EP0195770A1 - Procédé pour la production de la fonte liquide ou de préproduits en acier - Google Patents
Procédé pour la production de la fonte liquide ou de préproduits en acier Download PDFInfo
- Publication number
- EP0195770A1 EP0195770A1 EP86890063A EP86890063A EP0195770A1 EP 0195770 A1 EP0195770 A1 EP 0195770A1 EP 86890063 A EP86890063 A EP 86890063A EP 86890063 A EP86890063 A EP 86890063A EP 0195770 A1 EP0195770 A1 EP 0195770A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- oxygen
- fixed bed
- fluidized bed
- containing gas
- iron
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 13
- 229910000805 Pig iron Inorganic materials 0.000 title claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 4
- 239000010959 steel Substances 0.000 title claims abstract description 4
- 239000007789 gas Substances 0.000 claims abstract description 39
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000002245 particle Substances 0.000 claims abstract description 24
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 22
- 239000001301 oxygen Substances 0.000 claims abstract description 22
- 239000000571 coke Substances 0.000 claims abstract description 16
- 229910052742 iron Inorganic materials 0.000 claims abstract description 15
- 239000003245 coal Substances 0.000 claims abstract description 12
- 239000000463 material Substances 0.000 claims abstract description 7
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims abstract description 3
- 238000007664 blowing Methods 0.000 claims abstract description 3
- 229910001882 dioxygen Inorganic materials 0.000 claims abstract 2
- 238000010405 reoxidation reaction Methods 0.000 abstract description 2
- 239000007788 liquid Substances 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- 239000002893 slag Substances 0.000 description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 description 1
- 239000003830 anthracite Substances 0.000 description 1
- 230000001914 calming effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000011551 heat transfer agent Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 238000010079 rubber tapping Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/0006—Making spongy iron or liquid steel, by direct processes obtaining iron or steel in a molten state
- C21B13/0013—Making spongy iron or liquid steel, by direct processes obtaining iron or steel in a molten state introduction of iron oxide into a bath of molten iron containing a carbon reductant
- C21B13/002—Reduction of iron ores by passing through a heated column of carbon
Definitions
- the invention relates to a process for the production of molten pig iron or intermediate steel products from particulate ferrous material, in particular from pre-reduced iron sponge, and for the production of reducing gas in a melter gasifier by adding coal and by blowing in oxygen-containing gas by means of nozzle pipes penetrating the wall of the melter gasifier, one of which being a fixed bed of coke particles through which the oxygen-containing gas flows and above which a fluidized bed (fluidized bed) of coke particles is formed and the iron-containing material is given to the fluidized bed.
- EP-A1-0 114 040 A method of the type described is described in EP-A1-0 114 040, the oxygen-containing gas being introduced at two different levels, respectively into the fixed bed and into the fluid bed of coke particles above it.
- the invention aims at avoiding the difficulties described and has as its object to avoid reoxidation of the molten products in the melter and to reduce the primary energy requirement.
- This object is achieved according to the invention in a method of the type described in the introduction in that a non-gasified fixed bed of coke particles is provided below the fixed bed through which oxygen-containing gas flows and in that the fluidized bed is flowed through by oxygen-free or oxygen-poor gas over the fixed bed through which oxygen-containing gas flows.
- the height of the fixed bed through which oxygen-containing gas flows is expediently set and maintained via the grain size distribution of the coal introduced into the melter gasifier.
- the fixed bed can be particularly pronounced if the co-classification of the coarse fraction of the coal introduced is within narrow limits.
- the refractory lined melter 1 has a lower section 1 ', a middle section 1 "and an enlarged upper section 1" ".
- the lower section 1 ' is intended for receiving the molten bath.
- at least one discharge 5 for the reducing gas formed is provided in the upper section.
- coarser coke sticks are used to form the fixed beds (fixed bed zones) labeled I and II.
- the melt pool that accumulates underneath consists of - molten metal 6 and the slag 7, whereby a tapping can be provided for both components.
- the fixed bed I has no gas supply, so it is not gas-fired.
