EP0341071A2 - Waschmittelzusammensetzungen - Google Patents

Waschmittelzusammensetzungen Download PDF

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Publication number
EP0341071A2
EP0341071A2 EP19890304522 EP89304522A EP0341071A2 EP 0341071 A2 EP0341071 A2 EP 0341071A2 EP 19890304522 EP19890304522 EP 19890304522 EP 89304522 A EP89304522 A EP 89304522A EP 0341071 A2 EP0341071 A2 EP 0341071A2
Authority
EP
European Patent Office
Prior art keywords
betaine
alkyl
apg
active
amine oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP19890304522
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English (en)
French (fr)
Other versions
EP0341071B2 (de
EP0341071A3 (en
EP0341071B1 (de
Inventor
Appaya Raghunath Naik
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Original Assignee
Unilever PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Application filed by Unilever PLC filed Critical Unilever PLC
Publication of EP0341071A2 publication Critical patent/EP0341071A2/de
Publication of EP0341071A3 publication Critical patent/EP0341071A3/en
Application granted granted Critical
Publication of EP0341071B1 publication Critical patent/EP0341071B1/de
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0094—High foaming compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/32—Amides; Substituted amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides

Definitions

  • the present invention relates to novel detergent compositions and especially, but not exclusively, to foaming liquid compositions useful for light-duty applications such as manual dishwashing.
  • the compositions may also have use for fabric washing, cleaning carpets and as shampoos.
  • Light-duty liquid detergent compositions such as are suitable for use in washing dishes are well known.
  • Many commercially-available formulations are based on a sulphate - or sulphonate-type anionic detergent, especially alkyl sulphate, alkyl benzene sulphonate and alkane sulphonate, in conjunction with an alkyl polyethoxy sulphate (alkyl ether sulphate).
  • the sulphonate-type detergent generally predominates.
  • Alkyl mono- and poly-glycosides are known and have been disclosed in a number of prior art patents and literature publications.
  • Boettner (US3219656) discusses the utility of alkyl mono-glycosides as foam stabilisers for anionic and nonionic surfactants.
  • Lew (US 3772269) discloses that decyl glucoside containing less than 1.6 glucose units acts as a good foamer.
  • Several Procter and Gamble disclosures eg EP 0 070 074, EP 0 070 075 and EP 0 070 076) discuss the utility of alkylpolyglucosides having greater than 1.5 glucose units in detergent compositions.
  • Henkel (EP 216 301 A) disclose the beneficial use of alkyl glycosides having from 1 to 1.4 glucose units which are incorporated in dishwashing liquids comprising ether sulphate and ethanolamide.
  • the present invention relates to safe, mild liquid detergents with a good foam stability and a good cleansing ability based upon alkyl polyglycosides.
  • the invention aims to provide novel, high-foaming nonionic-based liquid detergents comprising an alkyl polyglycoside. It is a further aim to provide a mild, ecologically safe liquid detergent.
  • an aqueous liquid detergent composition comprising:
  • Alkyl polyglycosides though nonionic in nature, differ from conventional ethoxylated nonionics such as alkyl ethoxylates or alkylphenol ethoxylates in having a different type of hydrophilic group and in consequence exhibit different physical, chemical and hence functional properties compared to conventional ethoxylated nonionics.
  • ethoxylates are low melting solids or liquids at room temperature, are completely miscible in non-polar solvents and their aqueous solutions have cloud points.
  • alkyl polyglycosides are high melting solids, sparingly soluble in non-polar solvents and their aqueous solutions do not show cloud points.
  • Alkyl polyglycosides also generally give lower surface tensions and give a more stable foam compared to comparable, conventional nonionics.
  • Alkyl polyglycosides are also prepared by different routes and can be produced entirely based on natural raw materials. Hence the compounds and compositions made therewith can be expected to be biologically safer and more acceptable than conventional nonionics and compositions containing them. Impurities present will also differ from conventional nonionics.
  • Alkyl polyglycosides may be manufactured by the Fischer glycoxidation of a detergent alcohol, eg C8-C18 Alcohol + "glucose” + catalyst ⁇ ROG x +H2O (ROH) + (G)
  • ROG x product depends on control of the ratios of the reactants.
  • a product will be a ratio of, eg ROG1:ROG2:ROG3.
  • the alkyl polyglycosides used in the present invention have a hydrophobic group containing approximately 8 to 20 carbon atoms, preferably about 10 to about 16, most preferably from 12 to 14, and a polysaccharide hydrophilic group containing from about 1 to about 3, preferably 1 to 1.5, most preferably 1.2 to 1.4 saccharide units on average.
  • the saccharide unit may be, for example, a galactoside, glucoside, fructoside or glycosyl. Mixtures thereof may be used.
  • alkyl polyglycosides are APG 500 and APG 550 from Horizon (APG is a trademark).
