EP0349935A3 - Wässrige Lösungen von Polyamidoamin-Epichlorhyrin-Harzen, Verfahren zu ihrer Herstellung und ihre Verwendung - Google Patents

Wässrige Lösungen von Polyamidoamin-Epichlorhyrin-Harzen, Verfahren zu ihrer Herstellung und ihre Verwendung Download PDF

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Publication number
EP0349935A3
EP0349935A3 EP19890112049 EP89112049A EP0349935A3 EP 0349935 A3 EP0349935 A3 EP 0349935A3 EP 19890112049 EP19890112049 EP 19890112049 EP 89112049 A EP89112049 A EP 89112049A EP 0349935 A3 EP0349935 A3 EP 0349935A3
Authority
EP
European Patent Office
Prior art keywords
resin
component
amine
epichlorhydrine
resines
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP19890112049
Other languages
English (en)
French (fr)
Other versions
EP0349935A2 (de
EP0349935B1 (de
Inventor
Manfred Marten
Walter Dr. Kamutzki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Priority to AT89112049T priority Critical patent/ATE90405T1/de
Publication of EP0349935A2 publication Critical patent/EP0349935A2/de
Publication of EP0349935A3 publication Critical patent/EP0349935A3/de
Application granted granted Critical
Publication of EP0349935B1 publication Critical patent/EP0349935B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/54—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
    • D21H17/55—Polyamides; Polyaminoamides; Polyester-amides
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/18—Reinforcing agents
    • D21H21/20—Wet strength agents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paper (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Polyamides (AREA)

Abstract

Lagerstabile, wäßrige Harzlösung mit einem pH-Wert von höchstens 7, enthaltend als Harz ein wasserverdünnbares Polyamidoamin-Epichlorhydrin-Harz (A), erhalten durch Umsatz eines wasserverdünnbaren, basischen Polyamidoamins (B), bestehend aus einer Säurekomponente (B₁), und einer Aminkomponente (B₂), mit Epichlorhydrin (C), wobei der Gehalt an organisch gebundenem Chlor in dem Harz (A) höchstens 4 Gew.-% beträgt und wobei die Komponente (B₂) - falls die Säurekomponente (B₁) eine aliphatische oder aromatische Carbonsäure oder deren funktionelle Derivate, gegebenenfalls in Abmischung mit einer Aminocarbonsäure oder deren Lactamen darstellt - aus einem Gemisch aus Polyaminen und Alkanolmonoaminen besteht.
Weiterhin betrifft die Erfindung ein Verfahren zur Herstellung dieser Produkte und deren Verwendung insbesondere zur Erhöhung der Naßfestigkeit von Papier.
EP89112049A 1988-07-02 1989-07-01 Wässrige Lösungen von Polyamidoamin-Epichlorhyrin-Harzen, Verfahren zu ihrer Herstellung und ihre Verwendung Expired - Lifetime EP0349935B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT89112049T ATE90405T1 (de) 1988-07-02 1989-07-01 Waessrige loesungen von polyamidoamin-epichlorhyrin-harzen, verfahren zu ihrer herstellung und ihre verwendung.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3822490 1988-07-02
DE3822490A DE3822490A1 (de) 1988-07-02 1988-07-02 Waessrige loesungen von polyamidoamin-epichlorhyrin-harzen, verfahren zu ihrer herstellung und ihre verwendung

Publications (3)

Publication Number Publication Date
EP0349935A2 EP0349935A2 (de) 1990-01-10
EP0349935A3 true EP0349935A3 (de) 1991-05-08
EP0349935B1 EP0349935B1 (de) 1993-06-09

Family

ID=6357862

Family Applications (1)

Application Number Title Priority Date Filing Date
EP89112049A Expired - Lifetime EP0349935B1 (de) 1988-07-02 1989-07-01 Wässrige Lösungen von Polyamidoamin-Epichlorhyrin-Harzen, Verfahren zu ihrer Herstellung und ihre Verwendung

Country Status (5)

