Classifications

• • C—CHEMISTRY; METALLURGY
  • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
  • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
  • C23F13/00—Inhibiting corrosion of metals by anodic or cathodic protection
  • C23F13/02—Inhibiting corrosion of metals by anodic or cathodic protection cathodic; Selection of conditions, parameters or procedures for cathodic protection, e.g. of electrical conditions
  • C23F13/06—Constructional parts, or assemblies of cathodic-protection apparatus
  • C23F13/08—Electrodes specially adapted for inhibiting corrosion by cathodic protection; Manufacture thereof; Conducting electric current thereto
  • C23F13/10—Electrodes characterised by the structure
• • C—CHEMISTRY; METALLURGY
  • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
  • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
  • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
  • C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
  • C25B11/03—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
• • C—CHEMISTRY; METALLURGY
  • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
  • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
  • C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
  • C25C7/02—Electrodes; Connections thereof
• • C—CHEMISTRY; METALLURGY
  • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
  • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
  • C23F2201/00—Type of materials to be protected by cathodic protection
  • C23F2201/02—Concrete, e.g. reinforced

Definitions

• This invention relates generally to cathodic protection systems for steel-reinforced concrete structures such as bridge decks, parking garage decks, piers and supporting pillars therefor, as well as to methods of installation of such systems.
• chloride ions whether contained in deicing salt, in sea water, or added to fresh concrete, destroy the ability of concrete to keep the surface of the steel in a passive state. It has been determined that a chloride concentration of 0.6 to 0.8 Kg per cubic meter of concrete is the critical value above which corrosion of steel in concrete can occur. The resulting corrosion products occupy 2.5 times the volume of the original steel, and this exerts tensile stresses on the surrounding concrete. When these stresses exceed the tensile strength of the concrete, cracking and delaminations develop. With continued corrosion, freezing and thawing, and traffic load, further deterioration occurs and potholes develop.
• the conductive overlay was the first anode to be used and is still regarded as a useful system.
• the anode typically consists of a mixture of asphalt, metallurgical coke breeze, and aggregate in conjunction with high silicon cast iron serving as the current contact.
• This system provides very uniform current distribution over the deck surface, and because the anode surface area is high, no evidence of acid or other chemical attack from anodic reaction products has been found on the underlying portland cement.
• the coke-asphalt overlay has exhibited structural degradation in a number of instances, however, and the time to replacement is limited to a few years. Also, freeze-thaw deterioration of improperly air-entrained concrete beneath the overlay has limited its use to decks with proper air-void systems.
• Slotted non-overlay anodes were developed to extend anode life and applicability, and to realize a system which would not increase the dead load and height of the bridge deck.
• parallel slots are first cut into the deck approximately 30-45 cm. apart.
• the slots are filled with a "conductive grout" mixture of carbon and organic resin which serves as the anode surface. Because the conductive grout has a limited conductivity, current is distributed to the anode by a system of platinized metal and carbon strand conductors. This anode exhibited adequate strength and freeze-thaw durability, but because its surface area is small, the adjacent concrete often experiences attack from the acid and gases which are a product of the anodic reaction. Also, distribution of current to the reinforcing steel is not ideal since the slots are widely separated.
• An alternative anode for use with rigid ion-conductive overlays utilizes a flexible polymeric anode material which does not require a conductive backfill. It is produced as a continuous cable and woven into a large mesh, placed on the deck and covered with a conventional rigid overlay. This system is less time consuming to install, but still has the disadvantages of current distribution, acid or gas attack, and lack of redundancy.
• Such polymer anodes have been described in U.S. Patents 4,473,450 and 4,502,929. As commercially offered, these polymer anodes are woven into a mesh with voids measuring about 20 cm. by 40 cm. Any breakage of the cable at a given point will thus impair the cathodic protection effect over a considerable area.
• a fourth type of system has more recently evolved for use on substructures in which the anode material is painted or sprayed directly on the concrete surface. For example, carbon loaded paints and mastics can be applied to the concrete. This provides a large anode area and ideal current distribution to the reinforcing steel. Additional platinized wire or carbon strand current connectors are needed, however, since the resistivity is high, and the anode material often peels off resulting in a short lifetime.
• published UK Patent Application 2 140 456A describes a conductive overlay system in which a conductive paint is applied to the surface of concrete to form an anode film. Primary anodes of platinized titanium or niobium are spaced apart each 10 - 50 meters for the supply of current to the anode film and thus serve essentially as current lead-ins.
• carbon Since pure carbon is not available in a structure which would be suitable for use in concrete, carbon was used as a conductive filler in organic resins, thermoplastic polymers, paints, and mastics. This technique put carbon into a physical form which could be used in conjunction with concrete, but other disadvantages of carbon remain. Carbon has a low electrical conductivity relative to metals, requiring an elaborate system of current conductors. Also, carbon is thermodynamically unstable as an anode, reacting to form carbon dioxide CO-, carbonic acid H_CO , and carbonates HCO ⁇ and CO_ ⁇ , reaction products which are potentially harmful to portland cement.
