EP0286773A3 - Water insoluble encapsulated enzymes protected against deactivation by halogen bleaches - Google Patents

Water insoluble encapsulated enzymes protected against deactivation by halogen bleaches Download PDF

Info

Publication number
EP0286773A3
EP0286773A3 EP88100045A EP88100045A EP0286773A3 EP 0286773 A3 EP0286773 A3 EP 0286773A3 EP 88100045 A EP88100045 A EP 88100045A EP 88100045 A EP88100045 A EP 88100045A EP 0286773 A3 EP0286773 A3 EP 0286773A3
Authority
EP
European Patent Office
Prior art keywords
substance
time
release
enzyme
bleach
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP88100045A
Other versions
EP0286773B1 (en
EP0286773A2 (en
Inventor
Keith Edward Olson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ecolab Inc
Original Assignee
Ecolab Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ecolab Inc filed Critical Ecolab Inc
Publication of EP0286773A2 publication Critical patent/EP0286773A2/en
Publication of EP0286773A3 publication Critical patent/EP0286773A3/en
Application granted granted Critical
Publication of EP0286773B1 publication Critical patent/EP0286773B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38672—Granulated or coated enzymes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Enzymes And Modification Thereof (AREA)
  • Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
  • Manufacturing Of Micro-Capsules (AREA)
  • Channel Selection Circuits, Automatic Tuning Circuits (AREA)
  • Electronic Switches (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Surface Acoustic Wave Elements And Circuit Networks Thereof (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
  • Lubricants (AREA)
  • Immobilizing And Processing Of Enzymes And Microorganisms (AREA)

Abstract

A composition capable of releasing active enzyme into an aqueous, active chlorine containing media which in a first aspect comprises an enzyme core encapsulated with an initial coating of a time-release substance, a first coating of a bleach-neutralizing substance and a second coating of a time-release substance. In a second aspect, the composition comprises an enzyme encapsulated in a time-release substance designed to delay release of the enzyme in dissolution for a first-time delay, and a bleach-neutralizing substance, present as either a core material and/or a first coating on a diluent core, which is encapsulated in a time-release substance designed to delay release of the bleach-neutralizing substance into solution for a second-time delay; the first-time delay being longer than the second-time delay so that the bleach-neutralizing substance will be released and completely neutralize all active chlorine present in the solution before the enzyme is released. In a third aspect, the composition comprises an enzyme core encapsulated with a time-release substance, a diluent core encapsulated with a first coating of a bleachneutralizing substance and a second coating of a time-release substance, and a bleach-neutralizing substance core encapsulated with a time-release substance. The invention further includes a cleaning composition which is particularly effective in warewashing which comprises one of the encapsulated enzyme-containing compositions described above, chlorine bleach, and at least one additional detergent component.
EP88100045A 1987-04-17 1988-01-05 Water insoluble encapsulated enzymes protected against deactivation by halogen bleaches Expired - Lifetime EP0286773B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US4019187A 1987-04-17 1987-04-17
US40191 1987-04-17

Publications (3)

Publication Number Publication Date
EP0286773A2 EP0286773A2 (en) 1988-10-19
EP0286773A3 true EP0286773A3 (en) 1990-03-21
EP0286773B1 EP0286773B1 (en) 1994-08-10

Family

ID=21909631

Family Applications (1)

Application Number Title Priority Date Filing Date
EP88100045A Expired - Lifetime EP0286773B1 (en) 1987-04-17 1988-01-05 Water insoluble encapsulated enzymes protected against deactivation by halogen bleaches

Country Status (13)