- the fixed bed II is formed, in which the coke particles are flowed through by the oxygen-containing gas flowing in from the supply lines 2 to form carbon monoxide
- the gas supply lines are only kept in motion by the reaction gases in the fixed bed II, which contain carbon monoxide.
- Small coal or coke particles remain in the fluidized bed zone III. Larger coal or coke particles, for which the empty pipe speed of the gas flow is below the loosening point for a ent protruding particle bed, are only slowed down, fall through the fluidized bed III and settle to form the fixed bed II or the fixed bed I.
- zone III As a result of the fact that zone III is not exposed to oxygen or oxygen-containing gas, there is a reducing gas atmosphere in this zone, as a result of which the carbon content of the pre-reduced iron-containing particles, such as sponge iron, introduced from above is retained
- the heat required for the process is generated in a known manner by gasifying coal, the sponge iron to be melted is countercurrently communicated, and the melt formed, consisting of slag and metal, is overheated.
- the overheating must be so strong (approx. that the heat demand for the endothermic reactions taking place in the fixed bed zones I and II is covered and that the melt collected in the lower part of the melter gasifier still has a temperature sufficient for the further treatment.
- Another advantage of the method according to the invention is that the assembly or. Instrumentation effort is lower because, compared to the method of operation mentioned at the beginning, there is no nozzle plane
- the slag or Metal bath had a temperature of 1400 to 1500 ° C; in the expanded upper section 1 ′′ of the melter gasifier, a gas temperature of 1500 ° C. was measured at the upper limit of the fluidized bed III, and a gas temperature of 1100 ° C. in the so-called calming zone above.
- the reducing gas was withdrawn via outlets 5 in an amount of 1330 m 3 (under normal conditions) / t of pig iron, the pig iron formed had a C content of 3.5%, an Si content of 0.3% and an S content of 0.1%.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Iron (AREA)
- Crucibles And Fluidized-Bed Furnaces (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Casting Support Devices, Ladles, And Melt Control Thereby (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT0084685A AT382390B (de) | 1985-03-21 | 1985-03-21 | Verfahren zur herstellung von fluessigem roheisen oder stahlvorprodukten |
AT846/85 | 1985-03-21 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0195770A1 true EP0195770A1 (fr) | 1986-09-24 |
EP0195770B1 EP0195770B1 (fr) | 1988-12-14 |
Family
ID=3501117
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP86890063A Expired EP0195770B1 (fr) | 1985-03-21 | 1986-03-17 | Procédé pour la production de la fonte liquide ou de préproduits en acier |
Country Status (15)
Country | Link |
---|---|
US (1) | US4708736A (fr) |
EP (1) | EP0195770B1 (fr) |
JP (1) | JPS61221315A (fr) |
KR (1) | KR930007308B1 (fr) |
CN (1) | CN86101817B (fr) |
AT (1) | AT382390B (fr) |
AU (1) | AU574906B2 (fr) |
BR (1) | BR8601242A (fr) |
CA (1) | CA1268633A (fr) |
CS (1) | CS264273B2 (fr) |
DD (1) | DD247025A5 (fr) |
DE (1) | DE3661424D1 (fr) |
IN (1) | IN166414B (fr) |
SU (1) | SU1473716A3 (fr) |
ZA (1) | ZA861922B (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998021370A1 (fr) * | 1996-11-08 | 1998-05-22 | Voest-Alpine Industrieanlagenbau Gmbh | Procede de transformation de minerais de fer en fonte brute liquide ou en produits bruts en acier |
