EP0337716B1 - Magnetic ribbon and magnetic core - Google Patents
Magnetic ribbon and magnetic core Download PDFInfo
- Publication number
- EP0337716B1 EP0337716B1 EP89303542A EP89303542A EP0337716B1 EP 0337716 B1 EP0337716 B1 EP 0337716B1 EP 89303542 A EP89303542 A EP 89303542A EP 89303542 A EP89303542 A EP 89303542A EP 0337716 B1 EP0337716 B1 EP 0337716B1
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- EP
- European Patent Office
- Prior art keywords
- ribbon
- magnetic
- fine particles
- core
- magnetic ribbon
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F41/00—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties
- H01F41/02—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets
- H01F41/0206—Manufacturing of magnetic cores by mechanical means
- H01F41/0213—Manufacturing of magnetic circuits made from strip(s) or ribbon(s)
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
- H01F1/147—Alloys characterised by their composition
- H01F1/153—Amorphous metallic alloys, e.g. glassy metals
- H01F1/15383—Applying coatings thereon
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
- H01F1/16—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of sheets
- H01F1/18—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of sheets with insulating coating
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F27/00—Details of transformers or inductances, in general
- H01F27/24—Magnetic cores
- H01F27/25—Magnetic cores made from strips or ribbons
Definitions
- the present invention relates to a magnetic ribbon and a magnetic core formed by using said magnetic ribbon.
- a magnetic core is formed by winding or laminating a magnetic ribbon, and if insulation between layers of the ribbon is poor, an eddy current flowing across the ribbon layers occurs and an increase in eddy current losses results in an increase in overall core losses (magnetic losses). This tendency is particularly noticeable in the case of high frequencies. In addition, the frequency characteristics of permeability is poor, and it is impossible to expect any advantageous use at 100 kHz or more.
- an insulating layer formed of a nonmagnetic material is conventionally provided between the ribbon layers, and a uniform insulating film is formed on the ribbon surface as one means thereof, so as to solve the aforementioned problem.
- annealing is usually carried out at 400°C or thereabouts. However, if such annealing is carried out, because of a difference in the coefficient of linear expansion, i.e., since the coefficient of linear expansion of the insulating film is greater than that of the amorphous ribbon, compressive stress occurs in the ribbon, and magnetic characteristics deteriorate due to the adverse effect of magnetostriction.
- an insulating film is generally interposed between ribbon layers, and the greatest matter of concern to those skilled in the art lies in finding an insulating material having an excellent insulating performance.
- JP-A-62/10278 describes an alloy strip coated with colloidal silica in a metallic phosphate solution and upon this document, the prior art portion of claims 1 and 4 are based.
- EP-A-0 214 305 describes an alloy strip coated with an adhesive of a borosilicone resin for producing a laminated core.
- a magnetic ribbon for winding or lamination into a magnetic core the magnetic ribbon being formed of an amorphous metal and having fine particles coated on at least one surface thereof said fine particles having electrically-insulating properties; characterised in that said fine particles are antimony pentoxide particles having a size in the range of from 10 nm to 2 »m, and in that the fine particles are coated on said at least one surface in an amount in the range of from 10 ⁇ 7 cm3 to 2 x 10 ⁇ 4 cm3 per cm2 of surface area.
- the invention also provides a process for making the ribbon and a magnetic core of such a ribbon wound therearound or laminated thereon.
- the particles may be attached so as to secure a layer of air so that in the absence of a conventional insulating film, the air present between the layers can serve as an insulating layer and prevent an eddy current, and the space factor can be made as large as possible.
- particles formed of antimony pentoxide are attached on at least one surface of the magnetic ribbon, so that if the magnetic ribbon is wound or laminated to form a magnetic core, the particles serve as a spacer, thereby forming a layer of air between adjacent layers of the ribbon.
- the particles may be attached uniformly and densely on at least one surface of the ribbon.
- the particles themselves function as an insulating layer. Nevertheless, in this case as well, it is possible to obtain the same effect as that obtained by securing a layer of air by means of the particles. Accordingly, the present invention includes both the case where the particles are attached coarsely and the case where they are attached densely.
