EP0308314B1 - Procédé de traitement par l'ozone de matériaux ligno-cellulosiques, notamment de pâtes à papier et réacteur pour la mise en oeuvre de ce procédé - Google Patents
Procédé de traitement par l'ozone de matériaux ligno-cellulosiques, notamment de pâtes à papier et réacteur pour la mise en oeuvre de ce procédé Download PDFInfo
- Publication number
- EP0308314B1 EP0308314B1 EP88402296A EP88402296A EP0308314B1 EP 0308314 B1 EP0308314 B1 EP 0308314B1 EP 88402296 A EP88402296 A EP 88402296A EP 88402296 A EP88402296 A EP 88402296A EP 0308314 B1 EP0308314 B1 EP 0308314B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- ozone
- enclosure
- mechanical
- reactor
- carrier gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/147—Bleaching ; Apparatus therefor with oxygen or its allotropic modifications
- D21C9/153—Bleaching ; Apparatus therefor with oxygen or its allotropic modifications with ozone
Definitions
- the present invention relates to the treatment with ozone of lignocellulosic material and in particular of paper pulps of the chemico-thermo-mechanical, mechanical, thermo-mechanical type.
- ozone has an action on lignocellulosic materials in general and in particular on lignin. This action, which leads to chemical degradation resulting in elimination of the wood structure, has been used for bleaching, in particular pulp.
- ozonization has not made evident the favorable influence of ozone on the improvement of the paper qualities, in particular of the mechanical qualities of certain pulps, like that of so-called “thermo-mechanical”, “mechanical”, “chemico-thermo-mechanical” dough, that is to say dough obtained by grating logs in a humid environment on grinding stones, or by shredding chips previously softened with water or steam, with a slight chemical and / or heat treatment.
- a process for bleaching chemical pulp with ozone of paper which consists in treating a pulp previously brought to a desired hygrometric state and to a surface state which is suitable for ensuring good contact between ozone and pulp.
- Such a process is not entirely satisfactory, in particular as regards the mechanical properties of the material obtained when it is a question of pasta of the mechanical, thermo-mechanical or chemico-thermo-mechanical type.
- the present invention proposes to provide a method of treatment with ozone, improved compared to the prior art and providing unexpected results which will be reported below.
- an interface of maximum value is characterized in that the ozone concentration of the carrier gas is between 4 and 10% by mass relative to said carrier gas, and in that the amount of ozone introduced is between 2 and 8% by mass relative to the dry matter .
- the material is treated before ozonation by any means whatsoever, so that its dryness is in a range between 20 and 50%.
- the improvement of the paper qualities of the finished products obtained after treatment with ozone according to the process according to the invention also makes it possible to increase the productivity by a significant gain on the speed of manufacture of paper or cardboard, as well as by an increase. speeds of machines ensuring processing or final use, printing, for example.
- the Applicant has also been able to demonstrate that, when the treatment with ozone is carried out in accordance with the process according to the invention, the compounds with aromatic structure which constitute the lignin framework are transformed into by-products no longer having the benzene function.
- This transformation has the advantage of limiting the weight loss due to the disappearance of the lignin to a minimal value and of retaining an excellent yield by weight of the lignocellulosic materials thus treated.
- a manufacture of paper pulp according to a conventional chemical process makes it possible to obtain an overall yield of the order of 45 to 60% while a manufacture of pulp according to a process according to the invention makes it possible to obtain a yield by weight of the order of 90% with an ozone level equal to 5% by mass relative to the material considered dry.
- Ozone is produced from oxygen carried by a pipe (1) and introduced into a generator (2) electrically supplied at medium frequency and cooled with chilled water brought by a pipe (3) and evacuated by a pipe ( 4).
- the characteristics of this generator are chosen so as to obtain high ozone concentrations of between 70 and 140 g / Nm3.
- the highly concentrated ozone gas thus produced is sent via a pipe (5) to a reactor (6) constituted by an elongated enclosure slightly inclined to the horizontal in which the flow and mixing of the cellulosic material to be ozonated is ensured by a simple screw system (7) like Archimedes screw provided with a cleaning device (not shown) and ensuring a propulsion and a flow of the lignocellulosic material to be treated and favoring a continuous renewal of the material interface -gas.
