EP0335815B1 - Vermeidung von Gelbildung in Polymeren - Google Patents

Vermeidung von Gelbildung in Polymeren Download PDF

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Publication number
EP0335815B1
EP0335815B1 EP89630059A EP89630059A EP0335815B1 EP 0335815 B1 EP0335815 B1 EP 0335815B1 EP 89630059 A EP89630059 A EP 89630059A EP 89630059 A EP89630059 A EP 89630059A EP 0335815 B1 EP0335815 B1 EP 0335815B1
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Prior art keywords
tert
butyl
carbon atoms
weight
group
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French (fr)
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EP0335815A2 (de
EP0335815A3 (en
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Joel Muse, Jr.
Donald Charles Grimm
Jerry John Dillon
Kirkwood Storer Cottman
Calvin Anderson Bennett, Jr.
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Goodyear Tire and Rubber Co
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Goodyear Tire and Rubber Co
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C08K5/134—Phenols containing ester groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G16/00—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00
    • C08G16/02—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes
    • C08G16/0212—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with acyclic or carbocyclic organic compounds
    • C08G16/0218—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with acyclic or carbocyclic organic compounds containing atoms other than carbon and hydrogen
    • C08G16/0237—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with acyclic or carbocyclic organic compounds containing atoms other than carbon and hydrogen containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/37—Thiols
    • C08K5/375—Thiols containing six-membered aromatic rings