Country Link
EP (1) EP0286773B1 (en)
JP (1) JP2588927B2 (en)
KR (1) KR970001229B1 (en)
AT (1) ATE109822T1 (en)
AU (1) AU8317487A (en)
BR (1) BR8801839A (en)
CA (1) CA1305082C (en)
DE (1) DE3850991T2 (en)
DK (1) DK8288A (en)
ES (1) ES2060609T3 (en)
FI (1) FI880456A (en)
NO (1) NO880372L (en)
NZ (1) NZ223135A (en)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5254287A (en) * 1985-08-21 1993-10-19 The Clorox Company Encapsulated enzyme in dry bleach composition
US5167854A (en) * 1985-08-21 1992-12-01 The Clorox Company Encapsulated enzyme in dry bleach composition
ATE72579T1 (en) * 1985-08-21 1992-02-15 Clorox Co STABLE PERSACID BLEACH.
US5733763A (en) * 1988-08-19 1998-03-31 Novo Nordisk A/S Enzyme granulate formed of an enzyme-containing core and an enzyme-containing shell
DK78189D0 (en) * 1989-02-20 1989-02-20 Novo Industri As ENZYMOUS GRANULATE AND PROCEDURE FOR PREPARING THEREOF
DK78089D0 (en) * 1989-02-20 1989-02-20 Novo Industri As DETERGENTAL GRANULATE AND PROCEDURES FOR PREPARING THEREOF
EP0723006A3 (en) * 1995-01-23 1998-07-01 The Procter & Gamble Company Cleaning methods and products providing compatibilized staged release of bleach followed by enzymes
GB2297978A (en) † 1995-02-15 1996-08-21 Procter & Gamble Detergent compositions containing amylase
DK1092007T3 (en) * 1998-06-30 2004-04-05 Novozymes As New improved enzyme-containing granule
WO2000063341A1 (en) * 1999-04-19 2000-10-26 The Procter & Gamble Company Process for making non-staining colored particles for improving aesthetics of a liquid automatic dishwashing detergent product, the particles, and a composition
US6730652B1 (en) 1999-04-19 2004-05-04 The Procter & Gamble Company Process for making non-staining colored particles for improving aesthetics of a liquid automatic dishwashing detergent product, the particles, and a composition
ES2836811T3 (en) 2010-01-15 2021-06-28 Kemin Ind Zhuhai Co Ltd Protected alpha-amylase
SE535628C2 (en) * 2010-01-29 2012-10-23 Kemira Oyj Active oxygen source
DE102015225873A1 (en) * 2015-12-18 2017-06-22 Henkel Ag & Co. Kgaa Two-stage washing process
US20200040283A1 (en) * 2017-03-31 2020-02-06 Danisco Us Inc Delayed release enzyme formulations for bleach-containing detergents

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE838125A (en) * 1975-01-31 1976-07-30 ENZYME GRANULES
US4421664A (en) * 1982-06-18 1983-12-20 Economics Laboratory, Inc. Compatible enzyme and oxidant bleaches containing cleaning composition
EP0206417A2 (en) * 1985-06-28 1986-12-30 The Procter & Gamble Company Dry bleach stable enzyme composition
WO1987007292A1 (en) * 1986-05-21 1987-12-03 Novo Industri A/S Coated detergent enzymes

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE838125A (en) * 1975-01-31 1976-07-30 ENZYME GRANULES
US4421664A (en) * 1982-06-18 1983-12-20 Economics Laboratory, Inc. Compatible enzyme and oxidant bleaches containing cleaning composition
EP0206417A2 (en) * 1985-06-28 1986-12-30 The Procter & Gamble Company Dry bleach stable enzyme composition
WO1987007292A1 (en) * 1986-05-21 1987-12-03 Novo Industri A/S Coated detergent enzymes

Also Published As

Publication number Publication date
NZ223135A (en) 1989-10-27
JPS63296690A (en) 1988-12-02
EP0286773B1 (en) 1994-08-10
AU8317487A (en) 1988-10-20
EP0286773A2 (en) 1988-10-19
FI880456A (en) 1988-10-18
DK8288A (en) 1988-10-18
DE3850991D1 (en) 1994-09-15
ATE109822T1 (en) 1994-08-15
BR8801839A (en) 1988-11-22
JP2588927B2 (en) 1997-03-12
NO880372L (en) 1988-10-18
KR970001229B1 (en) 1997-02-04
CA1305082C (en) 1992-07-14
DE3850991T2 (en) 1994-12-15
ES2060609T3 (en) 1994-12-01
DK8288D0 (en) 1988-01-08
NO880372D0 (en) 1988-01-28
KR880012755A (en) 1988-11-29
FI880456A0 (en) 1988-02-01

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