- the reactions of ozone on the lignocellulosic structures passing through a maximum depending on the height of the layer of material to be treated, the assembly is designed and adjusted so that the height of the layer of material being in the reactor remains weak and is advantageously around ten cm.
- the ozonated gas is injected at several points (8) distributed over the length of the reactor by means of orifices provided in the part of the pipeline (5) located inside the reactor so as to ensure a radial flow of interest over the entire volume. reactive.
- a conventional flow control device (not shown) allows this flow to be adjusted in each of the reaction zones defined by the injection points.
- the introduction of lignocellulosic material into the reactor (6) takes place using a hopper (9) supplying a screw (10) of the plug type ensuring both the regulation of the rate of introduction of the material in the reaction vessel and the seal necessary to prevent leakage of ozonated gas to the atmosphere.
- the extraction of the lignocellulosic material treated at the outlet of the reactor is carried out by means of a screw (11) also of the plug type ensuring both the regulation of the flow rate of the extracted product and the tightness necessary to prevent leakage of ozonated gas to the atmosphere.
- the lignocellulosic material is brought, before its introduction into the ozonization reactor, by any means or any device suitable for a state of controlled dryness between 30 and 45% humidity.
- the residence time of the lignocellulosic material necessary to obtain the desired paper qualities is adjusted by adjusting the speed of rotation of the screw (7) ensuring the progression of the material in the treatment enclosure.
- the small quantity of ozone which has not reacted with the lignocellulosic material is extracted from the reactor by suction and directed by a pipe (12) to a unit (14) for ozone destruction by thermal means.
- the breaking length represents the length in meters of a strip of uniform width thickness supposed to be suspended by one of its ends and breaking under the effect of its own weight.
- the burst index is an index reflecting the force to be applied, by means of a device capable of exerting hydrostatic pressure on a paper sample to cause it to burst.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Paper (AREA)
- Fertilizers (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT88402296T ATE82340T1 (de) | 1987-09-17 | 1988-09-12 | Verfahren zur ozonbehandlung von lignocellulosematerialien, insbesondere papiermassen, und reaktor zum ausfuehren des verfahrens. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8712890A FR2620744A1 (fr) | 1987-09-17 | 1987-09-17 | Procede de traitement par l'ozone de materiaux ligno-cellulosiques, notamment de pates a papier et reacteur pour la mise en oeuvre de ce procede |
FR8712890 | 1987-09-17 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0308314A1 EP0308314A1 (fr) | 1989-03-22 |
EP0308314B1 true EP0308314B1 (fr) | 1992-11-11 |
Family
ID=9354988
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP88402296A Expired - Lifetime EP0308314B1 (fr) | 1987-09-17 | 1988-09-12 | Procédé de traitement par l'ozone de matériaux ligno-cellulosiques, notamment de pâtes à papier et réacteur pour la mise en oeuvre de ce procédé |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP0308314B1 (sv) |
JP (1) | JP2731822B2 (sv) |
AT (1) | ATE82340T1 (sv) |
BR (1) | BR8804806A (sv) |
CA (1) | CA1314664C (sv) |
DE (2) | DE308314T1 (sv) |
ES (1) | ES2035339T3 (sv) |
FI (1) | FI93867C (sv) |
FR (1) | FR2620744A1 (sv) |
NO (1) | NO174781C (sv) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5164043A (en) | 1990-05-17 | 1992-11-17 | Union Camp Patent Holding, Inc. | Environmentally improved process for bleaching lignocellulosic materials with ozone |