- the particles may be applied by any suitable method for example by passing the magnetic ribbon through a suspension containing the particles. Where it is intended that the particles should act as a spacer trapping a layer of air between layers or windings of a core the proportion of particles in the suspension may be chosen to be suitably low. For example, when suspended in toluene, they may form 1% to 10%, preferably 2% to 5%, e.g. about 3%, by weight of the suspension.
- the particles should be attached more densely so as to act as the insulation then a higher proportion may be used in the suspension.
- a higher proportion may be used in the suspension.
- 20% by weight for example 20% to 50%, e.g. about 30% by weight.
- a magnetic ribbon and a magnetic core can be provided having excellent magnetic characteristics while securing insulating properties between ribbon layers with the space factor reduced.
- the magnetic ribbon referred to in the present invention is a thin magnetic strip, and, as magnetic materials, it is possible to cite the following: ferromagnetic elements such as Fe, Co, and Ni among transition metals, alloys of ferromagnetic elements, alloys of ferromagnetic elements and nonferromagnetic elements which are added to improve characteristics, ferrite, permalloy, amorphous alloys, etc.
- ferromagnetic elements such as Fe, Co, and Ni among transition metals
- alloys of ferromagnetic elements alloys of ferromagnetic elements and nonferromagnetic elements which are added to improve characteristics, ferrite, permalloy, amorphous alloys, etc.
- Fe-based alloys such as Fe-B, Fe-B-C, Fe-B-Si, Fe-B-Si-C, Fe-B-Si-Cr, Fe-Co-B-Si, and Fe-Ni-Mo-B
- Co-based alloys such as Co-B, Co-Fe-Si-B, Co-Fe-Ni-Mo-B-Si, Co-Fe-Ni-B-Si, Co-Fe-Mn-B-Si, Co-Fe-Mn-Ni, Co-Mn-Ni-B-Si, and Co-Fe-Mn-Ni-B, and other similar alloys.
- Inorganic fine particles of antimony pentoxide are attached to such a magnetic ribbon.
- Antimony pentoxide is non-magnetic, and has insulating properties. If the fine particles are magnetic and conductive, an averse effect is exerted on magnetic characteristics, and an eddy current is liable to flow.
- the size of the fine particles of the inorganic substance if consideration is paid to the fact that the fine particles are attached to the ribbon uniformly so as to form an insulating layer, the size of the fine particles may be small. However, if the particle size is made too small, it constitutes a factor making manufacture difficult. Meanwhile, if the particle size is too large, when the magnetic core is formed by a ribbon, the gap between the adjacent layers of the ribbon becomes too large, so that the space factor of the magnetic material becomes small. For this reason, it is preferred that the size of the fine particles is set in the range of 10 nm to 2 »m.
- the fine particles may preferably be attached in such a manner that they are attached by 10 ⁇ 7 cm3 to 2 x 10 ⁇ 4 cm3, more preferably 3 x 10 ⁇ 6 cm3 to 10 ⁇ 5 cm, per unit area (1 cm2). If this amount attached is calculated into the weight of fine particles per unit area, it is 3.8 x 10 ⁇ 7 g/cm2 to 7.6 x 10 ⁇ 4 g/cm2, preferably 1.1 x 10 ⁇ 5 g/cm2 to 3.8 x 10 ⁇ 5 g/cm2.
- Means for attaching the fine particles is so arranged that these fine particles are dispersed in water or a volatile organic solvent such as toluene and, after this solution is applied to the ribbon surface, force or natural drying is carried out, thereby allowing the fine particles to be attached to the ribbon.
- the concentration of this solution determines the amount of fine particles to be attached to the ribbon.
- the antimony pentoxide may be dispersed in toluene in a colloidal state at a rate of from 0.1 to 30 wt% with respect to toluene. 3 wt% or thereabouts in this range is also effective, a decline in the space factor is practically nil, and the magnetic characteristics do not deteriorate.
- the thickness of the film of the solution applied is preferably 10 »m or less in determining the aforementioned amount of fine particles to be attached.
