EP0243451A1 - Procede de formation d'un revetement resistant a l'abrasion sur un substrat transparent - Google Patents

Procede de formation d'un revetement resistant a l'abrasion sur un substrat transparent

Info

Publication number
EP0243451A1
EP0243451A1 EP19860906572 EP86906572A EP0243451A1 EP 0243451 A1 EP0243451 A1 EP 0243451A1 EP 19860906572 EP19860906572 EP 19860906572 EP 86906572 A EP86906572 A EP 86906572A EP 0243451 A1 EP0243451 A1 EP 0243451A1
Authority
EP
European Patent Office
Prior art keywords
substrate
aluminum oxide
intensity level
deposited
abrasion resistant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP19860906572
Other languages
German (de)
English (en)
Inventor
Ronald Alfred Ferrante
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NCR Voyix Corp
Original Assignee
NCR Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NCR Corp filed Critical NCR Corp
Publication of EP0243451A1 publication Critical patent/EP0243451A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/08—Oxides
    • C23C14/081—Oxides of aluminium, magnesium or beryllium
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • C03C17/23—Oxides
    • C03C17/245—Oxides by deposition from the vapour phase
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/20—Materials for coating a single layer on glass
    • C03C2217/21—Oxides
    • C03C2217/214—Al2O3
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00—Methods for coating glass
    • C03C2218/10—Deposition methods
    • C03C2218/15—Deposition methods from the vapour phase
    • C03C2218/151—Deposition methods from the vapour phase by vacuum evaporation