US5164044A (en) | 1990-05-17 | 1992-11-17 | Union Camp Patent Holding, Inc. | Environmentally improved process for bleaching lignocellulosic materials with ozone |
US5188708A (en) | 1989-02-15 | 1993-02-23 | Union Camp Patent Holding, Inc. | Process for high consistency oxygen delignification followed by ozone relignification |
US5554259A (en) | 1993-10-01 | 1996-09-10 | Union Camp Patent Holdings, Inc. | Reduction of salt scale precipitation by control of process stream Ph and salt concentration |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5181989A (en) * | 1990-10-26 | 1993-01-26 | Union Camp Patent Holdings, Inc. | Reactor for bleaching high consistency pulp with ozone |
US5409570A (en) * | 1989-02-15 | 1995-04-25 | Union Camp Patent Holding, Inc. | Process for ozone bleaching of oxygen delignified pulp while conveying the pulp through a reaction zone |
US5472572A (en) * | 1990-10-26 | 1995-12-05 | Union Camp Patent Holding, Inc. | Reactor for bleaching high consistency pulp with ozone |
US5211811A (en) * | 1989-02-15 | 1993-05-18 | Union Camp Patent Holding, Inc. | Process for high consistency oxygen delignification of alkaline treated pulp followed by ozone delignification |
FI89516B (fi) * | 1989-05-10 | 1993-06-30 | Ahlstroem Oy | Foerfarande foer blekning av cellulosamassa med otson |
AT395180B (de) * | 1989-08-16 | 1992-10-12 | Andritz Ag Maschf | Verfahren zur zerkleinerung von materialien und anlage zu dessen durchfuehrung |
US5441603A (en) * | 1990-05-17 | 1995-08-15 | Union Camp Patent Holding, Inc. | Method for chelation of pulp prior to ozone delignification |
US5174861A (en) * | 1990-10-26 | 1992-12-29 | Union Camp Patent Holdings, Inc. | Method of bleaching high consistency pulp with ozone |
US5520783A (en) * | 1990-10-26 | 1996-05-28 | Union Camp Patent Holding, Inc. | Apparatus for bleaching high consistency pulp with ozone |
EP0492040A1 (en) * | 1990-12-21 | 1992-07-01 | Kamyr, Inc. | Tumbling ozone reactor for paper pulp |
EP0492039A1 (en) * | 1990-12-27 | 1992-07-01 | Kamyr, Inc. | Pneumatic reactor ozone bleaching of paper pulp |
US5087326A (en) * | 1991-02-20 | 1992-02-11 | Union Camp Patent Holding, Inc. | Rotating pulp bleaching reactor having inner and outer shells and lifting means on the interior surface of the inner shell |
US5411633A (en) * | 1991-04-30 | 1995-05-02 | Kamyr, Inc. | Medium consistency pulp ozone bleaching |
DE69221385T2 (de) * | 1991-05-24 | 1997-12-11 | Union Camp Patent Holding, Inc., Wilmington, Del. | Zweistufiger Reaktor zum Bleichen von Zellstoff und Verfahren zum Bleichen mit Ozon |
FI925558A (fi) * | 1992-04-22 | 1993-10-23 | Ahlstroem Oy | Foerfarande och anordning foer blekning av massa |
US5387317A (en) * | 1993-01-28 | 1995-02-07 | The Mead Corporation | Oxygen/ozone/peracetic aicd delignification and bleaching of cellulosic pulps |
US5810973A (en) * | 1993-09-21 | 1998-09-22 | Beloit Technologies, Inc. | Apparatus for producing small particles from high consistency wood pulp |
CA2197190A1 (en) * | 1994-08-11 | 1996-02-22 | Lewis D. Shackford | Means for gas-sealingly conveying shredded pulp |
US5944952A (en) * | 1995-07-26 | 1999-08-31 | Beloit Technologies, Inc. | Method for bleaching high consistency pulp with a gaseous bleaching reagent |
US6077396A (en) * | 1997-05-16 | 2000-06-20 | Lariviere; Christopher J. | Apparatus for fluffing and contacting high consistancy wood pulp with a gaseous bleaching reagent |
US6174409B1 (en) | 1997-09-19 | 2001-01-16 | American Air Liquide Inc. | Method to improve final bleached pulp strength properties by adjusting the CI02:03 ration within a single (D/Z) stage of the bleaching process |
SE514416C2 (sv) * | 1999-06-10 | 2001-02-19 | Valmet Fibertech Ab | Metod och system för gastät inmatning av massa till en reaktor för ozonblekning |