• Electrocatalytically active anodes with valve metal substrates are known and have been successfully used in a number of applications, in particular chlorine, chlorate and hypochlorite production and as oxygen-evolving anodes in metal winning processes.
• the cost of such electrodes makes them particularly advantageous in "high" current density applications, e.g., 6 - 10 KA/m 2 for chlorine production in a mercury cell or 3 - 5 KA/m 2 in a membrane cell.
• Such electrodes have also been proposed for cathodic protection, but have found only limited applications in this area. In one typical cathodic protection arrangement, a wire of platinized copper-cored titanium is used to protect a metal structure.
• PCT Application WO80/01488 described such an arrangement in which the platinized wire is wound around an insulating rope.
• UK Patent Application 2 000 808A proposed replacing the conventional platinized wires or rods with a channel-sectioned valve metal strip having anodically active material on the U or V-shaped spine.
• Platinized valve metal meshes have also been proposed for cathodic protection of certain structures. See for example "Corrosion/79" paper number 194 which describes use of a rigid titanium expanded mesh measuring less that 2 0.05 m and coated with a layer of 1 - 15 micron of platinum capable of carrying a current density of 2.15
• U.S. 4,519,886 describes a linear type of anode structure for the cathodic protection of metal structures comprising a plurality of cylindrical anode segments spaced along and connected to a power supply cable.
• the cylindrical anode segments may be made of expanded titanium bent to shape and coated with a mixed metal oxide coating.
• none of the known coated valve metal electrodes including those proposed for other cathodic protection applications would be suitable for the cathodic protection of concrete structures.
• the anode designs are unsuitable for installation in this application and the cost of protecting an installation would be prohibitive.
• One main aspect of the invention as set out in the accompanying claims is a novel cathodically-protected steel-reinforced concrete structure comprising an impressed-current anode embedded in an ion-conductive overlay on the concrete structure, wherein the anode comprises at least one sheet of valve metal mesh having a pattern of voids defined by a network of valve metal strands.
• the strands of each mesh are connected at a multiplicity of nodes providing a redundancy of current-carrying paths through the mesh which ensures effective current distribution throughout the mesh even in the event of possible breakage of a number of individual strands.
• the surface of the valve metal mesh carries an electrochemically active coating.
• the anode comprises at least one current distribution member for supplying current to the valve metal mesh.
• the sheet or sheets of the valve metal mesh extend essentially continuously over an entire area of the structure to be protected with no discontinuity (i.e. between two adjacent sheets of the mesh) which is larger, in two mutually perpendicular directions, than twice the largest dimension of the voids of the mesh.
• the entire area of the structure to be protected, excluding non-protected openings for obstacles and the like, is covered by a single piece of the mesh, or several pieces in close proximity with one another.
• the mesh consists of a sheet of expanded valve metal, typically titanium and with a maximum thickness of 0.125 cm, which has been expanded by a factor of at least 10 times and preferably 15 to 30 times.
• This provides a substantially diamond shaped pattern of voids and a continuous network of valve metal strands interconnected by between about 500 to 2000 nodes per square meter of the mesh.
• Such a mesh is highly flexible and can be made in sheets of large dimensions which are conveniently coiled about an axis parallel to the long way of the diamond pattern. Further details of the coiled, highly expanded valve metal mesh and its method of production are given in concurrently filed Application
• valve metal mesh constructed of valve metal ribbons connected together, e.g., by welding typically in a hexagonal or honeycomb pattern.
• a composite mesh should meet up to the same requirements concerning its dimensions and configuration as set out above for the expanded meshes.
• Each current distribution member is preferably a strip of valve metal coated with the same electrochemically active coating as the mesh and is metallurgically bonded to the mesh.
• the current distributor strips may advantageously be bonded to the mesh with a spacing of between about 10 and 50 meters, calculated to provide an adequate current density to the mesh.
• the current distributor strips are spot welded to the nodes of the mesh. This spot welding can be achieved on the facing surfaces of the mesh and strip which are coated with an adequately thin electrocatalytic coating. Points of the mesh may be fixed to the concrete structure by fasteners inserted in drill holes in the structure. Alternative means of fixing the mesh to the structure prior to applying the ion-conductive overlay are also possible, including the use of adhesive. This will be more fully described in connection with the installation procedure.
• At least two sheets of the mesh may overlap with one another, either overlapping edges of two side-by-side long sheets which may assist in reducing the number of anchorage points during assembly, or overlapping end sections where the overlap may be designed to provide electrical connection.
• the sheets do not have to be in touching relationship but may be spaced apart conveniently up to a spacing corresponding to about the maximum size (LWD) of the usually diamond shaped apertures of the mesh.
