EP0280550B1 - Composition adoucissante pour textiles - Google Patents

Composition adoucissante pour textiles Download PDF

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Publication number
EP0280550B1
EP0280550B1 EP19880301628 EP88301628A EP0280550B1 EP 0280550 B1 EP0280550 B1 EP 0280550B1 EP 19880301628 EP19880301628 EP 19880301628 EP 88301628 A EP88301628 A EP 88301628A EP 0280550 B1 EP0280550 B1 EP 0280550B1
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EP
European Patent Office
Prior art keywords
ethoxylated
fabric softening
ethylene oxide
average
per molecule
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP19880301628
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German (de)
English (en)
Other versions
EP0280550A2 (fr
EP0280550A3 (en
Inventor
Eunice Sheila Blackmore
Brian William Topping
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Unilever NV
Original Assignee
Unilever PLC
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
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Application filed by Unilever PLC, Unilever NV filed Critical Unilever PLC
Publication of EP0280550A2 publication Critical patent/EP0280550A2/fr
Publication of EP0280550A3 publication Critical patent/EP0280550A3/en
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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/667—Neutral esters, e.g. sorbitan esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides

Definitions

  • the present invention relates to a fabric softening composition, in particular a fabric softening composition containing a water-insoluble cationic fabric softening agent, a fatty acid and other nonionic surfactants.
  • Nonionic surfactant materials may optionally be added to these compositions.
  • liquid fabric softening composition comprising
  • the water-insoluble cationic fabric softening agent can be any fabric-substantive cationic compound which has a solubility in water at pH 2.5 and 20 ° C of less than 10 g/1.
  • Highly preferred materials are quaternary ammonium salts having two C 12 ⁇ C 24 alkyl or alkenyl chains, optionally substituted or interrupted by functional groups such as -OH, -0-, -CONH-, -COO-, etc.
  • Ri and R 2 represent hydrocarbyl groups having from 12 to 24 carbon atoms
  • R 3 and R 4 represent hydrocarbyl groups containing from 1 to 4 carbon atoms
  • X is an anion, preferably selected from halide, methyl sulfate and ethyl sulfate radicals.
  • quaternary softeners include ditallow dimethyl ammonium chloride; ditallow dimethyl ammonium methyl sulfate; dihexadecyl dimethyl ammonium chloride; di(hydrogenated tallow alkyl) dimethyl ammonium chloride; dioctadecyl dimethyl ammonium chloride; dieicosyl dimethyl ammonium chloride; didocosyl dimethyl ammonium chloride; di(hydrogenated tallow) dimethyl ammonium methyl sulfate; dihexadecyl diethyl ammonium chloride; di(coconut alkyl) dimethyl ammonium chloride.
  • dialkyl ethoxyl methyl ammonium sulphates based on soft or hard fatty acids.
  • Ditallow dimethyl ammonium chloride, di(hydrogenated tallow alkyl) dimethyl ammonium chloride, di(coconut alkyl) dimethyl ammonium chloride and di(coconut alkyl) dimethyl ammonium methosulfate are preferred.
  • alkylimidazolinium salts believed to have the formula: wherein R 6 is an alkyl or hydroxyalkyl group containing from 1 to 4, preferably 1 or 2 carbon atoms, R 7 is an alkyl or alkenyl group containing from 8 to 25 carbon atoms, R a is an alkyl or alkenyl group containing from 8 to 25 carbon atoms, and R 9 is hydrogen or an alkyl containing from 1 to 4 carbon atoms and A- is an anion, preferably a halide, methosulfate or ethosulfate.
  • Preferred imidazolinium salts include 1-methyl-1-(tallowylamido-) ethyl -2-tallowyl- 4, 5-dihydro imidazolinium methosulfate and 1-methyl-1-(paimitoylamido)ethyl-2-octadecyl-4, 5- dihydro- imidazolinium chloride.
  • Other useful imidazolinium materials are 2-heptadecyl-1-methyl-l- (2-stearylamido)- ethyl-imidazolinium chloride and 2-lauryl-1-hydroxyethyl-l-oleyl-imidazolinium chloride.
  • Also suitable herein are the imidazolinium fabric softening components of US Patent No 4 127 489. Mixtures of various cationic fabric softening agents can also be used.