Definitions

  • This invention relates to discovery that the combination of a polyhydroxyacrylate or polyhydroxy-methacrylate, such as 2-(2-hydroxy-3-tert.butyl-5-methylbenzene)-4-methyl-6-tert.butyl phenyl methacrylate, and the reaction product derived from the acid catalyzed reaction of an alkylated phenol, formaldehyde and a mercaptan, will provide elastomers with enhanced protection from the formation of hard gel, soft gel and micro-gel during the processing and storage of said elastomers.
  • a polyhydroxyacrylate or polyhydroxy-methacrylate such as 2-(2-hydroxy-3-tert.butyl-5-methylbenzene)-4-methyl-6-tert.butyl phenyl methacrylate
  • reaction product derived from the acid catalyzed reaction of an alkylated phenol, formaldehyde and a mercaptan will provide elastomers with enhanced protection from the formation of hard gel, soft gel and micro
  • Gel formation in polymers can be caused during the isolation and drying of the polymers from either an aqueous system or a solvent or cement system wherein localized polymer hot-spots can result in the undesirable gelling or cross-linking phenomenon. Care must be taken to assure that during the processing of elastomers that the polymer's structure is not altered which will result in degradation of the polymer's physical properties.
  • the process for solution polymerization of synthetic elastomers such as polybutadiene is well known in the art.
  • Monomer and solvent are purified and dried.
  • the catalyst is prepared separately and then added to the reaction vessel containing the monomer or monomers, for example, butadiene and styrene.
  • the catalyst is deactivated, the unreacted monomer or monomers and solvent are removed, and the polymer is recovered, washed, dried and baled. It is usually during the recovery process, where the elastomer is dewatered and dried that the formation of gel occurs.
  • Japanese Patent No. 49,066,725 discloses gelation inhibitors that are obtained by mixing solid phenylenediamine derivatives with liquid reaction products derived from aromatic amines and acetone.
  • This patent discloses a stable suspension consisting of 100 parts of a 1:3 mixture of 4-(isopropyl-amino) diphenylamine and a toluidine-acetone condensate, 293 parts water, 2.5 parts of a 50% aqueous solution of KOH, and 4.5 parts of oleic acid.
  • This suspension was then combined with an SBR latex at ratios of the suspension to the SBR of about 0.6:100.
  • the rubber mixture was then flocculated to give rubber with 20% gel after 130 hours at 120°C compared to 80% gel for rubber containing dodecylphenylamine in place of the subject suspension.
  • Patents are reaction products of a polyphenolic compound such as 2,6-bis-(2-hydroxy-3-tert.butyl-5-methylbenzyl)-4-methylphenol; and 2,2′-methylene-bis-(4-methyl-6-tert.butylphenol) with an ester forming compound of the general formula: wherein R3 is selected from the group consisting of hydrogen and alkyl radicals having from 1 to 4 carbon atoms, R4 is selected from the group consisting of hydrogen and alkyl radicals having from 1 to 4 carbon atoms, and wherein A is selected from the group consisting of chlorine, iodine and bromine.
  • a polyphenolic compound such as 2,6-bis-(2-hydroxy-3-tert.butyl-5-methylbenzyl)-4-methylphenol
  • 2,2′-methylene-bis-(4-methyl-6-tert.butylphenol) with an ester forming compound of the general formula: wherein R3 is selected from the group consisting of hydrogen and alkyl radicals having from 1 to
  • US-A-4,707,300 relates to the reaction products of an acid catalyzed simultaneous reaction between a phenol, formaldehyde and a mercaptan in specific molar ratios under specific reaction conditions.
  • the reaction product is normally a liquid at room temperature and exhibits excellent antidegradative properties in oxidizable materials.
  • this U.S. patent is concerned with the autosynergistic phenolic reaction product itself and its incorporation into oxidizable organic materials.
  • the invention of this disclosure is directed to the discovery that the combination of materials disclosed in US-A-3,984,372 and 4,168,387 with those of US-A-4,707,300 lessen or prevents the formation of gel in elastomers.
  • esters of polyphenolics means the esters disclosed in US-A-3,984,372 and 4,168,387.
  • the esters of polyphenolics are prepared by reacting a polyphenolic compound of the structural formula: wherein R1 and R2 are the same or different radicals selected from the group consisting of hydrogen, alkyl radicals of 1 to 16 carbon atoms, cycloalkyl radicals of from 5 to 9 carbon atoms, aralkyl radicals of 7 to 12 carbon atoms, and substituted and unsubstituted aryl radicals of 6 to 12 carbon atoms and R1 preferably contains from 1 to 2 carbon atoms when para to the hydroxyl group;
  • X is the same or different radical selected from the group consisting of (1) cyclic dienes with non-adjacent carbon to carbon double bonds within the ring structure containing from 5 to 20 carbon atoms from which the divalent radicals are prepared and (2) a bivalent radical selected from the group consisting of -S-, -O
  • the amount of esterification depends on the molar ratios and steric hindrance of the materials used.
  • the polyphenolic material is treated with from 0.1 mole to 1.0 mole of ester forming compound for each functional hydroxyl group. More preferably, at least one functional hydroxyl group per polyphenolic molecule is esterified.
  • the esterification reaction may easily take place at elevated pressure and temperatures or from 0°C to the boiling point of the reactants. Preferably temperatures from 0°C to 60°C are preferred.
  • esters of polyphenolics that are useful in this invention are listed below: 2-(2-hydroxy-3-tert.butyl-5-methylbenzyl)-4-methyl-6-tert.butylphenyl acrylate 2-(2-hydroxy-3-tert.butyl-5-methylbenzyl)-4-methyl-6-tert.butyl phenylmethacrylate 2-(3,5-ditert.butyl-4-hydroxybenzyl)-4-methyl-phenyl methacrylate 2-(3,5-ditert.butyl-4-hydroxybenzyl)-4-methyl-phenyl acrylate 4-(3,5-ditert.butyl-4-hydroxybenzyl) phenyl acrylate 2-(2-hydroxy-3-tert.butyl-5-methylphenylthio)-4-methyl-6-tert.butyl phenyl methacrylate 2-(3,5-ditert.butyl-4-hydroxybenzyl) phenyl methacrylate 2,6-bis(2-hydroxy-3-tert
  • the autosynergistic phenolic reaction product can be derived from the process comprising:
  • Elastomers to be used in the instant invention are: natural rubber, and synthetic polymers containing carbon to carbon double bonds such as rubbery diene polymers both conjugated and non-conjugated.
  • Representative examples of the synthetic polymers that will benefit through the use of this invention are polychloroprene and homopolymers of conjugated 1,3-dienes such as isoprene and butadiene.
  • Copolymers of conjugated 1,3-dienes such as isoprene and butadiene with up to 50 percent by weight of at least one copolymerizable monomer including ethylenically unsaturated monomers such as styrene and acrylonitrile are included.
  • Butyl rubbers and polyurethanes which contain carbon to carbon double bonds can also benefit from the instant invention. In general, any organic material that is subject to gel formation or undesired crosslinking during preparation and/or processing will benefit from this invention.