  • APG 500 has an average degree of polymerisation of 1.4, APG 550 of 1.8.
  • US 4 599 188 (Llenado) gives further description and characterisation of alkyl polyglycosides.
  • the alkyl polyglycoside is preferably the major active component and may, for example, be present at from 30 to 60 wt% of the total active.
  • the co-active anionic surfactant used according to the present invention may be of the sulphate or sulphonate type, or a mixture thereof.
  • Suitable sulphates are from the linear, branched, primary or secondary alcohols, with or without ethoxylation. Preferred alcohols are:
  • Primary alcohols with substantial branching may be used.
  • the preferred cations which neutralise the anionic surfactant are sodium and ammonium, and the latter sulphates can be an aid to hydrotroping of the liquid compositions of the invention.
  • the sulphonates may be those conventionally used, including linear alkylbenzene sulphonate, secondary alkyl sulphonate and alpha olefin sulphonate.
  • the third essential feature of the present invention is the presence of an amine oxide or a betaine as a lather booster.
  • the amount of amine oxide is not more than 10% by weight of the active detergent mixture.
  • the amount of betaine is not more than 30% by weight of this mixture.
  • the total amount of amine oxide and betaine is from 12 to 30% by weight of the active detergent mixture.
  • the lather booster is preferably present at from 2 to 6% by weight of the total composition. It is preferred to use betaines alone.
  • Sitable betaines include simple betaines of the formula: and amido betaines of formula:
  • R is a C8 to C18 straight or branched alkyl group. It may be a lauryl group or a middle cut coconut alkyl group.
  • R6 and R7 are each C1 to C3 alkyl or C1 to C3 hydroxyalkyl. Examples of sulphobetaines have the above formulae with -CO2CO ⁇ 2 replaced by:
  • a suitable simple betaine is Empigen BB from Albright & Wilson. It has the formula quoted above in which R is C12 to C14 alkyl, derived from coconut, and R6 and R7 are both methyl. Also preferred is Tego L7 from Goldschmidt, which has a whole coconut alkyl group.
  • Suitable amine oxides have the formula: R R6 R7 N O wherein R is a straight- or branched-chain C8 to C18 alkyl group and R6 and R7 are each C1 to C3 alkyl, or C1 to C3 hydroxyalkyl.
  • a suitable amine oxide is Empigen OB from Albright & Wilson. In it R is middle-cut coconut alkyl and R6 and R7 are both methyl.
  • compositions according to the present invention may include other conventional ingredients such as minor amounts of builders, urea, sodium or ammonium chloride, corrosion inhibitors, colourings and perfumes.
  • Conventional foam boosters such as ethanolamides may be included.
  • ethanolamide is optional. If present, the total level of betaine and/or amine oxide and ehtanolamide is from 12 to 30 wt% of the total active.
  • a preferred ethanolamide is Empilan LME (Albright & Wilson).
  • compositions according to the present invention are of particular use as light duty liquid detergent compositions for manual dishwashing.
  • compositions for manual dishwashing comprise from about 5 to about 60 wt%, preferably about 10 to about 40 wt% of the mixture of active components hereinbefore described, the balance comprising water and solvents.
  • compositions according to the present invention are mild and environmentally safe. They exhibit good foam characteristics.
  • Foaming performance was assessed by means of a modified Schlachter-Dierkes test based on the principle described in Fette und Seifen 1951, 53 , 207.
  • a 100 ml aqueous solution of each material tested, having a concentration of 0.04% active detergent in 24°H water (French hardness) at 45°C was rapidly oscillated using a vertically oscillating perforated disc within a graduated cylinder.
  • increments (0.2 g) of soil 9.5 parts commercial cooking fat, 0.25 parts oleic acid, 0.25 parts stearic acid and 10 parts wheat starch in 120 parts water
  • the result was recorded as the number of soil increments (NSI score): a score difference of 6 or less is generally regarded as insignificant.
  • NAI score number of soil increments
  • a comparison of wheatgerm acid phosphatase (WGAP) test and flex wash test results indicated that formulations giving less than 50% enzyme inhibition under the test conditions are substantially mild; any mildness differences between products giving ⁇ 40% inhibition do not show any detectable mildness differences in flex wash test, indicating that the enzyme test is very sensitive and that in a real life situation there is a threshold level of protein denaturation below which all actives and products are indistinguishably mild.
  • the results of the WGAP test are expressed as percentage inhibition (ie, 100% minus percentage activity remaining). Water gave no inhibition at all, ie 100% of activity remained.
  • APG APG 500 or APG 550 from Horizon Chemicals. Both have C12-C14 alkyl groups. Average degree of polymerisation of 1.4 and 1.8 respectively.
  • PAS Dobanol 23-S (Shell) Betaine : Empigen BB (Albright & Wilson) Amine Oxide : Empigen OB (Albright & Wilson)
  • LME Emplilan LME (Albright & Wilson)

