US736036A - Apparatus for the recovery of precious metals. - Google Patents
Apparatus for the recovery of precious metals. Download PDFInfo
- Publication number
- US736036A US736036A US15851703A US1903158517A US736036A US 736036 A US736036 A US 736036A US 15851703 A US15851703 A US 15851703A US 1903158517 A US1903158517 A US 1903158517A US 736036 A US736036 A US 736036A
- Authority
- US
- United States
- Prior art keywords
- mercury
- interspace
- vessel
- precious metals
- conduit
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/10—Obtaining noble metals by amalgamating
Definitions
- the present invention relates to an imro proved method and apparatus for the recovery of precious metals from liquids containing them either in solution or suspension.
- the sufficiently finely ground ores or pulps mixed with a solvent or leached, filtered, or decanted solutions containing the values are passed up through a continuous vertical or inclined column, film, or sheet of mercury kept continuously charged with an electropositive metal, such as sodium, in order to decompose the compounds of the precious metals presented to the so-prepared mercury.
- an electropositive metal such as sodium
- a convenient form of apparatus comprises a series of two or more concentric inverted conical vessels, of which the center one may be a core, so arranged that an interspace of suitable width is maintained between the inner surface of one vess'el'and the outer surface of the next vessel.
- the vessels or cones are constructed of or covered with copper or other suitable metal, and the metal surfaces being amalgamated insure the maximum contact between the ore or solvent passing upward through the apparatus and the amalgam.
- any other convenient form of-apparatus may be used-- 40 for example, vertical hollow concentric cylinders, plain or fluted, or a'vessel containing a number of small tubes, rods, or baffles.
- a stream of sodium amalgam preferably continuous, is run into the extraction apparatus, while a corresponding amount of mercury depleted of electropositive metal is withdrawn.
- Such amalgam may be prepared by any well-known electrolytic method, as by the decomposition of an electrolyte-such as sodiumchlorid,hydrate,orcarbonatewith a cathode of mercury, by the introduction of metallic sodium into-mercury, or otherwise.v
- the electrolytic cell for preparing the desired amalgam may be separate from and placed outside the extraction apparatus and may be of anysuitable type, so arranged that mercury may becontinuously fed into it and the sodium or other amalgam produced there- I from continuously runoif into the extraction 6o apparatus, or the electrolytic cell may be part of the extraction apparatus, and theelectrolyte is then separated from the mercury amalgamby a porous diaphragm, such as a porous pot or cell or equivalent, the Whole being so arranged that the material under treatment is not submitted to direct electrolysis, but that the electropositive metal is continually deposited into the mercury from the electrolyte.
- an inverted conical vessel B of copper, and within it is a concentric copper cone 0, a narrow interspace D being left between the surfaces.
- the outer cone B is provided at the top with a launder E, having an outlet-pipe E, and the cone B terminates at the bottom in an inlet B, attached to a sleeve F.
- the apex of the inner cone 0 rests in a hollow socketG, which is carried on an externally-screwed tube F, which engages the inside of the sleeve F, and by screwing the tube F within the sleeve F the socket G and inner cone 0 can be raised or lowered and the distance between the cones varied.
- Apertures G are provided in the sides of the socket to allow of free pas- 9'0 sage of liquid through the socket G, which thus acts also as a distributor.
- the launder E carries a frame H, in which is screwed a central vertical pin J, serving as a support for the inner cone 0, and for this purpose the cone 0 has an axis 0, rigidly held in the center of the cone by stays G and'engaging with the pin J.
- the pin J can be correspondingly screwed up or down.
- the tube F is too attached to a union K, which is connected, through a non-return valve L and a pump, with suitable mixing or dissolving apparatus.
- a mercury-distributing cup 0 having outlet-tubes O, which conduct mercury to the interspace between the cones B O at any convenient height below the normal working level of the mercury between the cones, a groove 13 being formed on the outer cone B at the level of the mercury-inlet.
- the mercury is supplied to the cup 0 through a pipe P from an electrolytic vessel P and may be fed either from the inside, as shown, or from the outside.
- the mercury Q in the electrolytic vessel forms the cathode of the circuit of an electrolytic battery S or other source, the anode being a conducting-plate T, immersed in the electrolyte R.