  • the gel inhibiting mixture of this invention may be used with or without antioxidants, antiozonants, vulcanizing agents, synergists, accelerators or other compounding ingredients known in the art.
  • the amount of the gel inhibiting mixture may vary somewhat depending on the type and requirement of the elastomer to be protected.
  • the method of addition of the gel inhibiting composition to the material to be protected is not critical. It may be added by any of the conventional means such as by adding to a polymer latex, milling on an open mill or by internal mixing.
  • a convenient method of incorporation consists of adding the stabilizer to the polymer while it is in latex or cement forms. This is preferably done after the polymerization of the monomers is essentially complete.
  • the gel inhibiting composition Normally from about 0.01 part to about 5.0 parts of the gel inhibiting composition by weight based on the weight of the polymer can be used; however, the precise amount to be employed will depend on the nature of the polymer and the processing conditions to which the elastomer will be exposed. It has been found that an effective amount of the composition will generally range from about 0.01 to about 3.0 parts by weight although it is commonly preferred to use from about 0.25 to about 2.0 parts by weight based on 100 parts by weight of the elastomer. The above limits are merely guidelines and those skilled in this art will readily appreciate the proper amount of the composition that will be required to lessen or eliminate the formation of gel.
  • Example 2 This example was carried out in the same manner as Example 1 except that equal molar amounts of acryloyl chloride was used in place of methacryloyl chloride.
  • the autosynergistic phenolic antioxidant reaction product used herein was prepared in a production scale reaction vessel equipped with the appropriate controls.
  • the water of solution and production and the toluene were then distilled off at a final pot temperature of 140°C.
  • the mixture was then cooled to less than 98°C and the toluene sulfonic acid was then neutralized with an appropriate amount of sodium carbonate.
  • the water layer was removed and the product was again washed with water.
  • the mixture was then vacuum distilled to remove the remaining toluene at 160°C and 25 mm of Hg.
  • the product was filtered to remove traces of residual salts.
  • the antigelling composition of this invention which consists of the ester of a polyphenolic and the autosynergistic phenolic reaction product can easily be added to the polymer in the form of a solution.
  • Useful solvents for the antigelling composition include hexane and the like.
  • the solution of the antigelling agents is added to the polymeric cement or latex prior to the quenching system which utilizes the addition of water to form a crumb. The crumb is then dewatered and dried through mechanical means such as screws.
  • the mastication test has been found to correlate well with the gel formation experienced in the commercial processing of polybutadiene.
  • the lab test used to evaluate the instant invention uses a Haake mastication apparatus at temperatures and times near the commercially encountered conditions of 100-250°C and a few seconds of residence time to about 15 minutes. It was determined through experimentation that the developed test correlates far better than a 70°C oven agings with the conditions encountered in the commercial production of polybutadiene.
  • the mastication test uses a Haake Brabender with a #750 mixing head and banbury rotors. A computer is used to control temperature, rotor speed and run times. The mixing head temperature was 200°C and the banbury rotor speed was 70 rpm. The test times were varied from 4 to 20 minutes.
  • test samples were prepared by adding the appropriate amount of the antigelling solution to a sufficient amount of polymer cement containing 100 grams of dry rubber.
  • the stabilized polymer is then placed in a laboratory hood and dried for about 24 hours. After drying the stabilized polymer is ready for testing.
  • the mastication test device after reaching temperature equilibrium was started and 50 grams of stabilized polymer was loaded into the mixing chamber and the ram with 5 kgs of weight was lowered into position. After the specified time, the ram was raised and a 2-4 gram sample was removed from the mixing chamber. The ram was then again lowered into position and the test continued. In similar fashion, a number of samples are removed from the device at specified intervals of time.
  • the gel test consists of treating the sample with a solvent such as MEK or toluene.
  • the amount of gel is determined from the weight of the polymer not dissolved in the solvent as a percentage of the total polymer weight. Percent gel values are related to the amount of crosslinking present in a polymer.
  • the percent is determined by weighing out approximately 0.2 grams of the sample (cut into small pieces) to the nearest 0.0001 grams into a sealable bottle. It is very important that all measurements be made at constant temperature. Thus, the solvent and samples should be at a constant temperature before gel measurement is initiated.
  • One hundred ml of the solvent is then added to the bottle containing the polymer sample.
  • the bottle is then sealed and placed on a wrist shaker for 16 hours followed by centrifugation at 2000-2500 rpm for at least one hour or until turbidity is no longer observable.
  • the bottle is removed from the centrifuge and a 20 ml aliquot from the upper half of the solution is transferred to a clean tared aluminum pan.
  • a designed experiment was conducted to determine the optimum levels of the phenolic reaction product and the ester of a polyphenolic.
  • the levels of antigelling composition were varied from 0.05 to 0.20 phr of the ester and from 0.2 to 1.0 phr of the phenolic reaction product.
  • the gel results at 8 minutes mastication for the designed experiment are shown in Table II together with controls.
  • the ester of a polyphenolic [also known as 2,2′-methylenebis(6-t- butyl-p-phenyl)methacrylate] prepared in Example 1 was evaluated with the autosynergistic phenolic reaction product from Example 3. Samples with various levels of the ester and the reaction product were analyzed for percent gel after 6, 8, and 10 minutes on the Haake tester at 200°C. Table III sets forth the data.
  • the results from the tests conducted herein amply demonstrate that the combination of a ester of a polyphenolic with the autosynergistic phenolic reaction product is very useful in the prevention of gel formation in synthetic elastomers.
  • the instant invention provides a system that is low in cost, easy to manufacture without attendant pollution problems and provides unexpectedly superior antigelling protection.
  • the antigelling composition of this invention will have utility in the industry since it alleviates problems that have heretofore been tolerated in the manufacture and storage of elastomers.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Claims (12)

