (en) * | 1995-09-20 | 1999-02-23 | Sun Microsystems, Inc | Sorption refrigeration appliance |
| US5842356A (en) * | 1995-09-20 | 1998-12-01 | Sun Microsystems, Inc. | Electromagnetic wave-activated sorption refrigeration system |
| US5869817A (en) * | 1997-03-06 | 1999-02-09 | General Mills, Inc. | Tunable cavity microwave applicator |
| US7003979B1 (en) | 2000-03-13 | 2006-02-28 | Sun Microsystems, Inc. | Method and apparatus for making a sorber |
| US6630654B2 (en) * | 2001-10-19 | 2003-10-07 | Personal Chemistry I Uppsala Ab | Microwave heating apparatus |
| US20080223855A1 (en) * | 2005-10-19 | 2008-09-18 | Clearwave Ltd. | Microwave Oven Window |
| ES2342958B2 (es) * | 2008-09-03 | 2011-07-04 | Emite Ingenieria Slne | Analizador de multiples entradas y multiples salidas. |
| CN111854375A (zh) * | 2020-07-27 | 2020-10-30 | 北京金辉景新节能科技有限公司 | 一种真空微波脱水设备 |
| EP4657472A1 (en) | 2024-05-28 | 2025-12-03 | Martin Carlen | Method and device for drying insulation materials of high voltage electrotechnical equipment, in particular transformers |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE867670C (de) * | 1950-11-30 | 1953-02-19 | Siemens Ag | Vorrichtung zur Vakuumbehandlung, insbesondere Trocknung |
| US2740756A (en) * | 1951-04-19 | 1956-04-03 | Albert G Thomas | Electrical drying system |
| DE1278948B (de) * | 1965-01-26 | 1968-09-26 | Licentia Gmbh | Vakuum-Trocknungsverfahren fuer porige Trocknungsgueter |
| US3430351A (en) * | 1966-06-14 | 1969-03-04 | Asea Ab | Method of drying objects such as electrical machines and electrical insulating material |
| US3452176A (en) * | 1967-05-24 | 1969-06-24 | Melvin L Levinson | Heating a moving conductor by electromagnetic wave irradiation in the microwave region |
| US3590202A (en) * | 1970-02-24 | 1971-06-29 | Bechtel Corp | Construction for tuning microwave heating applicator |
| US3887722A (en) * | 1973-08-31 | 1975-06-03 | United Aircraft Corp | Method for producing a plurality of filaments in a radio frequency reactor |
| US4259560A (en) * | 1977-09-21 | 1981-03-31 | Rhodes George W | Process for drying coal and other conductive materials using microwaves |
| GB2042703A (en) * | 1979-02-06 | 1980-09-24 | Ciba Geigy Ag | Drying of Web Material |
| SE417780B (sv) * | 1980-01-22 | 1981-04-06 | Por Microtrans Ab | Dielektrisk uppvermningsanordning |
| FR2584258B1 (fr) * | 1985-06-28 | 1995-04-14 | Elf Aquitaine | Procede et dispositif pour le traitement thermique d'un element conducteur au moins partiellement constitue d'un materiau conducteur |
| DE3630567A1 (de) * | 1986-09-09 | 1988-03-10 | Kurt Dipl Ing Zeppenfeld | Zyklon-druckfilter mit mikrowellentrockner |
| US4771156A (en) * | 1986-10-20 | 1988-09-13 | Micro Dry Incorporated | Method and apparatus for heating and drying moist articles |
-
1988
- 1988-12-15 US US07/284,732 patent/US4889965A/en not_active Expired - Fee Related
-
1989
- 1989-09-29 CA CA000614712A patent/CA1317643C/fr not_active Expired - Fee Related
- 1989-12-14 ES ES198989420493T patent/ES2030999T3/es not_active Expired - Lifetime
- 1989-12-14 AT AT89420493T patent/ATE73921T1/de not_active IP Right Cessation
- 1989-12-14 JP JP1322827A patent/JPH0610939B2/ja not_active Expired - Lifetime
- 1989-12-14 DE DE8989420493T patent/DE68901033D1/de not_active Expired - Lifetime
- 1989-12-14 EP EP89420493A patent/EP0374062B1/fr not_active Expired - Lifetime
-
1992
- 1992-03-19 GR GR910402026T patent/GR3004093T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CA1317643C (fr) | 1993-05-11 |
| US4889965A (en) | 1989-12-26 |
| JPH02201824A (ja) | 1990-08-10 |
| DE68901033D1 (de) | 1992-04-23 |
| JPH0610939B2 (ja) | 1994-02-09 |
| GR3004093T3 (enExample) | 1993-03-31 |
| ATE73921T1 (de) | 1992-04-15 |
| EP0374062A3 (en) | 1990-08-08 |
| EP0374062A2 (fr) | 1990-06-20 |
| ES2030999T3 (es) | 1992-11-16 |
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