WO2009062611A1 (fr) * | 2007-11-13 | 2009-05-22 | Siemens Vai Metals Technologies Gmbh & Co | Procédé de fabrication et de fusion de fonte brute liquide ou de demi-produits d'acier liquide dans un gazéificateur de fusion |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT386006B (de) * | 1986-10-30 | 1988-06-27 | Voest Alpine Ag | Verfahren und anlage zur gewinnung von metallen bzw. metallegierungen |
AT386007B (de) * | 1986-10-30 | 1988-06-27 | Voest Alpine Ag | Verfahren und anlage zur gewinnung von metallen bzw. metallegierungen |
EP0297167B1 (fr) * | 1987-06-30 | 1993-08-11 | Kawasaki Steel Corporation | Procédé et appareil pour la production de métal liquide à partir de poudres de minerai |
BE1006828A3 (fr) * | 1991-07-12 | 1995-01-03 | Elsen Tooling Ireland Ltd | Procede en vue de la preparation de metaux, et en particulier de fer, a partir de minerais oxydes, a une temperature de reduction quelconque, dans un four de reduction a gouttes. |
US5354356A (en) * | 1992-10-06 | 1994-10-11 | Bechtel Group Inc. | Method of providing fuel for an iron making process |
US6197088B1 (en) | 1992-10-06 | 2001-03-06 | Bechtel Group, Inc. | Producing liquid iron having a low sulfur content |
US5320676A (en) * | 1992-10-06 | 1994-06-14 | Bechtel Group, Inc. | Low slag iron making process with injecting coolant |
US5397376A (en) * | 1992-10-06 | 1995-03-14 | Bechtel Group, Inc. | Method of providing fuel for an iron making process |
US5958107A (en) * | 1993-12-15 | 1999-09-28 | Bechtel Croup, Inc. | Shift conversion for the preparation of reducing gas |
AT503593B1 (de) * | 2006-04-28 | 2008-03-15 | Siemens Vai Metals Tech Gmbh | Verfahren zur herstellung von flüssigem roheisen oder flüssigen stahlvorprodukten aus feinteilchenförmigem eisenoxidhältigem material |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3216019A1 (de) * | 1981-06-10 | 1983-01-27 | Sumitomo Metal Industries, Ltd., Osaka | Kohlevergasung und roheisenherstellung und vorrichtung dafuer |
DE3345106A1 (de) * | 1983-01-03 | 1984-07-12 | Voest-Alpine Ag, Wien | Verfahren zum schmelzen von zumindest teilweise reduziertem eisenerz |
EP0114040A1 (fr) * | 1982-12-21 | 1984-07-25 | VOEST-ALPINE Aktiengesellschaft | Procédé et gazéificateur de fusion pour la production de la fonte brute liquide ou de produits de base de l'acier |
DD226157A3 (de) * | 1983-06-01 | 1985-08-14 | Bandstahlkombinat Matern Veb | Verfahren zur erzeugung von fluessigem roheisen und reduktionsgas in einem abstichgenerator |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3948640A (en) * | 1973-04-30 | 1976-04-06 | Boliden Aktiebolag | Method of carrying out heat-requiring chemical and/or physical processes |
DE3438487A1 (de) * | 1984-10-17 | 1986-04-24 | Korf Engineering GmbH, 4000 Düsseldorf | Verfahren zur herstellung von roheisen |
SU1479006A3 (ru) * | 1984-11-26 | 1989-05-07 | Фоест-Альпине (Фирма) | Способ получени жидкого чугуна или продуктов стали и восстановительного газа в плавильном газификаторе |
DE3504346C2 (de) * | 1985-02-06 | 1986-11-27 | Korf Engineering GmbH, 4000 Düsseldorf | Verfahren und Vorrichtung zur Erzeugung von Eisenschwammpartikeln und flüssigem Roheisen |
-
1985
- 1985-03-21 AT AT0084685A patent/AT382390B/de not_active IP Right Cessation
-
1986
- 1986-03-11 IN IN225/DEL/86A patent/IN166414B/en unknown
- 1986-03-12 AU AU54664/86A patent/AU574906B2/en not_active Expired