• At least one sheet of the mesh may have a cut-out section bounding an obstacle on the structure, such as a drain in a parking garage deck or an aperture through the deck for connection of the current distributors to a current supply.
• the ion-conductive layer comprises about 3-6 cm thick of portland current or polymer-modified concrete applied in a single pass e.g. by pouring.
• the overlay is preceded by the application of a bonding grout, i.e. a separate cement-based grout without large aggregate which is mixed-up, poured on the surface and brushed over the mesh immediately before overlay.
• the cathodically-protected structure according to the invention preferably also has a current supply connected to the current distributors and arranged to supply a cathodic protection current at a current density of up to
• the current distributor strip may conveniently extend through an aperture in the deck to a current supply disposed underneath the deck at a location where it is readily accessible for servicing etc.
• the protected structure may be an e.g. cylindrical pillar which is encased with the mesh and ion-conductive overlay.
• the current distributor may in this case be a strip disposed vertically on the pillar and the mesh is one or more sheets cut to size so that it is wrapped around the pillar with little or no overlap.
• the invention also pertains to a method of cathodically protecting the aforementioned structure by supplying a continuous or intermittent current to the valve metal mesh at a current density, usually below 100
• This current density can be established by taking periodic measurements of the corrosion potential of the steel using suitably distributed reference electrodes in the proximity of the reinforcing steel, and setting the operative current density to maintain the steel at a desired potential for preventing corrosion.
• the reference electrodes are very advantageously also constructed of a valve metal mesh with an electrocatalytic coating. However, these reference electrodes will be relatively small, for example about 1-3 cm wide by 2-10 cm long, and are preferably made of a conventional valve metal mesh which is quite rigid.
• reference electrodes are placed horizontally in recesses in the concrete structure at the same level as the steel reinforcement and spaced horizontally by about 2-3 cm from the steel; in this location they are favorably placed in the electric field and are exposed to an electrolyte composition representative of the corrosive environment around the steel. In most structures the steel is located about 3 to 10 cm below the concrete surface. Typically one or two reference electrodes are arranged for each
• the electrocatalytic coating on the reference electrodes may be the same as that on the anode mesh, or it can have a special formulation selected to produce oxygen evolution at a precise reference potential.
• These coated valve metal reference electrodes have considerable advantages over the heretofore used reference electrodes. For instance, the potential of this reference electrode is not dependent on the concentration of an ionic species which may vary greatly in the electrolyte, as is the case with silver/silver chloride and copper/copper sulfate reference electrodes. Nor is the potential subject to change due to a reaction of the electrode surface, as is the case with a molybdenum/molybdenum oxide reference electrode.
• non-corroding valve metal titanium
• the system involve no carbon or corrodable metals such as copper.
• the fine mesh structure of the anode insures uniform current distribution.
• the anode mesh has thousands of interconnected strands serving as multiple current paths. These assure that the system will continue to operate satisfactorily even if several strands are broken due to stresses in the structure or future coring.
• the electrocatalytic coating used in the present invention is such that the anode operates at a very low single electrode potential, and may have a life expectancy of greater than 20 years in a cathodic protection application. Unlike other anodes used heretofore for the cathodic protection of steel in concrete, it is completely stable dimensionally and produces no carbon dioxide or chlorine from chloride contaminated concrete. It furthermore has sufficient surface area such that the acid generated from the anodic reaction will not be detrimental to the surrounding concrete.
• Another main aspect of the invention as set out in the accompanying claims is a novel method of installing a coated valve metal electrode as impressed-current anode in a cathodic protection system for a steel-reinforced concrete structure.
• valve metal mesh consists of a network of valve metal strands connected at a multiplicity of nodes providing a redundancy of current-carrying paths through the mesh which provide effective current distribution throughout the mesh even in the event of possible breakage of a number of individual strands. It is greatly preferred that this valve metal mesh consists of a sheet of highly expanded valve metal with a pattern of voids having on its surface an electrochemically active coating, as set out above.
• the coiled mesh may have at least one valve metal current distribution member metallurgically bonded thereto and extending generally parallel to the axis of the roll.
• current distribution members may be bonded to the mesh on-site, i.e. after unrolling.
• the basic principle of the installation method according to the invention is that one or more rolls of the coated valve metal mesh are unrolled and installed in conformity with the concrete structure to be protected, the valve metal mesh is fixed to the structure and the fixed valve metal mesh is embedded in an ion-conductive overlay.
• a current-distribution member may be metallurgically bonded to the rolled mesh, i.e. prior to installation. This is particularly suitable for relatively small concrete structures such as supporting pillars. Such a current distribution member may be welded to the mesh prior to coating the mesh, or welding could take place on-site after unrolling the coated mesh and cutting it to size and before installing the mesh on the structure.