Definitions

  • This invention relates to a coating process and more particularly to a process for coating a glass substrate in order to improve the abrasion resistant characteristic of the surface of the glass substrate.
  • coded labels are attached to merchandise items such as cans of food or the like for use in processing the purchase of such items.
  • the coded label contains data which is used in retrieving from a price look-up table the price of the item to which the coded label is attached.
  • optical scanner devices have been incorporated into the check-out counters found in such check-out systems, in which a scanning light beam is projected through a transparent window located in the surface of the counter for scanning the coded label on the merchandise item being purchased. Movement of the merchandise item past the transparent window results in the reading of the coded label.
  • the transparent window which normally takes the form of a glass or plastic substrate, becomes scratched as a result of the movement of the can across the surface of the substrate, which interferes with the scanning light beam resulting in the generation of invalid scanning readings. This condition has limited the life of the glass window, thereby producing high maintenance cost as a result of replacing the window.
  • windows composed of a sapphire sheet-glass laminate have been used to eliminate this scratching condition since the hardness of the sapphire is much greater than any material commonly used in the packaging of merchandise items. Such windows are very expensive and therefore are limited to relatively small window dimensions. Less expensive coatings such as aluminum phosphate or other types of metallic coating applied to a transparent substrate have been used. However each of these coatings tends to exhibit low optical quality and high light absorption together with scattering of the light beams as they are transmitted through the coating. The scattering diminishes the effectiveness of the light beam in scanning the coded label.
  • a method for forming an abrasion resistant coating on a transparent substrate including the steps of: mounting a transparent substrate within a vacuum on a support member; positioning a body of aluminum' oxide material adjacent the substrate, the body having a planar surface facing the substrate; and directing a first stream of energy beams having a first intensity level at the planar surface of the body of aluminum oxide to raise the temperature of the body of aluminum oxide, enabling the molecules of aluminum oxide to be deposited on the surface of the substrate; characterized by directing a second stream of energy beams having a second intensity level at the surface of the substrate for providing a uniform surface of the aluminum oxide deposited on the substrate.
  • the preferred method of fabricating an abrasion resistant transparent substrate in which a thin film of aluminum oxide is applied to the surface of the substrate includes the steps of bombarding an aluminum oxide target with argon ion beams, thereby causing the ejection of oxide molecules from the target surface for deposit on a rotating transparent substrate positioned adjacent the oxide target.
  • a first argon-ion sputtering gun which is directed at the target of the substrate, is used in sputtering the molecules of the target of aluminum oxide located within a vacuum chamber for deposit on the surface of the substrate.
  • a second argon-ion sputtering gun is used to form a relatively uniform surface on the substrate after the aluminum oxide has been deposited thereon by the first gun.
  • the first ion gun is operated at an intensity level of 800-1000eV while the second gun is operated at an intensity level of 20- lOOeV.
  • Fig. 1 is a perspective view of a portion of a check-out counter showing the general arrangement of an optical scanner assembly
  • Fig. 2 is a schematic diagram of the ion gun arrangement for the deposition of the aluminum oxide on the glass substrate;
  • Fig. 3 is an enlarged sectional view of the substrate manufactured according to the present invention, showing the crystalline structure of the initial deposition of aluminum oxide on the glass substrate.
  • Fig. 4 is another enlarged sectional view of the substrate showing the crystalline structure of the finished layer of aluminum oxide.
  • Fig. 1 there is shown a perspective view of a portion of a typical check-out counter found in a merchandise check-out system in which is located an optical scanner assembly for scanning a coded label on a merchandise item purchased by a customer.
  • the system includes a light source 20 emitting an optical scanning light beam 22 in the visible or near infrared spectrum, the light beam being directed through a transparent substrate 24 which may take the form of a glass or plastic window which is mounted flush with the " supporting surface 26 of the check-out counter generally indicated by the numeral 28.
  • the light source 20 may. be a helium neon laser that is pumped to produce a continuous laser scanning beam 22 of monochromatic light of approximately 6328 angstroms wavelength.
  • the light beam 22 produced by the source 20 may be focused by a lens system 30 onto a multi-faced mirror 32.
  • the mirror 32 is mounted on the shaft 34 of a motor 36 which rotates the mirror 32 at a substantially constant speed.
  • the mirror 32 is positioned to intercept the light beam 22 and project same through the substrate 24 to scan encoded indicia located on a label 38 affixed to a merchandise item 40, the encoded indicia comprising a plurality of black and white coded areas (not shown) representing data concerning the identity of the merchandise item.
  • the rotation of the mirror 32 causes a succession of light beams 22 to scan any encoded label 38 positioned over the substrate 24.
  • the light beams 22 are reflected off the label 38 and back through the substrate 24 and an optical filter 42 to a photo- responsive pick-up device such as a photo-multiplier 44 which converts the reflective light beams into electrical signals in a manner that is well-known in the art. Movement of the merchandise item 40 across the substrate 24 enables the light beams 22 to scan the complete label 38. If the merchandise item 40 is a metal container, it has been found that the glass window 24 becomes scratched and pitted, thereby interfering with the scanning of the label 28 by scattering the light beams 22 as they are projected through the window 24, thus preventing the scanning system from properly reading the label.
  • a protective thin film layer of aluminum oxide (AI2O3) on a suitable transparent substrate such as glass, the above disadvantages can be overcome.
  • a glass substrate 41 is mounted on a rotatably mounted support member 43 which in turn is secured to the shaft 45 of a motor 46, all of which are positioned within a vacuum chamber 47.
  • the atmosphere within the chamber 47 is a mixture of oxygen and argon gas with the oxygen comprising 30-40% of the mixture.
  • the motor 46 will rotate the support member 43 when operated.
  • a target 48 composed of solid aluminum oxide is mounted adjacent the support member 43 and has a planar surface portion 49 which is orientated at a predetermined angle to the substrate 41.
  • the target 48 is bombarded with ion beams 50 generated by an argon-ion sputtering gun 52.
  • the gun 52 is operated at an intensity level of between 800-1000 eV, plus or minus 10 eV.
  • the ion beams 50 from the gun 52 will, upon striking the target 48, impart energy to the surface molecules of the target, thereby heating the target to a temperature of between 10 and 150 degrees C, causing the molecules to be sputtered or ejected from the material, which molecules are then deposited on the rotating glass substrate 41.
  • the molecules of aluminum oxide are deposited on the glass substrate 41 in the form of a filamentary layer structure 54 whose filament structure 56 results in reduced hardness and film strength.
  • the substrate 41 is bombarded with ion beams 58 from a second argon-ion sputtering gun 60 (Fig. 2) which is operated at an energy level of between 20-100 eV plus or minus 10 eV, which operation disrupts the growth of the filaments 56 in the layer structure 54.
  • This bombardment allows aluminum oxide to form between the filaments 56 resulting in a relatively uniform surface 62 (Fig. 4) whose index of refraction approximates that of aluminum oxide bulk material, thereby increasing the hardness of the structure 54.
  • the glass substrate 41 and the layer structure 54 have similar indices of refraction to eliminate any reflection losses of the light beams as they travel through the layered substrate 41.
  • the bombardment of the target 48 and the substrate 41 takes place in a vacuum of 1 X 10 -4 to 92 x 10 ⁇ 7 Torr. It has been found that with this method, the index of refraction of the deposited layer is between 1.71 and 1.73, which is close to that of bulk sapphire, which is 1.77.
  • the glass substrate 42 is constructed to have a similar index.
  • the crystalline structure 54 does not have an index of refraction close to 1.77, while the substrate 41 has such an index, the hardness and durability of the deposited film are greatly reduced, together with increasing the attenuation of the scanning light beams as they pass through the substrate, thereby producing errors in the reading operation of the scanning device. It has been found that with an ion energy output of 600 eV from the first gun 52, the resulting thickness of the crystalline structure 54 is between .5 and 1.5 microns, with the aluminum oxide atoms being deposited on the substrate 41 at a rate of approximately 4 angstroms per minute.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Physical Vapour Deposition (AREA)
  • Surface Treatment Of Glass (AREA)

