EP0177739A2 - Emploi d'un acier pour des pièces utilisées dans la technique du froid - Google Patents

Emploi d'un acier pour des pièces utilisées dans la technique du froid Download PDF

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Publication number
EP0177739A2
EP0177739A2 EP85110945A EP85110945A EP0177739A2 EP 0177739 A2 EP0177739 A2 EP 0177739A2 EP 85110945 A EP85110945 A EP 85110945A EP 85110945 A EP85110945 A EP 85110945A EP 0177739 A2 EP0177739 A2 EP 0177739A2
Authority
EP
European Patent Office
Prior art keywords
steel
temperature
toughness
cold
contents
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP85110945A
Other languages
German (de)
English (en)
Other versions
EP0177739A3 (fr
Inventor
Franz-Josef Biniasz
Bernhard Dr. Engl
Axel Dr. Fuchs
Margit Hüser
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoesch Stahl AG
Original Assignee
Hoesch Stahl AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoesch Stahl AG filed Critical Hoesch Stahl AG
Publication of EP0177739A2 publication Critical patent/EP0177739A2/fr
Publication of EP0177739A3 publication Critical patent/EP0177739A3/fr
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/08Ferrous alloys, e.g. steel alloys containing nickel
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/005Modifying the physical properties by deformation combined with, or followed by, heat treatment of ferrous alloys
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C13/00Details of vessels or of the filling or discharging of vessels
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/06Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0634Materials for walls or layers thereof
    • F17C2203/0636Metals
    • F17C2203/0639Steels
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2209/00Vessel construction, in particular methods of manufacturing
    • F17C2209/22Assembling processes
    • F17C2209/221Welding
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2221/00Handled fluid, in particular type of fluid
    • F17C2221/03Mixtures
    • F17C2221/032Hydrocarbons
    • F17C2221/033Methane, e.g. natural gas, CNG, LNG, GNL, GNC, PLNG
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2223/00Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
    • F17C2223/01Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
    • F17C2223/0146Two-phase
    • F17C2223/0153Liquefied gas, e.g. LPG, GPL
    • F17C2223/0161Liquefied gas, e.g. LPG, GPL cryogenic, e.g. LNG, GNL, PLNG

