EP0298827A1 - Lösung und Verfahren zur gemischten Phosphatisierung - Google Patents
Lösung und Verfahren zur gemischten Phosphatisierung Download PDFInfo
- Publication number
- EP0298827A1 EP0298827A1 EP88401614A EP88401614A EP0298827A1 EP 0298827 A1 EP0298827 A1 EP 0298827A1 EP 88401614 A EP88401614 A EP 88401614A EP 88401614 A EP88401614 A EP 88401614A EP 0298827 A1 EP0298827 A1 EP 0298827A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- ion
- acid
- solution according
- mixed
- zinc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims description 14
- 230000008569 process Effects 0.000 title claims description 11
- 239000011701 zinc Substances 0.000 claims abstract description 53
- 239000011572 manganese Substances 0.000 claims abstract description 51
- 239000002253 acid Substances 0.000 claims abstract description 35
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 33
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 31
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 29
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 23
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000002738 chelating agent Substances 0.000 claims abstract description 21
- 229910052742 iron Inorganic materials 0.000 claims abstract description 17
- 229920000388 Polyphosphate Polymers 0.000 claims abstract description 15
- 239000001205 polyphosphate Substances 0.000 claims abstract description 15
- 235000011176 polyphosphates Nutrition 0.000 claims abstract description 15
- 229910052751 metal Inorganic materials 0.000 claims abstract description 13
- 239000002184 metal Substances 0.000 claims abstract description 13
- 239000000758 substrate Substances 0.000 claims abstract description 13
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 7
- 102100039207 Exportin-T Human genes 0.000 claims abstract description 7
- 101000745703 Homo sapiens Exportin-T Proteins 0.000 claims abstract description 7
- 150000001342 alkaline earth metals Chemical class 0.000 claims abstract description 7
- 239000003513 alkali Substances 0.000 claims abstract description 6
- 229910021645 metal ion Inorganic materials 0.000 claims abstract description 5
- 230000008021 deposition Effects 0.000 claims abstract description 3
- 150000002500 ions Chemical class 0.000 claims description 55
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 21
- 229910001437 manganese ion Inorganic materials 0.000 claims description 19
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims description 17
- 150000003839 salts Chemical class 0.000 claims description 16
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 15
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 15
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 claims description 14
- 229910017604 nitric acid Inorganic materials 0.000 claims description 12
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 11
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical class O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 229910001453 nickel ion Inorganic materials 0.000 claims description 9
- 238000011282 treatment Methods 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 7
- RGHNJXZEOKUKBD-SQOUGZDYSA-M D-gluconate Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O RGHNJXZEOKUKBD-SQOUGZDYSA-M 0.000 claims description 6
- 150000007513 acids Chemical class 0.000 claims description 6
- 229940050410 gluconate Drugs 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- 230000007420 reactivation Effects 0.000 claims description 5
- 239000011670 zinc gluconate Substances 0.000 claims description 5
- 235000011478 zinc gluconate Nutrition 0.000 claims description 5
- 229960000306 zinc gluconate Drugs 0.000 claims description 5
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims description 4
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- 238000005238 degreasing Methods 0.000 claims description 4
- 150000002596 lactones Chemical group 0.000 claims description 4
- 235000021317 phosphate Nutrition 0.000 claims description 4
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 claims description 3
- 229940005740 hexametaphosphate Drugs 0.000 claims description 3
- -1 iron ion Chemical class 0.000 claims description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N Gluconic acid Natural products OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 229910002651 NO3 Inorganic materials 0.000 claims description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims description 2
- 229910003074 TiCl4 Inorganic materials 0.000 claims description 2
- 150000001510 aspartic acids Chemical class 0.000 claims description 2
- FATUQANACHZLRT-KMRXSBRUSA-L calcium glucoheptonate Chemical compound [Ca+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)C([O-])=O FATUQANACHZLRT-KMRXSBRUSA-L 0.000 claims description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 229960001484 edetic acid Drugs 0.000 claims description 2
- 125000005611 glucoheptonic acid group Chemical group 0.000 claims description 2
- 239000000174 gluconic acid Substances 0.000 claims description 2
- 235000012208 gluconic acid Nutrition 0.000 claims description 2
- 238000007654 immersion Methods 0.000 claims description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 2
- 150000002691 malonic acids Chemical class 0.000 claims description 2
- 235000010755 mineral Nutrition 0.000 claims description 2
- 239000011707 mineral Substances 0.000 claims description 2
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 claims description 2
- 150000002823 nitrates Chemical class 0.000 claims description 2
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 claims description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 2
- 229940095064 tartrate Drugs 0.000 claims description 2
- 150000003609 titanium compounds Chemical class 0.000 claims description 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 2
- 239000000080 wetting agent Substances 0.000 claims description 2
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 238000004090 dissolution Methods 0.000 claims 1
- 239000000243 solution Substances 0.000 description 55
- 230000007797 corrosion Effects 0.000 description 7
- 238000005260 corrosion Methods 0.000 description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- 238000000576 coating method Methods 0.000 description 5
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 4
- 229910000357 manganese(II) sulfate Inorganic materials 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- WHMDKBIGKVEYHS-IYEMJOQQSA-L Zinc gluconate Chemical compound [Zn+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O WHMDKBIGKVEYHS-IYEMJOQQSA-L 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 3
- 229910000368 zinc sulfate Inorganic materials 0.000 description 3
- 239000011686 zinc sulphate Substances 0.000 description 3
- 235000009529 zinc sulphate Nutrition 0.000 description 3
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 2
- 241001080024 Telles Species 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 239000011683 manganese gluconate Substances 0.000 description 2
- 235000014012 manganese gluconate Nutrition 0.000 description 2
- 229940072543 manganese gluconate Drugs 0.000 description 2
- WJZHMLNIAZSFDO-UHFFFAOYSA-N manganese zinc Chemical compound [Mn].[Zn] WJZHMLNIAZSFDO-UHFFFAOYSA-N 0.000 description 2
- OXHQNTSSPHKCPB-IYEMJOQQSA-L manganese(2+);(2r,3s,4r,5r)-2,3,4,5,6-pentahydroxyhexanoate Chemical compound [Mn+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O OXHQNTSSPHKCPB-IYEMJOQQSA-L 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 238000005554 pickling Methods 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 239000000176 sodium gluconate Substances 0.000 description 2
- 235000012207 sodium gluconate Nutrition 0.000 description 2
- 229940005574 sodium gluconate Drugs 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- CPSYWNLKRDURMG-UHFFFAOYSA-L hydron;manganese(2+);phosphate Chemical compound [Mn+2].OP([O-])([O-])=O CPSYWNLKRDURMG-UHFFFAOYSA-L 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 230000003902 lesion Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/23—Condensed phosphates
Definitions
- Iron acts as a catalyst (or reducer) for conversion. Indeed, in the absence of iron or in the presence of too small an amount of iron, less than 0.3 g / l, it is found that no phosphate deposit forms on the metal substrate. It is only when, due to the attack of the substrate by the solution, the concentration of the latter in iron has reached the minimum value necessary, that the conversion phenomenon takes place.
- this deposit has the disadvantage of a small, irregular thickness, comprising gaps in certain places on the treated plate; the irregularity of the deposit is incompatible with good protection against corrosion and effective lubrication of the metal part, in the event that it must undergo a cold deformation operation.
- This solution leads to obtaining a deposit rich in manganese particularly suitable for use as a coating before cold deformation.
- this fine, dense and regular crystalline deposit ensures good protection against corrosion.
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Catalysts (AREA)
- Saccharide Compounds (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT88401614T ATE92979T1 (de) | 1987-06-25 | 1988-06-24 | Loesung und verfahren zur gemischten phosphatisierung. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8708989 | 1987-06-25 | ||
| FR8708989A FR2618164B1 (fr) | 1987-06-25 | 1987-06-25 | Solution et procede de phosphatation mixte. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0298827A1 true EP0298827A1 (de) | 1989-01-11 |
| EP0298827B1 EP0298827B1 (de) | 1993-08-11 |
Family
ID=9352522
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP88401614A Expired - Lifetime EP0298827B1 (de) | 1987-06-25 | 1988-06-24 | Lösung und Verfahren zur gemischten Phosphatisierung |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5045130A (de) |
| EP (1) | EP0298827B1 (de) |
| JP (1) | JPS6436772A (de) |
| AT (1) | ATE92979T1 (de) |
| DE (1) | DE3883100T2 (de) |
| ES (1) | ES2042783T3 (de) |
| FR (1) | FR2618164B1 (de) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0946786A1 (de) * | 1996-11-27 | 1999-10-06 | Henkel Corporation | Wässrige zusammensetzung und verfahren zur herstellung von metallsubstraten zum kaltverformen |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5595611A (en) * | 1996-02-14 | 1997-01-21 | Henkel Corporation | Moderate temperature manganese phosphate conversion coating composition and process |
| US5728235A (en) * | 1996-02-14 | 1998-03-17 | Henkel Corporation | Moderate temperature manganese phosphate conversion coating composition and process |
| US6162508A (en) * | 1998-11-02 | 2000-12-19 | Nortel Networks Limited | Molybdenum phosphate based corrosion resistant conversion coatings |
| CN101384751B (zh) * | 2006-02-14 | 2013-01-02 | 汉高股份及两合公司 | 在金属表面上使用的原地干燥的三价铬抗腐蚀涂料的组合物与方法 |
| CA2651393C (en) * | 2006-05-10 | 2016-11-01 | Henkel Ag & Co. Kgaa | Improved trivalent chromium-containing composition for use in corrosion resistant coatings on metal surfaces |
| US10156016B2 (en) | 2013-03-15 | 2018-12-18 | Henkel Ag & Co. Kgaa | Trivalent chromium-containing composition for aluminum and aluminum alloys |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2826517A (en) * | 1954-01-11 | 1958-03-11 | Kelite Products Inc | Process and composition for phosphatizing steel |
| DE973195C (de) * | 1951-01-18 | 1959-12-17 | Metallgesellschaft Ag | Verfahren zum UEberziehen von Metalloberflaechen mit einer Phosphatschicht |
| US2955967A (en) * | 1958-09-25 | 1960-10-11 | Amchem Prod | Method and solution for phosphatizing metals |
| DE2247165A1 (de) * | 1972-09-26 | 1974-03-28 | Kluthe Kg Chem Werke | Mischphosphatierungsmittel |
| DE2931693A1 (de) * | 1979-05-29 | 1980-12-11 | In Accomandita Semplice Fosfa | Loesung zur phosphatisierung metallischer flaechen |
| EP0042631A1 (de) * | 1980-06-24 | 1981-12-30 | Metallgesellschaft Ag | Verfahren zur Phosphatierung von Metalloberflächen |
| FR2492413A1 (fr) * | 1980-10-22 | 1982-04-23 | Chaffoteaux Et Maury | Procede et compositions pour la protection des surfaces de zinc au moyen de depots de pyrophosphates de zinc |
| EP0102284A1 (de) * | 1982-08-03 | 1984-03-07 | Roquette FrÀ¨res | Lösung und Verfahren zur chemischen Konversion metallischer Oberflächen |