Abstract

Le procédé de dépôt d'un revêtement résistant à l'abrasion (54) sur un substrat transparent (41) consiste à diriger un premier courant d'ions argon (50) sur une cible en oxyde d'aluminium (48), en augmentant ainsi la température de l'oxyde d'aluminium jusqu'à ce que des molécules d'oxyde d'aluminium soient libérées pour se déposer sur un substrat transparent rotatif (41) positionné à proximité de la cible (48). Un deuxième courant d'ions argon (58) est appliqué sur l'oxyde d'aluminium déposé pour rendre uniforme la surface de la couche d'oxyde d'aluminium déposé (54). Le premier courant d'ions (50) appliqué sur la cible en oxyde d'aluminium agit à un niveau d'intensité supérieur au niveau d'intensité du deuxième courant d'ions (58) appliqué sur la couche d'oxyde d'aluminium déposé (54). Un substrat en verre (24) pourvu d'un revêtement résistant à l'abrasion appliqué par le procédé ci-décrit peut être utilisé dans un guichet de contrôle de sortie (28) pour servir de support pour les marchandises (40) balayées par un scanner optique (42, 44).
EP19860906572 1985-10-31 1986-10-09 Procede de formation d'un revetement resistant a l'abrasion sur un substrat transparent Withdrawn EP0243451A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US79350785A 1985-10-31 1985-10-31
US793507 1985-10-31

Publications (1)

Publication Number Publication Date
EP0243451A1 true EP0243451A1 (fr) 1987-11-04

Family

ID=25160070

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19860906572 Withdrawn EP0243451A1 (fr) 1985-10-31 1986-10-09 Procede de formation d'un revetement resistant a l'abrasion sur un substrat transparent

Country Status (3)

Country Link
EP (1) EP0243451A1 (fr)
JP (1) JPS63501223A (fr)
WO (1) WO1987002713A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5527596A (en) * 1990-09-27 1996-06-18 Diamonex, Incorporated Abrasion wear resistant coated substrate product
US5637353A (en) * 1990-09-27 1997-06-10 Monsanto Company Abrasion wear resistant coated substrate product
US5643423A (en) * 1990-09-27 1997-07-01 Monsanto Company Method for producing an abrasion resistant coated substrate product