FR2811320B1 (fr) * | 2000-07-06 | 2002-08-23 | Adir | Nouvelle forme cristalline alpha du sel de tert-butylamine du perindopril, son procede de preparation et les compositions pharmaceutiques qui la contiennent |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1591070A (en) * | 1925-02-27 | 1926-07-06 | Robert B Wolf | Bleaching apparatus |
US2013115A (en) * | 1931-09-21 | 1935-09-03 | Thorne Carl Busch | Process and apparatus for the refining of pulp |
US2466633A (en) * | 1948-05-26 | 1949-04-05 | James M Daily | Method of bleaching cellulosic pulp |
FR1441787A (fr) * | 1965-04-30 | 1966-06-10 | Progil | Procédé de blanchiment des pâtes à papier |
NO137651C (no) * | 1975-10-31 | 1978-03-29 | Myrens Verksted As | Fremgangsmaate og apparat til kontinuerlig behandling av findelt fibermateriale eller celluloseholdig masse med gass uten overtrykk. |
JPS5319404A (en) * | 1976-04-19 | 1978-02-22 | Toyo Pulp Co Ltd | Process and apparatus for treating cellulose material |
CA1090510A (en) * | 1976-06-02 | 1980-12-02 | Arthur W. Kempf | Delignification and bleaching of a lignocellulosic pulp slurry with ozone |
JPS5536313A (en) * | 1978-08-30 | 1980-03-13 | Hokusan Kk | Production of mechanical pulp |
US4363697A (en) * | 1979-12-03 | 1982-12-14 | The Black Clawson Company | Method for medium consistency oxygen delignification of pulp |
FR2474550A1 (fr) * | 1980-01-24 | 1981-07-31 | Scott Paper Co | Procede de blanchiment de pate cellulosique |
FR2609067B1 (fr) * | 1986-12-31 | 1990-06-15 | Beghin Say Sa | Procede pour le traitement a l'ozone d'une pate cellulosique |
-
1987
- 1987-09-17 FR FR8712890A patent/FR2620744A1/fr not_active Withdrawn
-
1988
- 1988-09-12 DE DE198888402296T patent/DE308314T1/de active Pending
- 1988-09-12 ES ES198888402296T patent/ES2035339T3/es not_active Expired - Lifetime
- 1988-09-12 EP EP88402296A patent/EP0308314B1/fr not_active Expired - Lifetime
- 1988-09-12 AT AT88402296T patent/ATE82340T1/de not_active IP Right Cessation
- 1988-09-12 DE DE8888402296T patent/DE3875893T2/de not_active Expired - Fee Related
- 1988-09-12 CA CA000577157A patent/CA1314664C/fr not_active Expired - Fee Related
- 1988-09-16 NO NO884128A patent/NO174781C/no not_active IP Right Cessation
- 1988-09-16 FI FI884267A patent/FI93867C/sv not_active IP Right Cessation
- 1988-09-16 BR BR8804806A patent/BR8804806A/pt not_active IP Right Cessation
- 1988-09-17 JP JP63233374A patent/JP2731822B2/ja not_active Expired - Lifetime
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5188708A (en) | 1989-02-15 | 1993-02-23 | Union Camp Patent Holding, Inc. | Process for high consistency oxygen delignification followed by ozone relignification |
US5164043A (en) | 1990-05-17 | 1992-11-17 | Union Camp Patent Holding, Inc. | Environmentally improved process for bleaching lignocellulosic materials with ozone |
US5164044A (en) | 1990-05-17 | 1992-11-17 | Union Camp Patent Holding, Inc. | Environmentally improved process for bleaching lignocellulosic materials with ozone |
US5554259A (en) | 1993-10-01 | 1996-09-10 | Union Camp Patent Holdings, Inc. | Reduction of salt scale precipitation by control of process stream Ph and salt concentration |
US5693184A (en) | 1993-10-01 | 1997-12-02 | Union Camp Patent Holding, Inc. | Reduction of salt scale precipitation by control of process stream pH and salt concentration |
Also Published As
Publication number | Publication date |
---|---|
DE3875893T2 (de) | 1993-03-18 |
FR2620744A1 (fr) | 1989-03-24 |
NO174781C (no) | 1994-07-06 |
JPH0197290A (ja) | 1989-04-14 |
EP0308314A1 (fr) | 1989-03-22 |
BR8804806A (pt) | 1989-04-25 |
NO884128D0 (no) | 1988-09-16 |
FI93867C (sv) | 1995-06-12 |
CA1314664C (fr) | 1993-03-23 |
JP2731822B2 (ja) | 1998-03-25 |
DE308314T1 (de) | 1989-10-05 |
FI884267A (sv) | 1989-03-18 |
ES2035339T3 (es) | 1993-04-16 |
NO174781B (no) | 1994-03-28 |
DE3875893D1 (de) | 1992-12-17 |
ATE82340T1 (de) | 1992-11-15 |
FI93867B (sv) | 1995-02-28 |
NO884128L (no) | 1989-03-20 |
FI884267A0 (sv) | 1988-09-16 |
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