EP0191033A4 - Fuel compositions. - Google Patents

Fuel compositions.

Info

Publication number
EP0191033A4
EP0191033A4 EP19850903551 EP85903551A EP0191033A4 EP 0191033 A4 EP0191033 A4 EP 0191033A4 EP 19850903551 EP19850903551 EP 19850903551 EP 85903551 A EP85903551 A EP 85903551A EP 0191033 A4 EP0191033 A4 EP 0191033A4
Authority
EP
European Patent Office
Prior art keywords
fuels
fuel
polyolefin
additive
believed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP19850903551
Other languages
German (de)
French (fr)
Other versions
EP0191033A1 (en
Inventor
Kenneth Mekenon
Timothy J Tierney
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EPOCH INTERNATIONAL HOLDING SA
EPOCH INT HOLDING
Original Assignee
EPOCH INTERNATIONAL HOLDING SA
EPOCH INT HOLDING
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EPOCH INTERNATIONAL HOLDING SA, EPOCH INT HOLDING filed Critical EPOCH INTERNATIONAL HOLDING SA
Publication of EP0191033A1 publication Critical patent/EP0191033A1/en
Publication of EP0191033A4 publication Critical patent/EP0191033A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • C10L1/1625Hydrocarbons macromolecular compounds
    • C10L1/1633Hydrocarbons macromolecular compounds homo- or copolymers obtained by reactions only involving carbon-to carbon unsaturated bonds
    • C10L1/1641Hydrocarbons macromolecular compounds homo- or copolymers obtained by reactions only involving carbon-to carbon unsaturated bonds from compounds containing aliphatic monomers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/143Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • C10L1/1608Well defined compounds, e.g. hexane, benzene
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/19Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • C10L1/191Esters ester radical containing compounds; ester ethers; carbonic acid esters of di- or polyhydroxyalcohols
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/192Macromolecular compounds
    • C10L1/198Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
    • C10L1/1985Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyethers, e.g. di- polygylcols and derivatives; ethers - esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/222Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02BINTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B3/00Engines characterised by air compression and subsequent fuel addition
    • F02B3/06Engines characterised by air compression and subsequent fuel addition with compression ignition

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Control Of The Air-Fuel Ratio Of Carburetors (AREA)

Abstract

Improved fuels having significantly increased combustion efficiencies, desirable octane ratings and lowered polution emissions which are supplemented by a minor amount of a polyolefinic additive containing recurring C2-C10 monomer moieties therein. The fuels preferably include a liquid hydrocarbon such as a gasoline or diesel fuel, with up to about 2.5% by weight polyolefin, or in certain cases a polyolefin derivative. The most preferred additive for use in the fuel of the invention is polybutene. Stable emulsified fuels are also provided which comprise respective fractions of water, liquid combustible hydrocarbon, one or more surfactants, and a polyolefin additive. Test results demonstrate that the fuels of the invention exhibit greater work output per pound of fuel than straight unmodified comparative fuels. The presence of polyolefins in the fuel is believed to generate reactions analogous to cracking during combustion of the fuel compositions, with the resultant exothermic heats of reaction adding substantially to the caloric values obtained from the fuels; in the case of emulsified fuels for example, this factor is believed to compensate for the potential caloric loss represented by the presence of significant amounts of water.
EP19850903551 1984-06-27 1985-06-26 Fuel compositions. Withdrawn EP0191033A4 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US62504584A 1984-06-27 1984-06-27
US625045 1984-06-27

Publications (2)

Publication Number Publication Date
EP0191033A1 EP0191033A1 (en) 1986-08-20
EP0191033A4 true EP0191033A4 (en) 1986-11-05

Family

ID=24504349

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19850903551 Withdrawn EP0191033A4 (en) 1984-06-27 1985-06-26 Fuel compositions.

Country Status (13)

Country Link
EP (1) EP0191033A4 (en)
JP (1) JPS62500525A (en)
AU (1) AU4608585A (en)
BR (1) BR8506797A (en)
DK (1) DK88886A (en)
ES (1) ES8609441A1 (en)
FI (1) FI860839A0 (en)
HU (1) HUT40156A (en)
MW (1) MW1186A1 (en)
NO (1) NO860669L (en)
OA (1) OA08217A (en)
RO (1) RO95015A (en)
WO (1) WO1986000333A1 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8710955D0 (en) * 1987-05-08 1987-06-10 Shell Int Research Gasoline composition
GB9114237D0 (en) * 1991-07-02 1991-08-21 Exxon Chemical Patents Inc Fuel oil treatment
GB9114236D0 (en) * 1991-07-02 1991-08-21 Exxon Chemical Patents Inc Fuel oil treatment
JPH11514044A (en) * 1997-05-30 1999-11-30 スン、ユ、ヒュン Emulsion fuel
ES2140350B1 (en) * 1998-06-30 2000-11-16 I Feliu Tomas Coll AN ADDITIVE TO MAKE STABLE WATER EMULSIONS WITH OILS OR FATS IN THE FORM OF EMULSIONS OR FUELS AND USE OF SUCH ADDITIVE.
GB2364325A (en) * 2000-04-03 2002-01-23 World Rubber Ltd Calorific enhancer
DE10046678C2 (en) * 2000-07-12 2002-09-19 Valerij Albrandt fuel
US10995291B2 (en) * 2018-12-15 2021-05-04 Hka Hydrofuel, Llc Fuel compositions
EP4048760A1 (en) * 2019-10-22 2022-08-31 Shell Internationale Research Maatschappij B.V. Method for reducing intake valve deposits