  1. Verfahren zur Verhinderung oder Reduktion von Gelbildung in Elastomeren, wobei das Verfahren gekennzeichnet ist durch Zugabe von 0,01 bis 5,0 Gewichtsteilen pro Hundert eines festen Elastomers einer Gel-inhibierenden Zusammensetzung zu einem Elastomer in fester, Latex- oder Lösungsform, worin das Elastomer ausgewählt ist aus der Gruppe, die aus Naturkautschuk und synthetischen Polymeren, die Kohlenstoff-Kohlenstoff-Doppelbindungen enthalten, besteht, wobei die Gel-inhibierende Zusammensetzung eine 1:15 bis 15:1-Gewichtsmischung umfaßt von
    (A) einem Ester einer polyphenolischen Verbindung, der erhältlich ist durch Umsetzen einer polyphenolischen Verbindung der Strukturformel:
    Figure imgb0014
     worin R¹ und R² gleiche oder verschiedene Reste sind, die aus der Gruppe, die aus Wasserstoff, Alkylresten mit 1 bis 16 Kohlenstoffatomen, Cycloalkylresten mit 5 bis 9 Kohlenstoffatomen, Aralkylresten mit 7 bis 12 Kohlenstoffatomen und substituierten und unsubstituierten Arylresten mit 6 bis 12 Kohlenstoffatomen besteht, ausgewählt sind; X ein gleicher oder verschiedener Rest ist, der ausgewählt ist aus der Gruppe, die aus (1) cyclischen Dienen mit nicht-benachbarten Kohlenstoff-Kohlenstoff-Doppelbindungen innerhalb der Ringstruktur, die 5 bis 20 Kohlenstoffatome enthalten, aus denen die zweiwertigen Reste hergestellt werden, und (2) einem zweiwertigen Rest, der aus der Gruppe, die aus -S-, -O-, 〉C(=O), -CH₂- und -S-S- besteht, ausgewählt ist, besteht; und worin das n aus der Gruppe, die aus 0 und reellen Zahlen von 1 bis 5 besteht, ausgewählt ist; mit einer Verbindung mit der allgemeinen Formel:
    Figure imgb0015
     worin R³ aus der Gruppe, die aus Wasserstoff und Alkylresten mit 1 bis 4 Kohlenstoffatomen besteht, ausgewählt ist, R⁴ aus der Gruppe, die aus Wasserstoff, Alkylresten mit 1 bis 4 Kohlenstoffatomen, Aralkylresten mit 7 bis 12 Kohlenstoffatomen, Cycloalkylresten mit 5 bis 8 Kohlenstoffatomen und substituierten oder unsubstituierten Arylresten mit 6 bis 12 Kohlenstoffatomen besteht, ausgewählt ist, und worin A aus der Gruppe, die aus Chlor, Brom und Iod besteht, ausgewählt ist; und
    (B) einem autosynergistischen phenolischen Reaktionsprodukt, wobei das autosynergistische phenolische Antioxidans-Reaktionsprodukt erhältlich ist durch ein Verfahren, das umfaßt:
    (1) Mischen von 1 Mol eines mono-alkylierten Phenols oder eines 2,4-dialkylierten Phenols oder einer Mischung davon, worin der Alkylrest gerade oder verzweigt sein kann und 1 bis 20 Kohlenstoffatome enthalten kann, mit
    (a) 0,5 bis 1,5 Mol eines primären Mercaptans mit 3 bis 20 Kohlenstoffatomen; und
    (b) 0 bis 50% molarem Überschuß von wäßrigem Formaldehyd, bezogen auf die Mol des primären Mercaptans, wenn das Molverhältnis von Mercaptan zu Phenol 1,0 oder größer ist, oder 0 bis 100% Überschuß wäßrigen Formaldehyds, wenn das Verhältnis von Mercaptan zu Phenol weniger als 1,0 ist; und
    (c) 0,04 bis 20 Gewichtsprozent, bezogen auf das Gewicht von alkyliertem Phenol, eines Säurekatalysators; und
    (d) einer adäquaten Menge eines azeotropierenden Lösungsmittels;
    (2) Erwärmen der Mischung von Umgebungstemperatur auf bis hinauf zu 180°C, während Wasser azeotrop entfernt wird, bis die Erzeugung der Reaktionswasser aufhört; und
    (3) Neutralisieren des Katalysators und Isolieren des Produkts.
  2. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß die Konzentration der Gel-inhibierende Zusammensetzung 0,01 bis 3,0 Gewichtsteile pro Hundert des festen Elastomers ist.
  3. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß die Zusammensetzung eine 1:10 bis 10:1 Gewichtsmischung von (A) einem Ester eines Polyphenols und (B) einem autosynergistischen phenolischen Reaktionsprodukt umfaßt.
  4. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß die Zusammensetzung eine 1:5 bis 5:1 Gewichtsmischung von (A) einem Ester eines Polyphenols und (B) einen autosynergistischen phenolischen Reaktionsprodukt umfaßt.
  5. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß (A) der Ester eines Polyphenols aus 2-(2-Hydroxy-3-tert-butyl-5-methylbenzyl)-4-methyl-6-tert-butyl-phenylmethacrylat und 2-(2-Hydroxy-3-tert-butyl-5-methylbenzyl)-4-methyl-6-tert-butylphenylacrylat ausgewählt ist.
  6. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß das Elastomer aus Naturkautschuk, Polybutadien und SBR ausgewählt ist.
  7. Verfahren zur Verhinderung oder Verminderung von Gelbildung in polymeren Elastomeren, wobei das Verfahren gekennzeichnet ist durch Zugabe zu dem Elastomer von 0,01 bis 5,0 Gewichtsteilen pro Hundert eines festen Elastomers einer Gel-inhibierenden Zusammensetzung, worin das Elastomer ausgewählt ist aus der Gruppe, die aus Naturkautschuk und synthetischen Polymeren, die Kohlenstoff-Kohlenstoff-Doppelbindungen enthalten, besteht, wobei die Gel-inhibierende Zusammensetzung eine 1:15 bis 15:1-Gewichtsmischung umfaßt von (1) einer Verbindung, die aus der Gruppe, die aus 2-(2-Hydroxy-3-tert-butyl-5-ethylbenzyl)-4-ethyl-6-tert-butylphenylmethacrylat, 2-(2-Hydroxy-3-tert-butyl-5-methylbenzyl)-4-methyl-6-tert-butylphenylmethacrylat, 2,6-Bis(2-hydroxy-3-tert-butyl-5-methylbenzyl)-4-methylphenylmethacrylat und 2-(2-Hydroxy-3-tert-butyl-5-methylbenzyl)-4-methyl-6-tert-butylphenylacrylat besteht, ausgewählt ist; und (2) einem autosynergistischen phenolischen Antioxidans-Reaktionsprodukt, wobei das autosynergistische phenolische Antioxidans-Reaktionsprodukt erhältlich ist durch ein Verfahren, das umfaßt:
    (1) Mischen von 1 Mol eines mono-alkylierten Phenols oder eines 2,4-dialkylierten Phenols oder einer Mischung davon, worin der Alkylrest gerade oder verzweigt sein kann und 1 bis 20 Kohlenstoffatome enthalten kann, mit
    (a) 0,5 bis 1,5 Mol eines primären Mercaptans mit 3 bis 20 Kohlenstoffatomen; und
    (b) 1 bis 50% molarem Überschuß von wäßrigen Formaldehyd, bezogen auf die Mol des primären Mercaptans, wenn das Molverhältnis von Mercaptan zu Phenol 1,0 oder größer ist, oder 0 bis 100% Überschuß wäßrigen Formaldehyds, wenn das Verhältnis von Mercaptan zu Phenol weniger als 1,0 ist; und
    (c) 0,04 bis 20 Gewichtsprozent, bezogen auf das Gewicht des alkylierten Phenols, eines Säurekatalysators; und
    (d) einer adäquaten Menge eines azeotropierenden Lösungsmittels;
    (2) Erwärmen der Mischung von Umgebungstemperatur auf bis hinauf zu 180°C, während Wasser azeotrop entfernt wird, bis die Erzeugung der Reaktionswasser aufhört, und
    (3) Neutralisieren des Katalysators und Isolieren des Produkts.
  8. Verfahren nach Anspruch 6, dadurch gekennzeichnet, daß die Gel-inhibierende Zusammensetzung zu 0,01 bis 3,0 Gewichtsteilen pro Hundert des festen Elastomers anwesend ist.
  9. Verfahren nach Anspruch 7, dadurch gekennzeichnet, daß das Verhältnis von Verbindung (1) zu Verbindung (2) 1:10 bis 10:1 beträgt.
  10. Verfahren nach Anspruch 7, dadurch gekennzeichnet, daß das Verhältnis von Verbindung (1) zu Verbindung (2) 1:5 bis 5:1 beträgt.
  11. Verfahren nach Anspruch 7, dadurch gekennzeichnet, daß das Elastomer aus Naturkautschuk, Polybutadien und SBR ausgewählt ist.
  12. Verfahren nach Anspruch 7, dadurch gekennzeichnet, daß (A) der Ester eines Polyphenols aus 2-(2-Hydroxy-3-tert-butyl-5-methylbenzyl)-4-methyl-6-tert-butylphenylmethacrylatund 2-(2-Hydroxy-3-tert-butyl-5-methylbenzyl)-4-methyl-6-tert-butylphenylacrylat ausgewählt ist.
EP89630059A 1988-03-28 1989-03-24 Vermeidung von Gelbildung in Polymeren Expired - Lifetime EP0335815B1 (de)

