EP0181369B1 - Verfahren zum färben einer flexiblen polymerbahn sowie nach diesem verfahren hergestellte produkte - Google Patents

Verfahren zum färben einer flexiblen polymerbahn sowie nach diesem verfahren hergestellte produkte Download PDF

Info

Publication number
EP0181369B1
EP0181369B1 EP85902282A EP85902282A EP0181369B1 EP 0181369 B1 EP0181369 B1 EP 0181369B1 EP 85902282 A EP85902282 A EP 85902282A EP 85902282 A EP85902282 A EP 85902282A EP 0181369 B1 EP0181369 B1 EP 0181369B1
Authority
EP
European Patent Office
Prior art keywords
film
transfer paper
paper
insulating film
heating means
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP85902282A
Other languages
English (en)
French (fr)
Other versions
EP0181369A1 (de
Inventor
James Louis Joyce, Jr.
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TE Connectivity Corp
Original Assignee
AMP Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by AMP Inc filed Critical AMP Inc
Publication of EP0181369A1 publication Critical patent/EP0181369A1/de
Application granted granted Critical
Publication of EP0181369B1 publication Critical patent/EP0181369B1/de
Expired legal-status Critical Current

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41F—PRINTING MACHINES OR PRESSES
    • B41F16/00—Transfer printing apparatus
    • B41F16/02—Transfer printing apparatus for textile material

