EP0255978A2 - Saure, flüssige Reinigungsmittelzusammensetzung - Google Patents
Saure, flüssige Reinigungsmittelzusammensetzung Download PDFInfo
- Publication number
- EP0255978A2 EP0255978A2 EP87201455A EP87201455A EP0255978A2 EP 0255978 A2 EP0255978 A2 EP 0255978A2 EP 87201455 A EP87201455 A EP 87201455A EP 87201455 A EP87201455 A EP 87201455A EP 0255978 A2 EP0255978 A2 EP 0255978A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- detergent
- active compound
- acid
- composition
- cationic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 30
- 230000002378 acidificating effect Effects 0.000 title claims abstract description 11
- 238000004140 cleaning Methods 0.000 title claims abstract description 11
- 239000007788 liquid Substances 0.000 title claims abstract description 8
- 150000001875 compounds Chemical class 0.000 claims abstract description 13
- 239000002253 acid Substances 0.000 claims abstract description 12
- 125000002091 cationic group Chemical group 0.000 claims abstract description 12
- 230000001419 dependent effect Effects 0.000 claims abstract description 6
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 150000003512 tertiary amines Chemical class 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 2
- 150000002462 imidazolines Chemical class 0.000 claims description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 2
- 239000002562 thickening agent Substances 0.000 claims description 2
- 239000003599 detergent Substances 0.000 abstract description 6
- 239000004615 ingredient Substances 0.000 abstract description 5
- 239000012895 dilution Substances 0.000 abstract description 4
- 238000010790 dilution Methods 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- 239000000975 dye Substances 0.000 description 4
- 235000013162 Cocos nucifera Nutrition 0.000 description 3
- 244000060011 Cocos nucifera Species 0.000 description 3
- HMEKVHWROSNWPD-UHFFFAOYSA-N Erioglaucine A Chemical compound [NH4+].[NH4+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 HMEKVHWROSNWPD-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000002070 germicidal effect Effects 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- 239000004150 EU approved colour Substances 0.000 description 1
- IZWSFJTYBVKZNK-UHFFFAOYSA-O N-dodecyl-N,N-dimethyl-3-ammonio-1-propanesulfonic acid Chemical compound CCCCCCCCCCCC[N+](C)(C)CCCS(O)(=O)=O IZWSFJTYBVKZNK-UHFFFAOYSA-O 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000001045 blue dye Substances 0.000 description 1
- 239000004161 brilliant blue FCF Substances 0.000 description 1
- 235000012745 brilliant blue FCF Nutrition 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- JROAZQFKSSYEBL-YWABOPJLSA-L disodium;5-[(e)-(3-carboxylato-5-methyl-4-oxocyclohexa-2,5-dien-1-ylidene)-(2,6-dichlorophenyl)methyl]-2-hydroxy-3-methylbenzoate Chemical compound [Na+].[Na+].C1=C(C([O-])=O)C(=O)C(C)=C\C1=C(C=1C(=CC=CC=1Cl)Cl)\C1=CC(C)=C(O)C(C([O-])=O)=C1 JROAZQFKSSYEBL-YWABOPJLSA-L 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- ONLRKTIYOMZEJM-UHFFFAOYSA-N n-methylmethanamine oxide Chemical compound C[NH+](C)[O-] ONLRKTIYOMZEJM-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229940006093 opthalmologic coloring agent diagnostic Drugs 0.000 description 1
- 239000007793 ph indicator Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- FJBHGWADYLMEJG-UHFFFAOYSA-M sodium;3-[[4-[[4-(diethylamino)phenyl]-[4-[ethyl-[(3-sulfonatophenyl)methyl]azaniumylidene]cyclohexa-2,5-dien-1-ylidene]methyl]-n-ethylanilino]methyl]benzenesulfonate Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C=CC(=CC=1)N(CC)CC=1C=C(C=CC=1)S([O-])(=O)=O)=C(C=C1)C=CC1=[N+](CC)CC1=CC=CC(S([O-])(=O)=O)=C1 FJBHGWADYLMEJG-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/40—Monoamines or polyamines; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/92—Sulfobetaines ; Sulfitobetaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
Definitions
- Acidic liquid toilet bowl cleaning compositions are well known in the art. They usually consist of an aqueous solution of a strong acid, to which various desirable additives have been added, such as detergent-active compounds, germicides, perfumes, corrosion inhibitors, colouring agents and so on. As detergent-active compounds anionic, nonionic and cationic detergents have been suggested for inclusion in such acidic liquid toilet bowl cleaning compositions. When desired, a pleasing colour is imparted to such compositions by adding a suitable dye, such as a blue dye. Such compositions are particularly effective in removing toilet scale deposits, derived from the water supply to the toilet.
- compositions contain the cationic detergent-active compound in an amount of 0.1-10% by weight. Mixtures of several cationic detergents, as well as of a cationic and a nonionic detergent may also be used.
- the dyestuffs suitable for use according to the present invention are those which undergo a pH-dependent colour change in the acid pH range, i.e. for the present invention in the range of 2-6 in aqueous solution.