• a preferred installation procedure involves unrolling two or more rolls of the mesh side-by-side and then connecting the meshes electrically by a common transverse current distributor strip which extends across the side-by-side meshes.
• this is achieved by laying current distributor strips on a generally flat structure to be protected.
• the strips of coated valve metal are spaced apart by a suitable distance calculated according to the desired current-carrying capacity of the system typically within the range from 15 to 50 meters. These strips are laid transverse to the direction of unrolling of the rolls.
• the first roll is unrolled and the mesh is spot welded at its nodes to the transverse strips prior to or, preferably, after fixing the mesh to the structure.
• the second roll of mesh is unrolled and welded to the transverse strips, and so on, until the entire structure is covered.
• the mesh can first be unrolled onto the ground. Then current distributor strips are welded and the sheets of mesh are cut to size and, if appropriate, joined by welding. Next, the mesh with current distributor can be applied to the surface of the structure and conformed to this structure. This operation may include wrapping around curved surfaces, bending around corners, bending the mesh in its own plane, e.g. to fit a spiral surface, and stretching of the mesh as needed prior to fixing it by adequate means.
• Various methods of fixing the mesh to the structure have been implemented successfully for different structures.
• One method involves drilling holes in the concrete and inserting fasteners of suitable shape which firmly hold the mesh down.
• the mesh is secured by an adhesive e.g. by applying a hot melt adhesive to nodes of the mesh and holding the mesh to the surface for example using a PTFE-coated steel heat sink. Hot melt adhesive cured in this manner sets in about 10 seconds.
• a snap-clip is secured by epoxy to the surface underneath a node of the mesh. After the epoxy has set, the hinged top of the clip is snapped down to fix the mesh. It is also possible to combine these methods, by drilling holes and inserting fasteners at some locations and by using adhesives at other locations.
• the unrolled mesh Prior to fixing, the unrolled mesh is preferably stretched longitudinally and/or laterally in order to improve its flatness and in particular to avoid any bulges. Generally a longitudinal stretching of up to about 10% increase in its nominal SWD dimension will be quite adequate. Because of the presence of the transverse current distributor strips, it is not necessary for the sides of adjacent meshes to contact one another or be welded together. In fact, a spacing of up to about 1 LWD dimension is quite satisfactory. Nevertheless, for structures requiring a large number of fastening points of the mesh e.g. if the surface is uneven or if for structural reasons the ion-conductive overlay must be very thin, it can be expedient to have the sides of the adjacent meshes slightly overlapping. This reduces the number of necessary fixing points.
• the end of one unrolled mesh may overlap with the next adjacent section to provide electrical connection, or the sections could be welded together or connected by a weld strip for this purpose. This is only necessary when the end section is of insufficient length to be connected to its own transverse current distribution strip.
• electrical connection is provided by overlap, firm fixing of the overlapping sections to the underlying surface is advantageous.
• the ion-conductive layer comprises about 3-6 cm thick of portland current or polymer-modified concrete applied in a single pass eg by spraying.
• the overlay is preceded by the application of a bonding grout, i.e. a separate cement-based grout without large aggregate which is mixed-up, poured on the surface and brushed over the mesh immediately before overlay.
• the ion-conductive overlay can be applied in several thin layers.
• the mesh may be substantially embedded by the first layer: for example more than 90% of the mesh may be covered. At this point, it is possible to identify protruding sections of the mesh and flatten and/or trim these before applying the next layer or layers.
• An advantage of the invention which typically employs a mesh having strands up to 0.125 cm thick is that it can be effectively used in an overlay as thin as 6 mm. This cannot be achieved effectively with any other known system.
• the described method of installation of a cathodic protection system according to the invention has many advantages. The installation method is easy to perform, is not labor intensive and can be adapted easily to structures of different shapes and dimensions.
• valve metal anode mesh By employing a valve metal anode mesh in convenient coiled form, large areas of structure to be protected can be fitted rapidly.
• the fine anode mesh structure provides thousands of interconnected strands which serve as multiple current paths. This insures that the system will continue to operate even if any strands are broken due to stresses in the structure or future coring.
• On-site welding of the current distributors is simple and convenient and several welds can easily be provided for each sheet of the mesh even though only one or two would suffice.
• the ease of installation of the mesh combined with the low cost of the highly expanded mesh with a low catalyst loading makes the system very cost effective.
• FIGURE 1 shows a diamond-shaped unit of a greatly expanded valve metal mesh employed in this invention.
• FIGURE 2 is a section of the valve metal mesh having a current distributor welded along the LWD and welded to mesh nodes.
• FIGURE 3 is an enlarged view of a mesh node showing the node double.
• FIGURE 4 is a perspective view illustrating the installation procedure on a steel-reinforced concrete deck.