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Application Number Priority Date Filing Date Title
US07/172,749 US4847313A (en) 1988-03-28 1988-03-28 Gel prevention in polymers
US172749 1998-10-14

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EP0335815A2 EP0335815A2 (de) 1989-10-04
EP0335815A3 EP0335815A3 (en) 1990-02-07
EP0335815B1 true EP0335815B1 (de) 1994-03-09

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JP (1) JP2701929B2 (de)
BR (1) BR8901386A (de)
CA (1) CA1338227C (de)
DE (1) DE68913572T2 (de)
ES (1) ES2063159T3 (de)
TR (1) TR23604A (de)

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JP5166137B2 (ja) * 2008-06-30 2013-03-21 住友化学株式会社 梱包体及び熱可塑性樹脂フィルムの製造方法

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US3984372A (en) * 1974-05-06 1976-10-05 The Goodyear Tire & Rubber Company Polymer compositions containing esters of polyphenolic compounds as built-in antioxidants
US4168387A (en) * 1974-05-06 1979-09-18 The Goodyear Tire & Rubber Company Esters of polyphenolic compounds as built-in antioxidants
JPH0653828B2 (ja) * 1985-07-16 1994-07-20 住友化学工業株式会社 ブタジエン系ポリマ−組成物
US4707300A (en) * 1987-03-09 1987-11-17 The Goodyear Tire & Rubber Company Autosynergistic phenolic antioxidant reaction product

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JP2701929B2 (ja) 1998-01-21
BR8901386A (pt) 1989-11-07
EP0335815A2 (de) 1989-10-04
JPH01284539A (ja) 1989-11-15
CA1338227C (en) 1996-04-02
EP0335815A3 (en) 1990-02-07
DE68913572D1 (de) 1994-04-14
TR23604A (tr) 1990-04-30
DE68913572T2 (de) 1994-08-18
US4847313A (en) 1989-07-11

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