EP0220073B1 - Cementitious compositions and products - Google Patents

Cementitious compositions and products Download PDF

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Publication number
EP0220073B1
EP0220073B1 EP19860308093 EP86308093A EP0220073B1 EP 0220073 B1 EP0220073 B1 EP 0220073B1 EP 19860308093 EP19860308093 EP 19860308093 EP 86308093 A EP86308093 A EP 86308093A EP 0220073 B1 EP0220073 B1 EP 0220073B1
Authority
EP
European Patent Office
Prior art keywords
water
composition
plus
cross
composition according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP19860308093
Other languages
German (de)
English (en)
French (fr)
Other versions
EP0220073A1 (en
Inventor
Howard Anthony Barker
Eric Arthur Rirsch
John Maxfield
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Redland Technology Ltd
Monier Braas Research and Development Ltd
Original Assignee
Redland Technology Ltd
Redland Technologies Ltd
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Publication date
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Application filed by Redland Technology Ltd, Redland Technologies Ltd filed Critical Redland Technology Ltd
Priority to AT86308093T priority Critical patent/ATE63103T1/de
Publication of EP0220073A1 publication Critical patent/EP0220073A1/en
Application granted granted Critical
Publication of EP0220073B1 publication Critical patent/EP0220073B1/en
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B16/00—Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B16/04—Macromolecular compounds
    • C04B16/06—Macromolecular compounds fibrous
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00241—Physical properties of the materials not provided for elsewhere in C04B2111/00
    • C04B2111/00301—Non-porous materials, e.g. macro-defect free [MDF] products
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/91—Use of waste materials as fillers for mortars or concrete