| EP0175606A1 (de) * | 1984-08-16 | 1986-03-26 | Compagnie Francaise De Produits Industriels | Verfahren zur chemischen Konversionsbehandlung von Zink oder seinen Legierungen, Konzentrat und Lösung zum Ausführen dieses Verfahrens |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3338755A (en) * | 1963-09-03 | 1967-08-29 | Hooker Chemical Corp | Production of phosphate coatings on metals |
| DE2160784C3 (de) * | 1971-12-08 | 1979-04-12 | Joachim Dipl.-Chem. Dr. 4330 Muelheim Marx | Verfahren zur Herstellung von Schutzschichten auf Gegenständen aus Metallen durch Aufbringen von PoIyphosphaten |
| LU81038A1 (fr) * | 1978-03-14 | 1979-06-18 | Centre Rech Metallurgique | Procede pour le traitement superficiel d'une bande metallique |
| JPH0788585B2 (ja) * | 1986-11-21 | 1995-09-27 | 日本ペイント株式会社 | リン酸塩皮膜処理剤 |
| JPH0672311B2 (ja) * | 1987-04-08 | 1994-09-14 | トヨタ自動車株式会社 | リン酸亜鉛化成処理方法 |
-
1987
- 1987-06-25 FR FR8708989A patent/FR2618164B1/fr not_active Expired - Fee Related
-
1988
- 1988-06-23 US US07/211,448 patent/US5045130A/en not_active Expired - Fee Related
- 1988-06-24 EP EP88401614A patent/EP0298827B1/de not_active Expired - Lifetime
- 1988-06-24 AT AT88401614T patent/ATE92979T1/de not_active IP Right Cessation
- 1988-06-24 ES ES88401614T patent/ES2042783T3/es not_active Expired - Lifetime
- 1988-06-24 DE DE88401614T patent/DE3883100T2/de not_active Expired - Fee Related
- 1988-06-25 JP JP63156031A patent/JPS6436772A/ja active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE973195C (de) * | 1951-01-18 | 1959-12-17 | Metallgesellschaft Ag | Verfahren zum UEberziehen von Metalloberflaechen mit einer Phosphatschicht |
| US2826517A (en) * | 1954-01-11 | 1958-03-11 | Kelite Products Inc | Process and composition for phosphatizing steel |
| US2955967A (en) * | 1958-09-25 | 1960-10-11 | Amchem Prod | Method and solution for phosphatizing metals |
| DE2247165A1 (de) * | 1972-09-26 | 1974-03-28 | Kluthe Kg Chem Werke | Mischphosphatierungsmittel |
| DE2931693A1 (de) * | 1979-05-29 | 1980-12-11 | In Accomandita Semplice Fosfa | Loesung zur phosphatisierung metallischer flaechen |
| EP0042631A1 (de) * | 1980-06-24 | 1981-12-30 | Metallgesellschaft Ag | Verfahren zur Phosphatierung von Metalloberflächen |
| FR2492413A1 (fr) * | 1980-10-22 | 1982-04-23 | Chaffoteaux Et Maury | Procede et compositions pour la protection des surfaces de zinc au moyen de depots de pyrophosphates de zinc |
| EP0102284A1 (de) * | 1982-08-03 | 1984-03-07 | Roquette FrÀ¨res | Lösung und Verfahren zur chemischen Konversion metallischer Oberflächen |
| EP0175606A1 (de) * | 1984-08-16 | 1986-03-26 | Compagnie Francaise De Produits Industriels | Verfahren zur chemischen Konversionsbehandlung von Zink oder seinen Legierungen, Konzentrat und Lösung zum Ausführen dieses Verfahrens |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0946786A1 (de) * | 1996-11-27 | 1999-10-06 | Henkel Corporation | Wässrige zusammensetzung und verfahren zur herstellung von metallsubstraten zum kaltverformen |
| EP0946786A4 (de) * | 1996-11-27 | 1999-10-06 | ||
| US6068710A (en) * | 1996-11-27 | 2000-05-30 | Henkel Corporation | Aqueous composition and process for preparing metal substrate for cold forming |
Also Published As
| Publication number | Publication date |
|---|---|
| ATE92979T1 (de) | 1993-08-15 |
| JPS6436772A (en) | 1989-02-07 |
| DE3883100D1 (de) | 1993-09-16 |
| DE3883100T2 (de) | 1994-03-10 |
| FR2618164B1 (fr) | 1994-02-04 |
| US5045130A (en) | 1991-09-03 |
| EP0298827B1 (de) | 1993-08-11 |
| ES2042783T3 (es) | 1993-12-16 |
| FR2618164A1 (fr) | 1989-01-20 |
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