EP0219473A1 - Procédé de récupération sélective du plomb à partir de minearais complexes sulfurés de métaux non ferreux - Google Patents

Procédé de récupération sélective du plomb à partir de minearais complexes sulfurés de métaux non ferreux Download PDF

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Publication number
EP0219473A1
EP0219473A1 EP86850290A EP86850290A EP0219473A1 EP 0219473 A1 EP0219473 A1 EP 0219473A1 EP 86850290 A EP86850290 A EP 86850290A EP 86850290 A EP86850290 A EP 86850290A EP 0219473 A1 EP0219473 A1 EP 0219473A1
Authority
EP
European Patent Office
Prior art keywords
lead
concentrate
electrolytic cell
electrolyte
cell
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP86850290A
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German (de)
English (en)
Other versions
EP0219473B1 (fr
Inventor
Lars Artur Hedström
Nils Folke Rune Lindström
Kenneth Ake Sören Sjöberg
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Boliden Mineral AB
Original Assignee
Boliden AB
Boliden Mineral AB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Boliden AB, Boliden Mineral AB filed Critical Boliden AB
Publication of EP0219473A1 publication Critical patent/EP0219473A1/fr
Application granted granted Critical
Publication of EP0219473B1 publication Critical patent/EP0219473B1/fr
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C5/00—Electrolytic production, recovery or refining of metal powders or porous metal masses
    • C25C5/02—Electrolytic production, recovery or refining of metal powders or porous metal masses from solutions
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/18—Electrolytic production, recovery or refining of metals by electrolysis of solutions of lead
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells

Definitions

  • the present invention relates to a method for selectively recovering lead from complex sulphidic non-ferrous metal concentrates in an electrolytic cell incorporating at least one anode and one cathode and an electrolyte which contains chloride ions, at a temperature beneath the boiling point of the concentrate-containing electrolyte and at a pH beneath 7, and the sulphur present in the concentrate being converted into an elementary form and at least the major part of the lead content passing into solution and being subsequently precipitated out selectively through a cathodic process.
  • DE-C-27 32 817 discloses the selective recovery of lead from complex sulphide material, but requires first total leaching and then selective precipitation of the cations.
  • EP-B-0 026 207 proposes a method for selectively recovering lead from complex sulphide concentrates in which physical contact of the particles with the anodes is avoided to the greatest possible extent while, at the same time, limiting the current density to as low a level as possible, preferably between 50 and 100 A/m 2 . It is true that this known method provides a high degree of selectivity, although at the price of low specific lead recovery, i.e. the quantity of lead recovered per unit area of anode, due to the necessary restriction of current density.
  • the complex sulphide concentrate charged to the process is collected in the electrolyte to form a suspension.
  • the suspension formed in the electrolytic cell is caused to flow onto or closely adjacent to the surfaces of anodes located in the cell.
  • surfaces is meant here, and in the following, an electrochemically active surface of the anode.
  • the highest possible anodic current density is maintained during the recovery process.
  • “highest possible” is meant an anodic current density which will enable the highest possible quantities of lead to be recovered selectively without resulting in troublesome chlorine-gas emission from the cell.
  • the anodic current density In order to maintain required selectivity with regard to the lead recovery the anodic current density must not exceed a value at which the concentrate suspension present does not reduce the oxidation agent formed at the anode. Simultaneously a low oxidation potential must be maintained within the suspension in the cell. In this respect there is used in the majority of cases a lowest anodic current density of about 200 A/m 2 .
  • the lead leaching and recovery processes are thus carried out in one and the same vessel, electrolytic cell, which is preferably of cylindrical form with electrodes placed radially therein.
  • the cell preferably incorporates a diaphragm which separates the anolyte from the catholyte in a known manner.
  • the cell is suitably provided with agitating means which lifts the suspension from the bottom of the cell and transports the same upwardly in the centre of said cell. At the upper part of the cell the suspension is caused to flow outwardly from the cell edge and then obliquely down into contact with or along the vertical anode surfaces.
  • the agitating means can also be arranged to reverse the direction of flow, in which case the suspension is caused to flow outwardly from the cell edge at the bottom of said cell.
  • the flow of suspension into contact with or along, i.e. closely adjacent, the anode surface is controlled in a manner to maintain the rate of flow at a sufficiently high level over all parts of the anode surfaces present in the cell. This will counteract to a large extent the generation of chlorine gas in the cell. The presence of chlorine gas is liable to cause anode corrosion, and is therefore not desirable.
  • the maximum current density is dependent on the mass transfer at the anode surface.
  • the concentrate is forced into contact with the anode surface, as in the case of the present invention, there is also obtained an effective mass transfer through the high flow of suspension over the anode surfaces.
  • the flow is also uniform over the whole of the anode surface.
  • the oxidizing agent i.e. the electrolyte
  • the oxidizing agent i.e. the electrolyte
  • the lead sulphide it is possible, seen as a whole, to supply a maximum amount of oxidizing agent per unit of time to the lead sulphide while retaining the desired degree of selectivity, which is to great advantage.
  • the method ensures that in this way lead is leached from the solution in the fastest time possible with respect to the kinetics of the dissolution of the lead sulphide.
  • the method can be carried out in any type of electro-winning cell in which a flow of concentrated suspension can be maintained in the immediate vicinity of the anode or anodes.
  • an electrolytic cell of cylindrical construction having a first conical bottom in which the electrodes are placed alternately in a star-shaped formation.
  • the cell incorporates means for guiding the suspension towards and against the anode surfaces, and also an agitating means placed centrally in the cell.
  • the cell is suitably of a construction in which the cathode chambers extend down to the bottom of the cell and through said bottom, beneath which there is arranged a second conical bottom. All lead recovered is collected in this second bottom in the form sponge lead, this lead first forming on the surfaces of the cathode and then falling down gravitationally into the second bottom.
  • the sponge lead can be tapped-off through the cell bottom.
  • FIG. 1 is a vertical sectional view of the cell and Figure 2 is a top plan view of the cell.
  • the cell 1 comprises a vessel 2 having a first conical bottom 3 and a second conical bottom 4 located beneath said first bottom.
  • the cell has electrodes arranged radially therein, i.e. in the form of anodes 5 and cathodes 6.
  • a diaghragm 7 is placed inbetween the electrodes.
  • the cathode chamber 8 is connected directly with the second bottom 4, whereas the anode chamber 9 is connected to the first bottom.
  • the electrolyte present in the anode chamber 9 is referred to as anolyte, and the electrolyte present in the cathode chamber as catholyte.
  • the agitator 10 causes the suspension of concentrate and anolyte to flow into and up through a conduit 11, as shown by arrows 12,13, and then outwardly and downwardly onto the surfaces 15 of the anodes 5, as shown by the arrows 14.
  • the lead ions formed in the anodic reaction precipitate onto the cathodes 6, from which lead metal falls progressively in the form of sponge lead, to be collected in the lowermost conical bottom 4.
  • the sponge lead can then be removed through the apex of the conical bottom 4 with the aid of means 16 intended herefor.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Metals (AREA)
EP86850290A 1985-09-05 1986-09-04 Procédé de récupération sélective du plomb à partir de minearais complexes sulfurés de métaux non ferreux Expired - Lifetime EP0219473B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE8504140 1985-05-09
SE8504140A SE8504140L (sv) 1985-09-05 1985-09-05 Forfarande for selektiv utvinning av bly fran komplexa sulfidiska icke-jernmetallsliger

Publications (2)

Publication Number Publication Date
EP0219473A1 true EP0219473A1 (fr) 1987-04-22
EP0219473B1 EP0219473B1 (fr) 1990-07-04

Family

ID=20361307

Family Applications (1)

Application Number Title Priority Date Filing Date
EP86850290A Expired - Lifetime EP0219473B1 (fr) 1985-09-05 1986-09-04 Procédé de récupération sélective du plomb à partir de minearais complexes sulfurés de métaux non ferreux

Country Status (9)

Country Link
US (1) US4734172A (fr)
EP (1) EP0219473B1 (fr)
JP (1) JPS6260886A (fr)
AU (1) AU584450B2 (fr)
CA (1) CA1300554C (fr)
DE (1) DE3672443D1 (fr)
FI (1) FI81614C (fr)
SE (1) SE8504140L (fr)
ZA (1) ZA866571B (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5635051A (en) * 1995-08-30 1997-06-03 The Regents Of The University Of California Intense yet energy-efficient process for electrowinning of zinc in mobile particle beds

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3673061A (en) * 1971-02-08 1972-06-27 Cyprus Metallurg Process Process for the recovery of metals from sulfide ores through electrolytic dissociation of the sulfides
US4204922A (en) * 1977-12-06 1980-05-27 The Broken Hill Propietary Company Limited Simultaneous electrodissolution and electrowinning of metals from simple sulphides
WO1980002164A1 (fr) * 1979-04-09 1980-10-16 Dextec Metallurg Production de plomb a partir de minerais et concentres
EP0061392A1 (fr) * 1981-03-19 1982-09-29 Centre National De La Recherche Scientifique (Cnrs) Procédé et dispositif pour l'électrotraitement de matériaux composites pulvérulents
WO1984002356A1 (fr) * 1982-12-10 1984-06-21 Dextec Metallurg Cellule electrolytique pour la recuperation de metaux a partir de materiaux contenant du metal

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3673061A (en) * 1971-02-08 1972-06-27 Cyprus Metallurg Process Process for the recovery of metals from sulfide ores through electrolytic dissociation of the sulfides
US4204922A (en) * 1977-12-06 1980-05-27 The Broken Hill Propietary Company Limited Simultaneous electrodissolution and electrowinning of metals from simple sulphides
WO1980002164A1 (fr) * 1979-04-09 1980-10-16 Dextec Metallurg Production de plomb a partir de minerais et concentres
EP0061392A1 (fr) * 1981-03-19 1982-09-29 Centre National De La Recherche Scientifique (Cnrs) Procédé et dispositif pour l'électrotraitement de matériaux composites pulvérulents
WO1984002356A1 (fr) * 1982-12-10 1984-06-21 Dextec Metallurg Cellule electrolytique pour la recuperation de metaux a partir de materiaux contenant du metal

Also Published As

Publication number Publication date
EP0219473B1 (fr) 1990-07-04
FI81614B (fi) 1990-07-31
AU584450B2 (en) 1989-05-25
JPS6260886A (ja) 1987-03-17
AU6152586A (en) 1987-03-12
FI863351A (fi) 1987-03-06
CA1300554C (fr) 1992-05-12
SE8504140D0 (sv) 1985-09-05
FI81614C (fi) 1990-11-12
ZA866571B (en) 1987-05-27
FI863351A0 (fi) 1986-08-19
DE3672443D1 (de) 1990-08-09
US4734172A (en) 1988-03-29
SE8504140L (sv) 1987-03-06

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