- Typical examples of such dyestuffs are the triarylmethane types such as Acid Blue 1 (CI 42045), Acid Blue 9 (CI 42090), Acid Violet 17 (CI 42650) and Mordant Blue 1 (CI 43830).
- the compositions contain from 0.0001-1% by weight of the dyestuff.
- other dyestuffs which do not undergo a pH-dependent colour change may additionally be included so as to achieve a change to a desired colour.
- inorganic acids such as hydrochloric acid, sulphuric acid, nitric acid and sulphamic acid are suitable; the compositions contain the acid in an amount of 0.5-25% by weight.
- the pH of the compositions of the present invention is below 2, and in most useful cases below 1.
- compositions of the invention can be thickened by surfactants, by polymeric materials such as xanthan gums, polyacrylates and by inorganic thickeners such as silicas and clays.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8619391 | 1986-08-08 | ||
| GB868619391A GB8619391D0 (en) | 1986-08-08 | 1986-08-08 | Acidic liquid cleaning composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0255978A2 true EP0255978A2 (de) | 1988-02-17 |
| EP0255978A3 EP0255978A3 (de) | 1989-03-08 |
Family
ID=10602444
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP87201455A Ceased EP0255978A3 (de) | 1986-08-08 | 1987-07-30 | Saure, flüssige Reinigungsmittelzusammensetzung |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0255978A3 (de) |
| JP (1) | JPS6343999A (de) |
| AU (1) | AU607708B2 (de) |
| BR (1) | BR8703992A (de) |
| CA (1) | CA1329751C (de) |
| GB (1) | GB8619391D0 (de) |
| ZA (1) | ZA875848B (de) |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2717108A1 (fr) * | 1994-03-14 | 1995-09-15 | Sgb | Procédé de nettoyage, gamme de produits d'entretien et produits utilisés dans le procédé. |
| EP0754749A1 (de) * | 1995-07-20 | 1997-01-22 | The Procter & Gamble Company | Textilweichmacher, die wasserlösliche Farbstoffe für verringerte Verfärbung enthalten |
| US5691291A (en) * | 1994-10-28 | 1997-11-25 | The Procter & Gamble Company | Hard surface cleaning compositions comprising protonated amines and amine oxide surfactants |
| US5965514A (en) * | 1996-12-04 | 1999-10-12 | The Procter & Gamble Company | Compositions for and methods of cleaning and disinfecting hard surfaces |
| US5990064A (en) * | 1994-10-28 | 1999-11-23 | The Procter & Gamble Company | Compositions and methods for cleaning hard surfaces using protonated amines and amine oxide surfactants |
| WO2003014282A1 (en) * | 2001-08-06 | 2003-02-20 | Colgate-Palmolive Company | Color changing liquid cleaning composition |
| WO2004078896A1 (en) * | 2003-03-05 | 2004-09-16 | Unilever Plc | Method of treating a textile using a colour changing foam |
| WO2005003276A1 (en) * | 2003-06-18 | 2005-01-13 | Unilever Plc | Laundry treatment compositions |
| WO2006041739A1 (en) * | 2004-10-04 | 2006-04-20 | The Procter & Gamble Company | A composition with a metal-complexing dye and surfactant |
| WO2008117235A1 (en) * | 2007-03-26 | 2008-10-02 | The Procter & Gamble Company | Liquid composition system having a visual indication change |
| WO2008117233A1 (en) * | 2007-03-26 | 2008-10-02 | The Procter & Gamble Company | Liquid detergent composition system having a visual indication change |
| US7651989B2 (en) | 2003-08-29 | 2010-01-26 | Kimberly-Clark Worldwide, Inc. | Single phase color change agents |
| US8067350B2 (en) | 2005-12-15 | 2011-11-29 | Kimberly-Clark Worldwide, Inc. | Color changing cleansing composition |
| US20140158166A1 (en) * | 2012-12-10 | 2014-06-12 | Milliken & Company | Cleaning composition and method for using the same |
| WO2017200496A1 (en) | 2016-05-18 | 2017-11-23 | Hayat Kimya Sanayi Anonim Sirketi | Dual purpose cleaning composition for limescale removal |
| US9926519B2 (en) | 2012-06-08 | 2018-03-27 | S. C. Johnson & Son, Inc. | Self-adhesive detergent compositions with color-changing systems |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4743395A (en) * | 1986-09-12 | 1988-05-10 | The Drackett Company | Thickened acid cleaner compositions containing quaternary ammonium germicides and having improved thermal stability |
| JPH01240600A (ja) * | 1988-03-18 | 1989-09-26 | Seiwa Kogyo Kk | トイレ用洗浄剤 |
| GB9000028D0 (en) * | 1990-01-02 | 1990-03-07 | Shell Int Research | Cleaning of equipment used in a liquid phase oxidation process |
| JP4884768B2 (ja) * | 2005-12-28 | 2012-02-29 | 花王株式会社 | 硬質表面用洗浄剤 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1313180A (en) * | 1970-09-23 | 1973-04-11 | Unilever Ltd | Surface active liquids |