Definitions

  • This invention relates to the manufacture of conductor cables and in particular to the manufacture of multiconductor flat flexible cables.
  • Conductor cables typically are comprised of a number of longitudinally extended spaced-apart conductor elements encapsulated within an insulating sheath.
  • the conductor elements may be composed of any suitable electroconductive material that exhibits the required qualities of flexibility and strength, such as copper and the like.
  • the insulating material is usually polyester, polyvinyl chloride or other plastic material.
  • the insulating materials used are generally manufactured as a transparent or translucent matte film. Generally these films must be heat stabilized to control shrinkage prior to being made into cable.
  • the cable is made by sandwiching the conductor elements between webs of adhesive coated insulating material and laminating the layers by applying heat and pressure to the sandwich. Typical methods and apparatus for making flexible cables are disclosed in US-A-3 513 045 and 4 351 689, the latter disclosing methods of making flat multi-conductor cable using polyester film.
  • Standard methods for coloring the plastic film prior to making flexible cable are unsatisfactory. Although it is possible to add pigment to the raw materials prior to extruding or forming the insulating film of material, this method is economically feasible only for very high volume production. Applying color to the surface of the film by means of dipping, spraying, or otherwise coating at least one surface of the film with a pigmented solution is also unsatisfactory. The colored coating is not sufficiently adhered to the surface or heat resistant to remain on the surfaces during the cable manufacturing process, particularly during lamination.
  • Flexible cable can also be colored by adding dye to the adhesive layers or by adding a layer of colored insulating material between the outer dielectric web and the conducting elements. While these methods eliminate the problems associated with surface coating, they produce true vivid colors only when used with transparent film. These methods are generally unsatisfactory for coloring translucent film because true vivid colors are unattainable due to the diffusion and refraction properties of the matte film. Furthermore, these methods increase the number of manufacturing steps required to make a finished product.
  • a processing for making a flat ribbon-like flexible electrical cable comprised of one or more spaced apart longitudinal extending conductor elements encapsulated between two layers of flexible insulating film according to the present invention includes the steps of:
  • This process allows for provision of means to impart a multicolored design and alphanumeric characters as well as solid color to the film.
  • the process for dyeing a continuous flexible polymeric substrate uses a strip of transfer paper having one or more sublimable dyes deposited on one surface.
  • the substrate and transfer paper are fed simultaneously into a heat transfer apparatus comprised of a heating means and a substrate retaining means.
  • the layers are fed into the apparatus so that the uncoated side of the transfer paper is proximate the heating means, the coated side of the transfer paper is proximate one surface of the substrate and the other surface of the substrate is proximate the substrate retaining means.
  • the substrate retaining means is used to hold the transfer paper securely between the substrate and the heating means. Sufficient heat is applied to the transfer paper to cause the dye to sublime from the paper and diffuse into the interstices of the substrate as it is swelled during the heating process. The colored substrate is removed from the heat transfer apparatus.
  • the color Since the color is diffused into the interstices of the substrate by this process, it becomes an integral part of the substrate and is not merely a coating. The color remains stable during subsequent processing and is not affected by cleaning solvents or abrasion.
  • Products such as a flat ribbon-like flexible electrical cable dyed in accordance with this method are also disclosed.
  • the cable is comprised of one or more spaced apart, longitudinally extending conductor elements encapsulated between two layers of flexible insulating film wherein at least one of the film layers has been dyed in accordance with the process disclosed herein.
  • the process for making the cable is comprised of the steps of applying adhesive to one surface of the film colored in accordance with the invention; simultaneously feeding said adhesive coated film, at least one conductor element and a second layer of adhesive coated insulating film into a laminating means such that said at least one conductor element lies between the adhesive coated surfaces of the film layers and laminating said at least one conductor element between said two film layers thus encapsulating said at least one conductor with insulating film.
  • sublimation dyeing it is new, however, to use sublimation dyeing to impart color to a continuous strip of flexible plastic film that is used for manufacturing flexible cable. Further, it is new to use sublimation dyeing as one of the initial steps in a cable manufacturing process. Using the method as disclosed herein also eliminates the necessity of prestabilizing film prior to making the cable. Sublimation dyeing requires a higher temperature than that normally used for stabilizing the material. Thus, the film can be stabilized and colored at the same time. Furthermore, tests show that flexible cable that has been colored by sublimation dyeing in accordance with the herein disclosed process surprisingly and unexpectedly exhibits greater resistance to being peeled apart than cable that has not been colored by this process.
  • Figure 1 shows a schematic view of the apparatus used for sublimating dyeing in the disclosed method.
  • Apparatus 10 is comprised of a rotating heatable drum 30 and a continuous belt 32 which is held against the rotating drum 30.