Country Link
US (1) US5019606A (de)
EP (1) EP0349935B1 (de)
AT (1) ATE90405T1 (de)
DE (2) DE3822490A1 (de)
ES (1) ES2058408T3 (de)

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DE4114657A1 (de) * 1991-05-06 1992-11-12 Hoechst Ag Waessrige loesungen von kationischen polyamidoamin-harzen
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US5256727A (en) * 1992-04-30 1993-10-26 Georgia-Pacific Resins, Inc. Resins with reduced epichlorohydrin hydrolyzates
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DE4426008A1 (de) 1994-07-22 1996-01-25 Cassella Ag Hydrophile, hochquellfähige Hydrogele
US5567798A (en) * 1994-09-12 1996-10-22 Georgia-Pacific Resins, Inc. Repulpable wet strength resins for paper and paperboard
US5614597A (en) 1994-12-14 1997-03-25 Hercules Incorporated Wet strength resins having reduced levels of organic halogen by-products
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US5972691A (en) * 1995-06-07 1999-10-26 Hercules Incorporated Dehalogenation of polyamine, neutral curing wet strength resins
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US6429267B1 (en) * 1997-12-31 2002-08-06 Hercules Incorporated Process to reduce the AOX level of wet strength resins by treatment with base
DE19807502B4 (de) 1998-02-21 2004-04-08 Basf Ag Verfahren zur Nachvernetzung von Hydrogelen mit 2-Oxazolidinonen, daraus hergestellte Hydrogele und deren Verwendung
US6503979B1 (en) 1998-02-26 2003-01-07 Basf Aktiengesellschaft Method for cross-linking hydrogels with bis- and poly-2-oxazolidinones
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DE19854574A1 (de) 1998-11-26 2000-05-31 Basf Ag Verfahren zur Nachvernetzung von Hydrogelen mit N-Acyl-2-Oxazolidinonen
DE19854573A1 (de) 1998-11-26 2000-05-31 Basf Ag Verfahren zur Nachvernetzung von Hydrogelen mit 2-Oxo-tetrahydro-1,3-oxazinen
ES2384726T3 (es) * 1999-06-11 2012-07-11 Hercules Incorporated Proceso para preparar resinas de poliamina-epihalohidrina con un contenido reducido de subproductos
US20030070783A1 (en) * 2000-12-09 2003-04-17 Riehle Richard James Reduced byproduct high solids polyamine-epihalohydrin compositions
CA2398630C (en) * 2000-12-09 2009-02-24 Hercules Incorporated Reduced byproduct high solids polyamine-epihalohydrin compositions
DE50202149D1 (de) * 2001-10-05 2005-03-03 Basf Ag Verfahren zur vernetzung von hydrogelen mit morpholin-2,3-dionen
US7081512B2 (en) * 2003-05-21 2006-07-25 Hercules Incorporated Treatment of resins to lower levels of CPD-producing species and improve gelation stability
DE102004038015A1 (de) * 2004-08-04 2006-03-16 Basf Ag Verfahren zur Nachvernetzung wasserabsorbierender Polymere mit zyklischen Carba-maten und/oder zyklischen Harnstoffen
DE102004057868A1 (de) * 2004-11-30 2006-06-01 Basf Ag Unlösliche Metallsulfate in wasserabsorbierenden Polymerpartikeln
US20060142432A1 (en) * 2004-12-29 2006-06-29 Harrington John C Retention and drainage in the manufacture of paper
US7589153B2 (en) * 2005-05-25 2009-09-15 Georgia-Pacific Chemicals Llc Glyoxalated inter-copolymers with high and adjustable charge density
US7576162B2 (en) * 2005-06-30 2009-08-18 Akzo Nobel N.V. Chemical process
WO2007025178A2 (en) * 2005-08-26 2007-03-01 New York University Rolyvalent multimeric compositions containing active polypeptides, pharmaceutical compositions and methods of using the same