- 1986-03-12 US US06/838,669 patent/US4708736A/en not_active Expired - Lifetime
- 1986-03-14 ZA ZA861922A patent/ZA861922B/xx unknown
- 1986-03-14 CA CA000504112A patent/CA1268633A/fr not_active Expired - Fee Related
- 1986-03-17 DE DE8686890063T patent/DE3661424D1/de not_active Expired
- 1986-03-17 EP EP86890063A patent/EP0195770B1/fr not_active Expired
- 1986-03-19 DD DD86288040A patent/DD247025A5/de unknown
- 1986-03-20 BR BR8601242A patent/BR8601242A/pt not_active IP Right Cessation
- 1986-03-20 CN CN86101817A patent/CN86101817B/zh not_active Expired
- 1986-03-20 CS CS861965A patent/CS264273B2/cs not_active IP Right Cessation
- 1986-03-20 SU SU864027155A patent/SU1473716A3/ru active
- 1986-03-20 JP JP61064659A patent/JPS61221315A/ja active Granted
- 1986-03-21 KR KR1019860002107A patent/KR930007308B1/ko not_active IP Right Cessation
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3216019A1 (de) * | 1981-06-10 | 1983-01-27 | Sumitomo Metal Industries, Ltd., Osaka | Kohlevergasung und roheisenherstellung und vorrichtung dafuer |
EP0114040A1 (fr) * | 1982-12-21 | 1984-07-25 | VOEST-ALPINE Aktiengesellschaft | Procédé et gazéificateur de fusion pour la production de la fonte brute liquide ou de produits de base de l'acier |
DE3345106A1 (de) * | 1983-01-03 | 1984-07-12 | Voest-Alpine Ag, Wien | Verfahren zum schmelzen von zumindest teilweise reduziertem eisenerz |
DD226157A3 (de) * | 1983-06-01 | 1985-08-14 | Bandstahlkombinat Matern Veb | Verfahren zur erzeugung von fluessigem roheisen und reduktionsgas in einem abstichgenerator |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998021370A1 (fr) * | 1996-11-08 | 1998-05-22 | Voest-Alpine Industrieanlagenbau Gmbh | Procede de transformation de minerais de fer en fonte brute liquide ou en produits bruts en acier |
CN1055503C (zh) * | 1996-11-08 | 2000-08-16 | 奥地利钢铁联合企业阿尔帕工业设备制造公司 | 用矿石生产生铁水或钢的预产物的方法 |
US6179896B1 (en) | 1996-11-08 | 2001-01-30 | Deutsche Voest-Alpine Industrieanlagenbau Gmbh | Process for producing liquid pig iron or semifinished steel products from ore |
WO2009062611A1 (fr) * | 2007-11-13 | 2009-05-22 | Siemens Vai Metals Technologies Gmbh & Co | Procédé de fabrication et de fusion de fonte brute liquide ou de demi-produits d'acier liquide dans un gazéificateur de fusion |
US8313552B2 (en) | 2007-11-13 | 2012-11-20 | Siemens Vai Metals Technologies Gmbh | Method for the production and the melting of liquid pig iron or of liquid steel intermediate products in a melt-down gasifier |
AU2008323317B2 (en) * | 2007-11-13 | 2014-01-09 | Posco | Method for the production and the melting of liquid pig iron or of liquid steel intermediate products in a melt-down gasifier |
Also Published As
Publication number | Publication date |
---|---|
KR860007386A (ko) | 1986-10-10 |
AT382390B (de) | 1987-02-25 |
JPS61221315A (ja) | 1986-10-01 |
ZA861922B (en) | 1986-11-26 |
CN86101817A (zh) | 1986-11-05 |
SU1473716A3 (ru) | 1989-04-15 |
JPS648044B2 (fr) | 1989-02-13 |
CN86101817B (zh) | 1988-07-06 |
AU574906B2 (en) | 1988-07-14 |
IN166414B (fr) | 1990-05-05 |
DE3661424D1 (en) | 1989-01-19 |
BR8601242A (pt) | 1986-12-02 |
US4708736A (en) | 1987-11-24 |
AU5466486A (en) | 1986-09-25 |
DD247025A5 (de) | 1987-06-24 |
CS196586A2 (en) | 1988-09-16 |
CA1268633A (fr) | 1990-05-08 |
KR930007308B1 (ko) | 1993-08-05 |
EP0195770B1 (fr) | 1988-12-14 |
ATA84685A (de) | 1986-07-15 |
CS264273B2 (en) | 1989-06-13 |
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