  • a continuous strip of dyed transfer paper 18 and a continuous polymeric substrate 12 are passed between the rotating drum 30 and belt 32.
  • Figure 1 also shows the use of blotting paper 24 which may be used between the polymeric substrate 12 and the belt 32 to absorb any excess dye that penetrates through the substrate during the sublimation process.
  • the transfer paper 18, the polymeric substrate 12 and the blotting paper 24 are fed into the apparatus 10 by use of supply reels 20, 14 and 26 respectively.
  • the spent transfer paper 18', the colored film 12' and the spent blotting paper 24' are wound on take-up reels 22, 16 and 28 respectively.
  • Figure 2 is an enlarged cross-sectional view of a portion of apparatus 10, showing the drum 30 and the belt 32 with the transfer paper 18, the film 12 and the optional blotting paper 24 situated between the drum 30 and the belt 32.
  • the belt 32 and the layers of paper 18, 24 and film 12 are held securely against the drum 30 by the tension means 34 as shown in Figure 1.
  • Figure 3 is a schematic representation of the steps used in producing flexible cable in accordance with the disclosed method.
  • the polymeric substrate is a plastic film commonly used for electrical cables.
  • the insulating film is dyed by sublimation and coated with an appropriate adhesive.
  • Flexible cable is made by laminating conductor elements between two layers of adhesive coated film.
  • Figure 3 also shows the use of a slitter which can be used to slit a wide strip of colored film into multiple strips. The film can be slit before or after adhesive is applied.
  • the transfer paper is made by printing sublimable dye having the desired color and in the desired design onto transfer paper.
  • the dye or ink and transfer paper used are the same as those used by the fabric industry. Paper can be obtained from commercial printing paper suppliers such as Crown Zeller Corp., San Francisco, California, 94104. Sublimable dyestuffs are available from manufacturers such as Ciba-Geigy, Ardsley, New York 10502 and Gotham Ink and Color Co., Inc., Long Island City, New York 11101.
  • the blotting paper if used, is also standard paper available and commonly used by the fabric industry. Blotting paper is necessary if the apparatus is operated under conditions that cause the dye to be sublimed through the film and onto the belt.
  • the belt is a seamless fiber belt as is used in the fabric industry.
  • cable is made from biaxially oriented polyester film.
  • Biaxially oriented film has greater dielectric strength, physical strength and flex life than non-oriented film. In order to have cable that is dimensionally stable the film must be normally stabilized by heating prior to being made into cable.
  • Biaxially oriented film can be obtained from companies such as E. I. DuPont de Nemours & Co. Inc., Wilmington, Delaware 19898; ICI Americas Inc., Wilmington, Delaware 19897 and American Hoechst Corp., Somerville, New Jersey 08876.
  • the apparatus used is a modification of standard equipment commonly used by the textile industry. Additional heaters and temperature control devices were added so that uniform heat could be maintined throughout the drum.
  • the temperature necessary for dyeing the film depends upon factors such as the dyestuff used, the speed of the drum and the thickness of the paper and film layers. It was found that polyester film dyed best when subjected to temperatures in the range of 350-450°F (177-232°C). The temperature and time relationship is extremely important. The time required for the dye to sublime and penetrate the plastic film is significantly longer than the time required to dye textile.
  • the tension on the film must be carefully controlled at all stages of the dyeing process, as the film is fed into the heat transfer apparatus, during the time the film remains in contact with the heat and after the film exits the apparatus.
  • the tension on the continuous belt must be controlled.
  • the take-up drive was also modified so that a contant tension could be maintained on the film despite the number of layers on the take-up reel.
  • the film begins to cool as soon as it is no longer in contact with the drum. If the tension on the exiting film is not controlled precisely, the film will buckle, wrinkle and have varying degrees of shrinkage across the web as the film cools.
  • Colored cable was made in accordance with the invention. Continuous strips of transfer paper and film were fed from reels onto the rotating drum. The drum was kept at a constant temperature throughout the dyeing process. By carefully controlling the temperature and speed of the drum the amount of dye sublimed into the film was optimized and the amount of wasted dye was minimized. The majority of the sublimed dye thus became part of the structure of the film. The film was maintained under constant tension as it exited from the drum and was wound onto the take-up reel. Adhesive was then applied to one surface of the colored film. In the preferred embodiment adhesive was applied to the surface of film that was against the transfer paper to ensure that any dye on that surface of the film was encased within the laminated cable. The film was then slit into the desired widths. In the preferred cable embodiment, conductor elements were sandwiched between two layers of the colored film and laminated.
  • the sublimation method can be used to impart a solid color a plurality of colors, alphanumeric characters, and designs to flexible polymeric substrate.
  • the design on the transfer paper is imparted to the substrate.
  • otherwise solidly colored substrate when used for electrical cables can be color coded to indicate specific conductors. If color coding is desired this method can be used to color code the film, the cable can be made with one color coded layer of film and one uncoded layer of film.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Transfer Or Thermal Recording In General (AREA)
  • Coloring (AREA)