• the metals of the valve metal mesh will most always be any of titanium, tantalum, zirconium and niobium. As well as the elemental metals themselves, the suitable metals of the mesh can include alloys of these metals with themselves and other metals as well as their intermetallic mixtures. Of particular interest for its ruggedness, corrosion resistance and availability is titanium. Where the mesh will be expanded from a metal sheet, the useful metal of the sheet will most always be an annealed metal. As representative of such serviceable annealed metals is Grade I titanium, an annealed titanium of low embrittlement. Such feature of low embrittlement is necessary where the mesh is to be prepared by expansion of a metal sheet, since such sheet should have an elongation of greater than 20 percent.
• Metals for expansion having an elongation of less than 20 percent will be too brittle to insure suitable expansion to useful mesh without deleterious strand breakage.
• the metal used in expansion will have an elongation of at least about 24 percent and will virtually always have an elongation of not greater than about 40 percent.
• metals such as aluminum are neither contemplated, nor are they useful, for the mesh in the present invention, aluminum being particularly unsuitable because of its lack of corrosion resistance.
• annealing may be critical as for example with the metal tantalum where an annealed sheet can be expected to have an elongation on the order of 37 to 40 percent, which metal in unannealed form may be completely useless for preparing the metal mesh by having an elongation on the order of only 3 to 5 percent.
• alloying may add to the embrittlement of an elemental metal and thus suitable alloys may have to be carefully selected.
• a titanium-palladium alloy commercially available as Grade 7 alloy and containing on the order of 0.2 weight percent palladium, will have an elongation at normal temperature of above about 20 percent and is expensive but could be serviceable, particularly in annealed form.
• the expected corrosion resistance of a particular alloy that might be selected may also be a consideration.
• Grade I titanium such is usually available containing 0.2 weight percent iron.
• Grade I titanium is also available containing less than about 0.05 weight percent iron. Generally, this metal of lower iron content will be preferable for many applications owing to its enhanced corrosion resistance.
• the metal mesh may then be prepared directly from the selected metal.
• the mesh be expanded from a sheet or coil of the valve metal.
• alternative meshes to expanded metal meshes may be serviceable.
• thin metal ribbons can be corrugated and individual cells, such as honeycomb shaped cells can be resistance welded together from the ribbons. Slitters or corrugating apparatus could be useful in preparing the metal ribbons and automatic resistance welding could be utilized to prepare the large void fraction mesh.
• a mesh of interconnected metal strands can directly result.
• a highly serviceable mesh will be prepared using such expansion technique with no broken strands being present.
• the highly serviceable annealed valve metals having desirable ruggedness coupled with the requisite elongation characteristic, some stretching of the expanded mesh can be accommodated during installation of the mesh. This can be of particular assistance where uneven substrate surface or shape will be most readily protected by applying a mesh with such stretching ability.
• a stretching ability of up to about 10 percent can be accommodated from a roll of Grade I titanium mesh.
• the mesh obtained can be expected to be bendable in the general plane of the mesh about a bending radius in the range of from 5 to 25 times the width of the mesh.
• the interconnected metal strands will have a thickness dimension corresponding to the thickness of the initial planar sheet or coil. Usually this thickness will be within the range of from about 0.05 centimeter to about 0.125 centimeter. Use of a sheet having a thickness of less than about 0.05 centimeter, in an expansion operation, can not only lead to a deleterious number of broken strands, but also can produce a too flexible material that is difficult to handle. For economy, sheets of greater than about 0.125 centimeter are avoided. As a result of the expansion operation, the strands will interconnect at nodes providing a double strand thickness of the nodes. Thus the node thickness will be within the range of from about 0.1 centimeter to about 0.25 centimeter.
• the nodes for the special mesh will be completely, to virtually completely, non-angulated. " By that it is meant that the plane of the nodes through their thickness will be completely, to virtually completely, vertical in reference to the horizontal plane of an uncoiled roll of the mesh.
• the weight of the mesh will usually be within the range of from about 0.05 kilogram per square meter to about 0.5 kilogram per square meter of the mesh. Although this range is based upon the exemplary metal titanium, such can nevertheless serve as a useful range for the valve metals generally. Titanium is the valve metal of lowest specific gravity. On this basis, the range can be calculated for a differing valve metal based upon its specific gravity relationship with titanium. Referring again to titanium, a weight of less than about 0.05 kilogram per square meter of mesh will be insufficient for proper current distribution in enhanced cathodic protection. On the other hand, a weight of greater than about 0.5 kilogram per square meter will most always be uneconomical for the intended service of the mesh.
• the m.esh can then be produced by expanding a sheet or coil of metal of appropriate thickness by an expansion factor of at least 10 times, and preferably at least 15 times.
• Useful mesh can also be prepared where a metal sheet has been expanded by a factor up to 30 times its original area. Even for an annealed valve metal of elongation greater than 20 percent, an expansion factor of greater than 30:1 may lead to the preparation of a mesh exhibiting strand breakage. On the other hand, an expansion factor of less than about 10:1 may leave additional metal without augmenting cathodic protection. Further in this regard, the resulting expanded mesh should have an at least 80 percent void fraction for efficiency and economy of cathodic protection.