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB399527A (en) * 1928-05-10 1933-10-04 Ig Farbenindustrie Ag A process for improving oils, especially lubricating oils
FR1188950A (en) * 1957-12-24 1959-09-28 Process for improving fuels intended for the production of motive power
GB1173788A (en) * 1966-04-29 1969-12-10 Texaco Development Corp Motor Fuel Composition
US3838990A (en) * 1968-10-23 1974-10-01 Standard Oil Co Middle distillate fuel oil compositions having improved pumpability
US3901665A (en) * 1972-10-06 1975-08-26 Du Pont Multi-functional fuel additive compositions
US3958915A (en) * 1974-02-15 1976-05-25 The Toyo Rubber Industry Co., Ltd. Method of burning emulsion oils
EP0022110A1 (en) * 1979-06-29 1981-01-07 Berol Kemi Ab Emulsifier and its use for the manufacture of an emulsion in mineral oil
GB1601174A (en) * 1977-02-23 1981-10-28 Lanko Inc Combustible emulsions or dispersions

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2550982A (en) * 1947-07-12 1951-05-01 Petrolite Corp Fog inhibited hydrocarbon product and method
US2873182A (en) * 1953-12-29 1959-02-10 Monsanto Chemicals Motor fuel
US3454379A (en) * 1964-10-23 1969-07-08 Sinclair Research Inc Hydrocarbon oil composition having improved low temperature pumpability
US3488704A (en) * 1966-05-27 1970-01-06 Exxon Research Engineering Co Lubricity agents
BE731123A (en) * 1968-04-11 1969-10-06
US4175926A (en) * 1974-09-18 1979-11-27 Exxon Research & Engineering Co. Polymer combination useful in fuel oil to improve cold flow properties
US4477258A (en) * 1980-10-30 1984-10-16 Labofina, S.A. Diesel fuel compositions and process for their production
US4381414A (en) * 1981-05-06 1983-04-26 Gulf Research & Development Company Fuel having reduced tendency to particulate dissemination under shock

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB399527A (en) * 1928-05-10 1933-10-04 Ig Farbenindustrie Ag A process for improving oils, especially lubricating oils
FR1188950A (en) * 1957-12-24 1959-09-28 Process for improving fuels intended for the production of motive power
GB1173788A (en) * 1966-04-29 1969-12-10 Texaco Development Corp Motor Fuel Composition
US3838990A (en) * 1968-10-23 1974-10-01 Standard Oil Co Middle distillate fuel oil compositions having improved pumpability
US3901665A (en) * 1972-10-06 1975-08-26 Du Pont Multi-functional fuel additive compositions
US3958915A (en) * 1974-02-15 1976-05-25 The Toyo Rubber Industry Co., Ltd. Method of burning emulsion oils
GB1601174A (en) * 1977-02-23 1981-10-28 Lanko Inc Combustible emulsions or dispersions
EP0022110A1 (en) * 1979-06-29 1981-01-07 Berol Kemi Ab Emulsifier and its use for the manufacture of an emulsion in mineral oil

Also Published As

Publication number Publication date
RO95015A (en) 1988-09-15
NO860669L (en) 1986-04-25
BR8506797A (en) 1986-11-25
EP0191033A1 (en) 1986-08-20
FI860839A (en) 1986-02-27
DK88886A (en) 1986-04-24
FI860839A0 (en) 1986-02-27
WO1986000333A1 (en) 1986-01-16
ES544573A0 (en) 1986-09-01
OA08217A (en) 1987-10-30
MW1186A1 (en) 1987-05-13
HUT40156A (en) 1986-11-28
ES8609441A1 (en) 1986-09-01
DK88886D0 (en) 1986-02-26
JPS62500525A (en) 1987-03-05
AU4608585A (en) 1986-01-24

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Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH DE FR GB IT LI LU NL SE

17P Request for examination filed

Effective date: 19860717

A4 Supplementary search report drawn up and despatched

Effective date: 19861105

R17P Request for examination filed (corrected)

Effective date: 19860715

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 19871231

RIN1 Information on inventor provided before grant (corrected)

Inventor name: TIERNEY, TIMOTHY, J.

Inventor name: MEKENON, KENNETH