  • the level of the cationic fabric softening agent in the composition is preferably more than 1% by weight, most preferably from 3% to 6% by weight.
  • Suitable fatty acids which can be used in the present invention are C s -C 24 alkyl or alkenyl linear or branched chain monocarboxylic acids or polymers thereof.
  • Preferably saturated fatty acids are used, in particular, hardened tallow C 16 ⁇ C 18 fatty acids. Mixtures of various fatty acids can also be used.
  • the level of the fatty acid in the composition is preferably less than 8% by weight, most preferably from 0.2% to 2.5% by weight.
  • the mole ratio of the cationic fabric softening agent to the fatty acid is at least 1:1, and preferably is within the range 4:1 to 9:1.
  • Suitable nonionic surfactants which can be used include in particular the reaction products of compounds having a hydrophobic group and a reactive hydrogen atom, for example aliphatic alcohols, acids, or alkyl phenols with alkylene oxides, especially ethylene oxide either alone or with propylene oxide.
  • Specific nonionic surfactants are alkyl (C 6 ⁇ C 22 ) phenols-ethylene oxide condensates, generally up to 25 EO, ie up to 25 units of ethylene oxide per molecule, the condensation products of aliphatic (Ca-C 22 ) primary or secondary linear or branched alcohols with ethylene oxide, generally up to 40 EO, and products made by condensation of ethylene oxide with the reaction products of propylene oxide and ethylenediamine.
  • Other so-called nonionic surfactants include amine oxides, alkyl polyglycosides, ethoxylated castor oils, sorbitan esters and ethoxylated derivatives thereof.
  • the level of the nonionic surfactant is within the range from 0.1 to 4.5% by weight, most preferably from 0.15% to 3% by weight.
  • the mole ratio of the cationic fabric softening agent to the nonionic surfactant is within the range from 18:1 to 3:1.
  • the composition can also contain one or more optional ingredients selected from non-aqueous solvents such as Ci-C 4 alkanols and polyhydric alcohols (although the benefits of this invention can be obtained without the addition of these materials), pH buffering agents, such as weak acids, eg phosphoric, benzoic or citric acids (the pH of the compositions are preferably less than 6.0), rewetting agents, viscosity modifiers, such as electrolytes and Cs-Cz4 fatty acids included at levels from 20 to 6000 ppm, an- tigelling agents, perfumes, perfume carriers, fluorescers, colourants, hydrotropes, antifoaming agents, antiredeposition agents, enzymes, optical brightening agents, opacifiers, stabilisers such as guar gum and polyethylene glycol, anti-shrinking agents, anti-wrinkle agents, fabric crisping agents, anti-spotting agents, soil-release agents, germicides,fungicides, anti-oxidants, anti-corrosion agents, preservatives
  • Suitable silicones for use in the compositions according to the invention include predominantly linear polydialkyl or alkylaryl siloxanes in which the alkyl groups contain one to five carbon atoms.
  • the siloxanes can be amido or amino substituted.
  • the siloxane is amine substituted the amine group may be quaternised.
  • compositions may also contain, in addition to the cationic fabric softening agent, other non-cationic fabric softening agents, such as nonionic fabric softening agents.
  • Suitable nonionic fabric softening agents include lanolin and derivatives thereof.
  • Suitable materials are disclosed in European Patent Ap- plieations 88 520 (Unilever). Typically such materials are included at a level within the range of from 0.5% to 10% by weight of the composition.
  • the fabric conditioning composition of the invention may be added to a large volume of water to form a liquor with which the fabrics to be treated are contacted.
  • the total concentration of the cationic fabric softening agent, the fatty acid and the nonionic surfactant in this liquor will be between 30 ppm and 500 ppm.
  • the weight ratio of the fabrics to liquor will preferably be less than 25:1, most preferably between 10:1 and 4:1.
  • compositions of the invention may be prepared by a variety of methods.
  • One suitable method is to form a molten mixture of the cationic fabric softening agent and the fatty acid, add this molten mixture to water with stirring to form a dispersion and thereafter add the nonionic surfactant and any optional ingredients.
  • Another suitable method is to add the nonionic surfactant to the molten mixture before the dispersion is formed.
  • a liquid fabric softening composition was made as follows.
  • the cationic fabric softening agent and the fatty acid were premixed and heated together until clear (60-75 ° C).
  • the molten mixture thus formed was added over a period of at least one minute, via a dip pipe, to water at 45-60°C, with constant stirring to form a dispersion.
  • Other minor ingredients including perfume were added with constant stirring whilst the temperature of the dispersion was greater than 35°C.
  • the nonionic surfactant was most preferably added after the mixture had cooled to 35 ° C or below.
  • Example 1 was repeated except that the Nonidet LE 6T was excluded from the composition (Example 1 A).
  • a freeze thaw cycle in this context involves storing 100 g of product in a screw-capped polyethylene bottle for 16 hours at a temperature of -12 ° C or less. Such low temperatures are essential to ensure that the products are completely frozen. The product is then allowed to thaw at ambient temperatures for 8 hours.
  • Example 1 After 1 freeze thaw cycle Example 1 gave a composition which was slightly thicker than normal. After 3 and 6 freeze thaw cycles Example 1 gave a composition which had normal rinse conditioner rheology, ie. was mobile and could be poured in a continuous stream. Example 1A after 1, 3 and 6 freeze thaw cycles gave a composition which was just mobile but which did not pour in a continuous stream.
  • compositions with the following formulations expressed as weight % were prepared by the method previously described.
  • Example 2L For comparison purposes a composition containing no nonionic (Example 2L) was prepared and tested. In Example 2A a level of APG 300 of 0.2% rather than 0.4% was used. Each composition was subjected to the following cap dispenser test after 1 and 3 freeze thaw cycles.
  • Products were allowed to recover from freezing and a known amount (usually 20 grams) was weighed into an internally screw threaded cap with a total capacity of approximately 25 cm 3 and of known weight. The cap was then inverted over a waste container for 10 seconds and re-weighed. The results obtained are expressed as a percentage of the amount of product weighed into the cap. Prior to freezing, the samples were found to leave up to approximately 10% residue in the cap.
  • Nonidet LE6T is replaced by Tween 20, Alfol 1214-7, Alfol 1214-11, Alfol 1214-13, Brij 30, Brij 35, Lutensol A07, Lutensol A08, and Synperonic All.
  • This example demonstrates the effect of increasing levels of nonionic surfactant on the freeze-thaw stability of a 4.2% active with a ratio of Arquad 2HT: Pristerene 4916 of 6:1 by weight and a perfume level of 0.13%.
  • the compositions were prepared by the method previously described.
  • the levels of nonionic are expressed in terms of wt% of the final formulation.
  • the products were assessed after one freeze thaw cycle via the cap dispenser test described above.
  • This example demonstrates the effect of low levels of Nonidet LE 6T on formulations other than those containing 4.2% active and a 6:1 weight ratio of cationic fabric softening agent to fatty acid.
  • the compositions were prepared as described above and the percentage ingredient refers to their weight % in the final product.
  • compositions were evaluated according to the cap dispenser test as described above.
  • compositions with the following formulations were prepared as described above. Once again the amount of each ingredient refers to weight % in the final product composition.
  • compositions were assessed visually after recovery from 1 freeze thaw cycle.
  • addition of a nonionic surfactant improved the appearance and flow characteristics of the composition.
  • This Example demonstrates that the beneficial effect of adding nonionic surfactant is not restricted to compositions containing Arquad 2HT and Pristerene 4916.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Claims (3)

1. Composition liquide d'adoucissement de textiles qui comprend:
i) une base aqueuse;
ii) de 1 à 6% en poids d'un agent d'adoucissement cationique non hydrosoluble de textiles;
iii) au moins 0,2% en poids d'un acide gras en Ce-24; et
iv) un surfactif non ionique, dans laquelle le rapport molaire de l'agent cationique d' adoucissement de textiles au surfactif non ionique est compris entre 18:1 et 3:1, et dans laquelle le rapport molaire de l'agent cationique d'adoucissement de textiles à l'acide gras est d'au moins 1:1.
2. Composition liquide d'adoucissement de textiles selon la revendication 1, dans laquelle le surfactif non ionique est choisi parmi:
i) les produits d'addition d'oxyde d'alkylène avec des alcools aliphatiques et des alkylphénols;
ii) les oxydes d'amines;
iii) les alkylpolyglycosides;
iv) l'huile de ricin éthoxylée ;
v) les esters de sorbitanne et leurs dérivés ethoxylés; et
vi) des mélanges des matières.citées.
3. Composition liquide d'adoucissement des textiles selon la revendication 2, dans laquelle le surfactif non ionique est choisi parmi:
i) l'oxyde de diméthyl-coco-amine;
ii) le nonylphénol éthoxylé avec, en moyenne, 20 motifs d'oxyde d'éthylène par molécule;
iii) le monolaurate de polyoxyéthylène-sorbitanne éthoxylé avec, en moyenne, 20 motifs d'oxyde d'éthylène par molécule;
iv) un mélange de monolaurate de polyéthylènesorbitanne éthoxylé avec, en moyenne, 20 motifs d'oxyde d'éthylène par molécule et de monolaurate de sorbitanne dans un rapport pondéral 50:50;
v) un alcool primaire à chaîne ramifiée contenant de 9 à 11 atomes de carbone et éthoxylé avec, en moyenne, 6 motifs d'oxyde d'éthylène par molecule;
vi) un alcool primaire à chaîne droite de 12 à 14 atomes de carbone éthoxylé avec en moyenne 4, 7, 11, 13 ou 23 motifs d'oxyde d'éthylène par molécule; et
vii) un alcool primaire a chaîne ramifiée de 13 à 15 atomes de carbone éthoxylé avec en moyenne 7, 8 ou 11 motifs d'oxyde d'éthylène par molécule.
EP19880301628 1987-02-27 1988-02-25 Composition adoucissante pour textiles Expired - Lifetime EP0280550B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8704711 1987-02-27
GB878704711A GB8704711D0 (en) 1987-02-27 1987-02-27 Fabric softening composition

Publications (3)

Publication Number Publication Date
EP0280550A2 EP0280550A2 (fr) 1988-08-31
EP0280550A3 EP0280550A3 (en) 1989-03-29
EP0280550B1 true EP0280550B1 (fr) 1990-10-24

Family

ID=10613088

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19880301628 Expired - Lifetime EP0280550B1 (fr) 1987-02-27 1988-02-25 Composition adoucissante pour textiles

Country Status (12)

Country Link
EP (1) EP0280550B1 (fr)
JP (1) JPS63282373A (fr)
KR (1) KR910009652B1 (fr)
AU (1) AU614073B2 (fr)
BR (1) BR8800833A (fr)
CA (1) CA1291302C (fr)
DE (1) DE3860842D1 (fr)
ES (1) ES2018338B3 (fr)
GB (1) GB8704711D0 (fr)
MY (1) MY103215A (fr)
TR (1) TR24515A (fr)
ZA (1) ZA881382B (fr)

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WO2012052349A1 (fr) 2010-10-22 2012-04-26 Unilever Plc Améliorations se rapportant à des assouplissants pour textile
US9150822B2 (en) 2010-12-03 2015-10-06 Conopco, Inc. Fabric conditioners

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GB8818593D0 (en) * 1988-08-04 1988-09-07 Albright & Wilson Fabric conditioners
GB8914054D0 (en) * 1989-06-19 1989-08-09 Unilever Plc Fabric softening composition
JP2641110B2 (ja) * 1990-12-19 1997-08-13 大日精化工業株式会社 柔軟仕上げ剤組成物
US5484540A (en) * 1991-03-08 1996-01-16 The Procter & Gamble Company Concentrated fabric softening compositions
US5409621A (en) * 1991-03-25 1995-04-25 Lever Brothers Company, Division Of Conopco, Inc. Fabric softening composition
GB9106308D0 (en) * 1991-03-25 1991-05-08 Unilever Plc Fabric softening composition
GB9115255D0 (en) * 1991-07-15 1991-08-28 Unilever Plc Fabric softening composition
JPH06506992A (ja) * 1991-04-30 1994-08-04 ザ、プロクター、エンド、ギャンブル、カンパニー 置換イミダゾリンおよび高度にエトキシル化された化合物を含む布帛柔軟化剤
WO1993024603A2 (fr) * 1992-06-02 1993-12-09 Unilever N.V. Produits de nettoyage liquides
EP0754215B1 (fr) * 1994-04-07 2001-05-23 Unilever Plc Composition assouplissante pour textiles
US5503756A (en) * 1994-09-20 1996-04-02 The Procter & Gamble Company Dryer-activated fabric conditioning compositions containing unsaturated fatty acid
NZ286025A (en) * 1995-03-01 1997-04-24 Colgate Palmolive Co Laundry detergent concentrates; contains nonionic surfactant and water insoluble oil with a hydrophilic polar group, converts to liquid crystal phase dispersion on dilution
US6221828B1 (en) 1999-02-12 2001-04-24 Kao Corporation Detergent composition comprising an alkylpolyglycoside, a germicide, and a fatty acid salt
GB9930430D0 (en) * 1999-12-22 2000-02-16 Unilever Plc A method of preparing fabric softening compositions
GB0014891D0 (en) † 2000-06-16 2000-08-09 Unilever Plc Fabric softening compositions
KR100591100B1 (ko) * 2000-06-26 2006-06-19 주식회사 코오롱 열가소성 합성섬유용 유제 조성물
EP2646532A1 (fr) 2010-12-03 2013-10-09 Unilever PLC Conditionneurs de tissu
WO2012072368A1 (fr) 2010-12-03 2012-06-07 Unilever Plc Conditionneurs de tissu
US10487292B2 (en) * 2016-08-31 2019-11-26 The Procter & Gamble Company Fabric enhancer composition
US20190264136A1 (en) * 2018-02-28 2019-08-29 The Procter & Gamble Company Fabric enhancer composition

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GB1599171A (en) * 1977-05-30 1981-09-30 Procter & Gamble Textile treatment composition
NZ191953A (en) * 1978-11-03 1982-05-25 Unilever Ltd Fabric softening composition comprising a fatty acid
EP0013780B2 (fr) * 1979-01-11 1988-08-31 THE PROCTER & GAMBLE COMPANY Composition concentrée d'adoucissement pour tissus
DE3150178A1 (de) * 1981-12-18 1983-06-30 Hoechst Ag, 6230 Frankfurt "konzentrierte waescheweichspuelmittel"
US4555349A (en) * 1983-04-08 1985-11-26 Lever Brothers Company Fabric softening compositions
DE3314677A1 (de) * 1983-04-22 1984-10-25 Henkel KGaA, 4000 Düsseldorf Konfektioniertes textilweichmacher-konzentrat

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012052349A1 (fr) 2010-10-22 2012-04-26 Unilever Plc Améliorations se rapportant à des assouplissants pour textile
US9150822B2 (en) 2010-12-03 2015-10-06 Conopco, Inc. Fabric conditioners

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ES2018338B3 (es) 1991-04-01
TR24515A (tr) 1991-11-12
AU614073B2 (en) 1991-08-22
CA1291302C (fr) 1991-10-29
KR880010184A (ko) 1988-10-07
DE3860842D1 (de) 1990-11-29
BR8800833A (pt) 1988-10-04
AU1206788A (en) 1988-09-01
ZA881382B (en) 1989-10-25
EP0280550A2 (fr) 1988-08-31
EP0280550A3 (en) 1989-03-29
KR910009652B1 (ko) 1991-11-25
GB8704711D0 (en) 1987-04-01
JPS63282373A (ja) 1988-11-18
MY103215A (en) 1993-05-29

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