- the mercury is removed from the bottom of the cone B through an outlettap U, connected with a pump U, which discharges the mercury into the vessel P.
- a gage-glass B is provided on the outer cone B to indicate the height of the mercury.
- the operation of the apparatus is as follows:
- the mercury is charged with metallic sodium in the electrolytic vessel and is conducted through the pipe P, distributer O, and tubes 0 to the interspace D between the cones B C and completely fills the space D approximately to the level of the groove B
- a solvent such as potassium cyanid
- any undissolved particles of free gold after these have been sub mitted to the action of the solvent are also recovered.
- Astream of the sodium mercury is passed into the apparatus, as above described, and an equal quantity of mercury partially free from sodium, but now carrying values, is withdrawn through the tap U and returned by the pump U to the electrolytic apparatus P to be recharged with fresh sodium and again returned to the apparatus, and so on until the mercury is sufiiciently rich in precious metals to be withdrawn from the cycle of operations for the recovery by distillation, filtration, or the like of the contained precious metals.
- filter-pressing or decantation is avoided, as is also zinc-box precipitation.
- the apparatus may comprise more than two conical vessels or may be otherwise arranged to secure the distribution factor given by cones.
- the vertical angle of the cones may be as great as desired or the apparatus may be flat; but as hydrogen is apt to collect under the upper amalgamated plate in a flat apparatus placed horizontally it is preferable to use cones or other surfaces so shaped that the hydrogen generated tends to escape from between them.
- the mercury may be charged with sodium otherwise than by electrolysis.
- This process is also applicable to the recovery of precious metals from solutions that have been removed by previous filtration or decantation from crushed ore or slimes.
- the mercury in circuit with an electric current in such manner that no electrolysis of the solutions containing the precious metals can take place but with the object of keeping the mercury amalgam in a highly efficient and active condition.
- the solution may be fed in through a central tube.
- an apparatus for recovering precious metals the combination of a vessel having an inner amalgamated surface, a body having its outer surface amalgamated disposed within the vessel and forming therewith a narrow interspace, a body of mercury charged with an electropositive metal in the interspace, an apparatus for charging the mercury with the electropositive metal, an inlet conduit for mercury from said apparatus to the top of the interspace, an outletconduit for mercury from the bottom of the interspace to said apparatus, and means for forcing the solution carrying the values upward through the interspace.
- an apparatus for recovering precious metals the combination of a vessel having an inner amalgamated surface, a body having its outer surface amalgamated disposed within the vessel and forming therewith a narrow interspace, a body of mercury charged with an electropositive metal in the interspace, an apparatus for charging the mercury with the electropositive metal, an inlet-conduit for mercury from said apparatus to the top of the interspace, an outletconduit for mercury from the bottom of the interspace to said apparatus, an inlet-conduit at the bottom of the vessel for the solution carrying the values, an outlet-conduit at the top of the vessel for solution, and means for forcing the solution upward through the interspace.
- an apparatus for recovering precious metals the combination of a vessel having an inner amalgamated surface, a body having its outer surface amalgamated disposed Within the vessel and forming therewith a narrow IIIO interspace, means for varying the interspace, a body of mercury charged with an electropositive metal in the interspace, an apparatus for charging the mercury with the electropositive metal, an inlet-conduit for mercury from said apparatus to the top of the interspace, an outlet-conduit for mercury from the bottom of the interspace to said apparatus, an inlet-conduit at the bottom of the vessel for the solution carrying the values, an out let-conduit at the top of the vessel for solution, and means for forcing the solution upward through the interspace.
- a conical vessel havinganinner amalgamated-coppersurface a conical body having an outer amalgamatedcopper surface disposed concentrically within the vessel and forming therewith a narrow interspace, a body of mercury charged with an electropositive metal in the interspace, an electrolytic vesssel for charging the mercury, a mercury-pump, an inlet-conduit to the top of the interspace from the electrolytic vessel, an outlet-conduit for mercury from the bottom of the interspace to the pump, a conduit from the pump to the electrolytic vessel, and means for forcing the solution carrying the values up through the interspace.
- a conical vessel having aninneramalgamated-copper surface a conical body having an outer amalgamatedcopper surface disposed concentrically within the vessel and forming therewith a narrow interspace, a body of mercury charged with an electropositive metal in the interspace, an electrolytic vessel for charging the mercury, a mercury-pump, an inlet-conduit to the top of the interspace from the electrolytic vessel, an outlet-conduit formercury from the bottom of the interspace to the pump, aconduit from the pump to the electrolytic vessel, an inlet-conduit at the bottom of the vessel for the solution carrying the values, means for forcing the solution up through the interspace, and a launder at the top of the vessel to receive the discharged solution.
- a conical vessel having an inner am algamated-copper surface
- a conical body having an outer amalgamatedcopper surface disposed concentrically within the vessel and forming therewith a narrow interspace
- a body of mercury charged with an electropositive metal in the interspace
- an electrolytic vessel for charging the mercury
- a mercury-pump an inlet-conduit to the top of the interspace from the electrolytic vessel
- an outlet-conduit for mercury from the bottom of the interspace to the pump aconduit from the pump to the electrolytic vessel
- an inlet-conduit at the bottom of the vessel for the solution carrying the values a non-return valve in said conduit
- a conical body having an outer amalgamated-' copper surface disposed concentrically within the vessel and forming therewith a narrow interspace, means for vertically moving the inner cone to vary the interspace, a body of mercury charged with an electropositive metal in the interspace, an electrolytic vessel for charging the mercury, a mercury-pump,
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Electrolytic Production Of Metals (AREA)
Description
PATENTED AUG. 11, 1903.
APPLICATION FILED MAY 23, 1903.
H. L. SULMAN & H. F. KIRKPATRIGK-PIGARD. APPARATUS FOR THE RECOVERY OF PRECIOUS METALS- 0 MODEL.
THE NORRS ET NlTED STATES Patented August 11, 1903.
PATENT OFFICE.
HENRY LIVINGSTONE SULMAN AND HUGH FITZALIS KIRKPATRICK-PIOARD,
OF LONDON, ENGLAND.
APPARATUS FOR THE RECOVERY OF PRECIOUS METALS.
SPECIFICATION forming part of Letters Patent NO. 736,036, dated August 11, 1903.
Application filed May 23, 1903. Serial No. 158,517. (No model.)
T aZZ whom it may concern:
Be it known that we, HENRY LIVINGSTONE SULMAN and HUGH FITZALIS KIRKPATRICK- PICARD, subjects of the King of England, re-
siding at London, England, have invented certain new and useful Improvements in or Relating to the Recovery of Precious Metals, of which the following is a specification.
The present invention relates to an imro proved method and apparatus for the recovery of precious metals from liquids containing them either in solution or suspension.
According to this invention the sufficiently finely ground ores or pulps mixed with a solvent or leached, filtered, or decanted solutions containing the values are passed up through a continuous vertical or inclined column, film, or sheet of mercury kept continuously charged with an electropositive metal, such as sodium, in order to decompose the compounds of the precious metals presented to the so-prepared mercury.
In carrying out the process the mercury is conveniently contained in the narrow interspace between two or more inclined or vertical surfaces, and in practice a convenient form of apparatus comprises a series of two or more concentric inverted conical vessels, of which the center one may be a core, so arranged that an interspace of suitable width is maintained between the inner surface of one vess'el'and the outer surface of the next vessel. The vessels or cones are constructed of or covered with copper or other suitable metal, and the metal surfaces being amalgamated insure the maximum contact between the ore or solvent passing upward through the apparatus and the amalgam. Any other convenient form of-apparatus may be used-- 40 for example, vertical hollow concentric cylinders, plain or fluted, or a'vessel containing a number of small tubes, rods, or baffles. In order to maintain the mercury in an efficient condition, a stream of sodium amalgam, preferably continuous, is run into the extraction apparatus, while a corresponding amount of mercury depleted of electropositive metal is withdrawn. Such amalgam may be prepared by any well-known electrolytic method, as by the decomposition of an electrolyte-such as sodiumchlorid,hydrate,orcarbonatewith a cathode of mercury, by the introduction of metallic sodium into-mercury, or otherwise.v The electrolytic cell for preparing the desired amalgam may be separate from and placed outside the extraction apparatus and may be of anysuitable type, so arranged that mercury may becontinuously fed into it and the sodium or other amalgam produced there- I from continuously runoif into the extraction 6o apparatus, or the electrolytic cell may be part of the extraction apparatus, and theelectrolyte is then separated from the mercury amalgamby a porous diaphragm, such as a porous pot or cell or equivalent, the Whole being so arranged that the material under treatment is not submitted to direct electrolysis, but that the electropositive metal is continually deposited into the mercury from the electrolyte.
The accompanying drawing is a perspective view, partly in section, of one form of apparatus suitable for carrying out this invention.
On a base A is supported an inverted conical vessel B, of copper, and within it is a concentric copper cone 0, a narrow interspace D being left between the surfaces. The outer cone B is provided at the top with a launder E, having an outlet-pipe E, and the cone B terminates at the bottom in an inlet B, attached to a sleeve F. The apex of the inner cone 0 rests in a hollow socketG, which is carried on an externally-screwed tube F, which engages the inside of the sleeve F, and by screwing the tube F within the sleeve F the socket G and inner cone 0 can be raised or lowered and the distance between the cones varied. Apertures G are provided in the sides of the socket to allow of free pas- 9'0 sage of liquid through the socket G, which thus acts also as a distributor. The launder E carries a frame H, in which is screwed a central vertical pin J, serving as a support for the inner cone 0, and for this purpose the cone 0 has an axis 0, rigidly held in the center of the cone by stays G and'engaging with the pin J. When adjusting the inner cone 0 in position, the pin J can be correspondingly screwed up or down. The tube F is too attached to a union K, which is connected, through a non-return valve L and a pump, with suitable mixing or dissolving apparatus.
At the top of the inner cone 0 is a mercury-distributing cup 0, having outlet-tubes O, which conduct mercury to the interspace between the cones B O at any convenient height below the normal working level of the mercury between the cones, a groove 13 being formed on the outer cone B at the level of the mercury-inlet. The mercury is supplied to the cup 0 through a pipe P from an electrolytic vessel P and may be fed either from the inside, as shown, or from the outside. The mercury Q in the electrolytic vessel forms the cathode of the circuit of an electrolytic battery S or other source, the anode being a conducting-plate T, immersed in the electrolyte R. The mercury is removed from the bottom of the cone B through an outlettap U, connected with a pump U, which discharges the mercury into the vessel P. A gage-glass B is provided on the outer cone B to indicate the height of the mercury.
The operation of the apparatus is as follows: The mercury is charged with metallic sodium in the electrolytic vessel and is conducted through the pipe P, distributer O, and tubes 0 to the interspace D between the cones B C and completely fills the space D approximately to the level of the groove B The sufficiently finely ground ore or slimes, mixed or previously treated with a solvent, such as potassium cyanid, are forced bya suitable pump through the valve L into the pipe F and up through the interspace' D containing sodium'amalgam, with the result that the double cyanid of precious metal and potassium or other precious-metal compounds held in solution are decomposed and the precious metal is retained by the mercury as an amal garn. At the same time any undissolved particles of free gold after these have been sub mitted to the action of the solvent are also recovered. Astream of the sodium mercury is passed into the apparatus, as above described, and an equal quantity of mercury partially free from sodium, but now carrying values, is withdrawn through the tap U and returned by the pump U to the electrolytic apparatus P to be recharged with fresh sodium and again returned to the apparatus, and so on until the mercury is sufiiciently rich in precious metals to be withdrawn from the cycle of operations for the recovery by distillation, filtration, or the like of the contained precious metals. By this process of treatment filter-pressing or decantation is avoided, as is also zinc-box precipitation.
The apparatus may comprise more than two conical vessels or may be otherwise arranged to secure the distribution factor given by cones. The vertical angle of the cones may be as great as desired or the apparatus may be flat; but as hydrogen is apt to collect under the upper amalgamated plate in a flat apparatus placed horizontally it is preferable to use cones or other surfaces so shaped that the hydrogen generated tends to escape from between them. The mercury may be charged with sodium otherwise than by electrolysis.
This process is also applicable to the recovery of precious metals from solutions that have been removed by previous filtration or decantation from crushed ore or slimes.
In the treatment of some solutions and of some ores suspended therein it may be advantageous to put the mercury in circuit with an electric current in such manner that no electrolysis of the solutions containing the precious metals can take place but with the object of keeping the mercury amalgam in a highly efficient and active condition. If desired, the solution may be fed in through a central tube.