Definitions

  • the invention relates to the use of a weldable, cold-tough ferritic Ni steel
  • LNG Liquid Natural Gas
  • B. ethylene, nitrogen, hydrogen and certain noble gases for ship transport in question.
  • Liquefied gas can be transported inexpensively since it takes up only a small part of its volume, which is gaseous at room temperature.
  • Low-temperature steels are ferritic or austenitic structural steels which are characterized by particularly good toughness properties down to very low operating temperatures. Such structural steels can be subjected to the usual processing operations such as cold forming, hot forming, thermal cutting and welding.
  • the most important alloying element for achieving sufficient toughness of ferritic structural steels at low temperatures is known to be nickel.
  • the ⁇ region is expanded by nickel, the A 3 conversion point and the critical cooling rate are markedly reduced.
  • the drop in toughness is shifted to lower temperatures.
  • the addition of 1% Ni causes the transition temperatures to decrease by approx. 30 ° C, above that there are improvements of about 10 ° C per 1% Ni.
  • the 9% nickel steel X 8 Ni 9 is used worldwide.
  • this material In the area of the boiling point of methane (- 161.5 ° C), this material has considerable toughness reserves; it is used up to the temperature of liquid nitrogen (- 196 ° C).
  • This 2-stage glow cycle may need to be repeated several times.
  • DE-OS 30 30 652 shows a cold-tough ferritic steel which essentially contains 0.02-0.06% carbon, 4-6% manganese, 0.1-0.4 molybdenum and 0-3% nickel and which also has to be subjected to a very complex heat treatment.
  • the invention has for its object to provide a weldable cold-tough ferritic steel that with the lowest possible nickel content for cryogenic applications, ie. H. is suitable for operating temperatures below - 100 ° C.
  • the steel of equivalent quality X 8Ni 9 should offer sufficient security against brittle failure.
  • other alloy metals such as manganese and molybdenum should also be saved and the steel should also be easy to manufacture, i.e. its manufacturing process should do without complicated, time, control and space-requiring operations with multi-stage annealing cycles, accelerated cooling and the like.
  • the invention proposes, according to claim 1, alloying a ferritic steel with specific analysis on the basis of closely selected C, Mn, and above all Ni contents with V and N, hot-rolling and allowing it to cool after melting . After normalizing under recrystallization, these steels are to be used as a weldable material with improved low-temperature toughness and high strength for the manufacture of refrigeration components in the range of - 100 ° C and below.
  • the cooling rate of the normalization temperature can be varied over a wide range without sacrificing the excellent toughness.
  • the large strength range specified in the Euronorm 129-76 for the X 8 Ni 9 for adaptation to customer requirements can be achieved for the steels according to the invention solely by varying the cooling rate, it being known that increased strengths are set by faster cooling (see Examples 1, 2 and 3).
  • the previously described "normalizing" represents an important simplification compared to the complex heat treatment of the X 8 Ni 9.
  • the steels according to the invention are e.g. B. with the known welding process for the X 8 Ni 9 crack-free and show a good low-temperature toughness of the weld (see Example 6).
  • Claim 2 preferably names Ni contents of 5-6%.
  • Fig. 1 shows the influence of the V and N alloy according to the invention on the low-temperature toughness.
  • the transition temperature Tü indicates the temperature up to which the notched impact strength with increasing cooling of the sample is still above the value of at least 42 J which is valid as the criterion of toughness for the longitudinal ISO sample.
  • Curve A shows, in comparison to curve B (without V and N alloy,) that the greatest possible effect by V and N to increase the low-temperature toughness and at the same time the lowest transition temperature is achieved when the steels 5-6% Ni contain.
  • the comparison of curve A with curve B further shows that the "VN effect" has an effect in the entire range of the Ni contents of 1-9%. It occurs preferably in the range of 4-7% Ni and preferably in a range restricted to 5-6% Ni.
  • Claim 5 defines the use of the steels according to the invention in a temperature range which was previously reserved for more complex steels with regard to alloy and production.
  • Claim 6 describes the effect of the measure according to the invention on the structure of the structure and the low-temperature properties caused thereby, which are at least the same as the X 8 Ni 9 (see Examples 1, 3, 5) or far exceed it in terms of the transition temperature (see Example 2).
  • FIGS. 1 to 6 represent the properties which are decisive for the use of the steels according to the invention.
  • 3 and 4 are only longitudinal values (33, 43).
  • Example 2 was rolled out in the same way as in Example 1 and normalized.
  • the high yield strength of this steel allows a weight-saving construction. It can be derived from the A v -T curve in FIG. 3 that the steel is still tough even at ⁇ 230 ° C. and has considerable toughness reserves with a toughness of 200 J in the LNG application area.
  • Example 2 was rolled out in the same way as in Example 1, then heated to 790 ° C. and then cooled in water. As the following test values show, this treatment results in a considerable increase in the yield strength and strength.
  • Another way to increase the yield strength and tensile strength is to alloy the material with copper.
  • Example 1 was rolled out and annealed as in Example 1.
  • this steel has excellent toughness properties. It also has a yield strength of 591 N / mm2, a tensile strength of 666 N / mm2 and an elongation of 29.2%.
  • the A v value at - 196 ° C is 116 J (ISO-V longitudinal).
  • An austenitic filler material was used for welding - as is common for steel X 8 Ni 9. No cracks were observed in the welded joints.
  • the notched impact strength was tested on ISO-V specimens (transverse to the rolling direction) at - 160 ° C and - 196 ° C.
  • weldable steels according to the invention can be used with sufficient security against brittle failure despite less complex alloy and significantly simplified production for high-strength components of refrigeration technology down to operating temperatures of -196 C and below.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Heat Treatment Of Steel (AREA)
  • Heat Treatment Of Sheet Steel (AREA)
EP85110945A 1984-09-03 1985-08-30 Emploi d'un acier pour des pièces utilisées dans la technique du froid Withdrawn EP0177739A3 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19843432337 DE3432337A1 (de) 1984-09-03 1984-09-03 Verfahren zur herstellung eines stahles und dessen verwendung
DE3432337 1984-09-03

Publications (2)

Publication Number Publication Date
EP0177739A2 true EP0177739A2 (fr) 1986-04-16
EP0177739A3 EP0177739A3 (fr) 1988-11-30

Family

ID=6244527

Family Applications (1)

Application Number Title Priority Date Filing Date
EP85110945A Withdrawn EP0177739A3 (fr) 1984-09-03 1985-08-30 Emploi d'un acier pour des pièces utilisées dans la technique du froid

Country Status (4)

Country Link
US (1) US4687525A (fr)
EP (1) EP0177739A3 (fr)
JP (1) JPS61124523A (fr)
DE (1) DE3432337A1 (fr)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61127815A (ja) * 1984-11-26 1986-06-16 Nippon Steel Corp 高アレスト性含Ni鋼の製造法
TW396254B (en) 1997-06-20 2000-07-01 Exxon Production Research Co Pipeline distribution network systems for transportation of liquefied natural gas
TW359736B (en) * 1997-06-20 1999-06-01 Exxon Production Research Co Systems for vehicular, land-based distribution of liquefied natural gas
TW444109B (en) * 1997-06-20 2001-07-01 Exxon Production Research Co LNG fuel storage and delivery systems for natural gas powered vehicles
TW396253B (en) * 1997-06-20 2000-07-01 Exxon Production Research Co Improved system for processing, storing, and transporting liquefied natural gas
TW436597B (en) * 1997-12-19 2001-05-28 Exxon Production Research Co Process components, containers, and pipes suitable for containign and transporting cryogenic temperature fluids
DZ2531A1 (fr) * 1997-12-19 2003-02-08 Exxon Production Research Co Procédé de préparation d'une tôle d'acier double phase cette tôle et procédé pour renforcer la résistance à la propagation des fissures.
US6159312A (en) * 1997-12-19 2000-12-12 Exxonmobil Upstream Research Company Ultra-high strength triple phase steels with excellent cryogenic temperature toughness
DE10050371A1 (de) * 2000-10-11 2002-05-02 Siemens Ag Vorrichtung mit im kryogenen Temperaturbereich ferromagnetischem und mechanisch belastbarem Bauteil
JP2005525509A (ja) 2001-11-27 2005-08-25 エクソンモービル アップストリーム リサーチ カンパニー 天然ガス車両のためのcng貯蔵及び送出システム
US6852175B2 (en) * 2001-11-27 2005-02-08 Exxonmobil Upstream Research Company High strength marine structures
SE0300224L (sv) * 2003-01-30 2004-06-29 Sandvik Ab En gängtapp för att skära gängor i bottenhål och metoder för dess tillverkning
US9746134B2 (en) * 2013-03-28 2017-08-29 GM Global Technology Operations LLC Method of storing and using natural gas in a vehicle

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1272555B (de) * 1963-11-18 1968-07-11 Yawata Iron & Steel Co Stahllegierung mit einer hohen Zaehigkeit bei niedrigen Temperaturen und Verfahren zuihrer Waermebehandlung
US3619302A (en) * 1968-11-18 1971-11-09 Yawata Iron & Steel Co Method of heat-treating low temperature tough steel
DE2039910B2 (de) * 1970-08-11 1973-08-02 Nippon Steel Corp , Tokio Waermebehandlungsverfahren fuer einen stahl
US3960612A (en) * 1973-08-15 1976-06-01 Nippon Steel Corporation Method for producing a low temperature high strength tough steel
DE3030652A1 (de) * 1979-08-13 1981-03-26 United States Department Of Energy, Washington, D.C. Stahllegierung

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL289859A (fr) * 1963-03-06
DE1483333B1 (de) * 1964-06-22 1971-08-26 Yawata Iron and Steel Co , Ltd , Tokio Verwendung eines stahles als tieftemperaturzaeh/er werk stoff
JPS4935485B1 (fr) * 1964-06-22 1974-09-24
US3834949A (en) * 1973-02-14 1974-09-10 Inland Steel Co Hot rolled flat steel article for cryogenic service and method for producing same
US4138278A (en) * 1976-08-27 1979-02-06 Nippon Steel Corporation Method for producing a steel sheet having remarkably excellent toughness at low temperatures
JPS5633425A (en) * 1979-08-24 1981-04-03 Sumitomo Metal Ind Ltd Manufacture of tempered high tensile steel sheet having excellent low temperature toughness

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1272555B (de) * 1963-11-18 1968-07-11 Yawata Iron & Steel Co Stahllegierung mit einer hohen Zaehigkeit bei niedrigen Temperaturen und Verfahren zuihrer Waermebehandlung
US3619302A (en) * 1968-11-18 1971-11-09 Yawata Iron & Steel Co Method of heat-treating low temperature tough steel
DE2039910B2 (de) * 1970-08-11 1973-08-02 Nippon Steel Corp , Tokio Waermebehandlungsverfahren fuer einen stahl
US3960612A (en) * 1973-08-15 1976-06-01 Nippon Steel Corporation Method for producing a low temperature high strength tough steel
DE3030652A1 (de) * 1979-08-13 1981-03-26 United States Department Of Energy, Washington, D.C. Stahllegierung

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
EURONORM, 129-76, M{rz 1976, Seiten 1-9 *

Also Published As

Publication number Publication date
JPH0244888B2 (fr) 1990-10-05
EP0177739A3 (fr) 1988-11-30
DE3432337A1 (de) 1986-03-13
JPS61124523A (ja) 1986-06-12
US4687525A (en) 1987-08-18
DE3432337C2 (fr) 1987-07-02

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Inventor name: HUESER, MARGIT