- a drying furnace may be used for evaporation of the solvent depending on the solvent, and drying may be carried out at 100°C or above.
- annealing may be carried out for 0.5 to 5 hours at a temperature of 300°C to 500°C in an inert gas atmosphere such as nitrogen so as to eliminate strain, as required.
- This annealing may be effected after the ribbon is wound or laminated into a magnetic core, or may be effected in the state of the ribbon.
- annealing may be effected at a temperature 10 to 50°C higher than the Curie point, a magnetic core exhibiting excellent characteristics with respect to high frequencies can be obtained.
- annealing may be effected in a magnetic field or in a nonmagnetic field.
- the magnetic core when the amorphous magnetic core with the ribbon wound therearound or laminated thereon is annealed since the fine particles disposed between adjacent ribbon layers are powders, the magnetic core is not subjected to linear expansion. The fine particles rather exhibit the action of absorbing the stress accompanying the shrinkage of the amorphous ribbon.
- a magnetic ribbon and a solution containing fine particles are prepared.
- the solution containing the fine particles is applied to at lest one surface of the magnetic ribbon by any of the various methods of application, and the solvent is allowed to dry.
- the resultant magnetic ribbon with the fine particles attached thereto is wound under tension, thereby obtaining a toroidal-type magnetic core.
- annealing for eliminating strain is carried out, as necessary.
- tension applied at the time of winding is preferably 0.05 o 2 kg.
- the ribbon with fine particles attached thereto is cut into a predetermined configuration, and the cut pieces are laminated so as to form the magnetic core.
- Annealing which is carried out as necessary may be effected prior to the lamination or after the magnetic core has been formed subsequent to the lamination.
- an amorphous ribbon 1a (2605S-2, Fe78-B13-Si9, 10 mm width) made by Allied Corp. is fed forward into a colloidal solution 2 of antimony pentoxide.
- a colloidal solution 2 of antimony pentoxide As the colloidal solution 2 of antimony pentoxide, toluene was used as the solvent, and 3 wt% of antimony was dispersed with respect to toluene 97 wt%.
- the ribbon 1b with the particles attached thereto was fed forward via a roller 5, and was wound under tension in a final stage, thereby forming an amorphous magnetic core 6.
- a plurality of magnetic cores having the same dimensions were then formed, and were subjected to annealing for two hours at 435°C in a nitrogen atmosphere.
- the magnetic cores of the Examples display a hysteresis which is closer to a linear configuration, and that the core loss is low as a whole, and a rise in the high-frequency component can be reduced to a low level.
- a substantially fixed permeability was obtained up to 200 kHz.
Abstract
Description
- The present invention relates to a magnetic ribbon and a magnetic core formed by using said magnetic ribbon.
- If a magnetic core is formed by winding or laminating a magnetic ribbon, and if insulation between layers of the ribbon is poor, an eddy current flowing across the ribbon layers occurs and an increase in eddy current losses results in an increase in overall core losses (magnetic losses). This tendency is particularly noticeable in the case of high frequencies. In addition, the frequency characteristics of permeability is poor, and it is impossible to expect any advantageous use at 100 kHz or more.
- Accordingly, in order to improve insulation between ribbon layers, an insulating layer formed of a nonmagnetic material is conventionally provided between the ribbon layers, and a uniform insulating film is formed on the ribbon surface as one means thereof, so as to solve the aforementioned problem.
- In cases where an amorphous magnetic ribbon is processed as a magnetic ribbon, annealing is usually carried out at 400°C or thereabouts. However, if such annealing is carried out, because of a difference in the coefficient of linear expansion, i.e., since the coefficient of linear expansion of the insulating film is greater than that of the amorphous ribbon, compressive stress occurs in the ribbon, and magnetic characteristics deteriorate due to the adverse effect of magnetostriction.
- In addition, there is another problem in that materials of such insulating films capable of withstanding annealing at 400°C or thereabouts are limited. Furthermore, if a magnetic core is formed by providing an insulating film, the filling factor (space factor) declines, which disadvantageously causes the magnetic core to become large in size.