• the expanded metal mesh will have a void fraction of at least about 90 percent, and may be as great as 92 to 96 percent or more, while still supplying sufficient metal and economical current distribution.
• the metal strands can be connected at a multiplicity of nodes providing a redundancy of current-carrying paths through the mesh which insures effective current distribution throughout the mesh even in the event of possible breakage of a number of individual strands, e.g., any breakage which might occur during installation or use.
• suitable redundancy for the metal strands will be provided in a network of strands most always interconnected by from about 500 to about 2000 nodes per square meter of the mesh. Greater than about 2000 nodes per square meter of the mesh is uneconomical. On the other hand, less than about 500 of the interconnecting nodes per square meter of the mesh may provide for insufficient redundancy in the mesh.
• strands within such thickness range will have width dimensions of from about 0.05 centimeter to about 0.20 centimeter.
• the total surface area of interconnected metal i.e., including the total surface area of strands plus nodes, will provide between about 10 percent up to about 50 percent of the area covered by the metal mesh. Since this surface area is the total area, as for example contributed by all four faces of a strand of square cross-section, it will be appreciated that even at a 90 percent void fraction such mesh can have a much greater than 10 percent mesh surface area.
• This area will usually be referred to herein as the "surface area of the metal” or the "metal surface area”. If the total surface area of the metal is less than about 10 percent, the resulting mesh can be sufficiently fragile to lead to deleterious strand breakage. On the other hand, greater than about 50 percent surface area of metal will supply additional metal without a commensurate enhancement in protection. After expansion the resulting mesh can be readily rolled into coiled configuration, such as for storage or transport or further operation. With the representative valve metal titanium, rolls having a hollow inner diameter of greater than 20 centimeters and an outer diameter of up to 150 centimeters, preferably 100 centimeters, can be prepared.
• rolls can be suitably coiled from the mesh when such is prepared in lengths within the range of from about 40 to about 200, and preferably up to 100, meters.
• such rolls will have weight on the order of about 10-50 kilograms, but usually below 30 kilograms to be serviceable for handling, especially following coating, and particularly handling in the field during installation for cathodic protection.
• the gap patterns in the mesh will be formed as diamond-shaped apertures.
• Such "diamond-pattern” will feature apertures having a long way of design (LWD) from about 4, and preferably from about 6, centimeters up to about 9 centimeters, although a longer LWD is contemplated, and a short way of design (SWD) of from about 2, and preferably from about 2.5, up to about 4 centimeters.
• LWD long way of design
• SWD short way of design
• diamond dimensions having an LWD exceeding about 9 centimeters may lead to undue strand breakage and undesirable voltage loss.
• FIG. 1 an individual diamond shape, from a sheet containing many such shapes is shown generally at 2.
• the shape is formed from strands 3 joining at connections (nodes) 4.
• the strands 3 and connections 4 form a diamond aperture having a long way of design in a horizontal direction.
• the short way of design is in the opposite, vertical direction.
• the surface area of the interconnected metal strands 3 When referring to the surface area of the interconnected metal strands 3, e.g., where such surface area will supply not less than about 10 percent of the overall measured area of the expanded metal as discussed hereinabove, such surface area is the total area around a strand 3 and the connections 4.
• the surface area of the strand 3 will be four times the depicted, one-side-only, area as seen in the Figure.
• the strands 3 and their connections 4 appear thin, they may readily contribute 20 to 30 percent surface area to the overall measured area of the expanded metal.
• the "area of the mesh" e.g., the square meters of the mesh, as such terms are used herein, is the area encompassed within an imaginary line drawn around the periphery of the Figure.
• the area within the diamond i.e., within the strands 3 and connections 4, may be referred to herein as the "diamond aperture " . It is the area having the LWD and SWD dimensions. For convenience, it may also be referred to herein as the "void”, or referred to herein as the "void fraction”, when based upon such area plus the area of the metal around the void. As noted in Fig. 1 and as discussed hereinbefore, the metal mesh as used herein has extremely great void fraction. Although the shape depicted in the figure is diamond-shaped, it is to be understood that many other shapes can be serviceable to achieve the extremely great void fraction, e.g., scallop-shaped or hexagonal.
• FIG. 2 several individual diamonds 21 are formed of individual strands 22 and their interconnections 25 thereby providing diamond-shaped apertures.
• a row of the diamonds 21 is bonded to a metal strip 23 at the intersections 25 of strands 22 with the metal strip 23 running along the LWD of the diamond pattern.
• the assembly is brought together by spotwelds 24, with each individual strand connection (node) 25 located under the strip 23 being welded by a spotweld 24.