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
EP89304522A 1988-05-06 1989-05-05 Waschmittelzusammensetzungen Expired - Lifetime EP0341071B2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB888810820A GB8810820D0 (en) 1988-05-06 1988-05-06 Detergent compositions
GB8810820 1988-05-06

Publications (4)

Publication Number Publication Date
EP0341071A2 true EP0341071A2 (de) 1989-11-08
EP0341071A3 EP0341071A3 (en) 1990-07-11
EP0341071B1 EP0341071B1 (de) 1994-08-03
EP0341071B2 EP0341071B2 (de) 2002-11-13

Family

ID=10636497

Family Applications (1)

Application Number Title Priority Date Filing Date
EP89304522A Expired - Lifetime EP0341071B2 (de) 1988-05-06 1989-05-05 Waschmittelzusammensetzungen

Country Status (9)

Country Link
EP (1) EP0341071B2 (de)
JP (1) JP2664474B2 (de)
AU (1) AU615740B2 (de)
BR (1) BR8902111A (de)
CA (1) CA1335876C (de)
DE (1) DE68917195T3 (de)
ES (1) ES2056215T5 (de)
GB (1) GB8810820D0 (de)
ZA (1) ZA893327B (de)

Cited By (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2234983A (en) * 1989-07-25 1991-02-20 Kao Corp Liquid detergent composition
WO1991011506A1 (de) * 1990-02-02 1991-08-08 Henkel Kommanditgesellschaft Auf Aktien Wässriges flüssiges reinigungsmittel
WO1992001772A1 (de) * 1990-07-23 1992-02-06 Henkel Kommanditgesellschaft Auf Aktien Flüssiges, fliess- und pumpfähiges tensidkonzentrat
WO1992006161A1 (en) * 1990-09-28 1992-04-16 The Procter & Gamble Company Detergent compositions containing polyhydroxy fatty acid amides and suds enhancing agent
US5118440A (en) * 1990-03-05 1992-06-02 The Procter & Gamble Company Light-duty liquid dishwashing detergent composition containing alkyl polysaccharide and alpha-sulfonated fatty acid alkyl ester surfactants
EP0490041A1 (de) * 1990-12-08 1992-06-17 Hüls Aktiengesellschaft Kosmetische Reinigungsflüssigkeit
EP0508507A1 (de) * 1991-04-09 1992-10-14 Akzo Nobel Surface Chemistry Aktiebolag Flüssiges Geschirrspülmittel
WO1994009102A1 (de) * 1992-10-14 1994-04-28 Henkel Kommanditgesellschaft Auf Aktien Wässrige detergensgemische
WO1994016042A1 (en) * 1993-01-12 1994-07-21 Henkel Corporation Dishwashing detergent
TR26609A (tr) * 1991-11-21 1995-03-15 Procter & Gamble ANYONIK SüRFAKTANLARI, POLIHIDROKSI YAGLI ASIT AMIDLERI VE ÖNEM TASIYAN BIR SEKILDE SECILEN KÖPüK ARTTIRICI MADDEYI IHTIVA EDEN DETERJAN BILESIMLER.
US5518647A (en) * 1993-12-20 1996-05-21 Colgate-Palmolive Company Foaming liquid emulsion composition
WO1996035770A1 (en) * 1995-05-10 1996-11-14 Unilever Plc Light duty cleaning composition