- Thus, as described above, when producing a magnetic core by using a magnetic ribbon, an insulating film is generally interposed between ribbon layers, and the greatest matter of concern to those skilled in the art lies in finding an insulating material having an excellent insulating performance.
- JP-A-62/10278 describes an alloy strip coated with colloidal silica in a metallic phosphate solution and upon this document, the prior art portion of
claims - EP-A-0 214 305 describes an alloy strip coated with an adhesive of a borosilicone resin for producing a laminated core.
- In accordance with the present invention, there is provided a magnetic ribbon for winding or lamination into a magnetic core, the magnetic ribbon being formed of an amorphous metal and having fine particles coated on at least one surface thereof said fine particles having electrically-insulating properties;
characterised in that said fine particles are antimony pentoxide particles having a size in the range of from 10 nm to 2 »m, and in that the fine particles are coated on said at least one surface in an amount in the range of from 10⁻⁷ cm³ to 2 x 10⁻⁴ cm³ per cm² of surface area. - The invention also provides a process for making the ribbon and a magnetic core of such a ribbon wound therearound or laminated thereon.
- The particles may be attached so as to secure a layer of air so that in the absence of a conventional insulating film, the air present between the layers can serve as an insulating layer and prevent an eddy current, and the space factor can be made as large as possible.
- That is,particles formed of antimony pentoxide are attached on at least one surface of the magnetic ribbon, so that if the magnetic ribbon is wound or laminated to form a magnetic core, the particles serve as a spacer, thereby forming a layer of air between adjacent layers of the ribbon.
- However, the particles may be attached uniformly and densely on at least one surface of the ribbon. In this case, rather than particularly securing a layer of air, the particles themselves function as an insulating layer. Nevertheless, in this case as well, it is possible to obtain the same effect as that obtained by securing a layer of air by means of the particles. Accordingly, the present invention includes both the case where the particles are attached coarsely and the case where they are attached densely.
- The particles may be applied by any suitable method for example by passing the magnetic ribbon through a suspension containing the particles. Where it is intended that the particles should act as a spacer trapping a layer of air between layers or windings of a core the proportion of particles in the suspension may be chosen to be suitably low. For example, when suspended in toluene, they may form 1% to 10%, preferably 2% to 5%, e.g. about 3%, by weight of the suspension.
- Where it is intended that the particles should be attached more densely so as to act as the insulation then a higher proportion may be used in the suspension. For example, with the same materials as above, above 20% by weight, for example 20% to 50%, e.g. about 30% by weight.
- Thus with the present invention a magnetic ribbon and a magnetic core can be provided having excellent magnetic characteristics while securing insulating properties between ribbon layers with the space factor reduced.
- The invention will be further described by way of non-limitative example with reference to the accompanying drawings, in which :-
- Figs. 1 to 3 are graphs illustrating magnetic characteristics in accordance with a first embodiment of the present invention, in which
- Fig. 1 illustrates B-H characteristics;
- Fig. 2 illustrates the frequency characteristics of core loss; and
- Fig. 3 illustrates the frequency characteristics of permeability;
- Figs. 4 to 6 are graphs illustrating the magnetic characteristics in accordance with a second embodiment of the present invention, in which
- Fig. 4 illustrates B-H characteristics;
- Fig. 5 illustrates the frequency characteristics of core loss; and
- Fig. 6 illustrates the frequency characteristics of permeability; and
- Fig. 7 illustrates the outline of apparatus for attaching fine particles; and
- Fig. 8 is a diagram schematically illustrating means for producing a toroidal type magnetic core.
- Referring now to the accompanying drawings, a description will be given of the preferred embodiments of the present invention.