Definitions

  • the invention relates to cementitious compositions and products made from such compositions. More particularly, the invention relates to substantially clay-free compositions comprising a hydraulic cement, water, a water-soluble polymer and a cross-linking agent for said polymer. It is to be understood that the compositions according to this invention are substantially clay-free.
  • reactive water-soluble polymer in this specification is meant any water-soluble or water dispersible polymer or mixture of such polymers which can be reacted with an appropriate cross-linking agent to cause the polymer to become insoluble, or substantially so, in products made from the cementitious compositions of this invention.
  • hydraulic cement in this specification, there is meant any material which sets and hardens by the addition of water, that is in the presence of water.
  • the hydraulic cement may, for example, be a silicate cement such as Portland cement or it may be an aluminate cement.
  • the term includes mixtures of two or more different hydraulic cements.
  • the resultant product should be of high strength and especially high flexural strength.
  • the products are to be used as building products, for example roofing slates, and for use in such applications it is desirable that the products should not only have a flexural strength of at least 15 MPa and advantageously 40 MPa, but also good durability, i.e. good resistance to:
  • Cementitious products produced from an hydraulic cement paste consisting of hydraulic cement and water only generally have low strength, especially low flexural strength, and poor durability.
  • a product formed from a cementitious composition which comprises an ordinary hydraulic cement with a typical spread of particle size range and an amount of water which is conventionally used in such compositions may have a flexural strength as low as 5 to 10 MPa.
  • substantial amounts of aggregate i.e. sand or crushed rock or the like
  • Fibrous materials which have been used in the past to increase the flexural strength of cementitious products include fibres of asbestos, glass, steel, ceramic, polymeric and vegetable materials.
  • the use of such fibres does, however, have certain disadvantages.
  • the flexural strength of products made from compositions including such materials may be appreciably increased to a figure of the order of 40 MPa in the short and medium terms; however, in the long term the presence of the fibrous material may not be entirely satisfactory because fibres may suffer degradation due to alkali attack, which coupled with long term weathering may also adversely affect the durability of the finished product.
  • the use of such fibres may add to the difficulty of processing the cementitious composition and in the case of some fibres, for example, asbestos, may involve health hazards.
  • processing aids examples include especially cellulose ethers and also polyacrylamides and hydrolysed polyvinyl acetates. Proposals for using such processing aids have described using up to 25% by weight of the processing aid in a cement/water composition.
  • the improved micro-structure and increase in strength of products made from such compositions results in part from the effect of the polymers on the rheology of the composition.
  • the polymers act as an adhesive between the cementitious entities of the composition.
  • the strength of the bond provided by the polymer adhesive depends, amongst other factors, upon the water content of the composition. Ultimately, therefore, there will be a complete loss of strength because the polymer may re-dissolve or otherwise become less effective if sufficient water is available.
  • a number of the compositions described in the specifications listed above while possessing relatively high initial flexural strength when dry, do not have adequate strength when wet or adequate durability for use as building products.
  • DE-A-2 300 206 there is disclosed curable composition comprising in admixture a hydraulic cement, a filler, water, an organic polyisocyanate and an isocyanate reactive water-soluble polymer in an amount sufficient to ensure that, after mixing, the composition remains compatible with, and dispersible by, water until the composition has cured to the point of initial set.
  • the water-soluble polymers which can be used include derivatives of cellulose, for example, various cellulose ethers including methyl cellulose and hydroxy ethyl cellulose.
  • the composition may also include one or more other isocyanate reactive organic compounds additional to the water-soluble polymer, and such compounds may be epoxy compounds.
  • DE-A-2 300 206 is concerned with cement compositions which are suitable for surfacing floors, walls and the like and the invention is designed to give an early initial set.
  • compositions of the present invention do not contain an isocyanate and compositions containing isocyanates are disclaimed from the claims of this invention.
  • the hardened composition has a low strength when saturated with water compared to the strength thereof in the dry state, or such products may also suffer gradual loss of strength during exposure to water or they will break down when subjected to freeze-thaw conditions even though such products are superior to those taught by the prior art.
  • the present invention provides an uncured cementitious composition which is free of isocyanates comprising in admixture:-
  • the water-soluble polymer is preferably capable of giving a viscosity exceeding 50 cps as a 5.0% solution by weight in water. Also it is preferred that the composition contains from 0.2, and more preferably 0.5 to 5 parts by weight of the water-soluble polymer per 100 parts per weight of the cement.
  • the water-soluble polymer to be used in the practice of this invention has to be reactive so that the cross-linking agent is able to react with the molecules of the polymer to insolubilise the polymer by forming the cross-links. It will be appreciated that a cross-linking agent which is very reactive with water is unsuitable for this purpose.
  • the susceptibility to water is overcome by the use of the cross-linking agent, rendering the polymer insoluble in water and reducing the absorption of water and loss of strength of the products.
  • Further benefits that may be derived from the addition of such cross-linking agents are (a) modifications to rheology of the mix which may assist in processing, (b) the formation of chemical links between two or more polymers used simultaneously in the mix, (c) formation of chemical links between the polymer and a fibrous reinforcement such as cellulose fibres, (d) a shortening of the time required to harden and develop strength in the cementitious composition, particularly when hot pressing is employed as the shaping method for the final product, and (e) formation of chemical bonds between cement and polymer.
  • cross-linking may proceed at a rate which allows complete uniform dissolution of the polymer in the cementitious mixture.
  • Cross-linking of water-soluble polymers can be achieved by condensation with difunctional reagents, free radical reaction at unsaturated carbon-carbon double bonds, and complexing reagents with polyvalent ions. These mechanisms can be illustrated by the behaviour of cellulose ethers as described below.
  • Cross-linking of cellulose ethers may be accomplished by condensation reaction through hydroxol groups. Under the alkaline conditions which exist during the mixing and hardening process for most hydraulic cements we have found that this reaction can be carried out with, for example;
  • cellulose ethers may be modified so that they can be cross-linked by a free radical mechanism.
  • modification can be introduced by reaction with allyl halides to introduce unsaturation which then serves as an active site for reaction which can be initiated later.
  • Hydroxy-propylmethyl cellulose can be reacted with acrylamide monomers, such as methylene bis-acrylamide at around 70°C in alkaline conditions to form a water insoluble cross-linked polymer.