EP0780464A2 (de) 1995-12-21 1997-06-25 Henkel Kommanditgesellschaft auf Aktien Verfahren zur Herstellung hellfarbiger, niedrigviskoser Tensidkonzentrate
US5646100A (en) * 1994-02-14 1997-07-08 Colgate-Palmolive Company Mild, aqueous skin cleansing composition
DE19714369A1 (de) * 1997-04-08 1998-10-15 Henkel Kgaa Mittel für die Reinigung harter Oberflächen
US5883068A (en) * 1994-10-04 1999-03-16 Henkel Kommanditgesellschaft Auf Aktien Pumpable water-containing surfactant concentrates
US5925747A (en) * 1994-10-04 1999-07-20 Henkel Kommanditgesellschaft Auf Aktien Pumpable water-containing surfactant concentrates
US5932535A (en) * 1995-12-21 1999-08-03 Henkel Kommanditgesellschaft Auf Aktien Process for the production of light-colored, low-viscosity surfactant concentrates
EP1003605A4 (de) * 1997-06-12 2001-04-18 Henkel Corp Verwendung von alkylpolyglycosiden um die stabilisierung von schäumen aus amphoacetaten zu verbessern
FR2826017A1 (fr) * 2001-06-15 2002-12-20 Cognis France Sa Melanges de tensioactifs
WO2009007166A1 (de) * 2007-07-09 2009-01-15 Henkel Ag & Co. Kgaa Wasch- oder reinigungsmittel mit tensiden auf basis nachwachsender rohstoffe
EP2133408A1 (de) * 2000-06-29 2009-12-16 Ecolab Inc. Klarspülmittelzusammensetzung und Verfahren zum Klarspülen einer Substratoberfläche
WO2017209708A1 (en) 2016-05-30 2017-12-07 Hayat Kimya San. A. Ş. A non-irritant hand dishwashing composition
US10329521B2 (en) 2014-05-21 2019-06-25 Colgate-Palmolive Company Aqueous liquid dishwashing composition comprising an ammonium alkyl ether sulfate and alkylamidopropyl betaine
EP4119645A1 (de) * 2021-07-16 2023-01-18 The Procter & Gamble Company Flüssige handspülreinigungszusammensetzung
EP4119644A1 (de) * 2021-07-16 2023-01-18 The Procter & Gamble Company Flüssige handspülreinigungszusammensetzung
EP4119643A1 (de) * 2021-07-16 2023-01-18 The Procter & Gamble Company Flüssige handspülreinigungszusammensetzung

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9201519D0 (en) * 1992-01-24 1992-03-11 Unilever Plc Detergent compositions
KR100494626B1 (ko) * 2002-04-19 2005-06-13 주식회사 엘지생활건강 헹굼성이 우수한 주방용 세제 조성물
JP2005255708A (ja) * 2004-03-09 2005-09-22 Teepol Diversey Kk 濃縮中性洗浄剤組成物
FR2913351B1 (fr) 2007-03-08 2010-11-26 Rhodia Recherches Et Tech Utilisation d'une betaine a titre d'agent de reduction du drainage de la mousse
JP5367243B2 (ja) * 2007-09-13 2013-12-11 ディバーシー株式会社 家庭用業務用兼用濃縮中性洗浄剤組成物
JP7414895B2 (ja) * 2021-07-16 2024-01-16 ザ プロクター アンド ギャンブル カンパニー 液体食器手洗い用洗浄組成物

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0070076B2 (de) * 1981-07-13 1992-11-04 THE PROCTER & GAMBLE COMPANY Schäumende, flüssige Geschirrspülmittel
JPS58132100A (ja) * 1981-09-28 1983-08-06 ザ・プロクタ−・エンド・ギヤンブル・カンパニ− 洗剤組成物
US4554098A (en) 1982-02-19 1985-11-19 Colgate-Palmolive Company Mild liquid detergent compositions
CA1209010A (en) * 1982-04-26 1986-08-05 Keith A. Jones Foaming surfactant compositions
JPS60197614A (ja) * 1984-03-21 1985-10-07 Shionogi & Co Ltd 低刺激性シヤンプ−組成物
US4668422A (en) 1985-05-31 1987-05-26 A. E. Staley Manufacturing Company Liquid hand-soap or bubble bath composition
DE3534082A1 (de) * 1985-09-25 1987-04-02 Henkel Kgaa Fluessiges reinigungsmittel
JP2585032B2 (ja) * 1987-11-30 1997-02-26 株式会社資生堂 洗浄剤組成物

Cited By (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2234983B (en) * 1989-07-25 1993-01-06 Kao Corp Liquid detergent composition
GB2234983A (en) * 1989-07-25 1991-02-20 Kao Corp Liquid detergent composition
WO1991011506A1 (de) * 1990-02-02 1991-08-08 Henkel Kommanditgesellschaft Auf Aktien Wässriges flüssiges reinigungsmittel
US5118440A (en) * 1990-03-05 1992-06-02 The Procter & Gamble Company Light-duty liquid dishwashing detergent composition containing alkyl polysaccharide and alpha-sulfonated fatty acid alkyl ester surfactants
WO1992001772A1 (de) * 1990-07-23 1992-02-06 Henkel Kommanditgesellschaft Auf Aktien Flüssiges, fliess- und pumpfähiges tensidkonzentrat
WO1992006161A1 (en) * 1990-09-28 1992-04-16 The Procter & Gamble Company Detergent compositions containing polyhydroxy fatty acid amides and suds enhancing agent
EP0490041A1 (de) * 1990-12-08 1992-06-17 Hüls Aktiengesellschaft Kosmetische Reinigungsflüssigkeit
EP0508507A1 (de) * 1991-04-09 1992-10-14 Akzo Nobel Surface Chemistry Aktiebolag Flüssiges Geschirrspülmittel
TR26609A (tr) * 1991-11-21 1995-03-15 Procter & Gamble ANYONIK SüRFAKTANLARI, POLIHIDROKSI YAGLI ASIT AMIDLERI VE ÖNEM TASIYAN BIR SEKILDE SECILEN KÖPüK ARTTIRICI MADDEYI IHTIVA EDEN DETERJAN BILESIMLER.
WO1994009102A1 (de) * 1992-10-14 1994-04-28 Henkel Kommanditgesellschaft Auf Aktien Wässrige detergensgemische
US5578560A (en) * 1992-10-14 1996-11-26 Henkel Corporation Water-containing detergent mixtures comprising oligoglycoside surfactants
WO1994016042A1 (en) * 1993-01-12 1994-07-21 Henkel Corporation Dishwashing detergent
US5686400A (en) * 1993-01-12 1997-11-11 Henkel Corporation Manual dishwashing method using betaine-anionic surfactant mixtures
US5683972A (en) * 1993-12-20 1997-11-04 Colgate-Palmolive Company Foaming oil-in-water emulsion
US5518647A (en) * 1993-12-20 1996-05-21 Colgate-Palmolive Company Foaming liquid emulsion composition
US5646100A (en) * 1994-02-14 1997-07-08 Colgate-Palmolive Company Mild, aqueous skin cleansing composition
US5883068A (en) * 1994-10-04 1999-03-16 Henkel Kommanditgesellschaft Auf Aktien Pumpable water-containing surfactant concentrates
US5925747A (en) * 1994-10-04 1999-07-20 Henkel Kommanditgesellschaft Auf Aktien Pumpable water-containing surfactant concentrates
WO1996035770A1 (en) * 1995-05-10 1996-11-14 Unilever Plc Light duty cleaning composition
US5807816A (en) * 1995-05-10 1998-09-15 Lever Brothers Company, Division Of Conopco, Inc. Light duty cleaning composition
EP0780464A2 (de) 1995-12-21 1997-06-25 Henkel Kommanditgesellschaft auf Aktien Verfahren zur Herstellung hellfarbiger, niedrigviskoser Tensidkonzentrate
US5932535A (en) * 1995-12-21 1999-08-03 Henkel Kommanditgesellschaft Auf Aktien Process for the production of light-colored, low-viscosity surfactant concentrates
DE19714369A1 (de) * 1997-04-08 1998-10-15 Henkel Kgaa Mittel für die Reinigung harter Oberflächen
US6015780A (en) * 1997-04-08 2000-01-18 Henkel Kommanditgesellschaft Auf Aktien Formulations for cleaning hard surfaces comprising a betaine surfactant having exactly 12 carbon atoms
EP1003605A4 (de) * 1997-06-12 2001-04-18 Henkel Corp Verwendung von alkylpolyglycosiden um die stabilisierung von schäumen aus amphoacetaten zu verbessern
EP2133408A1 (de) * 2000-06-29 2009-12-16 Ecolab Inc. Klarspülmittelzusammensetzung und Verfahren zum Klarspülen einer Substratoberfläche
FR2826017A1 (fr) * 2001-06-15 2002-12-20 Cognis France Sa Melanges de tensioactifs
WO2002102949A1 (de) * 2001-06-15 2002-12-27 Cognis France S.A. Tensidmischungen
US7279456B2 (en) 2001-06-15 2007-10-09 Gognis France S.A. Surfactant mixtures
WO2009007166A1 (de) * 2007-07-09 2009-01-15 Henkel Ag & Co. Kgaa Wasch- oder reinigungsmittel mit tensiden auf basis nachwachsender rohstoffe
US10329521B2 (en) 2014-05-21 2019-06-25 Colgate-Palmolive Company Aqueous liquid dishwashing composition comprising an ammonium alkyl ether sulfate and alkylamidopropyl betaine
WO2017209708A1 (en) 2016-05-30 2017-12-07 Hayat Kimya San. A. Ş. A non-irritant hand dishwashing composition
EP4119645A1 (de) * 2021-07-16 2023-01-18 The Procter & Gamble Company Flüssige handspülreinigungszusammensetzung
EP4119644A1 (de) * 2021-07-16 2023-01-18 The Procter & Gamble Company Flüssige handspülreinigungszusammensetzung
EP4119643A1 (de) * 2021-07-16 2023-01-18 The Procter & Gamble Company Flüssige handspülreinigungszusammensetzung

Also Published As

Publication number Publication date
AU615740B2 (en) 1991-10-10
DE68917195D1 (de) 1994-09-08
JP2664474B2 (ja) 1997-10-15
EP0341071B2 (de) 2002-11-13
ES2056215T5 (es) 2003-05-01
CA1335876C (en) 1995-06-13
ZA893327B (en) 1991-01-30
DE68917195T2 (de) 1994-12-01
ES2056215T3 (es) 1994-10-01
EP0341071A3 (en) 1990-07-11
JPH01318089A (ja) 1989-12-22
EP0341071B1 (de) 1994-08-03
DE68917195T3 (de) 2003-04-03
BR8902111A (pt) 1990-01-02
GB8810820D0 (en) 1988-06-08
AU3398989A (en) 1989-11-09

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