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8719794D0 (en) * 1987-08-21 1987-09-30 Scient Coatings Uk Ltd Depositing surface layers on substrates
GB2252333B (en) * 1991-01-29 1995-07-19 Spectra Physics Scanning Syst Improved scanner window
US5234769A (en) * 1992-04-16 1993-08-10 Deposition Sciences, Inc. Wear resistant transparent dielectric coatings
FR2699164B1 (fr) * 1992-12-11 1995-02-24 Saint Gobain Vitrage Int Procédé de traitement de couches minces à base d'oxyde ou de nitrure métallique.
US20140272346A1 (en) * 2013-03-15 2014-09-18 Rubicon Technology, Inc. Method of growing aluminum oxide onto substrates by use of an aluminum source in an oxygen environment to create transparent, scratch resistant windows
EP2778252A3 (fr) * 2013-03-15 2014-12-10 Apple Inc. Revêtements en couches pour structure de saphir

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1237400C2 (de) * 1961-04-17 1967-10-12 Siemens Ag Verfahren zum Vakuumaufdampfen eines feuchtigkeitsfesten isolierenden UEberzuges aufHalbleiterbauelemente, insbesondere auf Halbleiterbauelemente mit pn-UEbergang
FR1493822A (fr) * 1966-08-30 1967-09-01 Temescal Metallurgical Corp Article résistant à l'abrasion et son procédé de fabrication
JPS57188673A (en) * 1981-05-14 1982-11-19 Toshiba Corp Formation of thin film by vacuum
JPS59170270A (ja) * 1983-03-15 1984-09-26 Toshiba Corp 膜形成装置

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO8702713A1 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5527596A (en) * 1990-09-27 1996-06-18 Diamonex, Incorporated Abrasion wear resistant coated substrate product
US5635245A (en) * 1990-09-27 1997-06-03 Monsanto Company Process of making abrasion wear resistant coated substrate product
US5637353A (en) * 1990-09-27 1997-06-10 Monsanto Company Abrasion wear resistant coated substrate product
US5643423A (en) * 1990-09-27 1997-07-01 Monsanto Company Method for producing an abrasion resistant coated substrate product
US5844225A (en) * 1990-09-27 1998-12-01 Monsanto Company Abrasion wear resistant coated substrate product

Also Published As

Publication number Publication date
WO1987002713A1 (fr) 1987-05-07
JPS63501223A (ja) 1988-05-12

Similar Documents

Publication Publication Date Title
US5594231A (en) Scanner window
EP0039125B1 (fr) Article optique et procédé
NL194912C (nl) Bekleed glasmateriaal.
US4828346A (en) Transparent article having high visible transmittance
NL194913C (nl) Bekleed glasmateriaal.
US4497700A (en) Method of coating a transparent substrate
US5135808A (en) Abrasion wear resistant coated substrate product
US4846551A (en) Optical filter assembly for enhancement of image contrast and glare reduction of cathode ray display tube
US5268217A (en) Abrasion wear resistant coated substrate product
EP0243451A1 (fr) Procede de formation d'un revetement resistant a l'abrasion sur un substrat transparent
US2519722A (en) Metallic mirror and method of making same
US20100215950A1 (en) Glass or glass-ceramic substrate with scratch-resistant coating and method for the production thereof
US20020009621A1 (en) Durable sputtered metal oxide coating
EP1913170A2 (fr) Procede de depot d'une couche anti-rayure
JPH08510415A (ja) 銀／銅被覆を有する微小プリズム後方反射シート材料
GB2331764A (en) Optical monitoring of sputtering
JPH07182709A (ja) 光磁気記録媒体
IE57107B1 (en) Rear-view mirror for vehicles,particularly motor vehicles,having a coating on the rear face
CN110612001A (zh) 多色介电涂层及uv喷墨打印
US5037521A (en) Sputtering apparatus
JPS585855B2 (ja) 半反射ガラス
US3935458A (en) Method for monitoring the surface resistivity of metallized film
JP2908458B2 (ja) 分光フイルター
Kume et al. A new method of surface plasmon excitation using metallic fine particles
JP2019035885A (ja) 反射鏡、測距装置、及び反射鏡の製造方法

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): DE FR GB

17P Request for examination filed

Effective date: 19871023

DET De: translation of patent claims
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 19890503

RIN1 Information on inventor provided before grant (corrected)

Inventor name: FERRANTE, RONALD, ALFRED