Claims (6)

1. Verfahren zur Herstellung eines flachen, bandförmigen, flexiblen elektrischen Kabels, das aus einem oder mehreren beabstandeten, sich in Längsrichtung erstreckenden Leiterelementen besteht, die zwischen zwei Schichten aus flexiblem isolierendem Film eingekapselt sind, mit den folgenden Verfahrensschritten:
-Auswahl eines Transferpapiers (18), das aus einem kontinuierlichen Papierstreifen besteht, der auf einer Oberfläche wenigstens einen sublimierbaren Farbstoff aufweist;
-Zufuhr des Transferpapiers in ein Wärmetransfergerät (10), wobei das Gerät (10) Heizeinrichtungen (30) und Filmhalteeinrichtungen aufweist, so daß die unbeschichtete Seite des Transferpapiers (18) der Heizeinrichtung (30) zugewandt ist;
-gleichzeitige Zufuhr einer Schicht von flexiblem isolierendem Film in das Wärmetransfergerät (10), so daß eine Oberfläche des Films der beschichteten Oberfläche des Transferpapiers (18) zugewandt ist und die andere Oberfläche des Films der Filmhalteeinrichtung (32) zugewandt ist;
-Pressen des Films durch die Halteeinrichtung
(32) gegen die Heizeinrichtungen (30), wobei das Transferpapier (18) dadurch zwischen dem Film und der Heizeinrichtung (30) gehalten wird;
-Zufuhr ausreichender Wärme an das Transferpapier (18) durch die Heizeinrichtung (30), so daß der Farbstoff von dem Transferpapier sublimiert und in den flexiblen isolierenden Film endiffundiert und diesen färbt;
-Entfernen des gefärbten Films aus dem Wärmetransfergerät (10);
-Anbringung von Kleber an eine Oberfläche des gefärbten Films;
-Zufuhr des kleberbeschichteten gefärbten Films in eine Laminiereinrichtung;
-gleichzeitige Zufuhr wenigstens eines Leiterelements und einer weiteren Schicht von kleberbeschichtetem isolierendem Film in die Laminiereinrichtung, so daß sich das wenigstens eine Leiterelement in Längsrichtung zwischen den kleberbeschichteten Oberflächen der Filmschichten erstreckt; und
-Laminieren des wenigstens einen Leiterelements zwischen die beiden Filmschichten, wodurch das wenigstens eine Leiterelement mit dem isolierenden Film eingekapselt und von diesem umgeben wird.
2. Verfahren nach Anspruch 1, mit dem weiteren Verfahrensschritt, daß gleichzeitig ein kontinuierlicher Streifen von Löschpapier (24) mit der Schicht des flexiblen isolierenden Films (12) und dem Transferpapier (18) in das Wärmetransfergerät zwischen die Schichten des flexiblen isolierenden Films (12) und die Halteeinrichtung (32) eingefördert wird, wodurch die Schicht des flexiblen isolierenden Films (12) zwischen das Transferpapier (18) und das Löschpapier (24) eingeschichtet wird.
3. Verfahren nach Anspruch 1, bei dem ein oder mehrere sublimierbare Farbstoffe angewendet werden, um ein Muster auf der Oberfläche des Transferpapiers (18) zu bilden.
4. Ein flaches, bandförmiges, flexibles elektrisches Kabel, das mit dem Verfahren nach Anspruch 1 hergestellt wurde, wobei wenigstens eine der Filmschichten (12) mit einem Muster gefärbt wurde, das aus der Gruppe ausgewählt ist, die aus einer durchgehenden Farbe, einer mehrfarbigen Gestaltung und einem farbkodierten Muster besteht, welches spezielle Leiterelemente bezeichnet.
5. Ein flaches, bandförmiges, flexibles elektrisches Kabel, hergestellt nach dem Verfahren des Anspruchs 1 oder wie in Anspruch 4 beansprucht, bei dem die Filmschichten (12) aus der Gruppe ausgewählt sind, welche ein mattes texturiertes Polyester, matte texturierte Polymerfilme und im wesentlichen transparente Polymerfilme umfaßt.
EP85902282A 1984-05-11 1985-04-15 Verfahren zum färben einer flexiblen polymerbahn sowie nach diesem verfahren hergestellte produkte Expired EP0181369B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US60915884A 1984-05-11 1984-05-11
US609158 1990-11-02

Publications (2)

Publication Number Publication Date
EP0181369A1 EP0181369A1 (de) 1986-05-21
EP0181369B1 true EP0181369B1 (de) 1988-10-26

Family

ID=24439582

Family Applications (1)

Application Number Title Priority Date Filing Date
EP85902282A Expired EP0181369B1 (de) 1984-05-11 1985-04-15 Verfahren zum färben einer flexiblen polymerbahn sowie nach diesem verfahren hergestellte produkte

Country Status (5)

Country Link
EP (1) EP0181369B1 (de)
JP (1) JPS61502109A (de)
DE (1) DE3565799D1 (de)
ES (1) ES8703672A1 (de)
WO (1) WO1985005324A1 (de)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2224974A (en) * 1988-10-04 1990-05-23 Robert William Wilson Method and means for decorating a substrate
FR2764238B1 (fr) * 1997-06-04 1999-08-13 Glace Controle Procede de transfert d'image sur un film de polyester et produit ainsi obtenu
CN102285209B (zh) * 2011-07-08 2015-06-24 长胜纺织科技发展(上海)有限公司 自动控制型转移印花装置

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2086941A6 (de) * 1970-04-14 1971-12-31 Lemaire & Cie
GB1355856A (en) * 1971-10-07 1974-06-05 Basford Dyers Ltd Printing and bonding machines
FR2318742A1 (fr) * 1975-07-21 1977-02-18 Rejto Thomas Procede d'impression par transfert avec gaufrage simultane et installation pour la mise en oeuvre du procede
NL7608721A (nl) * 1975-09-01 1977-03-03 Kleinewefers Ind Co Gmbh Inrichting voor het bedrukken van textielbanen.
US4351689A (en) * 1979-12-26 1982-09-28 Western Electric Company, Inc. Apparatus for the manufacture of multi-conductor flat cable