  • cross-linking reagents can be chosen that react only at elevated temperatures with the polymer, do not alter the characteristics of the forming process, and are compatible with the other stages of processing such as hot pressing.
  • the reactive water-soluble polymer and the water-soluble cross-linking agent preferably, consist of at least one of the following pairs:
  • the cellulose ether is a hydroxypropyl methyl cellulose and the diepoxide is 1,4 butanadiol diglycidyl ether, or butadiene diepoxide, or the diglycidyl ether of 1,2,3 propane triol, or vinylcyclohexanone dioxide together with zinc fluoroborate as catalyst.
  • the dialdehyde is glutaraldehyde or glyoxal.
  • the water-soluble polymer is polyacrylamide it is preferably dissolved in a volatile, water-miscible solvent prior to mixing with the hydraulic cement.
  • the water-soluble polymer is hydroxypropylmethyl cellulose
  • the sulphone is bis(2-hydroxyethyl) sulphone, or alternatively in place of the sulphone the cross-linking agent is ethylene imine.
  • Another combination to be used in accordance with this invention is when the cellulose ether is hydroxypropylmethyl cellulose the cross-linking agent is one with labile chlorine, preferably dichloropropanol or epichlorohydrin.
  • An alternative cellulose ether which may be used in practicing the present invention is hydroxy ethyl cellulose, although other cellulose derivatives may be used including sodium carboxymethyl cellulose.
  • the water-soluble polymer may be polyvinyl alcohol, or a partially hydrolysed polyvinyl acetate.
  • the cellulose ether is hydroxypropylmethyl cellulose and the acrylamide monomer is methylene bis-acrylamide.
  • the water soluble polymer may be allyl substituted cellulose ether, such as acrylamido methylated cellulose and the free radical initiator may be potassium persulphate or nitrile N-oxide.
  • the allyl substituted cellulose ether may be allyl hydroxypropylmethyl cellulose and the free radical initiator may be potassium persulphate with sodium bisulphate.
  • the cementitious composition according to the present invention may contain, in addition to the cement, water and processing aid, other materials known in art.
  • these materials may include fibrous materials, fine fillers, dispersants and chemical modifiers which modify the setting ability of the composition.
  • the fillers and/or aggregates may include slate dust, various forms of sand and the like and these may be mixed with pigments in order to give the finished product a preferred colour.
  • the cementitious composition may furthermore comprise blast furnace slag or pulverised fuel ash or a natural or artificial pozzolana.
  • the constituents of the cementitious composition are desirably subjected to high shear mixing in order to plasticise the composition and convert it to a smooth paste or a material of dough-like consistency.
  • the high shear mixing may be achieved, for example, in a Z-blade mixer or a twin-roll-mill.
  • the paste or dough-like material is then compressed and maintained under pressure in order to remove substantially all of the larger voids in the material.
  • the invention also includes a method of making a cementitious composition wherein the specified ingredients (a), (b), (c) and (d) are mixed under conditions of high shear to produce a uniform composition and to remove all or substantially all of the voids from the composition and to convert the composition into a material of dough like consistency.
  • a material of dough like consistency is such that after hardening of the composition the composition has less than 2% of the apparent volume of the product of pores having a size of less than 100 microns, and preferably the composition has less than 2% of the apparent volume of the product of pores having a size of less than 50 microns, and more preferably the composition has less 2% of the apparent volume of the product of pores having a size in the range of 2 to 15 microns.
  • the dough-like material may subsequently be set and cured in a way generally known in the art to produce the finished product.
  • This process may include pressing of the material and/or forming into a desired shape of product and may also include curing which may be effected in a humid atmosphere for example up to 100% relative humidity, and/or with the application of heat to the product.
  • the curing may be effected in an autoclave and the temperature may be above 100°C; such a temperature is to be preferred when the cementitious composition contains the mixture of lime and silica as the hydraulic cement.
  • the cementitious composition may also comprise fibrous or textile reinforcement and in some applications it is preferred that the water-soluble polymer is also chemically cross-linked to the fibrous or textile reinforcement. It is preferred that the fibre is fibrillated polyethylene or polypropylene or a co-polymer of ethylene and propylene, such fibre having a secant elastic modulus of at least 10 GPa measured at 0.1% elongation.
  • the materials and processes described may be used, for example, to produce building products such as tiles, artificial slates, pipes and other moulded items for use in conditions exposed to natural weathering or water.
  • the invention is particularly suitable for providing roofing elements or for cladding the exterior walls of buildings.
  • a cross-linking agent is used which is relatively stable at ambient temperature; it is to be understood that such a cross-linking agent enables the composition to be handled and processed without complications arising from cross-linking of the water-soluble polymer; the use of a cross-linking agent which is relatively stable at ambient temperature is particularly preferred for the production of the cementitious composition in accordance with this invention which contains the above defined ingredients (a), (b) and (d) and which merely requires the subsequent addition of an appropriate amount of water when the composition is to be used in the production of a hardened cementitious product.
  • the amount of cross-linking agent is stoichiometrically sufficient to react with all available sites within the polymer; however, lower quantities, for example 50%, or greater may also be used.
  • the typical freeze-thaw test referred to is one in which the main cycle consists of maintaining the test pieces with one face in contact with water by placing on saturated foam rubber for 5 days while alternating the temperature from + 20°C to - 20°C twice a day thereby giving 10 cycles of freeze and thaw in this period.
  • the temperature of -20°C is maintained for 10 hours followed by +20°C for 2 hours.
  • the cooling from +20°C to -20°C is effected in about 30 mins. and the heating from -20°C tp +20°C is effected in about 30 mins.
  • test pieces This is followed by subjecting the test pieces to a temperature of 70°C in air for 2 days at a low relative humidity.
  • 100% of the samples were still intact after 60 of the main cycles whereas materials made in the same way without the addition of sulphone on average only exhibited 32% survival after this number of cycles.
  • Example 2 was repeated but with 2.5 parts by weight of chopped polypropylene fibre added during the mixing process on the roll-mill.
  • the cured product was subjected to the wet/dry cycling test described in Example 1. This material cracked only after 66 cycles of this test whereas a similar fibre reinforced material in which the sulphone cross-linking agent had been omitted cracked within 54 cycles.
  • Example 3 A material of the same composition described in Example 3, but with the addition of 2.5 parts by weight of chopped polypropylene fibre and processed in the manner described in Example 4 was subjected to the wet/dry cycling test described in Example 1. This material cracked only after 75 cycles which may again be compared with cracking within 54 cycles observed for similar material in which the cross-linking agent had been omitted.
  • Example 3 was repeated except that 150g of silica fume was added in place of an equal weight of cement and an additional 20g of water was added to render the mixture more workable.
  • dry strength 21 MPa
  • Wet strength 27 MPa

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
EP19860308093 1985-10-18 1986-10-17 Cementitious compositions and products Expired - Lifetime EP0220073B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT86308093T ATE63103T1 (de) 1985-10-18 1986-10-17 Zementhaltige mischungen und produkte.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8525723A GB8525723D0 (en) 1985-10-18 1985-10-18 Cementitious compositions
GB8525723 1985-10-18

Publications (2)

Publication Number Publication Date
EP0220073A1 EP0220073A1 (en) 1987-04-29
EP0220073B1 true EP0220073B1 (en) 1991-05-02

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ID=10586877

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EP19860308093 Expired - Lifetime EP0220073B1 (en) 1985-10-18 1986-10-17 Cementitious compositions and products

Country Status (6)

Country Link
US (1) US4778529A (es)
EP (1) EP0220073B1 (es)
AT (1) ATE63103T1 (es)
DE (1) DE3679026D1 (es)
ES (1) ES2022125B3 (es)
GB (2) GB8525723D0 (es)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7713615B2 (en) 2001-04-03 2010-05-11 James Hardie International Finance B.V. Reinforced fiber cement article and methods of making and installing the same
US7993570B2 (en) 2002-10-07 2011-08-09 James Hardie Technology Limited Durable medium-density fibre cement composite
US7998571B2 (en) 2004-07-09 2011-08-16 James Hardie Technology Limited Composite cement article incorporating a powder coating and methods of making same
US8281535B2 (en) 2002-07-16 2012-10-09 James Hardie Technology Limited Packaging prefinished fiber cement articles
US8297018B2 (en) 2002-07-16 2012-10-30 James Hardie Technology Limited Packaging prefinished fiber cement products
US8993462B2 (en) 2006-04-12 2015-03-31 James Hardie Technology Limited Surface sealed reinforced building element

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US5323581A (en) * 1992-04-30 1994-06-28 Jakel Karl W Lightweight cementitious roofing
US5290355A (en) * 1992-04-16 1994-03-01 Jakel Karl W Roofing shingle composition, method of formulation, and structure
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US6084011A (en) * 1997-08-29 2000-07-04 Lucero; Richard F. Freeze/thaw resistant cementitious adhesive for composite materials and method for production thereof
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US6541560B1 (en) * 2000-03-15 2003-04-01 Graphic Packaging Corporation Control of volatile carbonyl compound in compositions used in printing, printing methods and resulting printed structure
US6743830B2 (en) * 2001-03-07 2004-06-01 Innovative Construction And Building Materials Construction board materials with engineered microstructures
US7105587B2 (en) * 2001-03-07 2006-09-12 Innovative Construction And Building Materials Method and composition for polymer-reinforced composite cementitious construction material
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US6902797B2 (en) * 2002-11-12 2005-06-07 Innovative Construction And Building Materials Gypsum-based composite materials reinforced by cellulose ethers
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JP2010535700A (ja) * 2007-08-10 2010-11-25 コンストラクション リサーチ アンド テクノロジー ゲーエムベーハー ドライキャストセメント組成物用レオロジー調整添加剤
US8882907B2 (en) 2007-11-30 2014-11-11 Celanese International Corporation Additive composition for mortars, cements and joint compounds and cementitious compositions made therefrom
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7713615B2 (en) 2001-04-03 2010-05-11 James Hardie International Finance B.V. Reinforced fiber cement article and methods of making and installing the same
US8281535B2 (en) 2002-07-16 2012-10-09 James Hardie Technology Limited Packaging prefinished fiber cement articles
US8297018B2 (en) 2002-07-16 2012-10-30 James Hardie Technology Limited Packaging prefinished fiber cement products
US7993570B2 (en) 2002-10-07 2011-08-09 James Hardie Technology Limited Durable medium-density fibre cement composite
US7998571B2 (en) 2004-07-09 2011-08-16 James Hardie Technology Limited Composite cement article incorporating a powder coating and methods of making same
US8993462B2 (en) 2006-04-12 2015-03-31 James Hardie Technology Limited Surface sealed reinforced building element

Also Published As

Publication number Publication date
GB8525723D0 (en) 1985-11-20
ATE63103T1 (de) 1991-05-15
GB2181726A (en) 1987-04-29
ES2022125B3 (es) 1991-12-01
DE3679026D1 (de) 1991-06-06
US4778529A (en) 1988-10-18
GB8624951D0 (en) 1986-11-19
EP0220073A1 (en) 1987-04-29
GB2181726B (en) 1989-10-18

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