| US4016089A (en) * | 1974-11-11 | 1977-04-05 | Regan Glen B | Denture cleaning concentrate |
| US4302253A (en) * | 1980-02-19 | 1981-11-24 | R. T. Vanderbilt Company, Inc. | Thickeners for acid cleaning compositions |
-
1986
- 1986-08-08 GB GB868619391A patent/GB8619391D0/en active Pending
-
1987
- 1987-07-30 EP EP87201455A patent/EP0255978A3/de not_active Ceased
- 1987-07-30 CA CA000543417A patent/CA1329751C/en not_active Expired - Fee Related
- 1987-08-04 AU AU76549/87A patent/AU607708B2/en not_active Ceased
- 1987-08-04 JP JP62195144A patent/JPS6343999A/ja active Pending
- 1987-08-06 BR BR8703992A patent/BR8703992A/pt not_active Application Discontinuation
- 1987-08-07 ZA ZA875848A patent/ZA875848B/xx unknown
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2717108A1 (fr) * | 1994-03-14 | 1995-09-15 | Sgb | Procédé de nettoyage, gamme de produits d'entretien et produits utilisés dans le procédé. |
| US5691291A (en) * | 1994-10-28 | 1997-11-25 | The Procter & Gamble Company | Hard surface cleaning compositions comprising protonated amines and amine oxide surfactants |
| US5990064A (en) * | 1994-10-28 | 1999-11-23 | The Procter & Gamble Company | Compositions and methods for cleaning hard surfaces using protonated amines and amine oxide surfactants |
| EP0754749A1 (de) * | 1995-07-20 | 1997-01-22 | The Procter & Gamble Company | Textilweichmacher, die wasserlösliche Farbstoffe für verringerte Verfärbung enthalten |
| US5965514A (en) * | 1996-12-04 | 1999-10-12 | The Procter & Gamble Company | Compositions for and methods of cleaning and disinfecting hard surfaces |
| WO2003014282A1 (en) * | 2001-08-06 | 2003-02-20 | Colgate-Palmolive Company | Color changing liquid cleaning composition |
| WO2004078896A1 (en) * | 2003-03-05 | 2004-09-16 | Unilever Plc | Method of treating a textile using a colour changing foam |
| WO2005003276A1 (en) * | 2003-06-18 | 2005-01-13 | Unilever Plc | Laundry treatment compositions |
| US7858568B2 (en) | 2003-08-29 | 2010-12-28 | Kimberly-Clark Worldwide, Inc. | Single phase color change agents |
| US7651989B2 (en) | 2003-08-29 | 2010-01-26 | Kimberly-Clark Worldwide, Inc. | Single phase color change agents |
| WO2006041739A1 (en) * | 2004-10-04 | 2006-04-20 | The Procter & Gamble Company | A composition with a metal-complexing dye and surfactant |
| US7550422B2 (en) | 2004-10-04 | 2009-06-23 | The Procter & Gamble Company | Composition with a metal-complexing dye and surfactant |
| US8067350B2 (en) | 2005-12-15 | 2011-11-29 | Kimberly-Clark Worldwide, Inc. | Color changing cleansing composition |
| WO2008117233A1 (en) * | 2007-03-26 | 2008-10-02 | The Procter & Gamble Company | Liquid detergent composition system having a visual indication change |
| WO2008117235A1 (en) * | 2007-03-26 | 2008-10-02 | The Procter & Gamble Company | Liquid composition system having a visual indication change |
| US9926519B2 (en) | 2012-06-08 | 2018-03-27 | S. C. Johnson & Son, Inc. | Self-adhesive detergent compositions with color-changing systems |
| US20140158166A1 (en) * | 2012-12-10 | 2014-06-12 | Milliken & Company | Cleaning composition and method for using the same |
| WO2014092865A3 (en) * | 2012-12-10 | 2014-09-12 | Milliken & Company | Cleaning composition and method for using the same |
| US9688946B2 (en) | 2012-12-10 | 2017-06-27 | Milliken & Company | Cleaning composition and method for using the same |
| WO2017200496A1 (en) | 2016-05-18 | 2017-11-23 | Hayat Kimya Sanayi Anonim Sirketi | Dual purpose cleaning composition for limescale removal |
Also Published As
| Publication number | Publication date |
|---|---|
| BR8703992A (pt) | 1988-04-05 |
| GB8619391D0 (en) | 1986-09-17 |
| CA1329751C (en) | 1994-05-24 |
| AU7654987A (en) | 1988-02-11 |
| AU607708B2 (en) | 1991-03-14 |
| EP0255978A3 (de) | 1989-03-08 |
| ZA875848B (en) | 1989-04-26 |
| JPS6343999A (ja) | 1988-02-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
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| 17P | Request for examination filed |
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| 17Q | First examination report despatched |
Effective date: 19900430 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN REFUSED |
|
| 18R | Application refused |
Effective date: 19920606 |
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| RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: STIRLING, THOMAS |