- The magnetic ribbon referred to in the present invention is a thin magnetic strip, and, as magnetic materials, it is possible to cite the following: ferromagnetic elements such as Fe, Co, and Ni among transition metals, alloys of ferromagnetic elements, alloys of ferromagnetic elements and nonferromagnetic elements which are added to improve characteristics, ferrite, permalloy, amorphous alloys, etc. As amorphous alloys, it is possible to cite Fe-based alloys such as Fe-B, Fe-B-C, Fe-B-Si, Fe-B-Si-C, Fe-B-Si-Cr, Fe-Co-B-Si, and Fe-Ni-Mo-B, Co-based alloys such as Co-B, Co-Fe-Si-B, Co-Fe-Ni-Mo-B-Si, Co-Fe-Ni-B-Si, Co-Fe-Mn-B-Si, Co-Fe-Mn-Ni, Co-Mn-Ni-B-Si, and Co-Fe-Mn-Ni-B, and other similar alloys.
- Inorganic fine particles of antimony pentoxide are attached to such a magnetic ribbon. Antimony pentoxide is non-magnetic, and has insulating properties. If the fine particles are magnetic and conductive, an averse effect is exerted on magnetic characteristics, and an eddy current is liable to flow.
- As for the size of the fine particles of the inorganic substance, if consideration is paid to the fact that the fine particles are attached to the ribbon uniformly so as to form an insulating layer, the size of the fine particles may be small. However, if the particle size is made too small, it constitutes a factor making manufacture difficult. Meanwhile, if the particle size is too large, when the magnetic core is formed by a ribbon, the gap between the adjacent layers of the ribbon becomes too large, so that the space factor of the magnetic material becomes small. For this reason, it is preferred that the size of the fine particles is set in the range of 10 nm to 2 »m.
- In addition, as for the amount of the fine particles attached, the fine particles may preferably be attached in such a manner that they are attached by 10⁻⁷ cm³ to 2 x 10⁻⁴ cm³, more preferably 3 x 10⁻⁶ cm³ to 10⁻⁵ cm, per unit area (1 cm²). If this amount attached is calculated into the weight of fine particles per unit area, it is 3.8 x 10⁻⁷ g/cm² to 7.6 x 10⁻⁴ g/cm², preferably 1.1 x 10⁻⁵ g/cm² to 3.8 x 10⁻⁵ g/cm².
- Means for attaching the fine particles is so arranged that these fine particles are dispersed in water or a volatile organic solvent such as toluene and, after this solution is applied to the ribbon surface, force or natural drying is carried out, thereby allowing the fine particles to be attached to the ribbon. The concentration of this solution determines the amount of fine particles to be attached to the ribbon. In other words, the antimony pentoxide may be dispersed in toluene in a colloidal state at a rate of from 0.1 to 30 wt% with respect to toluene. 3 wt% or thereabouts in this range is also effective, a decline in the space factor is practically nil, and the magnetic characteristics do not deteriorate. The thickness of the film of the solution applied is preferably 10 »m or less in determining the aforementioned amount of fine particles to be attached. In addition, a drying furnace may be used for evaporation of the solvent depending on the solvent, and drying may be carried out at 100°C or above.
- With respect to the magnetic ribbon, or an amorphous ribbon, in particular, annealing may be carried out for 0.5 to 5 hours at a temperature of 300°C to 500°C in an inert gas atmosphere such as nitrogen so as to eliminate strain, as required. This annealing may be effected after the ribbon is wound or laminated into a magnetic core, or may be effected in the state of the ribbon. In particular, when annealing is effected at a
temperature 10 to 50°C higher than the Curie point, a magnetic core exhibiting excellent characteristics with respect to high frequencies can be obtained. Incidentally, annealing may be effected in a magnetic field or in a nonmagnetic field. - In addition, when the amorphous magnetic core with the ribbon wound therearound or laminated thereon is annealed since the fine particles disposed between adjacent ribbon layers are powders, the magnetic core is not subjected to linear expansion. The fine particles rather exhibit the action of absorbing the stress accompanying the shrinkage of the amorphous ribbon.
- On the basis of the foregoing, a description will now be given of a method of producing a magnetic core in accordance with the present invention.