• spotweld 24 Generally the welding employed will be electrical resistance welding and this will most always simply be spot welding, for economy, although other, similar welding technique, e.g., roller welding, is contemplated. This provides a firm interconnection for good electroconductivity between the strip 23 and the strands 22.
• the strands 22 and connections 25 can form a substantially planar configuration.
• particularly larger dimensional sheets of the mesh may be generally in coiled or rolled condition, as for storage or handling, but are capable of being unrolled into a "substantially planar" condition or configuration, i.e., substantially flat form, for use.
• the connections 25 will have double strand thickness, whereby even when rolled flat, the substantially planar or flat configuration may nevertheless have ridged connections.
• the nodes have double strand thickness (2T) .
• the individual strands have a lateral depth or thickness (T) not to exceed about 0.125 centimeter, as discussed hereinabove, and a facing width (W) which may be up to about 0.20 centimeter.
• the expanded metal mesh can be coated before or after it is in mesh form with a catalytic active material, thereby forming a catalytic anode structure.
• the valve metal mesh will be subjected to a cleaning operation, e.g., a degreasing operation, which can include cleaning plus etching, as is well known in the art of preparing a valve metal to receive an electrochemically active coating.
• a cleaning operation e.g., a degreasing operation, which can include cleaning plus etching
• a valve metal which may also be referred to herein as a "film-forming" metal, will not function as an anode without an electrochemically active coating which prevents passivation of the valve metal surface.
• This electrochemically active coating may be provided from platinum or other platinum group metal, or it may be any of a number of active oxide coatings such as the platinum group metal oxides, magnetite, ferrite, cobalt spinel, or mixed metal oxide coatings, which have been developed for use as anode coatings in the industrial electrochemical industry. It is particularly preferred for extended life protection of concrete structures that the anode coating be a mixed metal oxide, which can be a solid solution of a film-forming metal oxide and a platinum group metal oxide .
• the coating should be present in an amount of from about 0.05 to about 0.5 gram of platinum group metal per square meter of expanded valve metal mesh. Less than about 0.05 gram of platinum group metal will provide insufficient electrochemically active coating to serve for preventing passivation of the valve metal substrate over extended time, or to economically function at a sufficiently low single electrode potential to promote selectivity of the anodic reaction. On the other hand, the presence of greater than about 0.5 gram of platinum group metal per square meter of the expanded valve metal mesh can contribute an expense without commensurate improvement in anode lifetime.
• the mixed metal oxide coating is highly catalytic for the oxygen evolution reaction, and in a chloride contaminated concrete environment, will evolve no chlorine or hypochlorite.
• platinum group metal or mixed metal oxides for the coating are such as have been generally been described in one or more of U.S. Patents 3,265,526, 3,632,498, 3,711,385 and 4,528,084. More particularly, such platinum group metals include platinum, palladium, rhodium, iridium and ruthenium or alloys of themselves and with other metals. Mixed metal oxides include at least one of the oxides of these platinum group metals in combination with at least one oxide of a valve metal or another non-precious metal. It is preferred for economy that the coating be such as have been disclosed in the U.S. Patent No. 4,528,084.
• the metal mesh will be connected to a current distribution member, e.g., the metal strip 23 of Fig. 2.
• a current distribution member e.g., the metal strip 23 of Fig. 2.
• Such member will most always be a valve metal and preferably is the same metal alloy or intermetallic mixture as the metal most predominantly found in the expanded valve metal mesh.
• This current distribution member must be firmly affixed to the metal mesh.
• Such a manner of firmly fixing the member to the mesh can be by welding as has been discussed hereinabove. Moreover, the welding can proceed through the coating.
• a coated strip can be laid on a coated mesh, with coated faces in contact, and yet the welding can readily proceed.
• the strip can be welded to the mesh at every node and thereby provide uniform distribution of current thereto.
• Such a member positioned along a piece of mesh about every 30 meters will usually be sufficient to serve as a current distributor for such piece.
• the embedded portion of the current distribution member be also coated, such as with the same electrochemically active coating of the mesh.
• the member may be attached to the mesh before or after the member is coated.
• Such current distributor member can then connect outside of the concrete environment to a current conductor, which current conductor being external to the concrete need not be so coated.
• the current distribution member may be a bar extending through a hole to the underside of the deck surface where a current conductor is located. In this way all mechanical current connections are made external to the finished concrete structure, and are thereby readily available for access and service if necessary. Connections to the current distribution bar external to the concrete may be of conventional mechanical means such as a bolted spade-lug connector. Meshes produced according to the following specifications were used in the example of the method of installation described below.
• the same thin catalytic coating is applied to current distributors typically made from strips of the same titanium having a width of about 0-5 inch (1.25 cm), and a thickness of about 0.04 inch (0.1 cm).
• a roll of the greatly expanded valve metal mesh with a suitable electrochemically active coating can be unrolled onto the surface of such deck or substructure.
• means of fixing mesh to substructure can be any of those useful for binding a metal mesh to concrete that will not deleteriously disrupt the anodic nature of the mesh.
• non-conductive retaining members will be useful.
• Such retaining members for economy are advantageously plastic and in a form such as pegs or studs.
• plastics such as polyvinyl halides or polyolefins can be useful. These plastic retaining members can be inserted into holes drilled into the concrete.
• Such retainers may have an enlarged head engaging a strand of the mesh under the head to hold the anode in place, or the retainers may be partially slotted to grip a strand of the mesh located directly over the hole drilled into the concrete.
• an ionically conductive overlay will be employed to completely cover the anode structure. Such overlay may further enhance firm contact between the anode and the concrete substructure.
• Serviceable ionically conductive overlays include portland cement and polymer-modified concrete.
• the anode can be overlaid with from about 2 to about 6 centimeters of a portland cement or a latex modified concrete.
• the anode may be generally covered by from about 0.5 to about 2 centimeters of polymer modified concrete.
• the expanded valve metal mesh substrate of the anode provides the additional advantage of acting as a metal reinforcing means, thereby improving the mechanical properties and useful life of the overlay. It is contemplated that the metal mesh anode structure will be used with any such materials and in any such techniques as are well known in the art of repairing underlying concrete structures such as bridge decks and support columns and the like.
• FIG. 4 illustrates the installation of a mesh of highly expanded titanium as specified above on a steel-reinforced concrete deck designated generally by 40.
• the steel reinforcement of the deck is tested for its degree of corrosion and its suitability for preservation by cathodic protection, using known techniques including suitable potential measurements,
• catalytically coated titanium current distributor strips 23 are laid across the deck 40 with a suitable spacing.
• the current distributors 23 are typically spaced lengthwise by about 60 feet (18 meters). For the type 2 mesh, this spacing is about 100 feet (30 meters).
• the strips 32 extend through holes in the deck 40 for connection to a current supply; for the type 1 mesh the spacing of these power feed locations is about 24 feet (7.2 meters) widthwise of the meshes. For the type 2 mesh this widthwise spacing is about 32 feet (9.8 meters).
• FIG. 4 shows a first anode mesh 30 which has already been laid by unrolling from its roll, stretched longitudinally by about 5-10% and fixed to the deck 40 by inserting plastic clips 31 in holes drilled in the deck.
• the mesh 30 is spot welded to the transverse current distributor strips 23 at nodes 25 of the mesh (as shown in FIG. 2).
• a copper bar 35 is inserted under the mesh 30 and strip 23; this enables a sufficient welding current to be passed through the weld.
• the bar 35 is withdrawn from under the mesh and placed under the strip 23 in position to receive the next roll of mesh 30, as shown in FIG. 3.
• the adjacent unrolled sheets of mesh 30 are spaced by a distance D. Clear spacings of up to about 1 LWD dimension are possible while producing an even cathodic protection effect on the underlying steel. Alternatively the edges could overlap, e.g. by about 1 LWD of the mesh or more, if necessary to conform to the width of the deck 40.
• the deck 40 with mesh 30 is embedded in a thin layer of cement based grout. Then an ion-conductive layer of about 4-6 cm portland cement or polymer modified concrete is applied, by pouring or spraying.

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• Metallurgy (AREA)
• Organic Chemistry (AREA)
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• 1986
  • 1986-04-28 WO PCT/US1986/000932 patent/WO1986006758A1/en active IP Right Grant
  • 1986-04-28 AU AU58678/86A patent/AU583627B2/en not_active Expired
  • 1986-04-28 WO PCT/US1986/000933 patent/WO1986006759A1/en active IP Right Grant
  • 1986-04-28 DE DE8686903074T patent/DE3669545D1/de not_active Expired - Lifetime
  • 1986-04-28 JP JP61502631A patent/JPS62503040A/ja active Granted
  • 1986-04-28 DE DE8686903075T patent/DE3666232D1/de not_active Expired
  • 1986-04-28 JP JP61502622A patent/JPS62502820A/ja active Granted
  • 1986-04-28 EP EP86903074A patent/EP0225343B1/de not_active Expired
  • 1986-04-28 EP EP86903075A patent/EP0222829B2/de not_active Expired
  • 1986-04-28 AU AU58687/86A patent/AU587467B2/en not_active Expired
  • 1986-05-07 CA CA000508618A patent/CA1311442C/en not_active Expired - Fee Related
  • 1986-05-07 CA CA000508616A patent/CA1289910C/en not_active Expired - Lifetime
• 1990
  • 1990-08-01 SG SG641/90A patent/SG64190G/en unknown
  • 1990-08-30 SG SG713/90A patent/SG71390G/en unknown
  • 1990-10-28 SA SA90110114A patent/SA90110114B1/ar unknown
  • 1990-10-28 SA SA90110113A patent/SA90110113B1/ar unknown

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