WO2008024444A2 (en) * 2006-08-24 2008-02-28 Hercules Incorporated Adhesive composition of low molecular weight polyaminopolyamide-epichlorohydrin (pae) resin and protein
US7932349B2 (en) * 2006-09-18 2011-04-26 Hercules Incorporated Membrane separation process for removing residuals polyamine-epihalohydrin resins
US20080292886A1 (en) * 2007-03-23 2008-11-27 Hercules Inc. Adhesive formulations containing urea additives, methods of forming plywood therewith, and plywood products made thereby
US7868071B2 (en) * 2007-07-30 2011-01-11 Georgia-Pacific Chemicals Llc Method of stabilizing aqueous cationic polymers
ES2367409T3 (es) * 2007-10-09 2011-11-03 Hercules Incorporated Composiciones adhesivas que contienen reticulante.
EP2148003A1 (de) * 2008-07-22 2010-01-27 Mühle Rüningen GmbH & Co. KG Verfahren zur Herstellung eines modifizierten stärkehaltigen Produkts, in diesem Verfahren erzeugbares modifiziertes stärkehaltiges Produkt und seine Verwendung bei der Papierherstellung
EP2456828A1 (de) 2009-07-20 2012-05-30 Akzo Nobel Coatings International B.V. Haftsystem und verfahren zur herstellung eines produkts auf holzbasis
EP2456835A1 (de) 2009-07-20 2012-05-30 Akzo Nobel Coatings International B.V. Haftsystem und verfahren zur herstellung eines produkts auf holzbasis
EP2649145B1 (de) 2010-12-10 2014-11-26 Akzo Nobel Coatings International B.V. Wässriger klebstoff aus einem synthetischen polymer und lupinprotein
US20120247697A1 (en) 2011-03-29 2012-10-04 Kemira Oyj Polyamine Polyamidoamine Epihaloohydrin Compositions and Processes for Preparing and Using the Same
MX354457B (es) 2011-04-21 2018-03-06 Ecolab Usa Inc Resinas de poliamidoamina-epihalohidrina, método de fabricación y usos de las mismas.
ES2633188T3 (es) 2011-09-30 2017-09-19 Kemira Oyj Papel y procedimiento de fabricación de papel
US9777434B2 (en) 2011-12-22 2017-10-03 Kemira Dyj Compositions and methods of making paper products
US10624986B2 (en) 2012-09-26 2020-04-21 Kemira Oyj Absorbent materials, products including absorbent materials, compositions, and methods of making absorbent materials
EP2929087B1 (de) 2012-12-06 2017-02-08 Kemira OYJ In papier verwendete zusammensetzungen und verfahren zur papierherstellung
US9562326B2 (en) 2013-03-14 2017-02-07 Kemira Oyj Compositions and methods of making paper products
CA2958133C (en) 2014-08-13 2021-01-26 Solenis Technologies, L.P. Process to improve performance of wet-strength resins through base activation
CN105348524A (zh) * 2015-12-14 2016-02-24 广东省造纸研究所 一种环境友好型pae造纸湿强剂的制备方法
CN106589420A (zh) * 2015-12-15 2017-04-26 广东省造纸研究所 一种低氯丙醇pae造纸湿强剂的制备方法
WO2020181092A1 (en) * 2019-03-05 2020-09-10 Kemira Oyj Compositions and methods comprising wet strengthening resins
CN111203197A (zh) * 2020-01-14 2020-05-29 吉首大学 基于环氧和氨基交联的吸附材料及其制备方法
WO2025049834A1 (en) 2023-08-31 2025-03-06 Ecolab Usa Inc. Strengthening agents and processes for making and using same

Citations (1)

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Also Published As

Publication number Publication date
ES2058408T3 (es) 1994-11-01
DE58904602D1 (de) 1993-07-15
EP0349935A2 (de) 1990-01-10
DE3822490A1 (de) 1990-01-04
EP0349935B1 (de) 1993-06-09
US5019606A (en) 1991-05-28
ATE90405T1 (de) 1993-06-15

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