- First, a magnetic ribbon and a solution containing fine particles are prepared. The solution containing the fine particles is applied to at lest one surface of the magnetic ribbon by any of the various methods of application, and the solvent is allowed to dry. The resultant magnetic ribbon with the fine particles attached thereto is wound under tension, thereby obtaining a toroidal-type magnetic core. Finally, annealing for eliminating strain is carried out, as necessary. Incidentally, tension applied at the time of winding is preferably 0.05
o 2 kg. - Meanwhile, when a laminated type magnetic core is produced, the ribbon with fine particles attached thereto is cut into a predetermined configuration, and the cut pieces are laminated so as to form the magnetic core. Annealing which is carried out as necessary may be effected prior to the lamination or after the magnetic core has been formed subsequent to the lamination.
- Examples of the present invention will be described hereafter.
- By using the apparatus shown in Fig. 7, an amorphous ribbon 1a (2605S-2, Fe₇₈-B₁₃-Si₉, 10 mm width) made by Allied Corp. is fed forward into a
colloidal solution 2 of antimony pentoxide. When the amorphous ribbon 1a is lifted up, the amorphous ribbon 1a is clamped by a pair ofbar coaters 3 so as to allow excess solution to drop. Then, while the ribbon 1a is being dried with hot air by means of a hot air drier 4, the ribbon 1a was taken up. As for thecolloidal solution 2 of antimony pentoxide, toluene was used as the solvent, and 3 wt% of antimony was dispersed with respect to toluene 97 wt%. - Subsequently, as shown in Fig. 8, the ribbon 1b with the particles attached thereto was fed forward via a
roller 5, and was wound under tension in a final stage, thereby forming an amorphousmagnetic core 6. A plurality of magnetic cores having the same dimensions were then formed, and were subjected to annealing for two hours at 435°C in a nitrogen atmosphere. - With respect to the magnetic cores thus obtained, measurements were made of the B-H characteristics, frequency characteristics of the core loss, and frequency characteristics of permeability. As for the B-H characteristics, measurements were made of two cases: one in which a magnetic field of 10⁴ /4π A/m (10 Oe), and the other in which a magnetic field of 10³ /4π A/m (1 Oe) were applied.
- In addition, a colloidal solution in which 30 wt% of antimony pentoxide was dispersed with respect to 70 wt% of toluene was applied to the ribbon 1a, and measurements were similarly made. The detailed conditions in the respective examples were as follows:
- (1) Example 1 (3 wt% solution)
- (a) Magnetic core: a toroidal core with the aforementioned ribbon wound therearound
Inside diameter: 23.00 mm
Outside diameter: 37.00 mm
Height: 10.00 mm
Mass: 42.00 kg
Density of the material: 7.18 g/m³
Volume: 5.850 x 10⁻⁶ (m³)
Effective sectional area: 6.207 x 10⁻⁵ (m²)
Mean magnetic path length: 9.425 x 10⁻² (m)
Space factor: 88.67% (ratio of the volume of the ribbon to the total volume)
Tension during magnetic ribbon winding: 0.8 kg - (b) Colloidal solution applied
Organic solvent: toluene, 100 wt%
Fine particles: antimony pentoxide, 3 wt% - (c) Results
- * B-H characteristics are shown in Fig. 1.
- * Frequency characteristics of core loss are shown in Fig. 2.
The number of turns of the primary winding around the core was 5, while the number of turns of the secondary winding was 10. - * Frequency characteristics of permeability are shown in Fig. 3.
Measured magnetic field: 50/4π A/m (5 mOe)
Measured current: 2.65173 mA
- (a) Magnetic core: a toroidal core with the aforementioned ribbon wound therearound
- (2) Example 2 (30wt% solution)
- (a) Magnetic core: a toroidal core with the aforementioned ribbon wound therearound Inside diameter: 23.00 mm
Outside diameter: 37.00 mm
Height: 10.00 mm
Mass: 25.57 g
Density of the material 7.18 g/m³
Volume: 3.561 x 10⁻⁶ (m³)
Effective sectional area: 3.779 x 10⁻⁵ (m²)
Mean magnetic path length: 9.425 x 10⁻² (m)
Space factor: 53.98%
Tension during the magnetic ribbon winding:
0.8kg - (b) Colloidal solution applied
Organic solvent: toluene, 70 wt%
Fine particles: antimony pentoxide, 30 wt% - (c) Results
- * B-H characteristics are shown in Fig. 4.
- * Frequency characteristics of core loss are shown in Fig. 5.
The number of turns of the primary winding around the core was 5, while the number of turns of the secondary winding was 10. - * Frequency characteristics of permeability are shown in Fig. 6.
Measured magnetic field: 50/4π A/m (5 mOe)
Measured current: 2.65173 mA
- (a) Magnetic core: a toroidal core with the aforementioned ribbon wound therearound Inside diameter: 23.00 mm
- From the foregoing results, it can be appreciated that the magnetic cores of the Examples display a hysteresis which is closer to a linear configuration, and that the core loss is low as a whole, and a rise in the high-frequency component can be reduced to a low level. A substantially fixed permeability was obtained up to 200 kHz.
- As described above, in accordance with the present invention, since the above-described arrangement is adopted, it is possible to improve the magnetic characteristics at a frequency higher than 10 kHz, and the space factor can be made as large as possible, thereby making contributions to making the magnetic core compact.
Claims (6)
- A magnetic ribbon (1b) for winding or lamination into a magnetic core (6), the magnetic ribbon (1b) being formed of an amorphous metal and having fine particles coated on at least one surface thereof said fine particles having electrically-insulating properties;
characterised in that said fine particles are antimony pentoxide particles having a size in the range of from 10 nm to 2 »m, and in that the fine particles are coated on said at least one surface in an amount in the range of from 10⁻⁷ cm³ to 2 x 10⁻⁴ cm³ per cm² of surface area. - A magnetic core (6) formed by winding or laminating a magnetic ribbon (1b) according to claim 1, wherein a layer of the fine particles is positioned between the adjacent magnetic ribbon layers and air is present between said adjacent magnetic ribbon layers together with said fine particle layer.
- A process for manufacturing a metal core (6) comprising the steps of:a) winding or laminating the magnetic ribbon (1b) of claim 1; andb) annealing the wound or laminated magnetic ribbon for from 0.5 to 5 hours at a temperature in the range of from 300 to 500°C in an inert gas atmosphere.
- A process for manufacturing a magnetic ribbon (1b) comprising the steps of:a) coating a dispersion (2) containing fine particles having electrically insulating properties on at least one surface of an amorphous metal ribbon (1a); andb) drying the coated ribbon (1a); characterised by:
the further step of c) annealing the dried coated ribbon for from 0.5 to 5 hours at a temperature in the range of from 300 to 500°C in an inert gas atmosphere; and
said fine particles being antimony pentoxide particles with a size in the range of from 10 nm to 2 »m and being attached to the surface in an amount in the range of from 10⁻⁷ cm³ to 2 x 10⁻⁴ cm³ per cm² of surface area. - A process for manufacturing a magnetic core, comprising the steps of:a) manufacturing a magnetic ribbon (1b) according to the process of claim 4; andb) winding or laminating the magnetic ribbon (1b) prior to said annealing step.
- An electrical or electronic device comprising a magnetic core (6) according to claim 2.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP63088694A JP2716064B2 (en) | 1988-04-11 | 1988-04-11 | Magnetic ribbon and magnetic core |
JP88694/88 | 1988-04-11 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0337716A2 EP0337716A2 (en) | 1989-10-18 |
EP0337716A3 EP0337716A3 (en) | 1990-09-19 |
EP0337716B1 true EP0337716B1 (en) | 1995-03-01 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89303542A Expired - Lifetime EP0337716B1 (en) | 1988-04-11 | 1989-04-11 | Magnetic ribbon and magnetic core |
Country Status (6)
Country | Link |
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EP (1) | EP0337716B1 (en) |
JP (1) | JP2716064B2 (en) |
KR (1) | KR920005490B1 (en) |
AT (1) | ATE119309T1 (en) |
CA (1) | CA1340795C (en) |
DE (1) | DE68921363T2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11955261B2 (en) | 2021-08-25 | 2024-04-09 | Tdk Corporation | Magnetic alloy ribbon, laminate, and magnetic core |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5091253A (en) * | 1990-05-18 | 1992-02-25 | Allied-Signal Inc. | Magnetic cores utilizing metallic glass ribbons and mica paper interlaminar insulation |
EP0480265B1 (en) * | 1990-10-03 | 1995-05-17 | Nippon Steel Corporation | Method of producing permalloy cores |
JP2909349B2 (en) * | 1993-05-21 | 1999-06-23 | 日立金属株式会社 | Nanocrystalline soft magnetic alloy ribbon and magnetic core with insulating film formed thereon, pulse generator, laser device, accelerator |
US20060017010A1 (en) * | 2004-07-22 | 2006-01-26 | Axcelis Technologies, Inc. | Magnet for scanning ion beams |
JP5555725B2 (en) | 2012-01-13 | 2014-07-23 | 本田技研工業株式会社 | Electric load control device |
US11715591B2 (en) | 2020-03-27 | 2023-08-01 | Proterial, Ltd. | Method for manufacturing a wound magnetic core |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0214305A1 (en) * | 1985-02-27 | 1987-03-18 | Kawasaki Steel Corporation | Process for the production of a laminate of thinamorphous alloy strip and a core made of thin amorphous alloy strip |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS618903A (en) * | 1984-06-25 | 1986-01-16 | Kawasaki Steel Corp | Characteristics of amorphous alloy thin belt and improvement of dieing workability thereof |
JPS61181114A (en) * | 1985-02-07 | 1986-08-13 | Toshiba Corp | Manufacture of rolled iron core |
JPS61198611A (en) * | 1985-02-27 | 1986-09-03 | Kawasaki Steel Corp | Manufacture of transformer with amorphous alloy thin band core |
JPS6210278A (en) * | 1985-07-09 | 1987-01-19 | Kawasaki Steel Corp | Thin amorphous alloy strip having excellent paramagnetic permeability |
JPS6261308A (en) * | 1985-09-11 | 1987-03-18 | Toshiba Corp | Heat treatment of amorphous wound core |
JPS6265403A (en) * | 1985-09-18 | 1987-03-24 | Kawasaki Steel Corp | Improving magnetic characteristics of amorphous alloy thin band |
JPS62188209A (en) * | 1986-02-13 | 1987-08-17 | Tdk Corp | Manufacture of wound core |
-
1988
- 1988-04-11 JP JP63088694A patent/JP2716064B2/en not_active Expired - Fee Related
-
1989
- 1989-04-10 CA CA000596211A patent/CA1340795C/en not_active Expired - Lifetime
- 1989-04-11 KR KR1019890004745A patent/KR920005490B1/en not_active IP Right Cessation
- 1989-04-11 AT AT89303542T patent/ATE119309T1/en not_active IP Right Cessation
- 1989-04-11 DE DE68921363T patent/DE68921363T2/en not_active Expired - Fee Related
- 1989-04-11 EP EP89303542A patent/EP0337716B1/en not_active Expired - Lifetime
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0214305A1 (en) * | 1985-02-27 | 1987-03-18 | Kawasaki Steel Corporation | Process for the production of a laminate of thinamorphous alloy strip and a core made of thin amorphous alloy strip |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11955261B2 (en) | 2021-08-25 | 2024-04-09 | Tdk Corporation | Magnetic alloy ribbon, laminate, and magnetic core |
Also Published As
Publication number | Publication date |
---|---|
JPH01259510A (en) | 1989-10-17 |
DE68921363D1 (en) | 1995-04-06 |
EP0337716A3 (en) | 1990-09-19 |
ATE119309T1 (en) | 1995-03-15 |
EP0337716A2 (en) | 1989-10-18 |
CA1340795C (en) | 1999-10-19 |
DE68921363T2 (en) | 1995-07-13 |
KR920005490B1 (en) | 1992-07-06 |
KR890016591A (en) | 1989-11-29 |
JP2716064B2 (en) | 1998-02-18 |
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