What we claim as our invention, and desire to secure by Letters Patent, is-
1. In an apparatus for recovering precious metals the combination of a vessel having an inner amalgamated surface, a body having its outer surface amalgamated disposed within the vessel and forming therewith a narrow interspace, a body of mercury continuously charged with an electropositive metal in the interspace, and means for forcing the solution carrying the values upward through the interspace.
2. In an apparatus for recovering precious metals the combination of a vessel having an inner amalgamated surface, a body having its outer surface amalgamated disposed within the vessel and forming therewith a narrow interspace, a body of mercury charged with an electropositive metal in the interspace, an apparatus for charging the mercury with the electropositive metal, an inlet conduit for mercury from said apparatus to the top of the interspace, an outletconduit for mercury from the bottom of the interspace to said apparatus, and means for forcing the solution carrying the values upward through the interspace.
3. In an apparatus for recovering precious metals the combination of a vessel having an inner amalgamated surface, a body having its outer surface amalgamated disposed within the vessel and forming therewith a narrow interspace, a body of mercury charged with an electropositive metal in the interspace, an apparatus for charging the mercury with the electropositive metal, an inlet-conduit for mercury from said apparatus to the top of the interspace, an outletconduit for mercury from the bottom of the interspace to said apparatus, an inlet-conduit at the bottom of the vessel for the solution carrying the values, an outlet-conduit at the top of the vessel for solution, and means for forcing the solution upward through the interspace.
4. In an apparatus for recovering precious metals the combination of a vessel having an inner amalgamated surface, a body having its outer surface amalgamated disposed Within the vessel and forming therewith a narrow IIIO interspace, means for varying the interspace, a body of mercury charged with an electropositive metal in the interspace, an apparatus for charging the mercury with the electropositive metal, an inlet-conduit for mercury from said apparatus to the top of the interspace, an outlet-conduit for mercury from the bottom of the interspace to said apparatus, an inlet-conduit at the bottom of the vessel for the solution carrying the values, an out let-conduit at the top of the vessel for solution, and means for forcing the solution upward through the interspace.
5. In an apparatus for recovering precious metals the combination of a conical vessel having an inner amalgamated surface, a conical body having an outer amalgamated surface disposed concentrically within the vessel and forming therewith a narrow interspace, a body of mercury continuously charged with an electropositive metal in the interspace, and means for forcing the solution carrying the values up through the interspace.
6. In an apparatus for recovering precious metals the combination of a conical vessel havingan inneramalgamated-copper surface, a conical body having an outer amalgamatedcopper surface disposed concentrically within the vessel and forming therewith a narrow interspace, a body of mercury continuously charged with an electropositive metal in the interspace, and means for forcing the solution carrying the values up through the interspace.
7. In an apparatus for recovering precious metals the combination of a conical vessel havinganinner amalgamated-coppersurface, a conical body having an outer amalgamatedcopper surface disposed concentrically within the vessel and forming therewith a narrow interspace, a body of mercury charged with an electropositive metal in the interspace, an electrolytic vesssel for charging the mercury, a mercury-pump, an inlet-conduit to the top of the interspace from the electrolytic vessel, an outlet-conduit for mercury from the bottom of the interspace to the pump, a conduit from the pump to the electrolytic vessel, and means for forcing the solution carrying the values up through the interspace.
8. In an apparatus for recovering precious metals the combination of a conical vessel having aninneramalgamated-copper surface, a conical body having an outer amalgamatedcopper surface disposed concentrically within the vessel and forming therewith a narrow interspace, a body of mercury charged with an electropositive metal in the interspace, an electrolytic vessel for charging the mercury, a mercury-pump, an inlet-conduit to the top of the interspace from the electrolytic vessel, an outlet-conduit formercury from the bottom of the interspace to the pump, aconduit from the pump to the electrolytic vessel, an inlet-conduit at the bottom of the vessel for the solution carrying the values, means for forcing the solution up through the interspace, and a launder at the top of the vessel to receive the discharged solution.
9. In an apparatus for recovering precious metals the combination of a conical vessel having an inner am algamated-copper surface, a conical body having an outer amalgamatedcopper surface disposed concentrically within the vessel and forming therewith a narrow interspace, a body of mercury charged with an electropositive metal in the interspace, an electrolytic vessel for charging the mercury, a mercury-pump, an inlet-conduit to the top of the interspace from the electrolytic vessel, an outlet-conduit for mercury from the bottom of the interspace to the pump, aconduit from the pump to the electrolytic vessel, an inlet-conduit at the bottom of the vessel for the solution carrying the values, a non-return valve in said conduit, means for forcing the solution up through the interspace, and a launder at the top of the vessel to receive the discharged solution.
'10. In an apparatus for recovering precious metals the combination of a conical vessel having an inneramalgamated-coppersurface,
a conical body having an outer amalgamated-' copper surface disposed concentrically within the vessel and forming therewith a narrow interspace, means for vertically moving the inner cone to vary the interspace, a body of mercury charged with an electropositive metal in the interspace, an electrolytic vessel for charging the mercury, a mercury-pump,
an inlet-conduit to the top of the interspace from the electrolytic vessel an outlet-conduit for mercury from the bottom of the interspace to the pump, a conduit from the pump to the electrolytic vessel, an inlet-conduit at the bottom of the vessel for the solution carrying the values, a non-return valve in said In testimony whereof we have signed our names to this specification in the presence of two subscribing witnesses.
HENRY LIVINGSTONE SULMAN. HUGH FlTZALlS KIRKPATRIOK-PIOARD.
Witnesses:
CLAUDE MCKENZIE, G. O. WILLIAMS.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US15851703A US736036A (en) | 1903-05-23 | 1903-05-23 | Apparatus for the recovery of precious metals. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US15851703A US736036A (en) | 1903-05-23 | 1903-05-23 | Apparatus for the recovery of precious metals. |
Publications (1)
Publication Number | Publication Date |
---|---|
US736036A true US736036A (en) | 1903-08-11 |
Family
ID=2804544
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US15851703A Expired - Lifetime US736036A (en) | 1903-05-23 | 1903-05-23 | Apparatus for the recovery of precious metals. |
Country Status (1)
Country | Link |
---|---|
US (1) | US736036A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2657989A (en) * | 1950-08-17 | 1953-11-03 | Ruthner Othmar | Separation of metals in powder form from their salt solutions |
-
1903
- 1903-05-23 US US15851703A patent/US736036A/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2657989A (en) * | 1950-08-17 | 1953-11-03 | Ruthner Othmar | Separation of metals in powder form from their salt solutions |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3974049A (en) | Electrochemical process | |
US3787293A (en) | Method for hydroelectrometallurgy | |
JP3431148B2 (en) | Electrochemical system for recovery of metals from metal compounds. | |
US736036A (en) | Apparatus for the recovery of precious metals. | |
US3721611A (en) | Process for the production of metals | |
US2872393A (en) | Production of lithium hydroxide | |
US567503A (en) | pelatan | |
US1231967A (en) | Electrolytic recovery of metals from their solutions and in apparatus therefor. | |
US809089A (en) | Process of making caustic alkali. | |
US1467202A (en) | Process of and apparatus for separating platinum from platiniferous materials | |
RU2245378C1 (en) | Method of leaching-out polymetallic raw material and device for realization of this method | |
US3382163A (en) | Method of electrolytic extraction of metals | |
JPS6267191A (en) | Electrolytic collection cell | |
US1209835A (en) | Process of treating materials electrolytically. | |
US756223A (en) | Process of treating low-grade ores and tailings by electrolysis. | |
US214344A (en) | Improvement in separating metals by electrolysis | |
US528023A (en) | Louis pelatan | |
US760539A (en) | Process of recovering metals from ores or sands. | |
US668283A (en) | Amalgamation of ores. | |
JP3055821B2 (en) | Method and apparatus for high current density electrolysis | |
US818174A (en) | Process of reclaiming waste gold and other valuable metals from water and other liquids. | |
US3068165A (en) | Mercury cathode electrolytic cell | |
KR101941558B1 (en) | Method for electrolytically refining of coarse copper recovered from scrap of a printed circuit board | |
US661188A (en) | Process of separating metals from their combinations. | |
US3616431A (en) | Bipolar mercury cathode cell with mercury splitter |