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
VDI-Nachrichten, Volume 30, nr. 35, 1976, (VDI-Verlag GmbH, Düsseldorf) B.D. BÄHR: "Kostengünstiger Transferdruck" see page 12 *

Also Published As

Publication number Publication date
WO1985005324A1 (en) 1985-12-05
ES543010A0 (es) 1987-02-16
ES8703672A1 (es) 1987-02-16
JPS61502109A (ja) 1986-09-25
EP0181369A1 (de) 1986-05-21
DE3565799D1 (en) 1988-12-01

Similar Documents

Publication Publication Date Title
US8343574B2 (en) System and method for the transfer of color and other physical properties to laminate composite materials and other articles
US3080270A (en) Process for making metallic pattern effects on sheet material
US9339842B2 (en) Systems and methods for the transfer of color and other physical properties to laminate composite materials and other articles
JPS6223783A (ja) 感熱転写記録方法
EP0181369B1 (de) Verfahren zum färben einer flexiblen polymerbahn sowie nach diesem verfahren hergestellte produkte
US5078814A (en) Dyeing insulating film of a flat cable
US3481802A (en) Method and apparatus for preparing multiconductor cable with flat conductors
US3147582A (en) Method of producing multi-colored flat yarns
US3322605A (en) Decorated shelving film
KR20180091513A (ko) 휴대폰 데코레이션 필름의 제조방법
EP2532519B1 (de) Verfahren und Vorrichtung zur Herstellung eines dekorativen Films für Leder, Kunstleder und Stoff
JP3762887B2 (ja) ヘアライン装飾成形品の製造方法
JPS55116470A (en) Preparing decorative laminated sheet
JPS6040396B2 (ja) 耐熱部分蒸着転写材の製造法
CN1154918A (zh) 一种人造革的印花方法
JPH047141A (ja) 真珠光沢と金属調模様を有する包装用リボン、テープおよびその製造方法
EP0646065A1 (de) Verfahren zum herstellen von lichtdurchlässigen, gefärbten filmen
JP2834854B2 (ja) ジョーゼット加工用虹彩色金銀糸
KR100536745B1 (ko) 섬유에 형성된 입체무늬에 다색을 처리하기 위한 장치
JPH071639A (ja) 中間膜の製造方法
KR100258729B1 (ko) 스탬핑 호일
JPH07308989A (ja) スパンコール用フィルムおよびスパンコール
KR930021409A (ko) 투명한 폴리에스테르 필름(Polyester Film)을 이용한 전사지 및 그의 제조방법
JPH0419192A (ja) 染料熱転写プリンター用受像シート
JPH07117397A (ja) 化粧シート

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 19860214

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): BE DE FR GB IT NL

17Q First examination report despatched

Effective date: 19871015

ITF It: translation for a ep patent filed
GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): BE DE FR GB IT NL

REF Corresponds to:

Ref document number: 3565799

Country of ref document: DE

Date of ref document: 19881201

ET Fr: translation filed
PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

RAP4 Party data changed (patent owner data changed or rights of a patent transferred)

Owner name: AMP INCORPORATED (A NEW JERSEY CORPORATION)

26N No opposition filed
NLT2 Nl: modifications (of names), taken from the european patent patent bulletin

Owner name: AMP INCORPORATED (A NEW JERSEY CORPORATION) TE HAR

ITTA It: last paid annual fee
REG Reference to a national code

Ref country code: GB

Ref legal event code: 732E

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 19950317

Year of fee payment: 11

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 19950413

Year of fee payment: 11

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 19950428

Year of fee payment: 11

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 19950430

Year of fee payment: 11

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 19950511

Year of fee payment: 11

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Effective date: 19960415

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Effective date: 19960430

BERE Be: lapsed

Owner name: AMP INC. (UNE SOC. DE PENNSYLVANIE)

Effective date: 19960430

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Effective date: 19961101

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 19960415

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Effective date: 19961227

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Effective date: 19970101

NLV4 Nl: lapsed or anulled due to non-payment of the annual fee

Effective date: 19961101

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST